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    Processes for producing 2,3,3,3-tetrafluoropropene, a process for producing 1-chloro-2,3,3,3-pentafluoropropane and azeotropic compositions of 1-chloro-2,3,3,3-tetrafluoropropene with HF
    61.
    发明授权
    Processes for producing 2,3,3,3-tetrafluoropropene, a process for producing 1-chloro-2,3,3,3-pentafluoropropane and azeotropic compositions of 1-chloro-2,3,3,3-tetrafluoropropene with HF 有权

    公开(公告)号：US07906693B2

    公开(公告)日：2011-03-15

    申请号：US12442955

    申请日：2007-10-31

    申请人： Mario Joseph Nappa ,  Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

    发明人： Mario Joseph Nappa ,  Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

    IPC分类号： C07C17/00 ,  C07C19/08

    CPC分类号： C07C17/25 ,  C07C17/23 ,  C07C17/278 ,  C07C21/18 ,  C07C19/08 ,  C07C19/10

    摘要： A process is disclosed for making CH2═CFCF3. The process involves contacting CH2ClCF2CF3 with H2 in a reaction zone in the presence of a catalyst including a catalytically effective amount of palladium supported on a support selected from chromium oxide, fluorinated chromium oxide, chromium fluoride, aluminum oxide, aluminum fluoride and/or fluorinated alumina, to produce CH2═CFCF3. The mole ratio of H2 to the CH2ClCF2CF3 fed to the reaction zone is between about 1:1 and about 4:1. Also disclosed is another process for making CH2═CFCF3 that involves (a) reacting CH2ClCF2CF3 with H2 in the presence of a catalytically effective amount of hydrogenation catalyst to form CH3CF2CF3; and (b) dehydrofluorinating CH3CF2CF3 from (a) to form CH2═CFCF3; and another process for making CH2═CFCF3 that involves (1) dehydrofluorinating CH2ClCF2CF3 in the presence of a catalytically effective amount of dehydrofluorination catalyst to form CHCl═CFCF3; and (2) hydrogenating CHCl═CFCF3 from (1) in the presence of a hydrogenation catalyst including a catalytically effective amount of palladium supported on a support selected from chromium oxide, fluorinated chromium oxide, chromium fluoride, aluminum oxide, aluminum fluoride and/or fluorinated alumina to form CH2═CFCF3. Also disclosed is a process for making CH2ClCF2CF5. This process involves reacting CH2ClF with CF2═CF2 in a reaction zone in the presence of a catalytically effective amount of an aluminum halide composition having a bulk formula of AlClxBryF3-x-y wherein the average value of x is 0 to 3, the average value of y is 0 to 3-x, provided that the average values of x and y are not both 0. Also disclosed is an azeotropic composition including CF3CF═CHCl and HF.

    PHOSPHORUS-CONTAINING STABILIZERS FOR FLUOROOLEFINS
    62.
    发明申请
    PHOSPHORUS-CONTAINING STABILIZERS FOR FLUOROOLEFINS 有权
    含氟磷酸的含磷稳定剂

    公开(公告)号：US20100301259A1

    公开(公告)日：2010-12-02

    申请号：US12377474

    申请日：2007-08-31

    申请人： Thomas J. Leck ,  Nandini C. Mouli ,  Barbara Haviland Minor ,  Mario Joseph Nappa ,  Jon Lee Howell

    发明人： Thomas J. Leck ,  Nandini C. Mouli ,  Barbara Haviland Minor ,  Mario Joseph Nappa ,  Jon Lee Howell

    IPC分类号： C09K5/00

    CPC分类号： C09K5/045 ,  C09K2205/126

    摘要： The present disclosure relates to compositions comprising at least one fluoroolefin and an effective amount of a stabilizer comprising at least one phosphorus-containing compound selected from the group consisting of thiophosphates, butylated triphenylphosphorothionates, and organophosphates. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.

    摘要翻译： 本公开涉及包含至少一种氟代烯烃和有效量的稳定剂的组合物，其包含至少一种选自硫代磷酸酯，丁基化三苯基硫代硫酸酯和有机磷酸酯的含磷化合物。 稳定的组合物可用于冷却装置，例如制冷，空调，冷却器和热泵，以及作为泡沫发泡剂，溶剂，气溶胶推进剂，灭火剂和灭菌剂的应用。

    Catalytic Isomerization Between E and Z Isomers of 1,2,3,3,3 Pentafluoropropene Using Aluminum Catalyst
    63.
    发明申请
    Catalytic Isomerization Between E and Z Isomers of 1,2,3,3,3 Pentafluoropropene Using Aluminum Catalyst 失效
    使用铝催化剂的1,2,3,3,3-五氟丙烯的E和Z异构体之间的催化异构化

    公开(公告)号：US20100197979A1

    公开(公告)日：2010-08-05

    申请号：US12674961

    申请日：2008-08-14

    申请人： Mario Joseph Nappa

    发明人： Mario Joseph Nappa

    IPC分类号： C07C21/18

    CPC分类号： C07C17/358 ,  C07C21/18

    摘要： A starting material comprising 1,2,3,3,3-pentafluoropropene is contacted with an aluminum chlorofluoride (AlClxF3-x) catalyst to obtain a final product wherein the Z/E ratio of 1,2,3,3,3-pentafluoropropene is either increased or decreased relative to the Z/E ratio of 1,2,3,3,3-pentafluoropropene in said starting material.

    摘要翻译： 将包含1,2,3,3,3-五氟丙烯的起始材料与氯化铝铝（AlCl x F 3-x）催化剂接触以获得最终产物，其中1,2,3,3,3-五氟丙烯的Z / E比 相对于所述原料中的1,2,3,3,3-五氟丙烯的Z / E比增加或降低。

    THIOL AND THIOETHER STABILIZERS FOR FLUOROOLEFINS
    65.
    发明申请
    THIOL AND THIOETHER STABILIZERS FOR FLUOROOLEFINS 失效
    THIOL和THENTEHER稳定剂氟化物

    公开(公告)号：US20100090155A1

    公开(公告)日：2010-04-15

    申请号：US12377708

    申请日：2007-08-31

    申请人： Thomas J. Leck ,  Barbara Haviland Minor ,  Mario Joseph Nappa ,  Nandini C. Mouli

    发明人： Thomas J. Leck ,  Barbara Haviland Minor ,  Mario Joseph Nappa ,  Nandini C. Mouli

    IPC分类号： C09K5/04 ,  C07C21/18

    CPC分类号： C09K5/045 ,  C09K2205/126

    摘要： The present disclosure relates to compositions comprising at least one fluoroolefin and an effective amount of a stabilizer comprising at least one thiol or thioether, or mixtures thereof. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.

    摘要翻译： 本公开涉及包含至少一种氟烯烃和有效量的包含至少一种硫醇或硫醚的稳定剂或其混合物的组合物。 稳定的组合物可用于冷却装置，例如制冷，空调，冷却器和热泵，以及作为泡沫发泡剂，溶剂，气溶胶推进剂，灭火剂和灭菌剂的应用。

    PROCESSES FOR PRODUCING 2,3,3,3-TETRAFLUOROPROPENE, A PROCESS FOR PRODUCING 1-CHLORO-2,3,3,3-PENTAFLUOROPROPANE AND AZEOTROPIC COMPOSITIONS OF 1-CHLORO-2,3,3,3-TETRAFLUOROPROPENE WITH HF
    66.
    发明申请
    PROCESSES FOR PRODUCING 2,3,3,3-TETRAFLUOROPROPENE, A PROCESS FOR PRODUCING 1-CHLORO-2,3,3,3-PENTAFLUOROPROPANE AND AZEOTROPIC COMPOSITIONS OF 1-CHLORO-2,3,3,3-TETRAFLUOROPROPENE WITH HF 有权

    公开(公告)号：US20100076231A1

    公开(公告)日：2010-03-25

    申请号：US12442955

    申请日：2007-10-31

    申请人： Mario Joseph Nappa ,  Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

    发明人： Mario Joseph Nappa ,  Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

    IPC分类号： C07C17/25 ,  C07C17/278

    CPC分类号： C07C17/25 ,  C07C17/23 ,  C07C17/278 ,  C07C21/18 ,  C07C19/08 ,  C07C19/10

    摘要： A process is disclosed for making CH2═CFCF3. The process involves contacting CH2ClCF2CF3 with H2 in a reaction zone in the presence of a catalyst including a catalytically effective amount of palladium supported on a support selected from chromium oxide, fluorinated chromium oxide, chromium fluoride, aluminum oxide, aluminum fluoride and/or fluorinated alumina, to produce CH2═CFCF3. The mole ratio of H2 to the CH2ClCF2CF3 fed to the reaction zone is between about 1:1 and about 4:1. Also disclosed is another process for making CH2═CFCF3 that involves (a) reacting CH2ClCF2CF3 with H2 in the presence of a catalytically effective amount of hydrogenation catalyst to form CH3CF2CF3; and (b) dehydrofluorinating CH3CF2CF3 from (a) to form CH2═CFCF3; and another process for making CH2═CFCF3 that involves (1) dehydrofluorinating CH2ClCF2CF3 in the presence of a catalytically effective amount of dehydrofluorination catalyst to form CHCl═CFCF3; and (2) hydrogenating CHCl═CFCF3 from (1) in the presence of a hydrogenation catalyst including a catalytically effective amount of palladium supported on a support selected from chromium oxide, fluorinated chromium oxide, chromium fluoride, aluminum oxide, aluminum fluoride and/or fluorinated alumina to form CH2═CFCF3. Also disclosed is a process for making CH2ClCF2CF5. This process involves reacting CH2ClF with CF2═CF2 in a reaction zone in the presence of a catalytically effective amount of an aluminum halide composition having a bulk formula of AlClxBryF3-x-y wherein the average value of x is 0 to 3, the average value of y is 0 to 3-x, provided that the average values of x and y are not both 0. Also disclosed is an azeotropic composition including CF3CF═CHCl and HF.

    Tetrafluoropropene Production Processes
    68.
    发明申请
    Tetrafluoropropene Production Processes 有权
    四氟丙烯生产工艺

    公开(公告)号：US20090127496A1

    公开(公告)日：2009-05-21

    申请号：US12301070

    申请日：2007-06-22

    申请人： Velliyur Nott Mallikarjuna Rao ,  Mario Joseph Nappa ,  Allen Capron Sievert

    发明人： Velliyur Nott Mallikarjuna Rao ,  Mario Joseph Nappa ,  Allen Capron Sievert

    IPC分类号： C09K5/00 ,  C07C17/25

    CPC分类号： B01J37/26 ,  B01J21/04 ,  B01J27/125 ,  C07C17/25 ,  C07C17/386 ,  C07C21/18 ,  C07C19/08

    摘要： A process is disclosed for the manufacture of CF3CF═CH2 and CF3CH═CHF. The process involves dehydrofluorinating CF3CHFCH2F in the presence of a dehydrofluorination catalyst to produce a product mixture comprising CF3CF═CH2 and CF3CH═CHF, and recovering said CF3CF═CH2 and CF3CH═CHF from the product mixture.The present invention also provides a composition comprising (a) the Z-isomer of CF3CH═CHF and (b) HF; wherein the HF is present in an effective amount to form an azeotropic combination with the Z—CF3CH═CHF.

    摘要翻译： 公开了用于制造CF 3 CF-CH 2和CF 3 CH-CHF的方法。 该方法包括在脱氟化氢催化剂的存在下对CF 3 CHFCH 2 F进行脱氟化氢，以产生包含CF 3 CF-CH 2和CF 3 CH-CHF的产物混合物，并从产物混合物回收所述CF 3 CF-CH 2和CF 3 CH-CHF。 本发明还提供一种组合物，其包含（a）CF 3 CH-CHF的Z-异构体和（b）HF; 其中HF以有效量存在以与Z-CF 3 CH-CHF形成共沸组合。

    Process for perhalofluorinated butanes and hexanes
    69.
    发明授权
    Process for perhalofluorinated butanes and hexanes 失效
    全氟化丁烷和己烷的方法

    公开(公告)号：US06207869B1

    公开(公告)日：2001-03-27

    申请号：US09519791

    申请日：2000-03-07

    申请人： Mario Joseph Nappa ,  Allen Capron Sievert

    发明人： Mario Joseph Nappa ,  Allen Capron Sievert

    IPC分类号： C07C1908

    CPC分类号： C07C19/14 ,  B01J27/125 ,  C07C17/23 ,  C07C17/278 ,  C07C19/08 ,  C07C19/10

    摘要： The instant invention relates to producing perhalofluorobutanes and perhalofluorohexanes, more particularly it relates to their production by utilizing tetrafluoroethylene (hereinafter referred to as “TFE”) and chlorotrifluoro-ethylene (hereinafter referred to as “CTFE”) with selected perhalofluoroethanes containing 2 to 4 nonfluorine halogen and 2 to 4 fluorine substituents in the presence of a polyvalent metal halide such as an aluminum chloride or chlorofluoride as catalyst.

    摘要翻译： 本发明涉及生产全氟全氟代丁烷和全卤代己烷，更具体地说，涉及其使用四氟乙烯（以下称为“TFE”）和氯三氟乙烯（以下称为“CTFE”）的制备方法，该选择性全卤代乙烷含有2-4个非氟 卤素和2至4个氟取代基在多价金属卤化物如氯化铝或氯氟化物作为催化剂存在下进行。

    Process for the manufacture of halogenated propanes containing end-carbon fluorine
    70.
    发明授权
    Process for the manufacture of halogenated propanes containing end-carbon fluorine 有权
    制造含有末端碳氟的卤代丙烷的方法

    公开(公告)号：US6066769A

    公开(公告)日：2000-05-23

    申请号：US155841

    申请日：1998-10-06

    申请人： Mario Joseph Nappa ,  Allen Capron Sievert ,  Edwin J. Warwas

    发明人： Mario Joseph Nappa ,  Allen Capron Sievert ,  Edwin J. Warwas

    IPC分类号： B01J23/26 ,  B01J27/132 ,  B01J37/08 ,  C07C17/20 ,  C07C17/21 ,  C07C19/08 ,  C07C19/10 ,  C07C17/08

    CPC分类号： B01J23/26 ,  B01J27/132 ,  B01J37/088 ,  C07C17/206 ,  C07C17/21 ,  C07C19/08 ,  C07C19/10

    摘要： A process is disclosed for producing a compound of the formula: CF.sub.3 CHXCF.sub.3-z Y.sub.2 where X and Y are independently selected from the group consisting of H and Cl, and z is 0 or 1. The process involves (1) contacting CCl.sub.3 CHXCC.sub.3-z Y.sub.z,CCl.sub.2-z .dbd.CXCC.sub.3, and/or CCl.sub.2 CX.dbd.CC.sub.3-z Y.sub.z starting material, with hydrogen fluoride at a temperature of less than 200.degree. C. to produce a fluorination product of said starting material which includes at least 90 mole percent total of C.sub.3 HXY.sub.z Cl.sub.6-z-x F.sub.x saturated compounds and C.sub.3 XY.sub.z Cl.sub.5-z-y F.sub.y olefinic compounds, wherein x is an integer from 1 to 6-z and y is an integer from 1 to 5-z, (the fluorination product including no more than about 40 mole percent of the desired product, CF.sub.3 CHXCF.sub.3-z Y.sub.z); (2) contacting saturated compounds and olefinic compounds produced in (1) with hydrogen fluoride in the vapor phase at a temperature of from 200.degree. C. to about 400.degree. C. in the presence of a fluorination catalyst; and (3) reacting a sufficient amount of said compounds, wherein x is an integer from 1 to 5-z and olefinic compounds produced in (1) with hydrogen fluoride in the vapor phase at a temperature of from 200.degree. C. to about 400.degree. C. in the presence of a vapor phase fluorination catalyst to provide an overall selectivity to CF.sub.3 CHXCF.sub.3-z Y.sub.z of at least about 90 percent based upon the amount of starting material reacted with HF in (1) and (2).

    摘要翻译： PCT No.PCT / US97 / 06013 371 1998年10月6日第 102（e）日期1998年10月6日PCT 1997年4月4日PCT PCT。 WO97 / 37956 PCT公开号 日期1997年10月16日公开了制备下式化合物的方法：CF 3 CHXCF 3 -ZY 2其中X和Y独立地选自H和Cl，z是0或1.该方法包括（1） CCl 3 CHXCC 3 -ZYz，CCl 2 -Z = CXCC 3和/或CCl 2 C X = CCl 3 -ZYz起始原料，在低于200℃的温度下加入氟化氢，以产生所述原料的氟化产物，其包含至少90摩尔％ 总共C3HXYzCl6-z-xFx饱和化合物和C3XYzCl5-z-yFy烯属化合物，其中x是1至6-z的整数，y是1至5-z的整数（氟化产物不超过约 40摩尔％的所需产物，CF 3 CHXCF 3 -ZYz）; （2）在氟化催化剂存在下，将温度为200℃至约400℃的气相中的（1）中产生的饱和化合物和烯烃化合物与氟化氢接触; 和（3）将足量的所述化合物（其中x是1至5-z的整数）和（1）中制备的烯烃化合物与气相中的氟化氢在200℃至约400℃的温度下反应 在气相氟化催化剂的存在下，基于在（1）和（2）中与HF反应的原料的量，提供至少约90％的CF 3 CHXCF 3 -ZYz的总体选择性。