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公开(公告)号：US06977287B2
公开(公告)日：2005-12-20
申请号：US10602177
申请日：2003-06-24
申请人： Pawan Kumar Agarwal , Weiqing Weng , Aspy K. Mehta , Armenag H. Dekmezian , Main Chang , Rajan K. Chudgar , Christopher R. Davey , Chon-Yie Lin , Galen C. Richeson , Palanisamy Arjunan , Olivier Jean Georjon
发明人： Pawan Kumar Agarwal , Weiqing Weng , Aspy K. Mehta , Armenag H. Dekmezian , Main Chang , Rajan K. Chudgar , Christopher R. Davey , Chon-Yie Lin , Galen C. Richeson , Palanisamy Arjunan , Olivier Jean Georjon
IPC分类号： C08F4/659 , C08F4/6592 , C08F110/06 , C08F210/06 , C08L23/14 , C08L23/16 , C08F236/20
CPC分类号： C08F4/65927 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F110/06 , C08F210/06 , C08L23/14 , C08L23/145 , C08L23/16 , C08L2666/04 , C08F236/20 , C08F2500/12 , C08F2500/03 , C08F2500/04 , C08F2500/26
摘要： The co-polymerization reaction of one or more olefin monomers, such as propylene, with α,ω-diene units and the resulting copolymers are provided. More specifically, the copolymer may have from 90 to 99.999 weight percent of olefins and from 0.001 to 2.000 weight percent of α,ω-dienes. The copolymer may have a weight average molecular weight in the range from 50,000 to 2,000,000, a crystallization temperature in the range from 115° C. to 135° C. and a melt flow rate in the range from 0.1 dg/min to 100 dg/min. These copolymers may be employed in a wide variety of applications, the articles of which include, for example, films, fibers, such as spunbonded and meltblown fibers, fabrics, such as nonwoven fabrics, and molded articles. The copolymer may further include at least two crystalline populations. Desirably, the melting point range of one of the crystalline populations is distinguishable from the melting point range of another crystalline population by a temperature range of from 1° C. to 8° C. More desirably, one of the crystalline populations has a melting point in the range from 152° C. to 158° C. and another crystalline population has a melting point in the range from 142° C. to 148° C.
摘要翻译： 提供一种或多种烯烃单体如丙烯与α，ω-二烯单元和所得共聚物的共聚反应。 更具体地说，共聚物可以具有90至99.999重量％的烯烃和0.001至2.000重量％的α，ω-二烯。 该共聚物的重均分子量可以在50,000至2,000,000范围内，结晶温度在115℃至135℃的范围内，熔体流动速率在0.1dg / min至100dg / 分钟 这些共聚物可以用于各种应用中，其制品包括例如膜，纤维，例如纺粘和熔喷纤维，织物如无纺织物和模塑制品。 该共聚物可进一步包括至少两个结晶群。 理想地，一种结晶群体的熔点范围与另一结晶群体的熔点范围可以区别在1℃至8℃的温度范围内。更期望的是，一个结晶群体具有熔点 在152℃至158℃的范围内，另一结晶群的熔点范围为142℃至148℃。
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公开(公告)号：US20050027058A1
公开(公告)日：2005-02-03
申请号：US10478606
申请日：2002-05-29
申请人： Anthony Dias , Andy Tsou , David Chung , Weiqing Weng
发明人： Anthony Dias , Andy Tsou , David Chung , Weiqing Weng
IPC分类号： B60C5/14 , C08K3/00 , C08K3/34 , C08K5/17 , C08L21/00 , C08L23/22 , C08L23/28 , C08L101/00 , C08K9/00
CPC分类号： B60C1/0008 , C08K3/04 , C08K3/346 , C08K5/17 , C08L21/00 , C08L23/22 , C08L23/283 , C08L23/28 , C08L2666/04
摘要： The present invention includes blends of a halogenated elastomer such as a butyl rubber or an interpolymer of, on one embodiment, a C4 to C7 isomonoolefin, a para-methylstyrene and a para-(halomethylstyrene), the interpolymer having been pre-mixed with an exfoliating compound and clay, the entire blend forming a nanocomposite in one embodiment. The clay may or may not have undergone an additional exfoliating treatment prior to blending with the halogenated elastomer. The interpolymer/clay mixture forms a distinct phase in the nanocomposite blend of the invention. The blend of the invention has improved air barrier properties and is suitable as an air barrier.
摘要翻译： 本发明包括卤化弹性体如丁基橡胶或在一个实施方案中为C4至C7异单烯烃，对甲基苯乙烯和对 - （卤代甲基苯乙烯）的互聚物的共混体，该互聚物已经与 去角质化合物和粘土，在一个实施方案中，整个共混物形成纳米复合材料。 在与卤化弹性体共混之前，粘土可以或可以不经历额外的去角质处理。 互聚物/粘土混合物在本发明的纳米复合材料混合物中形成不同的相。 本发明的共混物具有改善的空气阻隔性能，并且适合作为空气屏障。
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53.发明授权公开(公告)号：US06569965B2
公开(公告)日：2003-05-27
申请号：US10278666
申请日：2002-10-23
IPC分类号： C08F464
CPC分类号： C08F210/16 , C08F4/65904 , C08F4/65908 , C08F4/65912 , C08F10/06 , C08F210/06 , Y10S526/943 , C08F4/65927 , C08F2500/03 , C08F2500/09
摘要： Branched ethylene-propylene compositions which have improved melt strength and shear thinning are provided. The weight average branching index g′ for the higher molecular weight region of the ethylene-propylene composition is less than 0.95. Additionally, a novel process is provided for efficiently producing a branched ethylene-propylene composition comprising: a) contacting propylene monomers and ethylene monomers in a reactor with an inert hydrocarbon solvent or diluent and a catalyst composition comprising one or more single site catalyst compounds capable of producing an ethylene-propylene polymer at a temperature from about 50° C. to about 180° C., wherein the ratio in the reactor of the propylene and ethylene monomers to the inert hydrocarbon solvent or diluent is less than 2.0, and further, wherein the propylene and ethylene monomers and the inert hydrocarbon solvent or diluent comprise no more than 90 percent of the total contents of the reactor; and b) recovering a branched ethylene-propylene composition, wherein the weight average branching index g′ for the higher molecular weight region of the ethylene-propylene composition is less than 0.95.
摘要翻译： 提供了具有改善的熔体强度和剪切稀化的分支乙烯 - 丙烯组合物。 乙烯 - 丙烯组合物的较高分子量区域的重均分支指数g'小于0.95。 另外，提供了一种有效生产支化乙烯 - 丙烯组合物的新方法，其包括：a）使反应器中的丙烯单体和乙烯单体与惰性烃溶剂或稀释剂和包含一种或多种单中心催化剂化合物的催化剂组合物接触， 在约50℃至约180℃的温度下生产乙烯 - 丙烯聚合物，其中丙烯和乙烯单体的反应器与惰性烃溶剂或稀释剂的比例小于2.0，此外，其中 丙烯和乙烯单体和惰性烃溶剂或稀释剂不超过反应器总含量的90％; 和b）回收支链乙烯 - 丙烯组合物，其中乙烯 - 丙烯组合物的较高分子量区域的重均分支指数g'小于0.95。
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公开(公告)号：US06197910B1
公开(公告)日：2001-03-06
申请号：US09020306
申请日：1998-02-06
IPC分类号： C08F11006
CPC分类号： C08L51/06 , C08F4/65912 , C08F10/00 , C08F10/06 , C08F110/06 , C08F255/00 , C08F255/02 , C08F290/042 , C08F297/08 , C08F297/083 , Y10S526/943 , C08F4/65927 , C08F2500/15 , C08F2500/03 , C08F2500/06 , C08F2500/09
摘要： A polyolefin composition is provided which consists essentially of isotactic polypropylene and, optionally, repeating units of one or more comonomers, wherein the total comonomer repeating unit content of the polyolefin composition is from 0 to 20 mole percent, and further, wherein the weight average branching index g′ for the lower molecular weight region of the polyolefin composition is less than 0.93. Additionally, a process is provided for producing a polyolefin composition comprising: a) contacting, in solution, at a temperature from about 90° C. to about 120° C., propylene monomers with a catalyst composition comprising a first chiral, stereorigid transition metal catalyst compound capable of producing isotactic polypropylene; b) copolymerizing the product of a) with propylene and, optionally, one or more copolymerizable monomers, in a polymerization reactor under suitable polypropylene polymerization conditions using a second chiral, stereorigid transition metal catalyst capable of producing isotactic polypropylene; and c) recovering a branched olefin polymer.
摘要翻译： 提供了聚烯烃组合物，其基本上由全同立构聚丙烯和任选的一种或多种共聚单体的重复单元组成，其中聚烯烃组合物的总共聚单体重复单元含量为0至20摩尔％，此外，其中重均分子量 聚烯烃组合物的较低分子量区域的指数g'小于0.93。 此外，提供了一种用于制备聚烯烃组合物的方法，其包括：a）在约90℃至约120℃的温度下在溶液中使丙烯单体与催化剂组合物接触，所述催化剂组合物包含第一手性立体刚性过渡金属 能够产生全同立构聚丙烯的催化剂化合物; b）在合适的聚丙烯聚合条件下，使用能够产生全同立构的第二手性立体刚性过渡金属催化剂，在聚合反应器中将a）的产物与丙烯和任选的一种或多种可共聚的单体共聚 聚丙烯; 和c）回收支链烯烃聚合物。
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55.发明授权Elastomeric nanocomposites, nanocomposite compositions, and methods of manufacture 有权弹性体纳米复合材料，纳米复合材料组合物和制造方法公开(公告)号：US08883906B2
公开(公告)日：2014-11-11
申请号：US12956877
申请日：2010-11-30
申请人： Michael B. Rodgers , Weiqing Weng , John P. Soisson , Robert N. Webb , Sunny Jacob , Molly W. Johnston
发明人： Michael B. Rodgers , Weiqing Weng , John P. Soisson , Robert N. Webb , Sunny Jacob , Molly W. Johnston
CPC分类号： C08J5/005 , B82Y30/00 , C08K5/19 , C08K2201/011 , C08L23/22 , C08L23/283
摘要： A nanocomposite is formed from at least one copolymer and at least one nanofiller. The copolymer is formed of units derived from isoolefins having from 4 to 7 carbon atoms and multiolefins. The nanofiller comprising a surfactant wherein the surfactant has the structure of (R1R2R3R4)N+ wherein R1 is benzyl derived unit, which may or may not be substituted, wherein R2 is selected from C1 to C26 alkyls, C2 to C26 alkenes, and C3 to C26 aryls, and wherein R3 and R4 are the same or different and are independently selected from C9 to C26 alkyls, C9 to C26 alkenes, and C9 to C26 aryls.
摘要翻译： 纳米复合材料由至少一种共聚物和至少一种纳米填料形成。 共聚物由衍生自具有4-7个碳原子的异烯烃和多烯烃的单元形成。 纳米填料包含表面活性剂，其中表面活性剂具有结构（R 1 R 2 R 3 R 4）N +，其中R 1是苄基衍生单元，其可以被取代或不被取代，其中R2选自C1至C26烷基，C2至C26烯烃和C3至C26 芳基，并且其中R 3和R 4相同或不同并且独立地选自C 9至C 26烷基，C 9至C 26烯烃和C 9至C 26芳基。
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公开(公告)号：US08481646B2
公开(公告)日：2013-07-09
申请号：US13033171
申请日：2011-02-23
申请人： Weiqing Weng , Sunny Jacob , Peijun Jiang , Armenag H. Dekmezian , Aspy K. Mehta , James R. Ayers , David J. Lohse , Peter W. Manders , Palanisamy Arjunan
发明人： Weiqing Weng , Sunny Jacob , Peijun Jiang , Armenag H. Dekmezian , Aspy K. Mehta , James R. Ayers , David J. Lohse , Peter W. Manders , Palanisamy Arjunan
CPC分类号： C08J3/005 , C08K3/011 , C08K5/0025 , C08L23/10 , C08L23/16 , C08L63/00 , C08L101/00 , C08L2312/04 , Y10T428/1372 , C08L2666/06
摘要： This invention relates to the preparation of thermoplastic vulcanizates (TPVs) with unique morphological features, more specifically, this invention relates to a method for preparing TPV compositions wherein the mixing of plastomers and elastomers are carried out in solvent with curatives to induce cross-linking.
摘要翻译： 本发明涉及具有独特形态特征的热塑性硫化橡胶（TPV）的制备，更具体地说，本发明涉及制备TPV组合物的方法，其中塑性体和弹性体的混合物在溶剂中用固化剂进行以引发交联。
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57.发明授权Elastomeric compositions comprising hydrocarbon polymer additives having improved impermeability 有权包含具有改善的不渗透性的烃聚合物添加剂的弹性组合物公开(公告)号：US08476352B2
公开(公告)日：2013-07-02
申请号：US12492837
申请日：2009-06-26
CPC分类号： B60C1/0008 , C08L23/20 , C08L57/02 , C08L2666/04
摘要： An elastomeric compositions having improved impermeability is disclosed. The cured elastomeric composition may comprise at least one C4-C7 monoolefin elastomer, a hydrocarbon polymer additive, and a clay. In some embodiments, the cured elastomeric composition has a permeation coefficient at 40° C. of 90 cc*mm/(m2-day) or less. In some embodiments, the elastomeric composition is substantially free of naphthenic oil.
摘要翻译： 公开了具有改进的不渗透性的弹性体组合物。 固化的弹性体组合物可以包含至少一种C 4 -C 7单烯烃弹性体，烃聚合物添加剂和粘土。 在一些实施方案中，固化的弹性体组合物在40℃下的渗透系数为90cc * mm /（m2-day）或更小。 在一些实施方案中，弹性体组合物基本上不含环烷油。
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公开(公告)号：US08242236B2
公开(公告)日：2012-08-14
申请号：US12788164
申请日：2010-05-26
CPC分类号： C08K3/34 , B60C1/00 , B82Y30/00 , C08J3/21 , C08J3/215 , C08J5/005 , C08J2323/22 , C08J2323/28 , C08L23/22 , Y10T428/31504 , C08L23/283 , C08L2666/02
摘要： An elastomeric nanocomposite is produced from an isobutylene-based polymer and a layered nanofiller. The process of preparing the nanocomposite includes the steps of a) polymerizing isobutylene monomers and multiolefin monomers to produce an isobutylene-based polymer; b) completing at least one mass transfer dependent stage in the process wherein, after completion of the stage and prior to any recovery of the polymer, the polymer is dissolved in a solvent to create a polymer cement; c) contacting the layered nanofiller and the polymer solvent to obtain the nanocomposite; and d) recovering the nanocomposite. The layered nanofiller may be in a slurry prior to contacting with the polymer cement.
摘要翻译： 弹性纳米复合材料由异丁烯基聚合物和层状纳米填料制成。 制备纳米复合材料的方法包括以下步骤：a）聚合异丁烯单体和多烯烃单体以制备异丁烯基聚合物; b）在该过程中完成至少一个传质相关阶段，其中在阶段完成之后和在任何回收聚合物之前，将聚合物溶解在溶剂中以产生聚合物粘合剂; c）使层状纳米填料和聚合物溶剂接触以获得纳米复合材料; 和d）回收纳米复合材料。 在与聚合物粘合剂接触之前，层状纳米填料可以是浆料。
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59.发明授权Heterogeneous polymer blend with continuous elastomeric phase and process of making the same 失效具有连续弹性相的非均相聚合物共混物和制备相同的方法公开(公告)号：US07951872B2
公开(公告)日：2011-05-31
申请号：US11295927
申请日：2005-12-07
申请人： Sunny Jacob , Peijun Jiang , Aspy K. Mehta , Pradeep P. Shirodkar , Armenag H. Dekmezian , Weiqing Weng
发明人： Sunny Jacob , Peijun Jiang , Aspy K. Mehta , Pradeep P. Shirodkar , Armenag H. Dekmezian , Weiqing Weng
IPC分类号： C08F8/00 , C08L9/00 , C08L23/00 , C08L25/02 , C08L27/04 , C08L33/14 , C08L45/00 , C08G18/42 , C08K5/00
CPC分类号： C08L23/16 , C08L23/10 , C08L2312/00 , C08L2666/06
摘要： A heterogeneous polymer blend comprises a dispersed phase comprising a thermoplastic first polymer having a crystallinity of at least 30% and a continuous phase comprising a second polymer different from the first polymer. The second polymer has a crystallinity of less than 20% and is at least partially cross-linked.
摘要翻译： 非均相聚合物共混物包含分散相，其包含结晶度至少为30％的热塑性第一聚合物和包含不同于第一聚合物的第二聚合物的连续相。 第二聚合物具有小于20％的结晶度并且至少部分交联。
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公开(公告)号：US07915345B2
公开(公告)日：2011-03-29
申请号：US11787856
申请日：2007-04-18
申请人： Weiqing Weng , Sunny Jacob , Peijun Jiang , Armenag H. Dekmezian , Aspy K. Mehta , James R. Ayers , David J. Lohse , Peter W. Manders , Palanisamy Arjunan
发明人： Weiqing Weng , Sunny Jacob , Peijun Jiang , Armenag H. Dekmezian , Aspy K. Mehta , James R. Ayers , David J. Lohse , Peter W. Manders , Palanisamy Arjunan
IPC分类号： C08F8/00 , C08L9/00 , C08L23/04 , C08L23/10 , C08L29/00 , C08L31/00 , C08L33/00 , C08L35/00 , C08L45/00
CPC分类号： C08J3/005 , C08K3/011 , C08K5/0025 , C08L23/10 , C08L23/16 , C08L63/00 , C08L101/00 , C08L2312/04 , Y10T428/1372 , C08L2666/06
摘要： This invention relates to the preparation of thermoplastic vulcanizates (TPVs) with unique morphological features, more specifically, this invention relates to a method for preparing TPV compositions wherein the mixing of plastomers and elastomers are carried out in solvent with curatives to induce cross-linking.
摘要翻译： 本发明涉及具有独特形态特征的热塑性硫化橡胶（TPV）的制备，更具体地说，本发明涉及制备TPV组合物的方法，其中塑性体和弹性体的混合物在溶剂中用固化剂进行以引发交联。
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