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公开(公告)号：US08273563B2
公开(公告)日：2012-09-25
申请号：US12497369
申请日：2009-07-02
Applicant: Robert DiCosimo , John Edward Gavagan , Mark Scott Payne , Frederick B. Cooling
Inventor： Robert DiCosimo , John Edward Gavagan , Mark Scott Payne , Frederick B. Cooling
CPC classification number: C11D3/38636 , A01N37/16 , C11D3/2093 , C11D3/221 , C11D3/226 , C11D3/3947 , C11D3/48 , C12P7/40 , A01N37/02 , A01N37/12 , A01N37/46 , A01N43/16 , A01N59/00 , A01N61/00 , A01N2300/00
Abstract: A process is provided for producing peroxycarboxylic acids from carboxylic acid esters. More specifically, carboxylic acid esters are reacted with an inorganic peroxide, such as hydrogen peroxide, in the presence of an enzyme catalyst having perhydrolysis activity. The present perhydrolase catalysts are classified as members of the carbohydrate esterase family 7 (CE-7) based on the conserved structural features. Further, disinfectant formulations comprising the peracids produced by the processes described herein are provided.
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公开(公告)号：US20120156159A1
公开(公告)日：2012-06-21
申请号：US13328364
申请日：2011-12-16
Applicant: Robert DiCosimo , Mark Scott Payne , John Edward Gavagan
Inventor： Robert DiCosimo , Mark Scott Payne , John Edward Gavagan
IPC: C12P7/40 , C12N15/63 , C12N9/18 , C12M1/40 , C12N1/15 , D21C9/16 , C12N1/21 , A01N37/16 , A01P1/00 , D06L3/02 , A61L2/16 , C12N15/55 , C12N1/19
CPC classification number: C11D3/2093 , A61L2/186 , C11D3/38627 , C11D3/38636 , C11D3/3942 , C11D3/3947 , C12N9/18 , C12P7/40 , C12P7/54 , C12Y301/01
Abstract: An acetyl xylan esterase variant having perhydrolytic activity is provided for producing peroxycarboxylic acids from carboxylic acid esters and a source of peroxygen. More specifically, a Thermotoga maritima acetyl xylan esterase gene was modified using error-prone PCR and site-directed mutagenesis to create an enzyme catalyst characterized by an increase in specific activity. The variant acetyl xylan esterase may be used to produce peroxycarboxylic acids suitable for use in a variety of applications such as cleaning, disinfecting, sanitizing, bleaching, wood pulp processing, and paper pulp processing applications.
Abstract translation: 提供具有过水解活性的乙酰木聚糖酯酶变体，用于从羧酸酯和过氧源产生过氧羧酸。 更具体地，使用易错PCR和定点诱变来修饰热转录海马乙酰木聚糖酯酶基因，以产生特征在于比活性增加的酶催化剂。 变体乙酰木聚糖酯酶可用于制备适用于各种用途的过氧羧酸，例如清洁，消毒，消毒，漂白，木浆加工和纸浆加工应用。
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公开(公告)号：US08148314B2
公开(公告)日：2012-04-03
申请号：US13213642
申请日：2011-08-19
Applicant: Robert Dicosimo , Arie Ben-Bassat , Mark S. Payne , Raymond Richard Zolandz
Inventor： Robert Dicosimo , Arie Ben-Bassat , Mark S. Payne , Raymond Richard Zolandz
CPC classification number: C12N9/18 , A61L2/183 , A61L2/186 , A61L2/22 , A61L2202/24 , C11D3/06 , C11D3/10 , C11D3/201 , C11D3/2017 , C11D3/2044 , C11D3/2048 , C11D3/2068 , C11D3/2079 , C11D3/2082 , C11D3/2086 , C11D3/2093 , C11D3/221 , C11D3/226 , C11D3/32 , C11D3/361 , C11D3/38636 , C11D3/3947 , C11D17/041 , C12P7/40 , C12Y301/01001 , Y02E50/16
Abstract: Disclosed herein is a method for stabilization of the perhydrolase activity of the CE-7 esterase in a formulation with a carboxylic acid ester that employs the addition of a buffering agent, substantially undissolved, to the mixture of the CE-7 esterase and the carboxylic acid ester. Further, disinfectant and laundry care formulations comprising the peracids produced by the processes described herein are provided.
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公开(公告)号：US20110312053A1
公开(公告)日：2011-12-22
申请号：US13162631
申请日：2011-06-17
Applicant: KEITH H. BURLEW , Robert Dicosimo , Michael Charles Grady , Ranjan Patnaik
Inventor： KEITH H. BURLEW , Robert Dicosimo , Michael Charles Grady , Ranjan Patnaik
CPC classification number: C12P7/16 , A23K10/38 , B01D3/002 , B01D11/0492 , B01D21/26 , B01D21/262 , C07C29/86 , C11B1/025 , C11B13/00 , C12F3/10 , C12M1/00 , C12M21/12 , C12M45/04 , C12M45/09 , C12N1/14 , C12N15/00 , C12P7/18 , C12P7/6418 , Y02E50/10 , Y02E50/16 , Y02E50/17 , Y02W30/74
Abstract: Fatty acids derived from biomass at a step in a fermentation process can be added to a fermentation medium comprising a recombinant microorganism that produces a product alcohol. At least one of growth rate and fermentable carbon consumption of the microorganism is greater in the presence of the fatty acids than the growth rate and the fermentable carbon consumption of the microorganism in the absence of the fatty acids. The addition of the fatty acids can increase glucose consumption, and can improve microorganism biomass production (cell growth/density) and growth rate, thereby reducing production time and increasing productivity of the fermentation process.
Abstract translation: 在发酵过程中的步骤中衍生自生物质的脂肪酸可以加入到包含产生产物醇的重组微生物的发酵培养基中。 在存在脂肪酸的情况下，微生物的生长速率和可发酵碳消耗量中的至少一种比在不存在脂肪酸时微生物的生长速率和可发酵碳消耗量更大。 脂肪酸的添加可以增加葡萄糖消耗，并且可以改善微生物生物量的生产（细胞生长/密度）和生长速率，从而减少生产时间并提高发酵过程的生产率。
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公开(公告)号：US08071343B2
公开(公告)日：2011-12-06
申请号：US12189890
申请日：2008-08-12
Applicant: Robert DiCosimo , Anna Panova , Jeffery Scott Thompson , Robert D. Fallon , F. Glenn Gallagher , Thomas Foo , Xu Li , George C. Fox , Joseph J. Zaher , Mark S. Payne , Daniel P. O'Keefe
Inventor： Robert DiCosimo , Anna Panova , Jeffery Scott Thompson , Robert D. Fallon , F. Glenn Gallagher , Thomas Foo , Xu Li , George C. Fox , Joseph J. Zaher , Mark S. Payne , Daniel P. O'Keefe
CPC classification number: C07C51/48 , C07C51/42 , C07C51/487 , C12P7/42 , C07C59/06
Abstract: A process is provided for producing glycolic acid from formaldehyde and hydrogen cyanide. More specifically, heat-treated formaldehyde and hydrogen cyanide are reacted to produce glycolonitrile having low concentrations of impurities. The glycolonitrile is subsequently converted to an aqueous solution of ammonium glycolate using an enzyme catalyst having nitrilase activity derived from Acidovorax facilis 72W (ATCC 57746). Glycolic acid is recovered in the form of the acid or salt from the aqueous ammonium glycolate solution using a variety of methods described herein.
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Patent Agency Ranking
公开(公告)号：US20110244535A1
公开(公告)日：2011-10-06
申请号：US12538525
申请日：2009-08-10
Applicant: Robert DiCosimo , John Edward Gavagan , Mark S. Payne
Inventor： Robert DiCosimo , John Edward Gavagan , Mark S. Payne
CPC classification number: A01N37/16 , C11D3/2093 , C11D3/221 , C11D3/226 , C11D3/38636 , C11D3/3947 , C11D3/48 , C12P7/40 , C12P7/42 , A01N37/02 , A01N37/12 , A01N37/46 , A01N43/16 , A01N59/00 , A01N61/00 , A01N2300/00
Abstract: A process is provided for producing peroxycarboxylic acids from carboxylic acid esters. More specifically, carboxylic acid esters are reacted with an inorganic peroxide, such as hydrogen peroxide, in the presence of an enzyme catalyst having perhydrolysis activity. The present perhydrolase catalysts are classified as members of the carbohydrate esterase family 7 (CE-7) based on the conserved structural features. Further, disinfectant formulations comprising the peracids produced by the processes described herein are provided.
Abstract translation: 提供了从羧酸酯制备过氧羧酸的方法。 更具体地说，羧酸酯与无机过氧化物如过氧化氢在具有过水解活性的酶催化剂存在下反应。 基于保守的结构特征，本发明的过水解酶催化剂被分类为碳水化合物酯酶家族7（CE-7）的成员。 此外，提供包含通过本文所述方法生产的过酸的消毒剂制剂。
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公开(公告)号：US08030038B2
公开(公告)日：2011-10-04
申请号：US12572086
申请日：2009-10-01
Applicant: Robert DiCosimo , Arie Ben-Bassat , Mark S. Payne , Raymond Richard Zolandz
Inventor： Robert DiCosimo , Arie Ben-Bassat , Mark S. Payne , Raymond Richard Zolandz
CPC classification number: C12N9/18 , A61L2/183 , A61L2/186 , A61L2/22 , A61L2202/24 , C11D3/06 , C11D3/10 , C11D3/201 , C11D3/2017 , C11D3/2044 , C11D3/2048 , C11D3/2068 , C11D3/2079 , C11D3/2082 , C11D3/2086 , C11D3/2093 , C11D3/221 , C11D3/226 , C11D3/32 , C11D3/361 , C11D3/38636 , C11D3/3947 , C11D17/041 , C12P7/40 , C12Y301/01001 , Y02E50/16
Abstract: Disclosed herein is a method for stabilization of the perhydrolase activity of the CE-7 esterase in a formulation with a carboxylic acid ester that employs the addition of a buffering agent, substantially undissolved, to the mixture of the CE-7 esterase and the carboxylic acid ester. Further, disinfectant and laundry care formulations comprising the peracids produced by the processes described herein are provided.
Abstract translation: 本文公开了一种在具有羧酸酯的制剂中稳定CE-7酯酶的过水解酶活性的方法，其使用向CE-7酯酶和羧酸的混合物中添加基本上未溶解的缓冲剂 酯。 此外，提供包含通过本文所述方法生产的过酸的消毒剂和衣物护理制剂。
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公开(公告)号：US20110236335A1
公开(公告)日：2011-09-29
申请号：US13070123
申请日：2011-03-23
Applicant: Robert Dicosimo , John Edward Gavagan , Mark Scott Payne
Inventor： Robert Dicosimo , John Edward Gavagan , Mark Scott Payne
IPC: C12P7/40 , C12N15/63 , C12N1/00 , C12N9/18 , C07H21/04 , C12M1/40 , A01N37/16 , D21C9/16 , A61L2/16 , D06L3/02 , A01P1/00
CPC classification number: C12N9/18 , C11D3/38636 , C11D3/3945 , C12P7/40 , D21C5/005 , D21C9/1036
Abstract: An acetyl xylan esterase variant having perhydrolytic activity is provided for producing peroxycarboxylic acids from carboxylic acid esters and a source of peroxygen. More specifically, a Thermotoga maritima acetyl xylan esterase gene was modified using error-prone PCR and site-directed mutagenesis to create an enzyme catalyst characterized by an increase in specific activity. The variant acetyl xylan esterase may be used to produce peroxycarboxylic acids suitable for use in a variety of applications such as cleaning, disinfecting, sanitizing, bleaching, wood pulp processing, and paper pulp processing applications.
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公开(公告)号：US20110150857A1
公开(公告)日：2011-06-23
申请号：US13036763
申请日：2011-02-28
Applicant: Robert Dicosimo , John Edward Gavagan , Mark S. Payne
Inventor： Robert Dicosimo , John Edward Gavagan , Mark S. Payne
IPC: A01N63/02 , A01N37/16 , A01P1/00 , C11D7/54 , C11D7/60 , C12N9/18 , C12P7/40 , C12M1/00 , D21H21/32 , C09K3/00
Abstract: An acetyl xylan esterase variant having perhydrolytic activity is provided for producing peroxycarboxylic acids from carboxylic acid esters and a source of peroxygen. More specifically, a Thermotoga maritima acetyl xylan esterase gene was modified using error-prone PCR and site-directed mutagenesis to create an enzyme catalyst characterized by an increase in the ratio of peracetic acid formation to peracetic acid hydrolysis specific activities (PAAF/PAAH ratio). The variant acetyl xylan esterase may be used to produce peroxycarboxylic acids suitable for use in a variety of applications such as cleaning, disinfecting, sanitizing, bleaching, wood pulp processing, and paper pulp processing applications.
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公开(公告)号：US07927854B1
公开(公告)日：2011-04-19
申请号：US12632438
申请日：2009-12-07
Applicant: Robert DiCosimo , John Edward Gavagan , Mark S. Payne
Inventor： Robert DiCosimo , John Edward Gavagan , Mark S. Payne
CPC classification number: C11D3/38636 , A61L2/186 , A61L2/22 , A61L2/23 , A61L2202/17 , A61L2202/24 , C12N9/18 , C12P7/40 , C12Y301/01072
Abstract: An acetyl xylan esterase variant having perhydrolytic activity is provided for producing peroxycarboxylic acids from carboxylic acid esters and a source of peroxygen. More specifically, a Thermotoga maritima acetyl xylan esterase gene was modified using error-prone PCR and site-directed mutagenesis to create an enzyme catalyst characterized by an increase in the ratio of peracetic acid formation to peracetic acid hydrolysis specific activities (PAAF/PAAH ratio). The variant acetyl xylan esterase may be used to produce peroxycarboxylic acids suitable for use in a variety of applications such as cleaning, disinfecting, sanitizing, bleaching, wood pulp processing, and paper pulp processing applications.
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