公开(公告)号：US20150360198A1

公开(公告)日：2015-12-17

申请号：US14836669

申请日：2015-08-26

Applicant: ASAHI KASEI CHEMICALS CORPORATION

Inventor： Tatsuo YAMAGUCHI ,  Hiroyuki NODA ,  Toru WATANABE ,  Shunya KIRINO

IPC: B01J19/18 ,  B01J19/00

CPC classification number: B01J19/18 ,  B01D3/009 ,  B01J19/0066 ,  B01J21/04 ,  B01J23/04 ,  B01J27/188 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/108 ,  B01J2219/185 ,  C07C1/24 ,  C07C29/04 ,  C07C2521/04 ,  C07C2523/04 ,  Y02P20/582 ,  C07C11/09 ,  C07C31/12

Abstract: An object of the present invention is to provide, for the production of isobutene, a high-yielding, highly-selective, and long-term stable production process of isobutene from TBA. With respect to the production of TBA, an object of the present invention is to provide a TBA production process in which, through long-term stable maintenance of a high reaction activity, long-term continuous operation is enabled and the productivity is improved. The present invention discloses a process for producing isobutene that employs a dehydration temperature of from 200 to 450° C. in use of an alumina catalyst that contains a Na content of 0.6% by weight or less in terms of NaO2 and a Na content of 0.4% by weight in terms of NaO2, and has a specific surface area of from 200 to 600 m2/g.

公开(公告)号：US20150360148A1

公开(公告)日：2015-12-17

申请号：US14763707

申请日：2014-02-03

Applicant: Sulzer Chemtech AG

Inventor： François LOVIAT

IPC: B01D19/00 ,  B29B13/00 ,  B01D3/00

CPC classification number: B01D19/00 ,  B01D3/009 ,  B01D19/0005 ,  B01D19/0021 ,  B01D19/0036 ,  B01D19/0042 ,  B01J4/001 ,  B29B13/00 ,  B29B2013/005 ,  C08F6/003 ,  C08L25/12 ,  C08L55/02

Abstract: A static devolatilisation apparatus (1) adapted for devolatilising a viscous liquid (2) comprising a volatile component is disclosed. The apparatus (1) comprises a phase separation chamber (100) in an upper region (5) for treating the viscous liquid (2) in a first devolatilisation step to form a first devolatilised viscous liquid (21), and a distributor sub-unit 200 is located below the phase separation chamber (100) and above a lower sump region (4). The sub-unit (200) has a second discharge region (222) embodied such that it is contacted by the first devolatilised viscous liquid (21), and the region (222) has a surface (223) embodied such that the first devolatilised viscous liquid (21) is treated in a second devolatilisation step. The present invention further relates to a process to devolatilising a viscous liquid using the apparatus (1) and also to the use of the apparatus (1) in the devolatilisation of polymer melt or solution.

Abstract translation: 公开了一种适于使包含挥发性组分的粘性液体（2）脱挥发分的静态脱挥发分装置（1）。 装置（1）包括在上部区域（5）中的相分离室（100），用于在第一脱挥发分步骤中处理粘性液体（2）以形成第一脱挥发分粘性液体（21）和分配器子单元 200位于相分离室（100）下方和下部集水区（4）的上方。 子单元（200）具有第二排放区域（222），其被实施为使得其与第一脱挥发分的粘性液体（21）接触，并且区域（222）具有表面（223），使得第一脱挥发粘的粘性 在第二脱挥发分步骤中处理液体（21）。 本发明还涉及使用该装置（1）使粘性液体脱挥发分的方法，还涉及在聚合物熔体或溶液的脱挥发分中使用该装置（1）。

公开(公告)号：US20150343409A1

公开(公告)日：2015-12-03

申请号：US14655680

申请日：2013-12-27

Applicant: STAMICARBON B.V.

Inventor： Fredericus Henricus Maria BUITINK ,  Luc Louis Maria DIELTJENS

IPC: B01J19/00 ,  B01D3/00

CPC classification number: B01J19/00 ,  B01D3/009 ,  B01J2219/00024 ,  B01J2219/00027 ,  B01J2219/0004 ,  B01J2219/185 ,  C07C273/04 ,  Y10T29/49718

Abstract: Disclosed is a method of increasing the capacity of an existing urea plant. With reference to the regular components of a urea plant, including a synthesis section comprising a high pressure carbamate condenser and a reactor, and a recovery section, the method comprises installing an additional reactor between the recovery section and the high pressure carbamate condenser. The additional reactor is preferably installed in connection with an ejector, so as to allow ground placement of the additional reactor.

Abstract translation: 公开了提高现有尿素装置的能力的方法。 关于尿素装置的常规部件，包括包含高压氨基甲酸酯冷凝器和反应器的合成部分和回收部分，该方法包括在回收部分和高压氨基甲酸铵冷凝器之间安装另外的反应器。 附加的反应器优选地与喷射器结合安装，以允许附加反应器的地面放置。

公开(公告)号：US09199926B2

公开(公告)日：2015-12-01

申请号：US14371144

申请日：2013-01-09

Applicant: SAIPEM S.p.A.

Inventor： Lino Carlessi ,  Alessandro Gianazza

IPC: C07C273/04 ,  B01D3/00

CPC classification number: C07C273/04 ,  B01D3/009 ,  Y02P20/142 ,  Y02P20/582

Abstract: A process for the direct synthesis of urea from ammonia and carbon dioxide with increased corrosion resistance, comprising, in the high-pressure synthesis section, a reaction step in a vertical reactor fed with at least one stream of fresh carbon dioxide containing a passivating agent and a decomposition-stripping step of the non-converted reagents, wherein the gas-liquid mixture collected at the head of the reactor is separated into a gaseous stream and a liquid stream fed to the tail and head of the stripper, respectively.

Abstract translation: 一种用于从具有增加的耐腐蚀性的氨和二氧化碳直接合成尿素的方法，包括在高压合成段中在垂直反应器中的反应步骤，该反应器供应至少一种含有钝化剂的新鲜二氧化碳流和 未转化试剂的分解汽提步骤，其中在反应器头部收集的气液混合物分离成气态物流和分别送入汽提塔尾部和头部的液体流。

公开(公告)号：US09193660B2

公开(公告)日：2015-11-24

申请号：US13986969

申请日：2013-06-20

Applicant: Kuang-Yeu Wu ,  Pai-Yu Polly Chiang ,  Ji-Young Jang ,  Karl Tze-Tang Chuang

Inventor： Kuang-Yeu Wu ,  Pai-Yu Polly Chiang ,  Ji-Young Jang ,  Karl Tze-Tang Chuang

IPC: C07C51/42 ,  B01D3/00 ,  C07C51/09 ,  C07C51/44

CPC classification number: C07C51/42 ,  B01D3/009 ,  C07C51/09 ,  C07C51/44 ,  Y02P20/127 ,  C07C53/08

Abstract: A carboxylic acid e.g. acetic acid, is recovered from an aqueous feed stream containing the corresponding ester, an alcohol and a small amount of water by catalytically dehydrating the alcohol to the corresponding ether and water, and reacting the water with the ester to generate a liquid carboxylic acid rich product stream. The acid is recovered by distillation. In a second embodiment, additional alcohol and/or water are co-fed with the feed or fed directly to a catalytic distillation column, resulting in a liquid bottom product stream of substantially pure acetic acid and a top distillate stream of substantially pure ether.

Abstract translation: 羧酸例如 乙酸通过将醇催化脱水至相应的醚和水从含有相应的酯，醇和少量水的含水进料流中回收，并使水与酯反应以产生液体富含羧酸的产物 流。 酸通过蒸馏回收。 在第二个实施方案中，额外的醇和/或水与进料共同进料或直接进料到催化蒸馏塔，导致基本上纯的乙酸的液体底部产物流和基本上纯的乙醚的顶部馏出物流。

公开(公告)号：US09181500B2

公开(公告)日：2015-11-10

申请号：US14225403

申请日：2014-03-25

Applicant: UOP LLC

Inventor： Xin X. Zhu ,  Trung Pham ,  Selman Z. Erisken ,  Haiyan Wang ,  David X. Wu

IPC: C10G69/04 ,  B01J8/22 ,  B01D3/00 ,  B01J8/18

CPC classification number: C10G69/04 ,  B01D3/009 ,  B01J8/003 ,  B01J8/0055 ,  B01J8/025 ,  B01J8/0457 ,  B01J8/1863 ,  B01J8/22 ,  B01J8/26 ,  B01J2208/00176 ,  B01J2219/00038 ,  B01J2219/0004 ,  C10G11/18 ,  C10G45/02 ,  C10G45/44 ,  C10G65/08

Abstract: A process and apparatus for recycling LCO and/or HCO to a hydroprocessing zone to saturate aromatics for cracking in an FCC unit is disclosed. The recycle cracked stream may be recycled to a downstream hydroprocessing zone to avoid a first hydroprocessing zone that is primarily for demetallizing (and desulfurizing) feed to the FCC unit.

Abstract translation: 公开了一种用于将LCO和/或HCO再循环到加氢处理区以使FCC中的芳族化合物裂化的方法和装置。 再循环裂解的物流可循环到下游加氢处理区，以避免主要用于使FCC单元脱金属（和脱硫）进料的第一加氢处理区。

公开(公告)号：US09150473B2

公开(公告)日：2015-10-06

申请号：US14221666

申请日：2014-03-21

Applicant: Dairen Chemical Corporation

Inventor： Shien-Chang Chen ,  Tian-Yuan Lin ,  Shih-Bo Hung

IPC: C07C29/09 ,  B01D3/00

CPC classification number: C07C29/095 ,  B01D3/009 ,  Y02P20/127 ,  C07C33/03

Abstract: A method for producing allyl alcohol is disclosed. The method includes steps of feeding allyl acetate and water into a reactive distillation column; performing a reaction in a reaction zone and separating a product containing allyl alcohol, acetic acid and water from the reactive distillation column. Accordingly, the method effectively enhances a conversion rate of hydrolysis for allyl acetate, simplifies the process and reduces energy consumption.

Abstract translation: 公开了一种生产烯丙醇的方法。 该方法包括将乙酸烯丙酯和水进料到反应性蒸馏塔中的步骤; 在反应区中进行反应，并从反应蒸馏塔中分离含有烯丙醇，乙酸和水的产物。 因此，该方法有效地提高乙酸烯丙酯的水解转化率，简化了工艺并降低了能量消耗。

公开(公告)号：US20150266799A1

公开(公告)日：2015-09-24

申请号：US14730424

申请日：2015-06-04

Applicant: OCCIDENTAL CHEMICAL CORPORATION

Inventor： John Lee DAWKINS ,  Darrell Gene HOLLIS ,  Rodney L. KLAUSMEYER ,  Keith S. KRAMER ,  Michael Andrew GARMON

IPC: C07C17/383 ,  B01D3/34 ,  B01D3/10

CPC classification number: C07C17/386 ,  B01D3/009 ,  B01D3/10 ,  B01D3/34 ,  B01D11/04 ,  C07C17/06 ,  C07C17/25 ,  C07C17/278 ,  C07C17/38 ,  C07C17/383 ,  C07C17/395 ,  C07C17/42 ,  Y02P20/127 ,  C07C19/01 ,  C07C21/04

Abstract: Processes for isolating 1,1,1,2,3-pentachloropropane from a crude product stream containing the 1,1,1,2,3-pentachloropropane and ferric chloride. The processes may include deep distillation of the crude, treatment of the crude with a reagent that deactivates the ferric chloride followed by distillation on the deactivated crude stream, aqueous washing of the crude product stream to remove ferric chloride followed by distillation on the deactivated crude stream. Other embodiments simultaneously prepare 1,1,2,3-tetrachloroprene and 1,1,1,2,3-pentachloroprane.

Abstract translation: 从含有1,1,1,2,3-五氯丙烷和氯化铁的粗产物流中分离1,1,1,2,3-五氯丙烷的方法。 该方法可以包括对粗产物进行深蒸馏，用试剂灭活处理粗产物，然后在失活的粗制物流上进行蒸馏，然后对粗产物流进行水洗，以除去氯化铁，随后在失活的粗产物流 。 其它实施方案同时制备1,1,2,3-四氯丁二烯和1,1,1,2,3-五氯代。

公开(公告)号：US20150251168A1

公开(公告)日：2015-09-10

申请号：US14717107

申请日：2015-05-20

Applicant: NESTE OIL OYJ

Inventor： Mika Kettunen ,  Jukka Myllyoja ,  Rami Piilola ,  Goran Sandstrom ,  Pekka Aalto

IPC: B01J27/051 ,  B01J23/883 ,  B01J23/04 ,  B01J35/00

CPC classification number: B01J27/0515 ,  B01D3/009 ,  B01J21/063 ,  B01J23/04 ,  B01J23/883 ,  B01J23/8872 ,  B01J35/0006 ,  B01J37/20 ,  C07C1/22 ,  C07C1/24 ,  C07C5/2735 ,  C07C5/2737 ,  C07C45/41 ,  C07C45/54 ,  C07C2523/16 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C10G3/42 ,  C10G3/44 ,  C10G3/45 ,  C10G3/46 ,  C10L1/04 ,  C10L2200/0484 ,  C10M105/04 ,  C10M105/24 ,  C10M177/00 ,  C11C1/005 ,  C11C3/123 ,  Y02P30/20

Abstract: The present invention provides a method for simultaneous production of components suitable for production of base oil and fuel components. In the method a feedstock comprising fatty acids and/or fatty acid esters is entered into a reaction zone and subjected to a ketonisation reaction in the presence of a dual catalyst system. This system is configured to perform a ketonisation reaction and a hydrotreatment reaction, under hydrogen pressure. Subsequently ketones are obtained.

公开(公告)号：US09120713B2

公开(公告)日：2015-09-01

申请号：US14375732

申请日：2012-11-01

Applicant: Neste Oil Oyj

Inventor： Mika Kettunen ,  Jukka Myllyoja ,  Rami Piilola ,  Goran Sandstrom ,  Pekka Aalto

IPC: C07C45/41 ,  C07C1/22 ,  B01J23/00 ,  C07C1/24 ,  C11C3/12 ,  C10L1/04 ,  C10G3/00 ,  B01J23/883 ,  C11C1/00 ,  C07C45/54 ,  C10M105/24 ,  B01D3/00 ,  B01J23/887 ,  C07C5/27 ,  C10M105/04 ,  C10M177/00 ,  B01J37/20 ,  B01J35/00 ,  B01J21/06 ,  B01J23/04

CPC classification number: B01J27/0515 ,  B01D3/009 ,  B01J21/063 ,  B01J23/04 ,  B01J23/883 ,  B01J23/8872 ,  B01J35/0006 ,  B01J37/20 ,  C07C1/22 ,  C07C1/24 ,  C07C5/2735 ,  C07C5/2737 ,  C07C45/41 ,  C07C45/54 ,  C07C2523/16 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C10G3/42 ,  C10G3/44 ,  C10G3/45 ,  C10G3/46 ,  C10L1/04 ,  C10L2200/0484 ,  C10M105/04 ,  C10M105/24 ,  C10M177/00 ,  C11C1/005 ,  C11C3/123 ,  Y02P30/20

Abstract: The present invention provides a method for simultaneous production of components suitable for production of base oil and fuel components. In the method a feedstock comprising fatty acids and/or fatty acid esters is entered into a reaction zone and subjected to a ketonization reaction in the presence of a dual catalyst system. This system is configured to perform a ketonization reaction and a hydrotreatment reaction, under hydrogen pressure. Subsequently ketones are obtained.

Abstract translation: 本发明提供了一种用于同时生产适用于生产基础油和燃料组分的组分的方法。 在该方法中，包含脂肪酸和/或脂肪酸酯的原料进入反应区并在双重催化剂体系的存在下进行酮化反应。 该系统配置为在氢气压力下进行酮化反应和加氢处理反应。 随后得到酮。