摘要:
A composition for use in an electro-optical device, particularly a display device, contains anthraquinone pleochroic dye of formula (I): ##STR1## where R.sub.1 is a substituted or unsubstituted amino group or a hydroxy group; each of R.sub.2, R.sub.3 and R.sub.4, which are identical or different, is a hydrogen atom, a substituted or unsubstituted amino group, a hydroxy group or a nitro group; R is a hydrogen or halogen atom or a hydroxy, lower alkyl or lower alkoxy group; n is 1, 2, 3 or 4, the Rs being identical or different when n is 2, 3 or 4; X is a hydrogen or halogen atom, a hydroxy or mercapto group, a straight, branched or cyclic C.sub.1-16 alkyl radical, a substituted or unsubstituted aryl group or a group of formula ##STR2## where R' is a hydrogen atom or a straight, branched or cyclic C.sub.1-10 alkyl residue, and Y is a hydrogen atom or a side chain of the formula: ##STR3## where X', R" and n' have the same definitions as and are respectively identical to or different from X, R and n, the side chain being in position 6 when the compound is substituted in position 2 and in position 7 when it is substituted in position 3.Compounds of formula (I) have a high order parameter and are very stable.
摘要:
A composition for nematic liquid crystal color display elements, said composition comprising at least one anthraquinonic dye represented by the following formula ##STR1## wherein X and Y are identical or different and represent --NH.sub.2 or --OH; Z represents halogen, --OR, --NHR, ##STR2## --CONHR.sub.2 or --COOR.sub.2, in which R represents an alkyl group having 1 to 15 carbon atoms or a lower alkyl group optionally substituted by --OH, ##STR3## represents hydrogen, halogen, --OH, --OCH.sub.3, an alkyl group having 1 to 15 carbon atoms, or a methoxy group optionally substituted by ##STR4## and R.sub.2 is a phenyl group, an alkyl group having 2 to 5 carbon atoms or a cyclohexyl group; and n is an integer of 1 or 2 provided that when X is --NH.sub.2 and Y is --OH, and when X and Y are both --OH, n is an integer of 1, and when n represents an integer of 2, the two Z's may be identical or different dissolved in at least one nematic liquid crystal.
摘要:
Basic dyes free from sulfo groups of the formula ##STR1## in which Q signifies an unsubstituted or substituted phenyl or naphthyl radical,R.sub.1 and R.sub.2 signify hydrogen, unsubstituted or substituted alkyl, phenyl or cycloalkyl,R.sub.3 signifies hydrogen, unsubstituted or substituted alkyl or phenyl,the Z containing group signifies a heterocyclic diazo radical containing a quaternary ammonium group,R.sub.4 signifies unsubstituted or substituted alkyl, alkenyl, cycloalkyl or alkoxy,x signifies 1 to 3,A.crclbar. signifies an anion, andD signifies an unsubstituted or substituted phenylene or naphthylene radical are useful for dyeing and printing homo- and co-polymers of acrylonitrile and asymmetrical dicyanoethylene and synthetic polyamides and polyesters modified to contain acid groups. The obtained dyeings are level and fast to light and wet treatments.
摘要:
Liquid crystal compositions containing pleochroic dyes. The pleochroic dyes are substituted anthraquinone dyes containing at least one carbocyclic or heterocyclic group linked to the anthraquinone moiety through a sulfur atom. The dyes are used in guest-host combinations with nematic liquid crystal compositions having positive dielectric anisotropy. Electro-optic devices containing these guest-host combinations are disclosed.
摘要:
A process for the preparation of new dyestuff compositions which contain one or more basic dyestuffs in the form of dyestuff bases from the series of the triarylmethane, indoldiarylmethane, azine, oxazine, thiazine or xanthene dyestuffs or one or more basic dyestuffs of the series of the azo, anthraquinone, phthalocyanine, styryl, quinophthalone, benzoxanthene, naphthoylene-benzimidazole, naphthalimide or nitro series, carrying a primary, secondary or tertiary amino group or a guanidino or hydrazino group, as well as one or more non-ionic or slightly cationic surface-active agents and, optionally, water and/or an organic solvent miscible with water, which process comprises synthesizing the dyestuff in the surface-active agent optionally containing water and/or an organic solvent miscible with water, and then adding, if necessary, water and/or a solvent miscible with water and a further surface-active agent, this process of the invention having the advantage that an intermediate isolation, drying or grinding of the dyestuffs contained in the dyestuff compositions defined above is not necessary, so that the dyestuffs need not be introduced as substance into the surface-active agent and the solvent in a process wherein compositions of this type are prepared by a usual mixing, kneading or melting process; moreover, higher dyestuff yields are obtained in the dyestuff synthesis, and it allows to prepare dyestuff compositions from dyestuffs which are difficult to be isolated in substance after synthesis and often precipitate as oily or smeary products. The dyestuff compositions obtained according to the process of the invention, which are pastes or liquids, have a high stability upon storage. After being diluted with an aqueous solution of an amount at least equivalent to the dyestuff of an inorganic or organic acid, as well as, optionally, after the addition of dyeing and/or printing auxiliaries, the novel dyestuff compositions are suitable for dyeing or printing textile material containing acid groups.
摘要:
NEW ANTHRAQUINONE COMPOUNDS HAVING AN ARYL RADICAL BEARING AN N-METHYLENELACTAM SUBSTITUTENT THEREON. THESE COMPOUNDS ARE USED AS DYES WITH EXCELLENT LIGHT AND SUBLIMATION FASTNESS FOR TEXTILE FIBERS SUCH AS POLYESTERS.
摘要:
ANTHRAQUINONE DYESTUFFS WHICH ARE SPARINGLY SOLUBLE IN WATER AND ARE FREE OF GROUPS WHICH DISSOCIATE IN WATER TO GIVE AN ACID REACTION AND IMPART SOLUBILITY IN WATER, OF THE FORMULA I
IN WHICH R1 AND R2, INDEPENDENTLY OF ONE ANOTHER, EACH DENOTE HYDROEN OR A LOWER ALKYL GROUP, X DENOTES HYDROGEN OR HALOGEN, Y1 AND Y2, INDEPENDENTLY OF ONE ANOTHER, EACH DENOTE A LOWER ALKYLENE GROUP WHICH IS OPTIONALLY SUBSTITUTED BY A HYDROXYL GROUP OR A LOWER ALKOXY GROUP, M AND N EACH DENOTE ONE OF THE NUMBERS 1 OR 2, AND R3 DENOTES AN OPTIONALLY SUBSTITUTED ALIPHATIC OR AROMATIC HYDROCARBON RADICAL OR A LOWER ALKYLAMINO, A CYCLOALKYLAMINO OR AN OPTIONALLY RING-SUBSTITUTED ARYLAMINO GROUP, AND IN WHICH THE BENZENE RING A IS OPTIONALLY SUBSTITUTED FURTHER BY HALOGEN, OR BY A LOWER ALKYL OR LOWER ALKOXY GROUP.
摘要:
Anthraquinone dyes are prepared in substantially quantitative yields by reacting a diaminodihydroxyanthraquinone, such as 4,5diaminochrysazin, with a benzenesulfonyl chloride in a thin fluid melt consisting essentially of anhydrous aluminum halide in admixture with a compound that gives a fluid melt at low temperatures. New dyes having improved substantivity on polyester fibers are made by an alternate embodiment involving the concurrent addition of a halogen such as bromine to the anhydrous aluminum halide melt.
摘要:
Mixtures of disperse anthraquinone dyestuffs which are obtained by reacting a leuco derivative of a 1:5-dihydroxy-4:8-di(amino, hydroxy or alkylamino) -2-(hydroxyaryl or alkoxyaryl)anthraquinone with an aldehyde, and the use of the said mixtures for coloring synthetic textile materials.