摘要:
Silicone rubbers in the form of crosslinked, particulate particles can be used as a grafting base for the preparation of thermoplastic moulding materials having good low-temperature impact strength and resistance to weathering-ageing, after they are provided with an intermediate shell of crosslinked acrylate rubber.
摘要:
A process for the preparation of polymer powders from polymer dispersions by feeding a polymer dispersion continuously into an atomization apparatus and separately therefrom but at the same time also introducing a liquid agent, the dispersion and the liquid agent being completely mixed within at the most one second and the mixture being immediately thereafter dried with evaporation of the volatile constituents to form a powder composed of particles having an average diameter of from 0.05 to 1 mm, and the polymer powders prepared by this process.
摘要:
The present invention relates to flame-retarding moulding compositions which are based on thermoplastic polycarbonates, copolymers of styrenes and maleic anhydride, phosphorus compounds of the formula (I) ##STR1## tetrafluoroethylene polymers, small amounts of graft polymers and optionally halogen compounds and which in addition can contain stabilizers, pigments, flow agents, release agents and/or antistatics, and to a process for their preparation.
摘要:
The present invention relates to flame-retarding, thermoplastic polycarbonate moulding materials of high impact strength consisting of halogen-containing polycarbonates, copolymers formed from styrenes and (meth)acrylonitrile, phosphorus compounds of the formula (I) ##STR1## tetrafluoroethylene polymers and small amounts of graft polymers and, if appropriate, effective amounts of stabilizers, pigments, lubricants, mould release agents and/or antistatic agents, and to a process for the preparation thereof.
摘要:
This invention relates to thermoplastic moulding compounds free from nitrile groups, containing a mixture of randomly structured copolymers containing methyl methacrylate, maleic acid anhydride and aromatic vinyl compounds, aromatic polycarbonate resins and an elastomer grafted with methyl methacrylate.
摘要:
This invention relates to thermoplastic moulding compounds which are free from nitrile groups, obtained from randomly structured aromatic vinyl copolymers containing N-phenyl- or methyl-maleimide, aromatic polycarbonate resins and an elastomer grafted with methyl methacrylate.
摘要:
The invention relates to flame-resistant ABS moulding materials containing a fluoro-organic polymer besides customary flameproofing additives and to a process for their manufactures.
摘要:
The present invention relates to a process for the preparation of bis-carbonic acid aryl esters of polyester-diols, lengthened via --OCOO-- groups, characterized in that polyester-diols with molecular weights Mn (number-average) of over 250, preferably over 600, are heated with carbonic acid bis-aryl esters at temperatures between about 100.degree. C. and 200.degree. C., preferably between about 110.degree. C. and 180.degree. C., in vacuo below about 35 mm Hg, preferably between about 25 and 1 mm Hg, in the presence of catalysts, less than one mol of carbonic acid bis-aryl ester being employed per OH group of the polyester-diol and the hydroxyaryl compounds formed being distilled off.The invention further relates to the bis-carbonic acid aryl esters of polyester-diols lengthened via --OCOO-- groups obtained according to the instant invention and their use for the preparation of polyester diol bis-diphenol carbonates, lengthened via carbonate groups, characterized in that polyester-diol bis-aryl carbonates are reacted with a diphenol at a temperature of from about 100.degree. to about 200.degree. C. in vacuo below about 35 mm Hg in the presence of a catalyst, wherein more than 1 mol of diphenol is employed per mol of carbonic acid aryl ester groups of the polyester-diol bis-aryl carbonate, lengthened via carbonate groups, and the resulting hydroxyaryl compound is distilled off.The invention finally relates to the polyester-diol bis-diphenol carbonates, lengthened via carbonate groups obtained according to the instant invention and their use for the preparation of polyester/polycarbonates and the polycarbonate/polyesters so prepared.
摘要:
This disclosure is concerned with a single step process for the production of diphenol terminated polycarbonates by the transesterification of diphenols, bis-aryl carbonates and polymeric diols with aliphatically bound terminal hydroxyl groups. These diols are selected from polyesters, polyethers, polythioethers and polyacetals. The transesterification is carried out at elevated temperatures under vacuum optionally in the presence of a catalyst with the ratios of the reactants being such as to avoid the retention of any terminal aliphatic hydroxyl groups or aryl carbonate groups.
摘要:
The present invention relates to the transesterification of the carbonic acid aryl esters obtainable according to German Published Patent Specification No. 2,650,533 with an excess of diphenol for the preparation of polyalkylene oxide-diol bis-diphenol carbonates lengthened via carbonate groups. The present invention also relates to the polyalkylene oxide-diol bis-diphenol carbonates, lengthened via carbonate groups, obtained according to the invention and their use for the preparation of polyether/polycarbonates. Finally, the present invention relates to the polyether/polycarbonates, obtained according to the invention, with an improved phase separation between the elastomeric segment and hard segment, which leads to better technological properties of the corresponding polycarbonate elastomers.