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    Phosphor and optical device using same
    61.
    发明申请
    Phosphor and optical device using same 有权
    荧光体和光学器件使用相同

    公开(公告)号：US20070035813A1

    公开(公告)日：2007-02-15

    申请号：US10539248

    申请日：2003-12-19

    Applicant: Gundula Roth ,  Walter Tews

    Inventor： Gundula Roth ,  Walter Tews

    IPC: G06K7/10

    CPC classification number: C09K11/757 ,  C09K11/0844 ,  C09K11/0894 ,  C09K11/592 ,  C09K11/595 ,  C09K11/643 ,  C09K11/666 ,  C09K11/753 ,  C09K11/756 ,  C09K11/7734 ,  C09K11/7735 ,  C09K11/7737 ,  C09K11/7739 ,  H01L2224/16145 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/48257 ,  Y02B20/181 ,  H01L2924/00014

    Abstract: A phosphor for converting ultraviolet light or blue light emitted from a light emitting element into a visible white radiation having a high level of color rendering properties, containing a light emitting component prepared from a solid system of an alkaline earth metal antimonate and a system derived from the solid system and exhibiting intrinsic photoemission, such as a fluoroantimonate, a light emitting component prepared from a manganese(IV)-activated antimonate, a titanate, silicate-germanate, and an aluminate, a light emitting component prepared from a europium-activated silicate-germanate or from a system containing a sensitizer selected from a group consisting of europium (II) and manganese (II) as a secondary activator and having an orange color or a dark red color in the spectrum range over 600 nm, or a light emitting component composed of a mixture of eight or less light emitting components having different emission bands and brought to a state of continuous emission of about 380 to 780 nm exhibiting a color temperature of about 10,000 to 6,500 K and a color temperature of about 3,000 to 2,000 K by virtue of the superposition of the light emitting bands.

    Abstract translation: 一种用于将从发光元件发射的紫外光或蓝光转换成具有高显色性能的可见白色辐射的荧光体，其包含由碱土金属锑酸盐的固体体系制备的发光组分和衍生自 固体系统和显示内在的光电子发射，例如氟锑酸盐，由锰（Ⅳ）活化的锑酸盐，钛酸盐，硅酸盐 - 锗酸盐和铝酸盐制备的发光组分，由铕活化的硅酸盐制备的发光组分 或含有选自铕（II）和锰（II）的敏化剂作为二次活化剂并且在600nm以上的光谱范围内具有橙色或深红色的系统的体系，或发光 由具有不同发射带的八个或更少发光组件的混合物组成的组分，并且达到连续发射的状态 通过发光带的叠加，显示色温为约10,000至6,500K，色温为约3,000至2,000K的380至780nm。

    Luminescent substances having Eu2+-doped silicate luminophores
    65.
    发明授权
    Luminescent substances having Eu2+-doped silicate luminophores 有权
    具有Eu2 +掺杂硅酸盐发光体的发光物质

    公开(公告)号：US08703014B2

    公开(公告)日：2014-04-22

    申请号：US12773514

    申请日：2010-05-04

    Applicant: Chung Hoon Lee ,  Walter Tews ,  Gundula Roth ,  Detlef Starick

    Inventor： Chung Hoon Lee ,  Walter Tews ,  Gundula Roth ,  Detlef Starick

    IPC: C09K11/08 ,  C09K11/66

    CPC classification number: C09K11/7792 ,  H05B33/14 ,  Y02B20/181

    Abstract: Exemplary embodiments of the present invention disclose inorganic luminescent substances with Eu2+-doped silicate luminophores, in which solid solutions in the form of mixed phases between alkaline earth metal oxyorthosilicates and rare earth metal oxyorthosilicates are used as base lattices for the Eu2+ activation leading to the luminescence. These luminophores are described by the general formula (1-x) MII3SiO5.xSE2SiO5:Eu, in which MII preferably represents strontium ion or another alkaline earth metal ion, or another divalent metal ion selected from the group consisting of the magnesium, calcium, barium, copper, zinc, and manganese. These ions may be used in addition to strontium and also as mixtures with one another.

    Abstract translation: 本发明的示例性实施方案公开了具有Eu 2+掺杂的硅酸盐发光体的无机发光物质，其中使用碱土金属氧化硅酸钙和稀土金属氧化硅酸盐之间的混合相形式的固溶体作为用于Eu 2+活化的基底晶格，导致发光 。 这些发光体由通式（1-x）MII3SiO5.xSE2SiO5：Eu表示，其中MII优选表示锶离子或另一碱土金属离子，或另外选自镁，钙，钡的二价金属离子 ，铜，锌和锰。 这些离子除了锶之外还可以彼此混合使用。

    Light emitting device employing non-stoichiometric tetragonal alkaline earth silicate phosphors
    66.
    发明授权
    Light emitting device employing non-stoichiometric tetragonal alkaline earth silicate phosphors 有权
    采用非化学计量的四方碱土金属硅酸盐荧光体的发光器件

    公开(公告)号：US08431954B2

    公开(公告)日：2013-04-30

    申请号：US13363130

    申请日：2012-01-31

    Applicant: Chung Hoon Lee ,  Walter Tews ,  Gundula Roth ,  Stefan Tews

    Inventor： Chung Hoon Lee ,  Walter Tews ,  Gundula Roth ,  Stefan Tews

    IPC: H01L33/00

    CPC classification number: H01L33/502 ,  C09K11/7734 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/73265 ,  H01L2224/8592 ,  H01L2924/181 ,  H01L2924/19107 ,  H05B33/14 ,  H01L2924/00014 ,  H01L2924/00012

    Abstract: Disclosed is a light emitting device employing non-stoichiometric tetragonal Alkaline Earth Silicate phosphors. The light emitting device comprises a light emitting diode emitting light of ultraviolet or visible light, and non-stoichiometric luminescent material disposed around the light emitting diode. The luminescent material adsorbs at least a portion of the light emitted from the light emitting diode and emits light having a different wavelength from the absorbed light. The non-stoichiometric luminescent material has tetragonal crystal structure, and contains more silicon in the crystal lattice than that in the crystal lattice of silicate phosphors having stoichiometric crystal structure. The luminescent material is represented as the formula (BauSrvCawCux)3-y(Zn,Mg,Mn)zSi1+bO5+2b:Eua. Light emitting devices having improved temperature and humidity stability can be provided by employing the non-stoichiometric tetragonal Alkaline Earth Silicate phosphors.

    Abstract translation: 公开了采用非化学计量的四方碱性硅酸盐磷光体的发光器件。 发光装置包括发射紫外线或可见光的发光二极管和设置在发光二极管周围的非化学计量的发光材料。 发光材料吸收从发光二极管发射的光的至少一部分，并发射与吸收光不同的波长的光。 非化学计量的发光材料具有四方晶体结构，并且在晶格中含有比在具有化学计量晶体结构的硅酸盐荧光体的晶格中更多的硅。 发光材料表示为式（BauSrvCawCux）3-y（Zn，Mg，Mn）zSi1 + bO5 + 2b：Eua。 具有改善的温度和湿度稳定性的发光器件可以通过使用非化学计量的四方碱性碱土硅酸盐荧光体来提供。

    Non stoichiometric tetragonal copper alkaline earth silicate phosphors and method of preparing the same
    68.
    发明授权
    Non stoichiometric tetragonal copper alkaline earth silicate phosphors and method of preparing the same 有权
    非化学计量的四方铜碱土金属硅酸盐荧光粉及其制备方法

    公开(公告)号：US08137589B2

    公开(公告)日：2012-03-20

    申请号：US12196923

    申请日：2008-08-22

    Applicant: Chung Hoon Lee ,  Walter Tews ,  Gundula Roth ,  Stefan Tews

    Inventor： Chung Hoon Lee ,  Walter Tews ,  Gundula Roth ,  Stefan Tews

    IPC: C09K11/70 ,  C09K11/02

    CPC classification number: C09K11/7734 ,  Y02B20/181

    Abstract: Disclosed are non stoichiometric Copper Alkaline Earth Silicate phosphors activated by divalent europium for using them as high temperature stable luminescent materials for ultraviolet or daylight excitation. The phosphors are represented as the formula (BauSrvCawCux)3−y(Zn,Mg,Mn)zSi1+bO5+2b:Eua. The nonstoichiometric tetragonal silicate is prepared in a high temperature solid state reaction with a surplus of silica in the starting mixture. Furthermore, luminescent tetragonal Copper Alkaline Earth Silicates are provided for LED applications, which have a high color temperature range from about 2,000K to 8,000K or 10,000K showing a CRI with Ra=80˜95, when mixed with other luminescent materials.

    Abstract translation: 公开了由二价铕活化的非化学计量的铜碱土硅酸盐荧光体，用于将其用作用于紫外线或日光激发的高温稳定发光材料。 磷光体用式（BauSrvCawCux）3-y（Zn，Mg，Mn）zSi1 + bO5 + 2b：Eua表示。 非化学计量的四方硅酸盐在起始混合物中与多余二氧化硅的高温固相反应制备。 此外，与其他发光材料混合时，为LED应用提供发光四方铜碱土硅酸盐，其具有约2,000K至8,000K或10,000K的高色温，其表现出Ra = 80〜95的CRI。

    Light emitting device employing non-stoichiometric tetragonal alkaline earth silicate phosphors
    69.
    发明授权
    Light emitting device employing non-stoichiometric tetragonal alkaline earth silicate phosphors 有权
    采用非化学计量的四方碱土金属硅酸盐荧光体的发光器件

    公开(公告)号：US08134165B2

    公开(公告)日：2012-03-13

    申请号：US12440001

    申请日：2008-08-14

    Applicant: Chung Hoon Lee ,  Walter Tews ,  Gundula Roth ,  Stefan Tews

    Inventor： Chung Hoon Lee ,  Walter Tews ,  Gundula Roth ,  Stefan Tews

    IPC: H01L29/20

    CPC classification number: H01L33/502 ,  C09K11/7734 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/73265 ,  H01L2224/8592 ,  H01L2924/181 ,  H01L2924/19107 ,  H05B33/14 ,  H01L2924/00014 ,  H01L2924/00012

    Abstract: Disclosed is a light emitting device employing non-stoichiometric tetragonal Alkaline Earth Silicate phosphors. The light emitting device comprises a light emitting diode emitting light of ultraviolet or visible light, and non-stoichiometric luminescent material disposed around the light emitting diode. The luminescent material adsorbs at least a portion of the light emitted from the light emitting diode and emits light having a different wavelength from the absorbed light. The non-stoichiometric luminescent material has tetragonal crystal structure, and contains more silicon in the crystal lattice than that in the crystal lattice of silicate phosphors having stoichiometric crystal structure. The luminescent material is represented as the formula (BauSrvCawCux)3−y(Zn,Mg,Mn)zSi1+bO5+2b:Eua. Light emitting devices having improved temperature and humidity stability can be provided by employing the non-stoichiometric tetragonal Alkaline Earth Silicate phosphors.

    Abstract translation: 公开了采用非化学计量的四方碱性硅酸盐磷光体的发光器件。 发光装置包括发射紫外线或可见光的发光二极管和设置在发光二极管周围的非化学计量的发光材料。 发光材料吸收从发光二极管发射的光的至少一部分，并发射与吸收光不同的波长的光。 非化学计量的发光材料具有四方晶体结构，并且在晶格中含有比在具有化学计量晶体结构的硅酸盐荧光体的晶格中更多的硅。 发光材料表示为式（BauSrvCawCux）3-y（Zn，Mg，Mn）zSi1 + bO5 + 2b：Eua。 具有改善的温度和湿度稳定性的发光器件可以通过使用非化学计量的四方碱性碱土硅酸盐荧光体来提供。

    Luminescent material
    70.
    发明授权
    Luminescent material 有权
    发光材料

    公开(公告)号：US08070984B2

    公开(公告)日：2011-12-06

    申请号：US11948813

    申请日：2007-11-30

    Applicant: Gundula Roth ,  Walter Tews ,  Chung-Hoon Lee

    Inventor： Gundula Roth ,  Walter Tews ,  Chung-Hoon Lee

    IPC: C09K11/08

    CPC classification number: C09K11/7734 ,  C09K11/58 ,  C09K11/592 ,  C09K11/66 ,  C09K11/665 ,  C09K11/666 ,  C09K11/7457 ,  C09K11/753 ,  C09K11/756 ,  C09K11/757 ,  C09K11/758 ,  C09K11/7706 ,  C09K11/7707 ,  C09K11/7709 ,  C09K11/7714 ,  C09K11/7735 ,  C09K11/7737 ,  C09K11/7738 ,  C09K11/7739 ,  C09K11/774 ,  C09K11/7742 ,  C09K11/7783 ,  C09K11/7792

    Abstract: A luminescent material is disclosed. The luminescent material may include a first compound having a host lattice comprising first ions and oxygen. A first portion of the first ions may be substituted by copper ions. In one embodiment, the host lattice may include silicon, the copper ions may be divalent copper ions and the first compound may have an Olivin crystal structure, a β-K2SO4 crystal structure, a trigonal Glaserite (K3Na(SO4)2) or monoclinic Merwinite crystal structure, a tetragonal Ackermanite crystal structure, a tetragonal crystal structure or an orthorhombic crystal structure. In another embodiment, the copper ions do not act as luminescent ions upon excitation with the ultraviolet or visible light.

    Abstract translation: 公开了一种发光材料。 发光材料可以包括具有包含第一离子和氧的主晶格的第一化合物。 第一离子的第一部分可以被铜离子取代。 在一个实施方案中，主晶格可以包括硅，铜离子可以是二价铜离子，并且第一化合物可以具有奥利文晶体结构，一种二氧化硅晶体结构，一种三角形的镓硅酸盐（K3Na（SO4）2））或单斜晶体 Merwinite晶体结构，四方晶系晶体结构，四方晶体结构或正交晶体结构。 在另一个实施方案中，当用紫外线或可见光激发时，铜离子不作为发光离子。

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