摘要:
A method of preparing aromatics processing catalysts which comprises incorporating a noble metal with a member or members of a useful class of zeolites, with such incorporation occurring after zeolite crystallization, but prior to final catalyst particle formation, i.e. extrusion into particles. Said useful class of zeolites is characterized by a silica to alumina mole ratio of at least 12 and a Constraint Index in the approximate range of 1 to 12.
摘要:
The liquid carrier in a Fischer-Tropsch synthesis slurry reactor system is periodically or continually separated and subjected to cracking and isomerization in the presence of suitable catalysts. The treated carrier is returned to the reactor system and the accumulation of high viscosity paraffin in the reactor slurry is minimized. Suitable catalysts include a mixture of cracking and isomerization catalysts. Zeolite ZSM-45 is a novel constituent of the catalyst system.
摘要:
A zeolite of improved stability for use in acid-catalyzed reactions is prepared by mildly presteaming the catalyst under controlled conditions of temperature, time, and steam partial pressure. The resulting catalyst retains nearly the same activity as that of a fresh unsteamed catalyst.
摘要:
The liquid carrier in a Fischer-Tropsch synthesis slurry reactor system is periodically or continually separated and subjected to cracking and isomerization in the presence of suitable catalysts. The treated carrier is returned to the reactor system and the accumulation of high viscosity paraffin in the reactor slurry is minimized. Suitable catalysts include a mixture of cracking and isomerization catalysts. Zeolite Beta is the novel constituent of the catalyst system.
摘要:
Zeolite supported, organometallic derived catalyst compositions are provided which are especially suitable for the polymerization of 1-olefins such as ethylene. Organotitanium and organochromium compounds such as tributylchromium and tetrabutyltitanium are reacted with ZSM-5 type zeolites to produce such novel catalysts.
摘要:
Octane and overall product quality improvement in catalytic cracking processes utilizing an essentially entirely amorphous cracking catalyst can be attained by using instead a catalyst comprising a minor amount, e.g. from about 0.01 to about 25 weight percent, of a class of crystalline zeolites characterized by a silica to alumina mole ratio greater than about 12 and a constraint index of about 1 to 12. The crystalline zeolites may be added to the conventional amorphous cracking catalyst in the cracking process by way of adding a separate additive composition in an amount which provides the zeolite component of the additive composition in said minor amount of the total catalyst in the cracking process.
摘要:
A process is disclosed for the dealkylation of durene resulting from a methanol to gasoline conversion by contacting a durene-containing fraction with zeolite ZSM-12 at elevated temperatures and pressures.
摘要:
Octane and total yield improvement in catalytic cracking processes can be attained by the addition to conventional cracking catalysts of very small amounts of additive catalyst comprising a class of zeolites characterized by a silica to alumina mole ratio greater than about 12 and a constraint index of about 1 to 12. The additive catalyst is added to the conventional cracking catalyst in the cracking process in an amount which provides the zeolite component of the additive catalyst at from about 0.01 weight percent to about 1.0 weight percent of the conventional cracking catalyst in the cracking process.
摘要:
A method is disclosed for the conversion of synthesis gas to a liquid hydrocarbon product having a boiling range of less than 400.degree. F. at a 90% overhead utilizing a novel catalyst prepared from a water-insoluble organic iron compound. The novel method involves contacting synthesis gas with a single particle catalyst containing iron, a crystalline acidic aluminosilicate zeolite having a silica-to-alumina ratio of at least 12, a pore size greater than about 5 Angstrom units, and a constraint index of about 1 to 12, and a matrix. The catalyst does not contain promoters.
摘要:
The invention relates to the use of particulate silicone resins in the absence of added organic solvents with particulate inorganic materials to form structured bodies and in particular molecular sieve containing structured bodies. The silicone resin is used in the form of a particulate with an average particle size of less than 700 um. Upon calcining, the silicone resin is converted to silica which acts as a binder.