Fluoride-containing crystalline alumino-silicates
    61.
    发明授权
    Fluoride-containing crystalline alumino-silicates 失效
    含氟化物的结晶铝氧化物

    公开(公告)号:US3702312A

    公开(公告)日:1972-11-07

    申请号:US3702312D

    申请日:1970-10-05

    申请人: SHELL OIL CO

    发明人: WILSON WILLIAM B

    摘要: A NOVEL CRYSTALLINE ALUMINO-SILICATE CONTAINING FLUORINE INCORPORATED INTO THE CRYSTALLINE STRUCTURE IS PREPARED BY TREATING A DIVALENT ALKALINE EARTH METAL FORM OF THE ALUMINO-SILICATE SEQUIENTIALLY WITH A SEQUESTERING AGENT FOLLOWED BY TREATMENT WITH A SOLUTION OF ALUMINUM, FLUORIDE AND CHORIDE IONS. THE FLUORIDE-CONTAINING ALUMINO-SILICATES ARE HIGHLY ACTIVE AND STABLE HYDROCONVERSION CATALYSTS WHEN COMPSITED WITH A HYDROGENATIVE METAL COMPONENT.

    Production of stabilized aluminum bromide solutions
    65.
    发明授权
    Production of stabilized aluminum bromide solutions 失效
    生产稳定的溴化铝溶液

    公开(公告)号:US3666686A

    公开(公告)日:1972-05-30

    申请号:US3666686D

    申请日:1969-05-07

    IPC分类号: B01J27/06 C01F7/64 B01J11/78

    CPC分类号: C01F7/64 B01J27/06

    摘要: Stabilized solutions of aluminum bromide in cyclohexane are produced by adding 0.5 - percent by volume of benzene or 0.5 - 2 percent by weight of triphenol (1,1,3(3-hydroxyphenyl) propane). The rapid degradation of unstabilized solutions at room temperature is markedly retarded for a period of at least 30 days so that the solutions may be shipped and stored and used instead of solid aluminum bromide as a Lewis acid type catalyst.

    摘要翻译: 通过加入0.5体积%的苯或0.5-2重量%的三酚[1,1,3(3-羟基苯基)丙烷]来制备溴化铝在环己烷中的稳定化溶液。 在室温下不稳定溶液的快速降解显着延迟至少30天的时间,因此溶液可以运输和储存并用于代替固体溴化铝作为路易斯酸型催化剂。

    Lead dioxide stabilization
    67.
    发明授权
    Lead dioxide stabilization 失效
    二氧化铅稳定

    公开(公告)号:US3661804A

    公开(公告)日:1972-05-09

    申请号:US3661804D

    申请日:1970-04-03

    申请人: POLYCHEMIE GMBH

    IPC分类号: C01G21/08 B01J11/78

    CPC分类号: C01G21/08

    摘要: STABILIZATION OF THE OXIDIZING CAPACTIY OF LEAD DIOXIDE TO PREVENT ACCELERATION THEREOF CAUSED BY HEAT WHICH IS OBTAINED BY THE ADDITION OF 0.1 TO 15% BY WEIGHT, BASED ON THE LEAD DIOXIDE, OF A MULTIVALENT METAL SALT WHEREIN THE METAL IS TIN, ZINC CADMIUM, NICKEL, COBALT, MANGANESE, IRON, CHROMIUM, BISMUTH, VANADIUM, TUNGSTEN OR MOLYBDENUM.

    Preparation of a crystalline aluminosilicate-alumina catalyst composition
    69.
    发明授权
    Preparation of a crystalline aluminosilicate-alumina catalyst composition 失效
    一种结晶铝氧化铝 - 氧化铝催化剂组合物的制备

    公开(公告)号:US3644219A

    公开(公告)日:1972-02-22

    申请号:US3644219D

    申请日:1970-02-11

    发明人: MITSCHE ROY T

    CPC分类号: C07C6/123 B01J29/18

    摘要: A method of preparing a catalyst composition comprising as essential components thereof, a crystalline aluminosilicate with a mordenite crystal structure containing alumina fixed in combination therewith. The catalyst composition is aged in an alkaline media to yield a catalyst substantially improved in activity, particularly with respect to the transalkylation of alkylaromatic hydrocarbons.

    摘要翻译: 一种制备包含其主要成分的催化剂组合物的方法,结晶硅铝酸盐与丝光沸石晶体结构包含与其组合固定的氧化铝。 催化剂组合物在碱性介质中老化以产生显着改善活性的催化剂,特别是关于烷基芳烃的烷基转移。

    Process for oxychlorination of ethylene
    70.
    发明授权
    Process for oxychlorination of ethylene 失效
    乙烯氧化方法

    公开(公告)号:US3624170A

    公开(公告)日:1971-11-30

    申请号:US3624170D

    申请日:1967-04-05

    CPC分类号: C07C17/156 B01J27/10

    摘要: There is provided an improvement in the process for the catalytic gas phase oxychlorination of ethylene. The process comprises reacting ethylene, hydrogen chloride and a member of the group of air and oxygen in an iron-type reactor to produce, 1,2-dichloroethane. The improvement of the invention relates to conducting the reaction at a temperature of about 220* C. to about 300* C. and in the presence of a catalyst supported on an inert porous carrier and comprising copper, sodium and magnesium in an atomic ratio of Cu:Na:Mg of 1:0.2 to 0.7:0.3 to 1.5. The novel catalyst compositions are also provided.