摘要:
A resin composition prepared by melting and kneading (A) a thermoplastic resin comprising a polyolefin resin together with (B) a functional compound having one or more bond(s) or one or more functional group(s) selected from the group consisting of non-aromatic carbon-carbon multiple bonds, oxirane groups and substituted carboxyl groups, and subsequently mixing thereinto (C) a polar compound having in one molecule one or more polar group(s) selected from the group consisting of substituted carboxyl groups, substituted hydroxyl groups, substituted amino groups, substituted mercapto groups, substituted sulfonic acid groups, oxazoline groups, isocyanato groups and oxirane groups, provided that at least one of the polar groups of (C) is different from at least one of the functional groups of the functional compound (B), as well as a process for producing said resin composition.
摘要:
A thermoplastic resin composition superior in impact resistance, heat resistance, flexural rigidity, processability and solvent resistance which comprises: (A) 100 parts by weight of a resin composition comprising 5-95% by weight of a polyphenylene ether, or a polyphenylene ether and polystyrene, and 95-5% by weight of a polyamide resin; (B) 5-50 parts by weight of a modified saturated rubber obtained by grafting 5-100 parts by weight of an aromatic vinyl compound on 100 parts by weight of a saturated type rubber and allowing 0.05-10 parts by weight of a compatibilizing agent to react with said rubber; and (c) 0.05-20 parts by weight of a compatibilizing agent.
摘要:
Disclosed is a thermoplastic resin composition comprising a polyphenylene ether and a polyamide and excellent in impact strength wherein an impact strength modifier having structure A--B--A (A or B is styrene) is partially dispersed in said polyphenylene ether and has layered or spherical structure of about 0.02-0.07 .mu.m.A process for producing the thermoplastic resin composition is also disclosed which comprises (1) previously melt kneading (i) at least one compatibilizing agent in an amount effective for compatibilization and (ii) a polyphenylene ether, and then (2) adding (iii) a polyamide in an amount necessary for formation of continuous phase and (iv) an impact strength modifier having structure A--B--A (A or B is styrene) and melt kneading the mixture at a maximum shear rate of 700 sec.sup.-1 or more.
摘要:
There is provided a polymer composition having improved discoloration resistance upon exposure to light comprising a polyphenylene ether, a polyamide, and a combination of (a), a inorganic filler selected from the group consisting of titanium oxide, zinc oxide, zinc sulfide, aluminum oxide, magnesium oxide, titanium oxide coated mica, and metal particles, and (b), an organic dye or pigment which bleaches upon exposure to light, in an amount effective to improve the discoloration resistance.
摘要:
A thermoplastic resin composition having a good balance among rigidity, impact strength and adhesion of coating is provided, which comprises:a total of 100 parts by weight of (a)-(c) wherein (a) is 1-60% by weight of a polyphenylene ether, (b) 0-60% by weight of an alkenyl aromatic resin excluding unhydrogenated alkenyl aromatic block copolymer of tile following component (e) and (c) 40-99% by weight of a polyamide,(d) 1-50 parts by weight of a polyolefin having a modulus of 10000 kg/cm2 or more at room temperature,(e) 1-50 parts by weight of an unhydrogenated alkenyl aromatic block copolymer, and(f) a compatibilizing agent in an amount necessary to improve compatibility of the above components (a) and (c), said (d)-(f) being every 100 parts by weight of (a)-(c), and wherein the thermoplastic resin composition is obtained by melt kneading firstly said (a), (d) and (f) and then secondly said (c) therewith.
摘要:
A resin composition having improved resistance to discoloration by sunlight comprising (A) a polymer mixture which comprises a polyphenylene ether, a polyamide and optionally a polystyrene and/or an agent to improve the impact resistance, and (B) an inorganic powder whose mean particle size is less than or equql to 5 micrometer, in an amount of more than or equal to 15 parts by weight based on 100 parts by weight of the polyphenylene ether in the polymer mixture (A), which is selected from the group consisting of titanium oxide, mica coated with titanium oxide, barium sulphate, zinc oxide and zinc sulfide.
摘要:
The present invention provides a thermoplastic resin composition which comprises:(i) at least one compatibilizing agent in an amount effective for compatibilization,(ii) (A) a polyphenylene ether in an amount of about 40-100% by weight based on the total amount of (A) and (B) and(B) a homopolymer of alkenyl aromatic compound or a random copolymer of alkenyl aromatic compound and unsaturated compound in an amount of 0-about 60% by weight based on the total amount of (A) and (B), the total amount of (A) and (B) being about 10% by weight or more based on total amount of all polymer components,(iii) at least one polyamide in an amount more than the amount required for forming a continuous phase, and(iv) a compound having a molecular weight of 2,000 or less, containing nitrogen element, and having ring opening or condensation polymerizability or reactivity with acid or amine.
摘要:
A process for making a thermoplastic resin composition which comprises a melting and mixing 100 parts by weight of polyphenylene ether (A) and 0.01-5.0 parts by weight of at least one compound (B) which contains in its molecule both (a) carbon-carbon double bond or carbon-carbon triple bond and (b) carboxyl group, acid anhydride group, acid amide group, imide group, carboxylic acid ester group, epoxy group, amino group or hydroxyl group in the presence of 0.01% or more and less than 0.1% by weight of radical initiator based on the polyphenylene ether (A),said polyphenylene ether (A) being obtained by oxidation-polymerization of at least one phenol compound represented by the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 represent a hydrogen atom, a halogen atom, a hydrocarbon or a substituted hydrocarbon group, with a proviso that at least one of them is a hydrogen atom, and said polyphenylene ether (a) having a reduced viscosity .eta..sub.sp/c of 0.40-0.58 deciliter/gram.
摘要翻译:一种制备热塑性树脂组合物的方法,其包括熔融并混合100重量份的聚苯醚(A)和0.01-5.0重量份的至少一种化合物(B),其在分子中包含(a)碳 - 碳双键或碳 - 碳三键,和(b)羧基,酸酐基,酰胺基,酰亚胺基,羧酸酯基,环氧基,氨基或羟基,在0.01%以上 相对于聚苯醚(A)为0.1重量%以上的自由基引发剂,所述聚苯醚(A)是通过至少一种由下式表示的酚化合物的氧化聚合得到的:其中R1,R2,R3, R 4和R 5表示氢原子,卤素原子,烃基或取代的烃基,条件是它们中的至少一个是氢原子,并且所述聚苯醚(a)具有降低的粘度eta sp / c 0.40-0.58分升/克。
摘要:
A novel thermoplastic resin composition excellent in heat resistance, mechanical properties and processability is provided which comprises a composition containing (A) a dispersing phase of polyphenylene ether obtained by oxidation polymerization of at least one phenol compound represented by the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 each represents a hydrogen atom, a halogen atom or a substituted or unsubstituted hydrocarbon residue and at least one of them is a hydrogen atom and (B) a crystalline thermoplastic resin matrix phase and (C) a mutual compatibilizer compatible with (A) and/or (B), an average particle diameter in said dispersing phase having of 0.01-10 .mu..
摘要:
A resin composition superior in impact resistance is provided which comprises (a) a polyphenylene ether and (b) an unsaturated aliphatic hydrocarbon, and, if necessary, (c) a polyolefin resin. These resin compositions are obtained by melt kneading the components (a) and (b) or the components (a), (b) and (c).