公开(公告)号：US06458990B1

公开(公告)日：2002-10-01

申请号：US09987613

申请日：2001-11-15

申请人： Hiroshi Sonoda ,  Kazunari Okada ,  Akira Takahashi ,  Kouki Fukumura ,  Hidetoshi Hayashi ,  Teruyuki Nagata ,  Yasuhiro Takano

发明人： Hiroshi Sonoda ,  Kazunari Okada ,  Akira Takahashi ,  Kouki Fukumura ,  Hidetoshi Hayashi ,  Teruyuki Nagata ,  Yasuhiro Takano

IPC分类号： C07C1716

CPC分类号： C07D233/68 ,  C07B39/00 ,  C07C17/16 ,  C07C17/18 ,  C07C51/60 ,  C07C205/12 ,  C07D233/02 ,  C07C22/08 ,  C07C19/01 ,  C07C21/18 ,  C07C22/04 ,  C07C19/075 ,  C07C23/10 ,  C07C19/08 ,  C07C25/18 ,  C07C25/13

摘要： Disclosed are a fluorinating agent represented by the general formula (1): wherein R1 to R4 are a substituted or unsubstituted, saturated or unsaturated alkyl group or a substituted or unsubstituted aryl group, and can be the same or different; R1 and R2 or R3 and R4 can bond to form a ring including a nitrogen atom or a nitrogen atom and other hetero atoms; or R1 and R3 can bond to form a ring including a nitrogen atom or a nitrogen atom and other hetero atoms, for example: a preparation process of the fluorinating agent and a process for preparing fluorine compounds by reacting various compounds with the fluorinating agent. The invention has also disclosed that the fluorinating agent is very effective for fluorinating oxygen containing functional compounds.

摘要翻译： 公开了由通式（1）表示的氟化剂：其中R 1至R 4是取代或未取代的饱和或不饱和的烷基或取代或未取代的芳基，并且可以相同或不同; R1和R2或R3和R4可键合形成包含氮原子或氮原子和其它杂原子的环; 或者R1和R3可以键合形成包含氮原子或氮原子和其它杂原子的环，例如：氟化剂的制备方法和通过使各种化合物与氟化剂反应制备氟化合物的方法。 本发明还公开了氟化剂对于含氟官能化合物的氟化是非常有效的。

公开(公告)号：US6127583A

公开(公告)日：2000-10-03

申请号：US282436

申请日：1999-03-31

申请人： Hiroshi Sonoda ,  Kazunari Okada ,  Kenichi Goto ,  Kouki Fukumura ,  Junko Naruse ,  Hidetoshi Hayashi ,  Teruyuki Nagata ,  Akira Takahashi

发明人： Hiroshi Sonoda ,  Kazunari Okada ,  Kenichi Goto ,  Kouki Fukumura ,  Junko Naruse ,  Hidetoshi Hayashi ,  Teruyuki Nagata ,  Akira Takahashi

IPC分类号： C07B35/06 ,  C07C1/24 ,  C07C37/00 ,  C07C205/06 ,  C07C15/48 ,  C07C15/54 ,  C07C39/18

CPC分类号： C07B35/06 ,  C07C1/24 ,  C07C201/12 ,  C07C37/002

摘要： A preparation process of an acetylene derivative comprising reacting a compound having a skeleton represented by the formula (1): ##STR1## in the molecular formula with a compound represented by the formula (2): ##STR2## wherein R.sup.1, R.sup.2 R.sup.3 and R.sup.4 are individually an alkyl group having 1 to 6 carbon atoms and can be the same or different, R.sup.1 and R.sup.3 can bond each other to form a ring, and R.sup.1 and R.sup.2 or R.sup.3 and R.sup.4 can be bond each other to form one or two heterocyclic rings: or with a compound represented by the formula (3): wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are the same as in the formula (2), and X.sub.1 is a ##STR3## chlorine, bromine or iodine atom.

摘要翻译： 一种乙炔衍生物的制备方法，其包括使分子式中具有式（1）表示的骨架的化合物与式（2）表示的化合物反应：其中R1，R2，R3和R4各自为具有 1至6个碳原子并且可以相同或不同，R 1和R 3可以彼此键合形成环，并且R 1和R 2或R 3和R 4可以彼此键合形成一个或两个杂环：或与化合物 由式（3）表示：其中R1，R2，R3和R4与式（2）中相同，X1是氯，溴或碘原子。

公开(公告)号：US06100362A

公开(公告)日：2000-08-08

申请号：US946347

申请日：1997-10-07

申请人： Koju Okazaki ,  Yoshinobu Kanemura ,  Teruyuki Nagata

发明人： Koju Okazaki ,  Yoshinobu Kanemura ,  Teruyuki Nagata

IPC分类号： G02B1/04 ,  C07C319/20 ,  C07C321/14 ,  C08G18/30 ,  C08G18/38 ,  C08G18/52 ,  C08G18/77

CPC分类号： C08G18/775 ,  C07C321/14 ,  C08G18/3876 ,  C08G18/52 ,  G02B1/041

摘要： A polythiol having four or more functional groups, a process for producing the polythiol comprising reacting thiourea with a specific compound, a sulfur-containing urethane-based resin prepared from the polythiol and a lens made of the resin. The resin has a high refractive index, and low dispersion of refractive index, is lightweight, colorless and transparent, has no optical distortion, and has excellent characteristics in weatherability, dye-affinity, heat resistance, impact resistance and machinability.

摘要翻译： 具有四个或更多个官能团的多硫醇，一种制备多硫醇的方法，包括使硫脲与特定化合物反应，由多硫醇制备的含硫氨基甲酸酯基树脂和由树脂制成的透镜。 该树脂折射率高，折射率分散性低，重量轻，无色透明，无变形，耐候性，染料亲合性，耐热性，耐冲击性和切削性优异。

公开(公告)号：US5647896A

公开(公告)日：1997-07-15

申请号：US544986

申请日：1995-10-30

申请人： Takeshi Nishimura ,  Tomoko Kamashita ,  Masaru Wada ,  Teruyuki Nagata ,  Yoshimitsu Tanabe ,  Kiyoharu Hasegawa ,  Masakatsu Nakatsuka

发明人： Takeshi Nishimura ,  Tomoko Kamashita ,  Masaru Wada ,  Teruyuki Nagata ,  Yoshimitsu Tanabe ,  Kiyoharu Hasegawa ,  Masakatsu Nakatsuka

IPC分类号： B41M5/155 ,  C09D11/02

CPC分类号： B41M5/155

摘要： Provided are a color-developing agent comprising a multivalent metal salt of a salicylic acid derivative and a sulfonated phenol and/or a metal salt thereof and having excellent initial and ultimate color-developing capacities and improved waterproofness; and a color-developing sheet making use of the color-developing agent.

摘要翻译： 提供一种显色剂，其包含水杨酸衍生物的多价金属盐和磺化苯酚和/或其金属盐，并且具有优异的初始和最终显色能力和改善的防水性; 和使用显色剂的显色片。

公开(公告)号：US5618980A

公开(公告)日：1997-04-08

申请号：US640022

申请日：1996-04-30

申请人： Teruyuki Nagata ,  Chiyuki Kusuda ,  Masaru Wada ,  Kenichi Satou ,  Masae Uchida

发明人： Teruyuki Nagata ,  Chiyuki Kusuda ,  Masaru Wada ,  Kenichi Satou ,  Masae Uchida

IPC分类号： C07C209/00 ,  C07C209/28 ,  C07C209/52 ,  C07C209/68

CPC分类号： C07C209/00 ,  C07C209/28 ,  C07C209/52 ,  C07C209/68

摘要： Disclosed are (1) a method for preparing an aromatic secondary amino compound which comprises reacting an N-cyclohexylideneamino compound in the presence of a hydrogen moving catalyst and a hydrogen acceptor by the use of a sulfur-free polar solvent and/or a cocatalyst, and(2) a method for preparing an aromatic secondary amino compound which comprises reacting cyclohexanone or a nucleus-substituted cyclohexanone, an amine and a nitro compound corresponding to the amine in a sulfur-free polar solvent in the presence of a hydrogen moving catalyst, a cocatalyst being added or not added. In a further aspect, a method is provided for the preparation of aminodiphenylamine by reacting phenylenediamine and cyclohexanone in the presence of a hydrogen transfer catalyst in a sulfur-free polar solvent while using nitroaniline as a hydrogen acceptor.

摘要翻译： 公开的是（1）一种制备芳香族仲氨基化合物的方法，其包括在氢移动催化剂和氢受体存在下，通过使用无硫极性溶剂和/或助催化剂使N-亚环己基氨基化合物反应， 和（2）一种制备芳族仲氨基化合物的方法，其包括在氢移动催化剂存在下，在无硫极性溶剂中使环己酮或核取代的环己酮，对应于胺的胺和硝基化合物反应， 添加或不添加助催化剂。 在另一方面，提供了一种通过在氢转移催化剂存在下，在无硫极性溶剂中使苯二胺和环己酮反应制备氨基二苯胺的方法，同时使用硝基苯胺作为氢受体。

公开(公告)号：US5583256A

公开(公告)日：1996-12-10

申请号：US494735

申请日：1995-06-26

申请人： Hiroshi Naruse ,  Hideki Mizuta ,  Shinichi Umeda ,  Teruyuki Nagata

发明人： Hiroshi Naruse ,  Hideki Mizuta ,  Shinichi Umeda ,  Teruyuki Nagata

IPC分类号： C07C275/14 ,  C07D233/34

CPC分类号： C07D233/34 ,  C07C275/14

摘要： A novel bis-urea compound, preparation process of the compound, and preparation process of 1,3-dialkyl-2-imidazolidinone are disclosed and the disclosure provides a novel preparation process of 1,3-dialkyl-2-imidazolidinone and simultaneously enables effective utilization of N,N',N"-trialkyldiethylentriamine which lacks a large amount use and is desired to develop new application.

摘要翻译： 公开了一种新的双脲化合物，该化合物的制备方法和1,3-二烷基-2-咪唑烷酮的制备方法，本公开提供了1,3-二烷基-2-咪唑烷酮的新型制备方法，同时使得有效 利用缺乏大量使用的N，N'，N“ - 三烷基二乙基三胺，需要开发新的应用。

公开(公告)号：US5545752A

公开(公告)日：1996-08-13

申请号：US458294

申请日：1995-06-02

申请人： Teruyuki Nagata ,  Chiyuki Kusuda ,  Masaru Wada

发明人： Teruyuki Nagata ,  Chiyuki Kusuda ,  Masaru Wada

IPC分类号： C07C209/18 ,  C07C209/28

CPC分类号： C07C209/18 ,  C07C209/28

摘要： A processes for the preparation of diphenylamine or a nucleus-substituted derivative thereof, which comprise, upon feeding into a reaction system a phenol compound and reacting in the reaction system a cyclohexanone compound with an aniline compound in the presence of a hydrogen transfer catalyst and a catalytic amount of the cyclohexanone compound corresponding to the phenol compound while using the phenol compound as a hydrogen acceptor and forming the cyclohexanone compound in the reaction system, (1) conducting reaction while adding dropwise the aniline compound and (2) employing a hydroxide, carbonate or bicarbonate of an alkali metal and/or alkaline earth metal when the hydrogen transfer catalyst is one of noble metals of Group VIII of the periodic table, respectively.

摘要翻译： 一种二苯胺或其取代衍生物的制备方法，其包括在反应体系中加入酚化合物，并在氢转移催化剂存在下使反应体系中的环己酮化合物与苯胺化合物反应， 催化量的对应于酚化合物的环己酮化合物，同时使用酚化合物作为氢受体并在反应体系中形成环己酮化合物，（1）在滴加苯胺化合物的同时进行反应，和（2）使用氢氧化物，碳酸酯 或氢过渡催化剂分别为周期表第Ⅷ族贵金属之一时，碱金属和/或碱土金属的碳酸氢盐。

公开(公告)号：US5449829A

公开(公告)日：1995-09-12

申请号：US260903

申请日：1994-06-15

申请人： Chiyuki Kusuda ,  Masaru Wada ,  Teruyuki Nagata

发明人： Chiyuki Kusuda ,  Masaru Wada ,  Teruyuki Nagata

IPC分类号： C07C209/26 ,  C07C209/28 ,  C07C209/04

CPC分类号： C07C209/28 ,  C07C209/26

摘要： A diphenylamine with both the phenyl groups being substituted is prepared by reacting a phenol with ammonia in the presence of a hydrogen transfer catalyst and a cyclohexanone; or by converting a portion of the phenol to the cyclohexanone in the presence of a hydrogen transfer catalyst and under hydrogen pressure and then reacting the remaining portion of the phenol with ammonia in the presence of the cyclohexanone so converted and the hydrogen transfer catalyst. The diphenylamine can be obtained very efficiently.

摘要翻译： 具有两个苯基取代的二苯胺通过在氢转移催化剂和环己酮的存在下使苯酚与氨反应来制备; 或者通过在氢转移催化剂的存在下和在氢气压力下将一部分酚转化为环己酮，然后在所转化的环己酮和氢转移催化剂的存在下使酚的剩余部分与氨反应。 可以非常有效地获得二苯胺。

公开(公告)号：US5194559A

公开(公告)日：1993-03-16

申请号：US854583

申请日：1992-03-20

申请人： Koju Okazaki ,  Masahiko Kusumoto ,  Hiroyuki Yamashita ,  Teruyuki Nagata

发明人： Koju Okazaki ,  Masahiko Kusumoto ,  Hiroyuki Yamashita ,  Teruyuki Nagata

IPC分类号： C08G18/38 ,  C08G18/70 ,  C08G18/77 ,  C08G18/80 ,  G02B1/04

CPC分类号： C08G18/8064 ,  C08G18/3876 ,  C08G18/70 ,  C08G18/775 ,  G02B1/04

摘要： Optical urethane resins according to the present invention are each obtained by reacting an active hydrogen compound with an isocyanate compound containing as a stabilizer a phenolic compound. Owing to their low yellowness, high light transmittance and optical-strain-free quality, these resins are useful as optical materials for plastic lenses or the like which are required to be colorless, transparent and uniform.

公开(公告)号：US4918186A

公开(公告)日：1990-04-17

申请号：US320228

申请日：1989-03-07

申请人： Nobuyuki Kajimoto ,  Teruyuki Nagata ,  Masaru Wada

发明人： Nobuyuki Kajimoto ,  Teruyuki Nagata ,  Masaru Wada

IPC分类号： C07D233/32 ,  C07D239/10 ,  C07D243/04 ,  C07D263/22

CPC分类号： C07D239/10 ,  C07D233/32 ,  C07D243/04 ,  C07D263/22

摘要： A process for producing a cyclic urea is provided. The process comprises reacting a diamine expressed by the formula (II)R-HN-R'-NH-R (II)wherein R represents hydrogen atom or a lower alkyl group and R' represent dimethylene group, a lower alkyl group-substituted dimethylene group, trimethylene group, a lower alkyl group-substituted trimethylene group, tetramethylene group, a lower alkyl group-substituted tetramethylene group, but a case where R represents hydrogen atom and R' represent dimethylene group, a case where R represents hydrogen atom and R' represents a lower alkyl group-substituted dimethylene group and a case where R represent methyl group and R' represents dimethylene group are excluded, with phosgene in the presence of a dehydrochlorinating agent. In the process, the diamine is first converted to its hydrochloride, followed by reacting the hydrochloride with phosgene in water solvent while maintaining a pH of the reaction liquid in the range of 5.0 to 8.0 by said dehydrochlorinating agent to obtain a cyclic urea expressed by the formula (I) ##STR1## wherein R and R' are each as defined above.

摘要翻译： 提供了一种制备环状尿素的方法。 该方法包括使由式（II）R-HN-R'-NH-R（II）表示的二胺反应，其中R表示氢原子或低级烷基，R'表示二亚甲基，低级烷基取代的二亚甲基 基团，三亚甲基，低级烷基取代的三亚甲基，四亚甲基，低级烷基取代的四亚甲基，但是R表示氢原子，R'表示二亚甲基的情况，R表示氢原子，R '表示低级烷基取代的二亚甲基，并且在脱氯化氢剂的存在下，光气被排除在外，R表示甲基，R'表示二亚甲基的情况。 在此过程中，首先将二胺转化为盐酸盐，然后将盐酸盐与光气在水溶剂中反应，同时用上述脱氯化氢将反应液的pH值保持在5.0〜8.0的范围内，得到由 式（I）其中R和R'各自如上所定义。