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公开(公告)号：US4570022A
公开(公告)日：1986-02-11
申请号：US732371
申请日：1985-05-09
申请人： Peter W. D. Mitchell
发明人： Peter W. D. Mitchell
CPC分类号： C07C29/103 , C07C35/17 , C07C35/18 , C07C2101/16
摘要： A method of preparing 1-terpinen-4-ol and 1(7)-terpinen-4-ol comprising an E2 elimination reaction of 1,4-cineole.
摘要翻译： 制备1-萜品烯-4-醇和1（7） - 萜品烯-4-醇的方法，其包括1,4-桉树脑的E2消除反应。
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公开(公告)号：US4337372A
公开(公告)日：1982-06-29
申请号：US266615
申请日：1981-05-22
IPC分类号： B01J27/00 , B01J27/057 , C07C27/00 , C07C29/56 , C07C33/025 , C07C67/00
CPC分类号： B01J27/0573 , C07C29/56 , C07B2200/09
摘要： The invention provides a novel method for the cis to trans isomerization of an alkenyl alcohol in a very simple process. The inventive method comprises heating the cis-isomer at a temperature of, for example, 150.degree. to 200.degree. C. in the presence of selenium metal in a powdery form with agitation.
摘要翻译： 本发明提供了一种在非常简单的方法中顺式 - 反式异构化烯基醇的新方法。 本发明的方法包括在搅拌的粉末形式的硒金属存在下，在例如150℃至200℃的温度下加热顺式异构体。
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公开(公告)号：US4229599A
公开(公告)日：1980-10-21
申请号：US947186
申请日：1978-09-29
申请人： Cynthia J. Mussinan , Braja D. Mookherjee , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala , Frederick L. Schmitt
发明人： Cynthia J. Mussinan , Braja D. Mookherjee , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala , Frederick L. Schmitt
CPC分类号： A24B15/345 , C07C29/56 , C11B9/0049 , C07B2200/07 , C07C2102/32
摘要： A process for preparing a mixture of isomers of caryophyllene alcohol and dihydrocaryophyllene alcohol including 10,10-dimethyl-2,6-dimethylene bicyclo[7.2.0]undecan-5-ol by isomerizing caryophyllene oxide or dihydrocaryophyllene oxide using an aluminum isopropylate catalyst in a toluene solvent at temperatures in the range of from about 100.degree. C. up to about 150.degree. C. is described.
摘要翻译： 使用异丙醇铝催化剂异构化氧化石脑烯或二氢氧杂环戊烯来制备石竹烯醇和二氢石竹烯醇的异构体混合物的方法，该方法包括10,10-二甲基-2,6-二亚甲基双环[7.2.0]十一烷-5-醇 描述了在约100℃至约150℃的温度范围内的甲苯溶剂。
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54.发明授权Cycloaliphatic unsaturated ketones as odor and taste modifying agents in tobacco products 失效环脂肪不饱和酮作为烟草制品中的气味和味觉改良剂
公开(公告)号：US4187863A
公开(公告)日：1980-02-12
申请号：US782536
申请日：1977-03-29
IPC分类号： A23L27/20 , A24B15/34 , C07C29/132 , C07C29/147 , C07C29/56 , C07C47/21 , C07D303/14 , C07D303/32 , C11B9/00 , A24B3/12
CPC分类号： C11B9/0076 , A23L27/203 , A24B15/34 , C07C17/16 , C07C29/132 , C07C29/56 , C07C403/08 , C07C403/16 , C07C45/298 , C07C45/516 , C07C45/54 , C07C45/67 , C07C45/676 , C07D303/14 , C07D303/32 , C11B9/0034 , C07B2200/09 , C07C2101/14 , C07C2101/16 , C07C2102/24
摘要： New cycloaliphatic unsaturated ketones used as flavoring and taste modifying agents in tobacco products.
摘要翻译： 新的脂环族不饱和酮用作烟草制品中的调味和调味剂。
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55.发明授权
公开(公告)号：US4113968A
公开(公告)日：1978-09-12
申请号：US616998
申请日：1975-09-26
申请人： Fumio Mori , Yoshiaki Omura , Takashi Nishida , Kazuo Itoi
发明人： Fumio Mori , Yoshiaki Omura , Takashi Nishida , Kazuo Itoi
IPC分类号： C07C29/38 , C07C29/56 , C07D307/45 , C07C67/30
CPC分类号： C07D307/42 , C07C29/38 , C07C29/56 , C07C67/00 , C07C67/27 , C07C2101/02
摘要： When 1-halogeno-3-alkene-2-ol is reacted with an ortho-carboxylic ester and/or a ketene acetal, a .gamma.-halogeno-.delta.-unsaturated-carboxylic ester is obtained as a main reaction product. When this intermediate is treated with a basic substance, a substituted cyclopropane-carboxylic ester is formed. This ester can be used as an insecticide or an agricultural chemical as it is or after the alcohol residue of the ester has been converted to other alcohol residue.
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公开(公告)号：US4006193A
公开(公告)日：1977-02-01
申请号：US340585
申请日：1973-03-12
申请人： Yoichi Ninagawa , Takashi Nishida , Kazuo Itoi
发明人： Yoichi Ninagawa , Takashi Nishida , Kazuo Itoi
IPC分类号： C07C29/56 , C07C29/80 , C07C33/025 , C07C33/05 , C07C33/02
CPC分类号： C07C403/08 , C07C29/56 , C07C29/80 , C07C33/025 , C07C2101/14 , C07C2101/16
摘要： Unsaturated alcohols represented by the general formulas (I) and (II) below ##STR1## wherein R is a substituted or unsubstituted hydrocarbon radical, R.sub.2 and R.sub.3 are hydrogen or lower alkyl groups, and R and R.sub.2 may be linked together are mutually isomerized in the presence of a catalyst comprising a transition metal compound of Groups V, VI and VII of the Mendeleev Periodic Table.
摘要翻译： 由下式（I）和（II）表示的不饱和醇，其中R是取代或未取代的烃基，R2和R3是氢或低级烷基，R和R2可以是 在包含门多列夫周期表的V，VI和VII族过渡金属化合物的催化剂的存在下相互异构化。
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57.发明授权
公开(公告)号：US3975310A
公开(公告)日：1976-08-17
申请号：US503738
申请日：1974-09-06
IPC分类号： A23L27/20 , A24B15/34 , C07C29/132 , C07C29/56 , C07C47/21 , C07D303/14 , C07D303/32 , C11B9/00 , A61K7/46
CPC分类号： C11B9/0076 , A23L27/203 , A24B15/34 , C07C29/132 , C07C29/56 , C07C403/08 , C07C403/16 , C07D303/14 , C07D303/32 , C11B9/0034 , C07C2101/16
摘要： New cycloaliphatic unsaturated ketones and their use as perfuming and odor-modifying agents in the manufacture of perfumes and perfumed products, and as flavoring and taste-modifying agents in the preparation of foodstuffs in general and imitation flavors for foodstuffs, beverages, animal feeds, pharmaceutical preparations and tobacco products.Methods for the preparation of said cycloaliphatic unsaturated ketones.
摘要翻译： 新的脂环族不饱和酮及其在香料和香料产品的制造中作为加香和气味改性剂的用途，以及作为食品制备中的调味剂和味道调节剂以及用于食品，饮料，动物饲料，药物 制剂和烟草制品。
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公开(公告)号：US11718640B2
公开(公告)日：2023-08-08
申请号：US16629487
申请日：2018-09-12
摘要： The present invention discloses an improved process for extracting cholesterol in high yield and purity from fish oil waste residue. The so obtained cholesterol of pharmaceutical grade is useful as a precursor for the preparation of vitamin D3.
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公开(公告)号：US20220127212A1
公开(公告)日：2022-04-28
申请号：US17293482
申请日：2019-12-16
发明人： Namjin JANG , Eun Jeong KIM , Sun Uk LEE , Jong Kwon LEE
IPC分类号： C07C29/158 , C07C29/56
摘要： The present disclosure relates to a method for preparation of 1,4-cyclohexanedimethanol. According to the present disclosure, two step reduction reactions are conducted using terephthalic acid as starting material, and an isomerization process for increasing the rate of trans isomers of CHDA is introduced therebetween, thereby providing a method capable of stably preparing CHDM with high rate of trans isomers.
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公开(公告)号：US11214532B2
公开(公告)日：2022-01-04
申请号：US16955421
申请日：2018-12-21
发明人： Jong Kwon Lee , Ki Don Kim , Eun Jeong Kim , Joo Hee Han , Ho Seong Nam
IPC分类号： C07C29/147 , C07C29/149 , C07C31/27 , C07C29/56 , B01J21/04 , B01J23/46 , B01J23/755 , B01J23/44 , B01J23/40 , B01J23/42 , B01J23/14 , B01J21/06 , B01J21/10 , B01J21/08
摘要： Provided is a preparation method for a cyclohexane dimethanol (CHDM), which can have a high trans content through particular conditions, additive addition, or reactant addition, which is controlled in a cyclohexane dicarboxylic acid (CHDA) hydrogenation reaction, and a cyclohexane dimethanol prepared thereby.
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