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    Production of secondary alkyl primary amines
    6.
    发明授权
    Production of secondary alkyl primary amines 失效
    仲烷基伯胺的生产

    公开(公告)号：US3923893A

    公开(公告)日：1975-12-02

    申请号：US42863973

    申请日：1973-12-26

    申请人： TEXACO INC

    发明人： GATES JR WALTER C ,  SUGGITT ROBERT M ,  HUDSON JR RALPH B

    IPC分类号： C07C7/163 ,  C07C85/11 ,  C07C85/00 ,  C07C87/04

    CPC分类号： C07C7/163 ,  C07C9/00

    摘要： A process for producing secondary alkyl primary amines from nparaffins where a portion of the paraffin is nitrated to nitroparaffin along with the formation of nitrated and oxygenated by-products, where the nitroparaffin is essentially completely hydrogenated to the amine, and where the amine is separated from a mixture composed of unreacted paraffin and by products, which comprises catalytically hydrogenating the mixture composed of paraffin and by-products in the presence of a catalyst composed of alumina and a Group VIII metal at a temperature of from about 600* to 750*F. and recycling the hydrogenated product for nitration with the n-paraffin.

    摘要翻译： 一种从正链烷烃生产仲烷基伯胺的方法，其中一部分石蜡被硝化为硝基链烷烃，同时形成硝化和含氧副产物，其中硝基石蜡基本上完全氢化成胺，其中胺是 从由未反应的石蜡和产物组成的混合物中分离，其包括在约600至750℃的温度下，在由氧化铝和Ⅷ族金属组成的催化剂存在下，将由石蜡和副产物组成的混合物进行催化氢化 并将氢化产物再循环用于与正链烷烃硝化。

    Homogeneous ruthenium catalysts useful in the selective reduction of nitroaromatics to amines
    10.
    发明授权
    Homogeneous ruthenium catalysts useful in the selective reduction of nitroaromatics to amines 失效
    用于将硝基芳族化合物选择性还原成胺的均相钌催化剂

    公开(公告)号：US3906045A

    公开(公告)日：1975-09-16

    申请号：US46283374

    申请日：1974-04-22

    申请人： TEXACO INC

    发明人： KNIFTON JOHN F ,  SUGGITT ROBERT M

    IPC分类号： C07C209/36 ,  C07F15/00 ,  C07C85/11

    CPC分类号： C07F15/0053 ,  C07C209/36

    摘要： This invention concerns the use of solubilized homogeneous ruthenium catalysts to initially and sequentially reduce the nitro group in mononitroaromatic substrates to the corresponding amine. The reduction must be carried out in a two component mixture consisting essentially of the mononitroaromatic and a mononitro ortho-substituted polyalkylaromatic component. In order to minimize the reduction of said nitropolyalkylaromatic component, the reduction should be halted when between about 80 to 95 % of the mononitroaromatic substrate present is reduced to the corresponding amine.

    摘要翻译： 本发明涉及使用溶解的均相钌催化剂来开始并依次将单硝基芳族底物中的硝基还原成相应的胺。 该还原必须在基本上由单硝基芳族化合物和单硝基邻位取代的聚烷基芳族组分组成的双组分混合物中进行。 为了最小化所述硝基聚烷基芳族成分的还原，当存在的单硝基芳族底物的约80-95％还原成相应的胺时，应该停止还原。