摘要:
The present invention relates to bis(fluorosulfonyl)imide salts, and their preparation methods. More specifically, the invention provides a new salt of bis(fluorosulfonyl)imide containing from 0.01 ppm to 10000 ppm of a halogenated alcohol. The invention further relates to a method for producing said salt of bis(fluorosulfonyl)imide, said method comprising a step of crystallizing a raw salt of bis(fluorosulfonyl)imide within a crystallization solvent comprising at least a halogenated alcohol. The use of said salt of bis(fluorosulfonyl)imide is also disclosed.
摘要:
Provided are an internal olefin sulfonate composition which shows excellent hue stability and excellent smell stability even when preserved for a long period of time, and a method for preserving an internal olefin sulfonate. The internal olefin sulfonate composition according to the present invention comprises an internal olefin sulfonate, one or more kinds of alkaline agents selected from among an alkali metal hydroxide and an alkaline earth metal hydroxide and water, wherein the content of the alkaline agents is 0.2 to 15 mmol inclusive per mol of the internal olefin sulfonate. The method according to the present invention for preserving an internal olefin sulfonate comprises mixing the internal olefin sulfonate at least with an alkaline agent to give a composition wherein the content of the alkaline agent is 0.2 to 15 mmol inclusive per mol of the internal olefin sulfonate.
摘要:
The present invention relates to a method of carrying out an organic reaction in aqueous solution in the presence of a hydroxyalkyl(alkyl)cellulose or an alkylcellulose.
摘要:
A process for preparing optically pure enantiomers of R-(-)tamsulosin of formiula Ia and S-(+)tamsulosin of formula Ib by resolving racemic tamsulosin of formula I by means of (IR)-(-)-camphor-10-sulfonic acid and (1S)-(+)-camphor-10-sulfonic acid, resp., in an environment of organic solvents, water or mixtures thereof.
摘要:
The invention provides a granular anionic surfactant and a detergent composition blended with the same. Disclosed are a process for producing a granular anionic surfactant, which including stirring particles containing 50 to 100 wt % of an anionic surfactant at a temperature at which the anionic surfactant exhibits thermoplasticity at a stirring Froude number as defined below by equation (i) of 0.1 or more and less than 2.0; a granular anionic surfactant obtained by the process; a granular anionic surfactant having a surface roughness (Ra) of 1.0 μm or less; and a detergent composition comprising the granular anionic surfactant. Fr=V/[(R×g)0.5] (i) wherein Fr is Froude number, V is the peripheral speed at the top of a stirring blade [m/s], R is the radius of gyration of a stirring blade [m], and g is the acceleration of gravity [m/s2].
摘要:
Nitroxyl inhibitors in combination with some oxygen reduce the premature polymerization of vinyl aromatic monomers during the manufacturing processes for such monomers. Even small quantities of air used in combination with the nitroxyl inhibitors result in vastly prolonged inhibition times for said monomers.
摘要:
The present invention relates to novel hydrates of the disodium salt or dipotassium salt of 4,4'-bis(2-sulfostyryl)biphenyl characterized by their water of hydration content, to the crystal forms associated therewith, characterized by their X-ray diffraction pattern, to processes for the preparation, and to their use for the preparation of concentrated formulations of fluorescent whitening agents.
摘要:
A process for separating and recovering paraffin sulphonic acids from mixtures with water and sulphuric acid is described, consisting of: bringing such a mixture into contact under extraction conditions with a saturated aliphatic or cycloaliphatic liquid hydrocarbon; separating an aqueous liquid phase containing sulphuric acid from an organic liquid phase consisting of the extraction solvent containing the paraffin sulphonic acids; and recovering the paraffin sulphonic acids from said organic liquid phase. The process is particularly applicable to products obtained from processes involving the sulphoxidation of paraffins with sulphur dioxide and oxygen, catalyzed by U.V. radiation.
摘要:
The mixture from which sulphuric acid must be separated according to the present invention are those which derive from the sulphoxidation of (C.sub.12 -C.sub.8)-n-paraffins with SO.sub.2 and O.sub.2 in the presence of water and of U.V. light at a temperature comprised within the range of from 25 to 50.degree. C., after the removal of n-paraffins, which separate spontaneously, and of SO.sub.2 excess. In order to remove said sulphuric acid, the refined mixture, possibly diluted with water, is mixed with one or more halogenated solvents, the separation being obtained of water and sulphuric acid from the refined mixture, to the total mixture (with the two phases) a cosolvent is added, which is constituted by alcohols or ethers, with the separation being obtained of a phase constituted by H.sub.2 O and H.sub.2 SO.sub.4, which is removed. The residual organic phase, practically free from sulphuric acid, is submitted to the removal of solvents and cosolvents by means of conventional techniques.
摘要:
A process for the removal of water from a lower alkanesulfonic acid-water mixture by causing the mixture to run down the internal walls of two vertical evaporator columns operated in series, is disclosed herein.