摘要:
Radiation-curable, tackifier-free compositions are provided which contain: (i) a blend of certain acrylate esters and monoethylenically-unsaturated copolymerizable monomers; (ii) certain .alpha.-olefin polymers; and (iii) a photoinitiator and optionally, a crosslinker. Pressure-sensitive adhesives having good adhesion to both low and high energy surfaces as well as possessing excellent low and high temperature performance properties are prepared by exposing the radiation-curable compositions to light having a wavelength in the range of from about 280 to 400 nm.
摘要:
New amphiphilic networks have been synthesized by free-radical copolymerization of hydrophobic methacryloyl capped polyisobutylenes (MA-PIB-MA) with hydrophilic 2-(dimethylamino)ethyl methacrylate (DMAEMA). Two MA-PIB-MAs have been prepared with M.sub.n =4920 and 10,200, and two series of networks were prepared with MA-PIB-MA contents between 48% and 71.5%. Variation of the molecular weight of MA-PIB-MA and its concentration in the network allows for a wide range of mechanical properties and swellability in hydrophilic and hydrophobic solvents. Differential scanning calorimetry shows the existence of two glass transitions in these networks and thus indicates a phase-separated domain structure. Tensile strengths and elongations are dependent on MA-PIB-MA contents, varying from 57.7 kg/cm.sup.2 to 39.8 kg/cm.sub.2 and 168% to 200%, respectively, with increasing MA-PIB-MA content. Solvent swelling of the networks range from 170% to 20% in water and from 40% to 170% in n-heptane with increasing MA-PIB-MA contents.
摘要翻译:已经通过疏水性甲基丙烯酰基封端的聚异丁烯(MA-PIB-MA)与亲水性2-(二甲基氨基)乙基甲基丙烯酸酯(DMAEMA)的自由基共聚合成了新的两亲网络。 制备了两种MA-PIB-MAs,Mn = 4920和10,200,制备了两个系列的网络,MA-PIB-MA含量在48%〜71.5%之间。 MA-PIB-MA的分子量的变化及其在网络中的浓度允许在亲水和疏水溶剂中具有广泛的机械性能和溶胀性。 差示扫描量热法显示这些网络中存在两个玻璃化转变,因此表明相分离的畴结构。 随着MA-PIB-MA含量的增加,拉伸强度和伸长率取决于MA-PIB-MA含量,从57.7 kg / cm2到39.8 kg / cm2和168%到200%不等。 随着MA-PIB-MA含量的增加,网络的溶剂溶胀范围在水中的170%至20%,正庚烷中的40%至170%。
摘要:
Aqueous ink compositions are disclosed which are an admixture a colorant, a resin binder which is the Diels-Alder adduct of maleic anhydride and 2,3- and 6,7-poly(alloocimene) or the partial-ester thereof and a solvating proportion of water. The inks are useful in flexographic and gravure printing.
摘要:
A composition comprising(A) the reaction product of(A)(1) one or more alpha-beta olefinically unsaturated carboxylic acid reagents containing 2 to about 20 carbon atoms exclusive of the carboxyl-based groups, with(A)(2) one or more olefin polymers of at least 30 carbon atoms selected from the group consisting ofhomopolymers and/or interpolymers of mono-olefins of from 12 to 30 carbon atoms, and chlorinated or brominated analogs thereof; and(B) the reaction product of(B)(1) one or more alpha-beta olefinically unsaturated carboxylic acid reagents containing 2 to about 20 carbon atoms exclusive of the carboxyl-based groups, with(B)(2) one or more olefin polymers of at least 30 carbon atoms selected from the group consisting ofhomopolymers and/or interpolymers of mono-1-olefins of from 2 to 8 carbon atoms and chlorinated or brominated analogs thereof.Compositions made by reacting mixtures of components (A) and (B) with one or more alcohols, one or more amines, or mixtures of one or more alcohols and/or one or more amines are also disclosed. Lubricant and fuel compositions, and additive concentrates for such lubricant and fuel compositions, containing the foregoing compositions are also disclosed.
摘要:
A composition comprising(A) the reaction product of(A)(1) one or more alpha-beta olefinically unsaturated carboxylic acid reagents containing 2 to about 20 carbon atoms exclusive of the carboxyl-based groups, with(A)(2) one or more olefin polymers of at least 30 carbon atoms selected from the group consisting of homopolymers and/or interpolymers of mono-olefins of from 12 to 30 carbon atoms, and chlorinated or brominated analogs thereof; and(B) the reaction product of(B)(1) one or more alpha-beta olefinically unsaturated carboxylic acid reagents containing 2 to about 20 carbon atoms exclusive of the carboxyl-based groups, with(B)(2) one or more olefin polymers of at least 30 carbon atoms selected from the group consisting of homopolymers and/or interpolymers of mono-1-olefins of from 2 to 8 carbon atoms and chlorinated or brominated analogs thereof.Compositions made by reacting mixtures of components (A) and (B) with one or more alcohols, one or more amines, or mixtures of one or more alcohols and/or one or more amines are also disclosed. Lubricant and fuel compositions, and additive concentrates for such lubricant and fuel compositions, containing the foregoing compositions are also disclosed.
摘要:
A propylene block copolymer comprising propylene, ethylene and a straight-chain .alpha.-olefin of 5 to 12 carbon atoms is characterized in that: its limiting viscosity is 0.3 to 15 dl/g (at 135.degree. C., in decalin); it comprises specified quantities of these monomers; and when it is subjected to successive extraction with o-dichlorobenzene at 40.degree. C. and 80.degree. C., the quantities, fusion peak temperatures, and content of the .alpha.-olefin of the resulting fractions are respectively within specific limits of values.
摘要:
High impact strength rubber modified styrene and styrene-acrylonitrile (SAN) thermoplastics are prepared by incorporating into the styrene or SAN copolymer a conjugated diene butyl rubber elastomer. Conventional processes are effective to provide products having suitable impact strength and related properties.
摘要:
The present invention relates to novel polymeric compositions of styrene and amorphous polyolefins which include amorphous polypropylene, amorphous propylene/alpha-olefin copolymers and blends thereof and to processes for their preparation. These polymeric compositions are useful in preparing hot melt adhesives.
摘要:
Aluminum trialkyl and aluminum dialkyl monohalide catalysts can be used to graft cationically polymerizable monomers, such as styrene, chloroprene, isobutylene, etc. to halogenated polymers with some highly reactive halogen atoms such as PVC, neoprene, chlorobutyl, etc.
摘要:
A POLYMERIC COMPOSITION OF 4-METHYL PENTENE-1 HAVING DISPERSED THROUGH IT A SMALL PROPORTION OF POLYMERIZED UNITS OF AN ALIPHATIC OLEFIN, THE HOMOPOLYMER OF SAID ALIPHATIC OLEFIN HAVING A MELTING POINT ABOVE 275*C., PREFERABLY ABOVE 320*C. THE COMPOSITION MAY ALSO INCLUDE UNITS OF A LINEAR 1-OLEFIN HAVING 4 TO 18 CARBON ATOMS. THE COMPOSITION IS PREPARED BY SEQUENTIAL POLYMERIZATION OF 4-METHYL PENTENE-1 AND THE ALIPHATIC OLEFIN. THE COMPOSITION MAY BE MOULDED INTO ARTICLES HAVING A MEAN SPHERULITE SIZE OF LESS THAN 5 MICRONS, WHICH, IF THE POLYMER HAS A LOW ASH CONTENT, MAY HAVE A LIGHT TRANSMISSION OF 1/8" SECTION OF AT LEAST 90%.