Stabilization of polyvinyl chloride
    62.
    发明授权
    Stabilization of polyvinyl chloride 失效
    聚氯乙烯的稳定化

    公开(公告)号:US4508863A

    公开(公告)日:1985-04-02

    申请号:US578936

    申请日:1984-02-10

    CPC分类号: C08K5/01 C08K5/005 C08K9/04

    摘要: The resistance to deterioration of polyvinyl chloride resins when heated and worked is improved by combinations of polyvinyl chloride resin stabilizers and alpha-olefin oligomers obtained by oligomerization of a 1-olefin having from six to about twelve carbon atoms, and having a highly branched chain with alkyl substituents of at least two carbon atoms.

    摘要翻译: 通过聚氯乙烯树脂稳定剂和通过使具有6至约12个碳原子的1-烯烃低聚而获得的α-烯烃低聚物的组合,并且具有高度支化的链可以改善聚氯乙烯树脂在加热和加工时的耐劣化性, 至少两个碳原子的烷基取代基。

    One-component RTV silicone rubber compositions with good self-bonding
properties to acrylate plastics
    63.
    发明授权
    One-component RTV silicone rubber compositions with good self-bonding properties to acrylate plastics 失效
    单组分RTV硅橡胶组合物与丙烯酸酯塑料具有良好的自粘性能

    公开(公告)号:US4489200A

    公开(公告)日:1984-12-18

    申请号:US483969

    申请日:1983-04-11

    申请人: John J. Dziark

    发明人: John J. Dziark

    IPC分类号: C08K5/57 C08L83/04 C08G77/06

    摘要: The present invention relates to an alkoxy-functional one-component RTV silicone rubber composition with improved adhesion to polyacrylate plastics. The improved adhesion is obtained by utilizing in the composition a pre-reacted mixture having therein the adhesion promoter, silane scavenger and tin condensation catalyst. Optionally there may also be in the mixture, a polyalkoxysilane cross-linking agent.

    摘要翻译: 本发明涉及具有改进的与聚丙烯酸酯塑料的粘附性的烷氧基官能的单组分RTV硅橡胶组合物。 通过在组合物中使用其中具有粘合促进剂,硅烷清除剂和锡缩合催化剂的预反应混合物,获得了改进的粘合性。 任选地,混合物中还可以存在聚烷氧基硅烷交联剂。

    Organohalide polymers stabilized with an organotin compound and an ortho
mercapto phenol compound
    68.
    发明授权
    Organohalide polymers stabilized with an organotin compound and an ortho mercapto phenol compound 失效
    用有机锡化合物和邻位巯基酚化合物稳定的有机卤化物聚合物

    公开(公告)号:US4315850A

    公开(公告)日:1982-02-16

    申请号:US238517

    申请日:1981-02-26

    申请人: Thomas G. Kugele

    发明人: Thomas G. Kugele

    CPC分类号: C08K5/37 C08K5/58

    摘要: Compositions which are effective in stabilizing polymers against the deteriorative effects of heat are provided comprising (1) an organic tin compound or mixture of organic tin compounds, (2) an organic compound having an aromatic ring which is substituted with a hydroxyl (--OH) group and a mercapto (--SH) group ortho to each other, and, optionally, (3) an organotin mercaptide or mixture of organotin mercaptides. Also provided are polymer compositions containing said stabilizers and articles of manufacture made from said stabilized polymer compositions.

    摘要翻译: 提供了有效稳定聚合物以防止热劣化作用的组合物,其包括(1)有机锡化合物或有机锡化合物的混合物,(2)具有被羟基(-OH)取代的芳环的有机化合物, 基团和巯基(-SH)基团彼此邻位,和任选地,(3)有机锡硫醇盐或有机锡硫醇盐的混合物。 还提供了含有由所述稳定化聚合物组合物制成的所述稳定剂和制品的聚合物组合物。

    Process for the production of methyl-alkyl tin dichlorides
    69.
    发明授权
    Process for the production of methyl-alkyl tin dichlorides 失效
    甲基 - 烷基二氯化锡的生产方法

    公开(公告)号:US4301085A

    公开(公告)日:1981-11-17

    申请号:US140404

    申请日:1980-04-14

    IPC分类号: C08K5/00 C07F7/22 C08K5/57

    CPC分类号: C07F7/2216

    摘要: A process for the production of compounds of the formula ICH.sub.3 (R)SnCl.sub.2 (I)wherein R is C.sub.4 -C.sub.20 alkyl, which process comprises reacting dimethyl tin dichloride and R-Cl, wherein R has the above meaning, in the presence of a catalyst of the formula IIR'(R").sub.3 M.sup..sym. X.sup..crclbar. (II)wherein R' is C.sub.1 -C.sub.20 alkyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 alkoxy, or is C.sub.7 -C.sub.20 aralkyl, the aryl moiety of which can be substituted by halogen or C.sub.1 -C.sub.4 alkoxy, R" has the same meaning as assigned to R' or is phenyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or halogen, M.sup..sym. is a cation N, P or Sb, and X is an anion selected from the group consisting of chlorine, SnCl.sub.3, CH.sub.3 -SnCl.sub.4, (CH.sub.3).sub.2 SnCl.sub.3, SnCl.sub.5 or SbCl.sub.4.The compounds of the formula I are intermediates for obtaining stabilizers for halogen-containing thermoplastics.

    摘要翻译: 制备式I CH 3(R)SnCl 2(I)的化合物的方法,其中R是C 4 -C 20烷基,该方法包括使二氯化二甲基锡和R-Cl反应,其中R具有上述含义,在 式II R'(R“)3M(+)X( - )(II)的催化剂其中R'是未被取代或被C 1 -C 4烷氧基取代的C 1 -C 20烷基,或者是C 7 -C 20芳烷基, 其可以被卤素或C 1 -C 4烷氧基取代,R“具有与R'相同的含义,或者是未被取代或被C 1 -C 4烷基,C 1 -C 4烷氧基或卤素取代的苯基,M(+)​​是阳离子N ,P或Sb,X为选自氯,SnCl 3,CH 3 -SiCl 4,(CH 3)2 SnCl 3,SnCl 5或SbCl 4的阴离子。 式I化合物是用于获得含卤素热塑性塑料的稳定剂的中间体。