摘要:
A process for forming an oxide layer includes forming a first oxide portion over a substrate at a temperature below a threshold temperature. A second oxide portion is formed under the first oxide portion at a temperature above the threshold temperature. The substrate is illustratively oxidizable silicon and the threshold temperature is the viscoelastic temperature of silicon dioxide.
摘要:
According to the present invention, the dishing of copper during chemical mechanical polishing (CMP) process can be significantly reduced, and in most instances eliminated, by the use of electroplated alloys of copper whereas the alloying metal forms a continuous solid solution with the copper. By forming electroplated alloys of copper with metals that form continuous solid solutions therewith, a deposition layer of such an alloy on the surface of a barrier metal layer allows for lowering the selectivity of the slurry polish used during the CMP process towards the alloy. The alloys of copper with metals that form a continuous solid solution in an electroplating process changes the oxidation characteristics, mechanical properties, electrical properties, stiffness parameters and hardness parameters of the copper. The change in these properties allows the alloy layer and barrier layer to be polished at an equivalent rate until the entire barrier layer has been polished. In this manner, dishing of the copper in the trenches of a wafer from the CMP process can be avoided.
摘要:
An apparatus for determining the endpoint in a chemical mechanical polishing operation used for polishing a metal-containing material includes an electrochemical cell and an electronic circuit. An acidic polishing slurry is used to oxidize the metal and the oxidized metal is included in an effluent slurry stream, a sample of which is provided to the apparatus. The apparatus includes a liquid-phase working electrode, a reference electrode and a solid electrolyte which allows for the interchange of ions between the electrodes. An electronic circuit is coupled to the electrode for monitoring the component activity of the effluent slurry stream by measuring the electric potential across the electrodes. When the measured electric potential changes, indicating a change in the composition of the effluent slurry, endpoint is indicated.
摘要:
A method of making a capacitor includes the steps of forming an interconnection line above a substrate, depositing a first dielectric layer on the interconnection line, and etching a via in the first dielectric layer. The via has a tapered width which increases in a direction toward the substrate. Further, the method includes filling the via with a conductive metal to form a metal plug, and etching a trench in the first dielectric layer around an upper portion of the metal plug. The metal plug has a tapered width which secures it into the dielectric layer. A second dielectric layer is deposited adjacent the metal plug and an upper electrode is deposited on the second dielectric layer. Preferably, a lower electrode is deposited to line the trench and contact the metal plug.
摘要:
A method of preventing diffusion penetration of the dopant used to dope polysilicon gate material in a MOSFET is disclosed. Atomic nitrogen is introduced into the substrate prior to gate oxide growth. The nitrogen later diffuses upward into the gate oxide and blocks subsequent ion implanted gate dopants from penetrating to the substrate. Low dosages of atomic nitrogen implantation, while not significantly affecting gate oxide growth rate, produce significant improvements in the damage immunity of thin gate oxides.