公开(公告)号：US06784221B2

公开(公告)日：2004-08-31

申请号：US09932731

申请日：2001-08-17

申请人： Martin Roth ,  Roger Salvin ,  Kurt Meier ,  Bernhard Sailer ,  Rolf Wiesendanger

发明人： Martin Roth ,  Roger Salvin ,  Kurt Meier ,  Bernhard Sailer ,  Rolf Wiesendanger

IPC分类号： C08L63110

CPC分类号： C09D163/10 ,  C08F290/144 ,  C08G59/066 ,  C08G59/1466 ,  C08G59/4284 ,  C08G59/4292 ,  G03F7/027 ,  G03F7/038

摘要： A carboxyl group-containing epoxy acrylate is prepared by the reaction of an epoxy resin advanced with an aromatic biphenol compound which is reacted with a polycarboxylic acid anhydride in the presence or absence of a catalyst and a polymerization inhibitor at an elevated temperature. The carboxyl group-containing epoxy acrylate is mixed with a photoinitiator to obtain a photoresist formulation.

摘要翻译： 通过环氧树脂与芳族联苯酚化合物的反应制备含羧基的环氧丙烯酸酯，所述芳香族联苯酚化合物在存在或不存在催化剂的条件下与聚羧酸酐反应，在高温下进行。 将含羧基的环氧丙烯酸酯与光引发剂混合以获得光致抗蚀剂制剂。

公开(公告)号：US06747101B2

公开(公告)日：2004-06-08

申请号：US08268094

申请日：1994-06-28

申请人： Martin Roth ,  Roger Salvin ,  Kurt Meier ,  Bernhard Sailer ,  Rolf Wiesendanger

发明人： Martin Roth ,  Roger Salvin ,  Kurt Meier ,  Bernhard Sailer ,  Rolf Wiesendanger

IPC分类号： C08G5917

CPC分类号： C09D163/10 ,  C08F290/144 ,  C08G59/066 ,  C08G59/1466 ,  C08G59/4284 ,  C08G59/4292 ,  G03F7/027 ,  G03F7/038

摘要： Epoxy acrylates and carboxyl group-containing epoxy acrylates of formulae III and IV of the claims that are relatively polymolecular and are chemically crosslinkable can be used in photoresist formulations with the additional use of highly polymerized polymer binders. Such resist formulations are used in particular in the field of printed circuit boards and printing plates, are applicable from aqueous medium, are almost tack-free and have very good edge coverage, especially on conductors.

摘要翻译： 具有相对多分子且具有化学交联性的权利要求中的式III和IV的环氧丙烯酸酯和含羧基的环氧丙烯酸酯可以用于另外使用高度聚合的聚合物粘合剂的光致抗蚀剂制剂中。 这种抗蚀剂制剂特别用于印刷电路板和印刷版领域，适用于水性介质，几乎无粘性，并且具有非常好的边缘覆盖率，特别是在导体上。

公开(公告)号：US06450725B1

公开(公告)日：2002-09-17

申请号：US09806102

申请日：2001-05-15

申请人： Martin Roth ,  Andreas Schuster ,  Heinz Voggenreiter ,  Harald Vorbrugg ,  Markus Reindl

发明人： Martin Roth ,  Andreas Schuster ,  Heinz Voggenreiter ,  Harald Vorbrugg ,  Markus Reindl

IPC分类号： B25G318

CPC分类号： B64G1/645 ,  B64G1/222 ,  B64G1/44 ,  B64G1/641 ,  F16B1/0014 ,  Y10T403/21

摘要： A retention and triggering mechanism with a shape memory actuator which ensures safe triggering and is of simple design and requires little energy. An end (7, 8) of a stressed wire is held by a free end of a wire made of shape memory material (9, 10) which contracts along its length when heated, thus withdrawing its free end from an opening (27, 28) formed in the end (7, 8) of the stressed wire thereby releasing the stressed wire.

摘要翻译： 具有形状记忆致动器的保持和触发机构，确保安全触发并且设计简单，并且需要很少的能量。 应力线的端部（7,8）由形状记忆材料（9,10）制成的线的自由端保持，其在加热时沿其长度收缩，从而将其自由端从开口（27,28）中取出 ）形成在应力线的端部（7,8）中，从而释放应力线。

公开(公告)号：US06361018B1

公开(公告)日：2002-03-26

申请号：US09738955

申请日：2000-12-15

申请人： Martin Roth ,  Arno Voit ,  Gerd Bethe

发明人： Martin Roth ,  Arno Voit ,  Gerd Bethe

IPC分类号： F16K3102

摘要： A coaxial valve includes an actuating drive, a valve housing (11), a valve sleeve (12) that is longitudinally slidable in the valve housing (11) between open and closed positions, and a closing body (13) arranged coaxially at one end of the valve sleeve (12). In the closed position, the valve sleeve seals against the closing body. In the open position, the valve sleeve is spaced from the closing body, to open a valve opening cross-section (V). The actuating drive includes an electric servomotor (21) with a linear actuator (22), and a transmission mechanism (30) for transmitting the linear movement of the actuator to the valve sleeve. The transmission mechanism includes a rocker lever with a first end articulately connected to the linear actuator, a second end articulately connected to the valve housing, and a middle section articulately connected to the valve sleeve.

公开(公告)号：US5994475A

公开(公告)日：1999-11-30

申请号：US886308

申请日：1997-07-01

申请人： Martin Roth ,  Qian Tang ,  Sameer Hosam Eldin

发明人： Martin Roth ,  Qian Tang ,  Sameer Hosam Eldin

IPC分类号： C08L33/00 ,  C08F8/32 ,  C08F212/14 ,  C08F220/06 ,  C08F220/26 ,  C08F222/12 ,  C08G59/40 ,  C08L63/00 ,  C08F26/06

CPC分类号： C08L63/00 ,  C08F8/44

摘要： Reaction products of a microgel that contains carboxylic acid groups with a nitrogen-containing base have a high latency and high stability towards mechanical influences and are suitable as hardeners for one-component epoxy resin systems.

摘要翻译： 含有羧酸基团的微凝胶与含氮基团的反应产物对于机械影响具有高潜伏期和高稳定性，并且适用于单组分环氧树脂体系的硬化剂。

公开(公告)号：US5523362A

公开(公告)日：1996-06-04

申请号：US412181

申请日：1995-03-28

申请人： Peter Flury ,  Martin Roth ,  Sameer H. Eldin

发明人： Peter Flury ,  Martin Roth ,  Sameer H. Eldin

IPC分类号： C07C279/28 ,  C08G18/02 ,  C08G59/40 ,  C08L63/02 ,  C08L63/04

CPC分类号： C07C279/28 ,  C08G18/025 ,  C08G59/4021

摘要： The present invention relates to a curable mixture which is useful in the formation of castings and which contains (a) an epoxy resin and (b) a mixture of oligomeric cyanoguanidines obtained by the reaction between a monoisocyanate and a diisocyanate to give a carbodiimide which is subsequently reacted with cyanamide.

摘要翻译： 本发明涉及可用于形成铸件的可固化混合物，其包含（a）环氧树脂和（b）通过单异氰酸酯和二异氰酸酯之间的反应获得的低聚氰胍的混合物，得到碳二亚胺，其为 随后与氨腈反应。

公开(公告)号：US5296330A

公开(公告)日：1994-03-22

申请号：US932128

申请日：1992-08-15

申请人： Reinhard Schulz ,  Norbert Munzel ,  Martin Roth ,  Wilhelm Knobloch

发明人： Reinhard Schulz ,  Norbert Munzel ,  Martin Roth ,  Wilhelm Knobloch

IPC分类号： G03F7/004 ,  C07C39/15 ,  C07C309/71 ,  C07C309/76 ,  C08K5/42 ,  C08L101/00 ,  G03F7/022 ,  H01L21/027 ,  H05K3/00 ,  G03F7/023 ,  G03C1/61

CPC分类号： C07C309/76 ,  C07C39/15 ,  G03F7/0226

摘要： Positive photoresist compositions comprising, in an organic solvent, at leasta) one alkali-soluble resin,b) one photosensitive quinone diazide,c) one aromatic hydroxy compound of formula I ##STR1## wherein each R is --H, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, --OCH.sub.2 C.sub.6 H.sub.5, --OC.sub.6 H.sub.5 or --COOC.sub.1 -C.sub.4 alkyl, and R.sub.1 and R.sub.2 are each independently of the other H, C.sub.1 -C.sub.4 alkyl, --C.sub.6 H.sub.5 or a cycloaliphatic 5- or 6-membered ring, a is an integer from 0 to 4, and m and n are each independently of the other 0, 1 or 2, which compound enhances the photosensitivity and/or the rate of development, and optionallyd) additional customary modifiers,are eminently suitable for making relief structures.

摘要翻译： 正性光致抗蚀剂组合物，其在有机溶剂中包含至少一种碱溶性树脂，b）一种光敏醌二叠氮化物，c）一种式I的芳族羟基化合物（*化学结构*）（I），其中每个R是 - H，C 1 -C 4烷基，C 1 -C 4烷氧基，-OCH 2 C 6 H 5，-OC 6 H 5或-COOC 1 -C 4烷基，R 1和R 2各自独立地为H，C 1 -C 4烷基，-C 6 H 5或脂环族五元或六元环， a是0至4的整数，m和n各自独立地为0,1或2，该化合物增强光敏性和/或显影速率，以及任选地d）另外的常规改性剂，特别适用于 做救济结构。

公开(公告)号：US5162547A

公开(公告)日：1992-11-10

申请号：US804309

申请日：1991-12-09

申请人： Martin Roth ,  Heinz Wolleb ,  Marc-Andre Truffer

发明人： Martin Roth ,  Heinz Wolleb ,  Marc-Andre Truffer

IPC分类号： B01J27/135 ,  C07B61/00 ,  C07D301/28 ,  C07D303/22 ,  C07D303/24

CPC分类号： C07D303/22 ,  C07D303/24

摘要： An improved process for the preparation of glycidyl ethers of formula I ##STR1## wherein Q is an aliphatic, cycloaliphatic or araliphatic radical of a valency m, R is --H or --CH.sub.3, and m is an integer from 1 to 10,by reacting an alcohol of formula Q--(OH).sub.m with m mol of an epihalohydrin of formula II ##STR2## in the presence of a catalyst to the corresponding halohydrin ether, and dehydrohalogenating said halohydrin ether with an alkali metal hydroxide to give a compound of formula I, wherein Q, m and R are as defined above and Hal is halogen,which process comprises using as catalysta) tin difluoride orb) a divalent tin halide in conjunction with a co-catalyst.

摘要翻译： 制备式I的缩水甘油醚的改进方法（I）其中Q是化合价m的脂族，脂环族或芳脂族基团，R是-H或-CH 3，m是1至10的整数 通过使式Q-（OH）m的醇与m摩尔式II的表卤代醇在催化剂存在下反应至相应的卤代醇醚，并用碱金属氢氧化物将所述卤代醇醚脱卤化氢 得到式I化合物，其中Q，m和R如上所定义，Hal为卤素，该方法包括使用二氯化锡或b）与助催化剂结合的二价卤化锡。

公开(公告)号：US4855367A

公开(公告)日：1989-08-08

申请号：US203792

申请日：1988-06-07

申请人： Peter Flury ,  Sameer H. Eldin ,  Martin Roth ,  Claus W. Rabener

发明人： Peter Flury ,  Sameer H. Eldin ,  Martin Roth ,  Claus W. Rabener

IPC分类号： C07D493/10 ,  C07B61/00 ,  C07D519/00 ,  C08G59/00 ,  C08G59/40 ,  C08K5/06 ,  C08K5/156 ,  C08L63/00

CPC分类号： C07D519/00 ,  C08G59/40 ,  C08K5/156

摘要： Orthocarbonates of the formula I ##STR1## in which R is C.sub.1 -C.sub.4 alkyl, x is zero, 1 or 2, and A is a trivalent radical derived from an aliphatic triol by omitting the hydroxyl groups, the hydroxyl groups of the triol being bonded to different carbon atoms, are suitable as cocomponents in the curing of epoxy resins in that they limit the reduction in volume occurring during curing of epoxy resins. In addition, the cured resins are distinguished by increased flexural strength and impact strength.

摘要翻译： 其中R是C 1 -C 4烷基，x是0,1或2的式I（I）的正碳酸酯，A是通过省略羟基衍生自脂族三醇的三价基团，三醇的羟基 结合到不同的碳原子上，适合作为环氧树脂固化中的共同组分，因为它们限制了环氧树脂固化过程中发生的体积减少。 此外，固化树脂的特征在于增加的弯曲强度和冲击强度。

公开(公告)号：US4754003A

公开(公告)日：1988-06-28

申请号：US38575

申请日：1987-04-15

申请人： Charles E. Monnier ,  Martin Roth

发明人： Charles E. Monnier ,  Martin Roth

IPC分类号： H01L23/29 ,  C08G59/02 ,  C08G59/08 ,  C08G59/20 ,  C08G59/32 ,  C08G59/38 ,  H01B3/40 ,  H01L23/31 ,  C08G8/28 ,  C08G8/36 ,  C08G59/24

CPC分类号： H01B3/40 ,  C08G59/02 ,  C08G59/3218 ,  C08G59/38

摘要： Novel epoxidised phenol ethers of formula I ##STR1## are described wherein R.sup.1 denotes C.sub.1 -C.sub.20 alkyl, C.sub.5 -C.sub.9 cycloalkyl or C.sub.7 -C.sub.14 aralkyl, R.sup.2 has one of the meanings of R.sup.1 or is, in addition hydrogen or a radical or formula II ##STR2## R.sup.3 denotes C.sub.1 -C.sub.6 alkyl or halogen, R.sup.4 and R.sup.5 denotes hydrogen or C.sub.1 -C.sub.6 alkyl, R.sup.6 denotes hydrogen or methyl, m is 0, 1 or 2 and n is an integer from 0 to 30, with the proviso that at least two radicals, R.sup.2, must be epoxide groups of formula II. The compounds are especially suitable for encasing electronic components.

摘要翻译： 描述了式I的新型环氧化酚醚（I），其中R1表示C1-C20烷基，C5-C9环烷基或C7-C14芳烷基，R2具有R1的含义之一，或另外是氢或基团或式II （II）R3表示C1-C6烷基或卤素，R4和R5表示氢或C1-C6烷基，R6表示氢或甲基，m表示0,1或2，n表示0至30的整数，条件是 至少两个基团R2必须是式II的环氧基团。 这些化合物特别适用于包装电子元件。