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公开(公告)号：US5202361A
公开(公告)日：1993-04-13
申请号：US812280
申请日：1991-12-23
IPC分类号： C08F2/46 , C08F2/48 , C08F255/00 , C08F255/08 , C08L23/02 , C09J4/06 , C09J7/02 , C09J123/18 , C09J133/08 , C09J151/00 , C09J151/06
CPC分类号： C09J4/06 , C09J123/18 , C09J133/08 , C09J7/0217 , C08L23/02 , C09J2201/606 , Y10S526/931 , Y10T428/2809 , Y10T428/2878 , Y10T428/2891
摘要： Radiation-curable, tackifier-free compositions are provided which contain: (i) a blend of certain acrylate esters and monoethylenically-unsaturated copolymerizable monomers; (ii) certain .alpha.-olefin polymers; and (iii) a photoinitiator and optionally, a crosslinker. Pressure-sensitive adhesives having good adhesion to both low and high energy surfaces as well as possessing excellent low and high temperature performance properties are prepared by exposing the radiation-curable compositions to light having a wavelength in the range of from about 280 to 400 nm.
摘要翻译： 提供了可辐射固化的，无增粘剂的组合物，其包含：（i）某些丙烯酸酯和单烯属不饱和可共聚单体的共混物; （ii）某些α-烯烃聚合物; 和（iii）光引发剂和任选的交联剂。 通过将辐射固化性组合物暴露于波长在约280〜400nm范围内的光，制备对低能量表面和高能量表面具有良好粘附性以及具有优异的低温和高温性能的压敏粘合剂。
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公开(公告)号：US5902836A
公开(公告)日：1999-05-11
申请号：US505350
申请日：1995-08-23
申请人： Greggory S. Bennett , Gaddam N. Babu , Kejian Chen , Louis E. Winslow , George F. Vesley , Patrick G. Zimmerman
发明人： Greggory S. Bennett , Gaddam N. Babu , Kejian Chen , Louis E. Winslow , George F. Vesley , Patrick G. Zimmerman
IPC分类号： B05D7/02 , B05D7/24 , C08F2/02 , C08F2/40 , C08F2/46 , C08F2/48 , C08F2/50 , C08F20/10 , C08F220/10 , C08F291/00 , C09D4/00 , C09D4/06 , C09J4/00 , C09J4/06 , C09J7/00 , C09J7/02 , G03F7/027 , C08J133/08 , C08J133/10
CPC分类号： G03F7/027 , C08F2/48 , C08F2/50 , C08F291/00 , C09D4/06 , C09J4/06 , Y10S522/904 , Y10S522/905
摘要： Solute polymers in solvent monomers form a coatable syrup that can be cured to a viscoelastomeric material when radiation-sensitive .alpha.-cleaving groups in either the polymer or one of the monomers are exposed to ultraviolet radiation. The solute polymers can be formed from the solvent monomers in situ or be added thereto to form the syrup.
摘要翻译： PCT No.PCT / US95 / 09601 Sec。 371日期1995年8月23日 102（e）日期1996年8月23日PCT提交1995年7月28日PCT公布。 出版物WO96 / 04346 日期1996年2月15日溶剂单体中的溶剂聚合物形成可涂覆的糖浆，当聚合物或单体之一中的辐射敏感的α-分离基团暴露于紫外线辐射时，其可以固化成粘弹性材料。 溶质聚合物可以由溶剂单体原位形成或加入其中形成糖浆。
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公开(公告)号：US4618525A
公开(公告)日：1986-10-21
申请号：US740577
申请日：1985-06-03
IPC分类号： C09J7/02 , C03B19/10 , C03C17/06 , C03C17/22 , C03C17/23 , C04B20/10 , C08J9/32 , C09C1/28 , C09C1/40 , B32B3/00
CPC分类号： C08J9/32 , C03B19/108 , C03C17/06 , C03C17/22 , C03C17/225 , C03C17/23 , C04B20/1055 , C09C1/28 , C09C1/405 , C01P2004/61 , C01P2004/80 , C01P2006/10 , C01P2006/12 , C01P2006/22 , C01P2006/60 , C03C2217/211 , C03C2217/214 , C03C2217/251 , C03C2217/26 , C03C2217/281 , C03C2217/282 , Y10T428/24917 , Y10T428/24926 , Y10T428/252 , Y10T428/261 , Y10T428/265 , Y10T428/2996
摘要： The invention concerns glass microbubbles having an inorganic thin-film coating not exceeding about 10 nm in thickness, especially a coating of a metal, a metalloid, or an alloy thereof. When dispersed throughout a matrix such as a polymer, the coated glass microbubbles can afford surprisingly good hiding power while also imparting esthetically pleasing colors to otherwise transparent articles.
摘要翻译： 本发明涉及具有不超过约10nm的无机薄膜涂层的玻璃微泡，特别是金属，准金属或其合金的涂层。 当分散在诸如聚合物的基质中时，涂覆的玻璃微泡可以提供令人惊讶的好的遮盖力，同时还赋予其他透明制品美观的颜色。
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公开(公告)号：US5446270A
公开(公告)日：1995-08-29
申请号：US180448
申请日：1994-01-12
申请人： Craig S. Chamberlain , Glen Connell , Pierre H. LePere , Chris A. Minick , Charlotte M. Palmgren , William C. Tait , George F. Vesley , Patrick G. Zimmerman
发明人： Craig S. Chamberlain , Glen Connell , Pierre H. LePere , Chris A. Minick , Charlotte M. Palmgren , William C. Tait , George F. Vesley , Patrick G. Zimmerman
CPC分类号： B65D81/3446 , B29C65/1425 , B29C65/4815 , B29C65/486 , B29C65/524 , B65D2581/3443 , B65D2581/3445 , B65D2581/3448 , B65D2581/3464 , B65D2581/3472 , B65D2581/3475 , B65D2581/3479 , B65D2581/3494 , Y10S99/14 , Y10T428/24901 , Y10T428/2991
摘要： Composition comprising (a) susceptors having the capability of absorbing microwave energy, said susceptors comprising a particulate substrate substantially non-reflective of microwave energy and a coating capable of absorbing microwave energy, and (b) a matrix substantially non-reflective of microwave energy. Susceptors are typically particles having a thin-film coating thereon. The matrix typically comprises polymeric or ceramic materials that are stable at temperatures conventionally used in microwave cooking. The composition allows reuse of the susceptors, eliminates decline in heating rate, eliminates arcing, allows the heating rate to be controlled, allows overheating to be controlled, and allows formation of microwave heatable composite materials having very low metal content.
摘要翻译： 组合物包括（a）具有吸收微波能量的能力的感受体，所述感受体包括基本上不反射微波能量的颗粒基质和能够吸收微波能量的涂层，以及（b）基本上不反射微波能量的基质。 感染剂通常是其上具有薄膜涂层的颗粒。 基质通常包含在微波烹饪中常规使用的温度下稳定的聚合物或陶瓷材料。 组合物允许再利用感受体，消除加热速率的下降，消除电弧，允许控制加热速率，允许过热控制，并允许形成具有非常低的金属含量的微波可加热复合材料。
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公开(公告)号：US4950537A
公开(公告)日：1990-08-21
申请号：US314479
申请日：1989-02-22
IPC分类号： C08K9/12 , C09C1/00 , C09J4/02 , C09J7/02 , C09J133/08
CPC分类号： C08K9/12 , C09C1/0081 , C09J133/08 , C09J7/0207 , C09J7/0217 , C01P2002/84 , C01P2004/50 , C01P2004/61 , C01P2004/80 , C01P2004/84 , C01P2006/10 , C01P2006/60 , C01P2006/62 , C01P2006/63 , C01P2006/64 , C08L2205/20 , C09J2201/606 , C09J2205/11 , Y10T428/28 , Y10T428/2809 , Y10T428/2848 , Y10T428/2887 , Y10T428/2891
摘要： The invention relates to a foamlike pressure-sensitive adhesive tape comprising a flexible carrier supporting one or more pressure-sensitive adhesive layers, at least one layer of the pressure-sensitive adhesive having pigment-coated microbubbles dispersed therein having an average diameter from 5 to 200 micrometers, wherein the coat comprises pigment particle aggregates having an average pigment aggregate size being from about 0.5 microns to about 5 microns.The invention further relates to pigment-coated microbubbles, and to a method for making coated microbubbles involving rolling the pigment and the microbubbles in a cylindrical container with two or more mixing rods having lengths at least about equal to the interior diameter of the container, and a combined surface area at least about 5% of the interior surface area of the container.
摘要翻译： 本发明涉及一种泡沫状压敏粘合带，其包括支撑一个或多个压敏粘合剂层的柔性载体，至少一层压敏粘合剂，其中分散有颜料涂覆的微泡，平均直径为5至200 微米，其中该涂层包含平均颜料聚集体尺寸为约0.5微米至约5微米的颜料颗粒聚集体。 本发明还涉及涂覆有颜料的微泡，以及一种制造包覆微泡的方法，其涉及将具有两个或更多个具有至少大约等于容器内径的长度的混合杆的圆柱形容器中的颜料和微泡滚动，以及 组合表面积为容器内表面积的至少约5％。
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公开(公告)号：US4612242A
公开(公告)日：1986-09-16
申请号：US740576
申请日：1985-06-03
CPC分类号： C09J7/0207 , Y10S428/906 , Y10T428/249974 , Y10T428/249984 , Y10T428/249986 , Y10T428/252 , Y10T428/261 , Y10T428/265 , Y10T428/2996
摘要： The invention primarily concerns a pressure-sensitive adhesive tape, the adhesive layer of which is filled with glass microbubbles and has a dark appearance by virtue of the microbubbles having a thin-film coating having an average thickness from 0.05 to 30 nm. A preferred thin-film coating is silver which can be applied by sputtering or by vapor deposition, preferably to an average thickness of between 1 and 10 nm.
摘要翻译： 本发明主要涉及粘合剂层被玻璃微泡填充的粘合带，并且由于具有平均厚度为0.05至30nm的薄膜涂层的微泡具有黑色外观。 优选的薄膜涂层是银，其可以通过溅射或通过气相沉积施加，优选平均厚度为1至10nm。
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7.发明授权Energy curable cationcally and free-radically polymerizable pressure-sensitive compositions 失效能量可固化的阳离子和可自由基聚合的压敏组合物
公开(公告)号：US5521227A
公开(公告)日：1996-05-28
申请号：US400459
申请日：1995-03-07
申请人： Michael C. Palazzotto , Henry B. Clark , George F. Vesley , Jerry W. Williams , Patrick G. Zimmerman
发明人： Michael C. Palazzotto , Henry B. Clark , George F. Vesley , Jerry W. Williams , Patrick G. Zimmerman
IPC分类号： C08F2/50 , C08F2/46 , C08F2/54 , C08G59/40 , C08G59/68 , C08K5/00 , C08L63/00 , C09J4/00 , C09J4/02 , C09J7/02 , C09J133/04 , C09J163/00
CPC分类号： C08K5/0091 , C08G59/68 , C09J133/04 , C08L63/00 , C09J2201/606
摘要： The present invention provides a pressure-sensitive adhesive composition and a method for producing the same. The pressure-sensitive adhesive composition is produced by the combination of at least one free-radically photopolymerizable monomer and at least one cationically polymerizable monomer and a suitable photoinitiation system consisting of at least one salt of a cationic organometallic complex, an optional additional free-radical initiator and the application of sufficient energy to photopolymerize same.
摘要翻译： 本发明提供一种压敏粘合剂组合物及其制造方法。 通过组合至少一种可自由基光聚合的单体和至少一种阳离子可聚合单体和由至少一种阳离子有机金属络合物盐，任选的另外的自由基组成的光引发剂体系来制备压敏粘合剂组合物 引发剂和应用足够的能量进行光聚合相同。
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公开(公告)号：US5462797A
公开(公告)日：1995-10-31
申请号：US193518
申请日：1994-02-08
IPC分类号： C08F283/00 , C08G18/22 , C08G18/63 , C09J4/02 , C09J175/00 , C09J175/04 , B32B7/12 , C09J133/08
CPC分类号： C09J175/04 , C08F283/006 , C08G18/22 , C08G18/637 , C08G2170/40 , Y10T428/2809 , Y10T428/2852
摘要： The present invention provides a pressure-sensitive adhesive composition and a method for producing the same. The pressure-sensitive adhesive composition is produced by the combination of at least one free-radically photopolymerizable monomer and at least one set of polyurethane precursors, and a suitable photoinitiation system consisting of at least one salt of a cationic organometallic complex, an additional free-radical photo initiator and the application of sufficient energy to photopolymerize same by sequential exposure to visible electromagnetic radiation and then to ultraviolet electromagnetic radiation.
摘要翻译： 本发明提供一种压敏粘合剂组合物及其制造方法。 通过组合至少一种可自由基光聚合的单体和至少一组聚氨酯前体以及由至少一种阳离子有机金属络合物的盐，另外的自由基聚合的前体组合的光引发剂体系， 自由基光引发剂和足够的能量通过顺序地暴露于可见电磁辐射然后进行紫外线电磁辐射而使其光聚合。
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公开(公告)号：US5294763A
公开(公告)日：1994-03-15
申请号：US588591
申请日：1990-09-26
申请人： Craig S. Chamberlain , Glen Connell , Pierre H. LePere , Chris A. Minick , Charlotte M. Palmgren , William C. Tait , George F. Vesley , Patrick G. Zimmerman
发明人： Craig S. Chamberlain , Glen Connell , Pierre H. LePere , Chris A. Minick , Charlotte M. Palmgren , William C. Tait , George F. Vesley , Patrick G. Zimmerman
CPC分类号： B65D81/3446 , B29C65/1425 , B29C65/4815 , B29C65/486 , B29C65/524 , B65D2581/3443 , B65D2581/3445 , B65D2581/3448 , B65D2581/3464 , B65D2581/3472 , B65D2581/3475 , B65D2581/3479 , B65D2581/3494 , Y10S99/14 , Y10T428/24901 , Y10T428/2991
摘要： Composition comprising (a) susceptors having the capability of absorbing microwave energy, and (b) a matrix substantially non-reflective of microwave energy. The susceptors comprise a particulate substrate having a thin-film coating thereon. The particulate substrate is substantially non-reflective of microwave energy and the coating is capable of absorbing microwave energy. The matrix typically comprises polymeric or ceramic materials that are stable at temperatures conventionally used in microwave cooking. The composition allows reuse of the susceptors, eliminates decline in heating rate, eliminates arcing, allows the heating rate to be controlled, allows overheating to be controlled, and allows formation of microwave heatable composite materials having very low metal content.
摘要翻译： 组合物包含（a）具有吸收微波能量能力的感受体，和（b）基本上不反射微波能量的基质。 感受体包括其上具有薄膜涂层的颗粒基底。 颗粒基质基本上不反射微波能量，并且涂层能够吸收微波能量。 基质通常包含在微波烹饪中常规使用的温度下稳定的聚合物或陶瓷材料。 组合物允许再利用感受体，消除加热速率的下降，消除电弧，允许控制加热速率，允许过热控制，并允许形成具有非常低的金属含量的微波可加热复合材料。
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10.发明授权Multi-stage irradiation process for production of acrylic based adhesives and adhesives made thereby 失效用于生产丙烯酸类粘合剂和由此制成的粘合剂的多级照射方法公开(公告)号：US06436532B1
公开(公告)日：2002-08-20
申请号：US09761370
申请日：2001-01-16
申请人： John D. Moon , Louise A. Ziegler , George F. Vesley , Robert C. Mehner , Mark S. Edberg , Robert D. Anderson
发明人： John D. Moon , Louise A. Ziegler , George F. Vesley , Robert C. Mehner , Mark S. Edberg , Robert D. Anderson
IPC分类号： B32B2716
CPC分类号： C09J4/00 , C08F2/46 , C08F2/48 , C08F20/12 , C09J7/385 , C09J2433/00 , Y10T428/2891 , C08F220/10
摘要： Disclosed is a novel, multi-stage irradiation process for the production of an acrylic-based adhesive or pressure-sensitive adhesive tape. The first irradiation step or stage employs electromagnetic radiation at a relatively low average intensity (i.e., 0.1 to 20 mW/cm2) and the subsequent step employs electromagnetic radiation at a relatively higher average intensity (i.e., greater than 20 mW/cm2.) Also disclosed are acrylic-based psa tape materials made by the novel process.
摘要翻译： 公开了用于生产丙烯酸类粘合剂或压敏粘合带的新颖的多级照射方法。 第一照射步骤或阶段采用相对低的平均强度（即0.1至20mW / cm 2）的电磁辐射，随后的步骤采用相对较高的平均强度（即大于20mW / cm 2）的电磁辐射。 公开了通过新颖方法制造的基于丙烯酸的psa胶带材料。
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