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    Quinoline-3-carboxamides, their manufacture and use
    62.
    发明授权
    Quinoline-3-carboxamides, their manufacture and use 失效
    喹啉-3-甲酰胺，其制造和使用

    公开(公告)号：US5972841A

    公开(公告)日：1999-10-26

    申请号：US988765

    申请日：1997-12-11

    Applicant: Wolfgang von Deyn ,  Hans Theobald ,  Christoph Nuebling ,  Uwe Kardorff ,  Helmut Walter ,  Karl-Otto Westphalen ,  Thomas Kappe ,  Matthias Gerber

    Inventor： Wolfgang von Deyn ,  Hans Theobald ,  Christoph Nuebling ,  Uwe Kardorff ,  Helmut Walter ,  Karl-Otto Westphalen ,  Thomas Kappe ,  Matthias Gerber

    IPC: A01N43/42 ,  C07D215/56

    CPC classification number: A01N43/42 ,  C07D215/56

    Abstract: Quinoline-3-carboxamides I ##STR1## where R.sup.1 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, and the organic radicals may be substituted or unsubstituted;R.sup.2 is hydrogen, hydroxyl, alkoxy, alkenyloxy, dialkylamino, alkyl, alkenyl, alkynyl, cycloalkyl, and the organic radicals may be substituted or unsubstituted;orR.sup.1, R.sup.2 together denote an alkylene chain of 4 to 7 members and which may be interrupted by oxygen, sulfur or N-methyl;R.sup.3 -R.sup.6 are hydrogen, alkyl, alkoxy, haloalkyl, haloalkoxy, alkylthio, haloalkylthio, halogen, cyano or nitro;X is oxygen or sulfur;with the proviso that R.sup.2 is not hydrogen, C.sub.1 -C.sub.3 -alkyl, n-butyl, 3-methylbutyl, cyclohexyl, hexyl, heptyl, octyl, 2-chlorobenzyl, 3-(dimethylamino)propyl, 3-(diethylamino)propyl, 2-morpholinoethyl or 2-(3,4-dimethoxyphenyl)ethyl when R.sup.1 and R.sup.3 to R.sup.6 are hydrogen and X is oxygen, and that R.sup.2 is not benzyl when R.sup.1 is methyl, R.sup.3 to R.sup.6 are hydrogen and X is oxygen, and that R.sup.1 and R.sup.2 do not jointly denote morpholino when R.sup.3 to R.sup.6 are hydrogen and X is oxygen.

    Abstract translation: 其中R 1是氢，烷基，烯基，炔基，环烷基和有机基团的喹啉-3-甲酰胺I可以是取代或未取代的; R2是氢，羟基，烷氧基，烯氧基，二烷基氨基，烷基，烯基，炔基，环烷基，有机基可以是取代或未取代的; 或R 1，R 2一起表示4至7个成员的亚烷基链，并且可被氧，硫或N-甲基中断; R3-R6是氢，烷基，烷氧基，卤代烷基，卤代烷氧基，烷硫基，卤代烷硫基，卤素，氰基或硝基; X是氧或硫; 条件是R2不是氢，C1-C3-烷基，正丁基，3-甲基丁基，环己基，己基，庚基，辛基，2-氯苄基，3-（二甲基氨基）丙基，3-（二乙基氨基）丙基， 当R 1和R 3至R 6为氢且X为氧时，R 2为苄基，R 3为R 6为氢，X为氧时，R 2为苄基， 当R 3至R 6为氢且X为氧时，R 2不共同表示吗啉代。

    Subtituted lactic acid derivatives having an N-organic radical in the .beta .
    63.
    发明授权
    Subtituted lactic acid derivatives having an N-organic radical in the .beta . 失效
    在β位具有N-有机基团的取代的乳酸衍生物

    公开(公告)号：US5750469A

    公开(公告)日：1998-05-12

    申请号：US605141

    申请日：1996-03-01

    Applicant: Ernst Baumann ,  Joachim Rheinheimer ,  Uwe Josef Vogelbacher ,  Matthias Gerber ,  Wilhelm Rademacher ,  Helmut Walter ,  Karl-Otto Westphalen

    Inventor： Ernst Baumann ,  Joachim Rheinheimer ,  Uwe Josef Vogelbacher ,  Matthias Gerber ,  Wilhelm Rademacher ,  Helmut Walter ,  Karl-Otto Westphalen

    IPC: C07D239/28 ,  A01N25/32 ,  A01N35/10 ,  A01N43/54 ,  A01N43/90 ,  A01N47/12 ,  C07C229/34 ,  C07C233/47 ,  C07C247/12 ,  C07C251/42 ,  C07D239/34 ,  C07D239/60 ,  C07D401/12

    CPC classification number: C07D401/12 ,  A01N25/32 ,  A01N43/54 ,  C07C229/34 ,  C07C233/47 ,  C07C247/12 ,  C07C251/42 ,  C07D239/60 ,  C07C2101/16

    Abstract: Substituted lactic acid derivatives having an N-organic radical in the .beta.-position, of the formula I ##STR1## where substituents R to R.sup.5, X and Y have the meanings mentioned in the description and N is one of the radicals: a) --N.sub.3, --NC, --NCS or --NCO b) ##STR2## where R.sup.14 and R.sup.15 have the meanings described in the description c) ##STR3## in which R.sup.16 is hydrogen, alkyl, haloalkyl, alkenyl, alkynyl, cycloalkyl or unsubstituted or substituted phenyl; and B is a group ##STR4## OR.sup.19 or --NR.sup.14 R.sup.15, where R.sup.14, R.sup.15, R.sup.17 and R.sup.19 have the meanings described in the description, or ##STR5## where R.sup.14 and R.sup.15.sub.1, have the abovementioned meanings; or ##STR6## where R.sup.20 and R.sup.21, which can be identical or different, are: hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl or phenyl, where the organic radicals can in each case be substituted; or R.sup.20 and R.sup.21 together form an unsubstituted or substituted C.sub.4 -C.sub.7 -alkylene chain which is closed to give a ring or together form an unsubstituted or substituted C.sub.3 -C.sub.6 -alkylene chain which is closed to give a ring and has a heteroatom selected from the group consisting of oxygen, sulfur and nitrogen are described.

    Abstract translation: PCT No.PCT / EP94 / 02825 Sec。 371日期1996年3月1日 102（e）1996年3月1日PCT 1994年9月25日PCT公布。 公开号WO95 / 07266 日期1995年3月16日在β位具有N-有机基团的式I的取代的乳酸衍生物，其中取代基R至R5，X和Y具有说明书中提到的含义，+ E，crc N + EE是自由基之一：a）-N3，-NC，-NCS或-NCO b）其中R14和R15具有其中R 16是氢的描述c）＆lt; IMAGE＆gt;中描述的含义，烷基 ，卤代烷基，烯基，炔基，环烷基或未取代或取代的苯基; 并且B是一个 OR 19或-NR 14 R 15基团，其中R 14，R 15，R 17和R 19具有说明书中描述的含义，或者其中R14和R151具有上述含义的 或者其中可以相同或不同的R20和R21是：氢，烷基，烯基，炔基，环烷基或苯基，其中有机基团可以在每种情况下被取代; 或R 20和R 21一起形成未取代或取代的C 4 -C 7亚烷基链，其被封闭以形成环或一起形成未取代或取代的C3-C6-亚烷基链，其闭合以产生环并且具有选自以下的杂原子 描述了由氧，硫和氮组成的组。

    Saccharin derivatives
    64.
    发明授权
    Saccharin derivatives 失效
    糖精衍生物

    公开(公告)号：US5716905A

    公开(公告)日：1998-02-10

    申请号：US776568

    申请日：1997-02-03

    Applicant: Peter Plath ,  Wolfgang von Deyn ,  Stefan Engel ,  Uwe Kardorff ,  Christoph Nubling ,  Hartmann Konig ,  Harald Rang ,  Matthias Gerber ,  Helmut Walter ,  Karl-Otto Westphalen

    Inventor： Peter Plath ,  Wolfgang von Deyn ,  Stefan Engel ,  Uwe Kardorff ,  Christoph Nubling ,  Hartmann Konig ,  Harald Rang ,  Matthias Gerber ,  Helmut Walter ,  Karl-Otto Westphalen

    IPC: C07D275/04 ,  A01N43/80 ,  C07D275/06

    CPC classification number: C07D275/06 ,  A01N43/80

    Abstract: Saccharin derivatives of the formula I ##STR1## where the substituents have the following meanings: L and M are hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, chlorine, cyano, methylsulfonyl, nitro or trifluoromethyl; Z is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.5 -alkynyl, C.sub.1 -C.sub.4 -acyl, benzyl or phenyl, the phenyl rings being unsubstituted or substituted by halogen or C.sub.1 -C.sub.4 -alkyl; R.sup.1 is cyclopropyl, 1-methylcyclopropyl, 1-methylthiocyclopropyl or tert-butyl; and agriculturally customary salts of the compounds I are described.

    Abstract translation: PCT No.PCT / EP95 / 02977。 371日期1997年2月3日 102（e）日期1997年2月3日PCT提交1995年7月27日PCT公布。 出版物WO96 / 05183 日期：1996年2月22日式Ⅰ的糖精衍生物其中取代基具有下列含义：L和M是氢，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，氯，氰基 ，甲基磺酰基，硝基或三氟甲基; Z是氢，C 1 -C 4 - 烷基，C 3 -C 8 - 环烷基，C 3 -C 6 - 烯基，C 3 -C 5炔基，C 1 -C 4酰基，苄基或苯基，苯环是未取代的或被卤素或C1- C4-烷基; R1是环丙基，1-甲基环丙基，1-甲硫基环丙基或叔丁基; 并描述了化合物I的农业常规盐。

    Substituted N-phenylglutarimides and N-phenylglutaramides, their preparation and use
    65.
    发明授权
    Substituted N-phenylglutarimides and N-phenylglutaramides, their preparation and use 失效
    取代的N-苯基戊二酰胺和N-苯基戊二酰胺，其制备和用途

    公开(公告)号：US5698494A

    公开(公告)日：1997-12-16

    申请号：US428107

    申请日：1995-04-26

    Applicant: Ralf Klintz ,  Gerhard Hamprecht ,  Elisabeth Heistracher ,  Peter Schaefer ,  Uwe Kardorff ,  Karl-Otto Westphalen ,  Matthias Gerber ,  Helmut Walter

    Inventor： Ralf Klintz ,  Gerhard Hamprecht ,  Elisabeth Heistracher ,  Peter Schaefer ,  Uwe Kardorff ,  Karl-Otto Westphalen ,  Matthias Gerber ,  Helmut Walter

    IPC: A01N37/46 ,  A01N43/40 ,  C07C233/07 ,  C07C233/34 ,  C07C233/54 ,  C07C323/60 ,  C07C327/38 ,  C07D211/84 ,  C07D211/86 ,  C07D211/88 ,  C07D211/90 ,  C07D211/96 ,  C07D211/40 ,  C07D401/10

    CPC classification number: C07C233/54 ,  A01N37/46 ,  C07D211/84 ,  C07D211/88 ,  C07D211/90

    Abstract: Substituted N-phenylglutarimides I ##STR1## X.sup.1, X.sup.2 =O, S; R.sup.1 =halogen, NO.sub.2, CN, CF.sub.3 ; R.sup.2 =H, halogen; R.sup.3, R.sup.4, R.sup.5 =H, halogen, CN, alkyl, cyctoalkyl, alkenyl, alkynyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkyl-thio, cyanoalkyl, alkoxycarbonyl, unsubstituted or substituted phenyl or benzyl,or 2 substituents of a C atom or 2 substituents of adjacent C atoms of the glutarimide ring are bonded to one another via a chain which may be substituted; A=CHR.sup.6 --CHR.sup.7 --CO--B or CR.sup.6 .dbd.CR.sup.8 --CO--B; R.sup.6 =H, C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -haloalkyl; R.sup.7 =halogen, haloalkyl, OH, alkoxy or alkylcarbonyloxy; R.sup.8 =H, CN, alkyl, alkylcarbonyl, alkoxycarbonyl or B=H, alkyl, alkenyl, alkynyl, haloalkyl, cycloalkyl, alkoxy-alkyl, dialkoxyalkyl, alkylthioalkyl, alkoxy, alkylthio or amino, the last three radicals may be substituted, unsubstituted or functionalized; and plant-tolerable salts of I; their preparation and use as herbicides and desiccating/defoliating agents, and precursors for the preparation of the N-phenylglutarimides I.

    Abstract translation: PCT No.PCT / EP93 / 02879 371日期1995年04月26日 102（e）日期1995年4月26日PCT提交1993年10月19日PCT公布。 公开号WO94 / 10147 日期1994年5月11日取代的N-苯基戊二酰胺I X1，X2 = O，S; R1 =卤素，NO2，CN，CF3; R2 = H，卤素; R3，R4，R5 = H，卤素，CN，烷基，烷基，烷基，烯基，炔基，卤代烷基，烷氧基，卤代烷氧基，烷硫基，卤代烷基 - 硫代，氰基烷基，烷氧基羰基，未取代或取代的苯基或苄基，或2个C原子取代基 或戊二酰亚胺环的相邻C原子的2个取代基通过可被取代的链彼此键合; A = CHR6-CHR7-CO-B或CR6 = CR8-CO-B; R6 = H，C1-C6-烷基或C1-C6-卤代烷基; R7 =卤素，卤代烷基，OH，烷氧基或烷基羰基氧基; R8 = H，CN，烷基，烷基羰基，烷氧基羰基或B = H，烷基，烯基，炔基，卤代烷基，环烷基，烷氧基 - 烷基，二烷氧基烷基，烷硫基烷基，烷氧基，烷硫基或氨基，最后三个基团可以是取代的，未取代的或 功能化 和I的植物耐受性盐; 它们作为除草剂和干燥/脱叶剂的制备和用途，以及N-苯基戊二酰胺Ⅰ的制备前体。

    Cyclohexenone oxime ethers
    67.
    发明授权
    Cyclohexenone oxime ethers 失效
    环己烯酮肟醚

    公开(公告)号：US5604183A

    公开(公告)日：1997-02-18

    申请号：US523682

    申请日：1995-09-05

    Applicant: Ulf Misslitz ,  Norbert Meyer ,  Juergen Kast ,  Matthias Bratz ,  Albrecht Harreus ,  Helmut Walter ,  Karl-Otto Westphalen ,  Matthias Gerber

    Inventor： Ulf Misslitz ,  Norbert Meyer ,  Juergen Kast ,  Matthias Bratz ,  Albrecht Harreus ,  Helmut Walter ,  Karl-Otto Westphalen ,  Matthias Gerber

    IPC: A01N35/10 ,  A01N39/00 ,  C07C317/30 ,  C07C323/47 ,  C07D333/16 ,  C07D333/28 ,  C07C251/50 ,  C07C251/52

    CPC classification number: A01N39/00 ,  A01N35/10 ,  C07C317/30 ,  C07C323/47 ,  C07D333/16 ,  C07D333/28 ,  C07C2101/02 ,  C07C2101/14 ,  C07C2101/16

    Abstract: Cyclohexenone oxime ethers I ##STR1## where n is from 0 to 5, m is from 0 to 2, R.sup.1 is C.sub.1 -C.sub.6 -alkyl, R.sup.2 is C.sub.1 -C.sub.4 -alkyl or benzyl, A is unsubstituted or substituted C.sub.1 -C.sub.6 -alkylene, unsubstituted or substituted C.sub.3 -C.sub.6 -alkenylene, unsubstituted or substituted C.sub.3 -C.sub.6 -alkynylene or an unsubstituted or substituted C.sub.3 -C.sub.6 -alkylene or C.sub.4 -C.sub.6 -alkenylene chain, where in each case a methylene group may be replaced with O, S, SO, SO.sub.2 or --N(R.sup.a)--, R.sup.a is H, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl, Z is phenyl, a 5-membered heteroaromatic radical or a 6-membered heteroaromatic radical having from 1 to 4 nitrogen atoms, X is NO.sub.2, CN, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkoxy, COOH, C.sub.1 -C.sub.4 -alkoxycarbonyl, unsubstituted or substituted benzyloxycarbonyl, unsubstituted or substituted phenyl, unsubstituted or substituted pyridyl or --NR.sup.b R.sup.c, R.sup.b is H, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl and R.sup.c is H, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl, C.sub.1 -C.sub.6 -acyl or unsubstituted or substituted benzoyl, and the agriculturally useful salts and esters of C.sub.1 -C.sub.10 -carboxylic acids and inorganic acids are suitable as herbicides.

    Abstract translation: 环己烯酮肟醚I其中n为0至5，m为0至2，R 1为C 1 -C 6烷基，R 2为C 1 -C 4 - 烷基或苄基，A为未取代或取代的C 1 -C 6 - 亚烷基，未取代或取代的C 3 -C 6亚烯基，未取代或取代的C 3 -C 6亚炔基或未取代或取代的C 3 -C 6亚烷基或C 4 -C 6亚烯基链，其中在每种情况下亚甲基可以被O， S，SO，SO2或-N（Ra） - ，Ra是H，C1-C4-烷基，C3-C6-烯基或C3-C6-炔基，Z是苯基，5元杂芳族基团或6元 具有1至4个氮原子的杂芳族基团，X是NO 2，CN，卤素，C 1 -C 4烷基，C 1 -C 4卤代烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4卤代烷氧基，COOH， C 1 -C 4烷氧基羰基，未取代或取代的苄氧基羰基，未取代或取代的苯基，未取代或取代的吡啶基或-NRbRc，Rb是H，C1-C4-烷基，C3-C6-烯基或C3-C6-炔基，Rc是H， C 1 -C 4 - 烷基，C 3 -C 6 - 烯基，C 3 -C 6炔基，C 1 -C 6 - 酰基或不饱和的 取代或取代的苯甲酰基，C1-C10-羧酸和无机酸的农业上有用的盐和酯适合作为除草剂。

    Dicarboximides and their use as herbicides
    69.
    发明授权
    Dicarboximides and their use as herbicides 失效
    二酰亚胺及其作为除草剂的用途

    公开(公告)号：US5378680A

    公开(公告)日：1995-01-03

    申请号：US931951

    申请日：1992-08-19

    Applicant: Volker Maywald ,  Klaus Ditrich ,  Thomas Kuekenhoehner ,  Gerhard Hamprecht ,  Wolfgang Freund ,  Karl-Otto Westphalen ,  Matthias Gerber ,  Helmut Walter

    Inventor： Volker Maywald ,  Klaus Ditrich ,  Thomas Kuekenhoehner ,  Gerhard Hamprecht ,  Wolfgang Freund ,  Karl-Otto Westphalen ,  Matthias Gerber ,  Helmut Walter

    IPC: A01N43/76 ,  A01N43/78 ,  A01N43/80 ,  A01N43/90 ,  C07D498/04 ,  C07D499/04 ,  C07D513/04

    CPC classification number: C07D513/04 ,  A01N43/90

    Abstract: Dicarboximides of the formulae Ia, Ib and Ic ##STR1## where X is oxygen or sulfur,R.sup.1 is hydrogen, halogen, cyano, alkyl, cycloalkyl, alkenyl, alkynyl, alkoxy, alkenyloxy, alkynyloxy, alkylthio, haloalkoxy, haloalkylthio, alkylsulfonyl, haloalkylsulfonyl, phenyl, phenylalkyl, phenoxy or phenylthio, a 5-membered or 6-membered saturated or aromatic heterocyclic radical containing one or two hetero atoms selected from the group consisting of oxygen, sulfur and nitrogen, where the stated organic radicals may be further substituted, andR.sup.2 is hydrogen, hydroxyl, alkoxy, alkyl, cycloalkyl, alkenyl, alkynyl, di-C.sub.1 -C.sub.4 - alkylamino, a 5-membered or 6-membered heterocyclic saturated or aromatic radical having one or two hetero atoms selected from the group consisting of oxygen, sulfur and nitrogen, phenyl or naphthyl, where the stated organic radicals may be further substituted,and plant-tolerated salts of the dicarboximides I, except for 3-methylisoxazole-4,5-dicarboximide and thiazole-4,5-dicarboximides in which R.sup.2 is phenyl when R.sup.1 is methyl or 2-thiazolyl,and herbicides containing these compounds.

    Abstract translation: 其中X是氧或硫，R 1是氢，卤素，氰基，烷基，环烷基，烯基，炔基，烷氧基，烯氧基，炔氧基，烷氧基， 烷硫基，卤代烷氧基，卤代烷硫基，烷基磺酰基，卤代烷基磺酰基，苯基，苯基烷基，苯氧基或苯硫基，含有一个或两个选自氧，硫和氮的杂原子的5元或6元饱和或芳族杂环基团， 所述有机基团可以被进一步取代，并且R 2是氢，羟基，烷氧基，烷基，环烷基，链烯基，炔基，二-C 1 -C 4 - 烷基氨基，5元或6元杂环饱和或芳族基， 选自氧，硫和氮的两个杂原子，苯基或萘基，其中所述有机基团可以被进一步取代，以及二甲酰亚胺I的植物耐受盐，除了3-甲基异恶唑-4,5-二甲酰亚胺 de和噻唑-4,5-二羧酰亚胺，其中当R 1是甲基或2-噻唑基时，R 2是苯基，以及含有这些化合物的除草剂。

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