-
公开(公告)号：US06368383B1
公开(公告)日：2002-04-09
申请号：US09589425
申请日：2000-06-07
IPC分类号： B01D5322
CPC分类号： B01D69/12 , B01D53/228 , B01D69/02 , B01D71/024 , B01D2257/104 , B01D2325/021 , B01D2325/26 , C01B13/0255 , C01B2210/0046 , C01B2210/0051
摘要： A method of separating oxygen from an oxygen containing gas with a composite membrane capable of conducting oxygen ions and electrons. In accordance with the method, the composite membrane is subjected to an operational temperature and the oxygen containing gas at a cathode side thereof. The composite membrane has a dense layer, at least one active porous layer contiguous to the dense layer, and at least one porous support layer. The active porous layer has a thickness and a distribution of pore radii. The distribution of pore radii has a standard deviation from a theoretical radius that would produce a maximum operation flux through the thickness when the thickness is about equal to a product of a constant and the square root of the theoretical radius. The constant is a function of a material used to fabricate the active porous layer, the operational temperature and an oxygen partial pressure within the active porous layer, and a porosity and a tortuosity produced by the pore radii. The standard deviation of the log of the theoretical radius is equal to a product of 1.45 and a shape factor, the shape factor being greater than 0 and no greater than about 0.5.
摘要翻译： 从含氧气体中分离出氧和能够导电氧离子和电子的复合膜的方法。 根据该方法，复合膜经受操作温度，阴极侧含有含氧气体。 复合膜具有致密层，与致密层邻接的至少一个活性多孔层和至少一个多孔载体层。 活性多孔层具有孔半径的厚度和分布。 孔半径的分布与理论半径的标准偏差，当理论半径的厚度约等于理论半径的常数和平方根的乘积时，将产生通过厚度的最大工作磁通。 常数是用于制造活性多孔层的材料的功能，活性多孔层内的操作温度和氧分压，以及由孔半径产生的孔隙率和曲折度。 理论半径的对数的标准偏差等于1.45的乘积和形状因子，形状因子大于0且不大于约0.5。
-
72.发明授权Tube and shell reactor with oxygen selective ion transport ceramic reaction tubes 失效管壳反应器采用氧选择离子迁移陶瓷反应管
公开(公告)号：US6139810A
公开(公告)日：2000-10-31
申请号：US89372
申请日：1998-06-03
申请人： Christian Friedrich Gottzmann , Ravi Prasad , Joseph Michael Schwartz , Victor Emmanuel Bergsten , James Eric White , Terry J. Mazanec , Thomas L. Cable , John C. Fagley
发明人： Christian Friedrich Gottzmann , Ravi Prasad , Joseph Michael Schwartz , Victor Emmanuel Bergsten , James Eric White , Terry J. Mazanec , Thomas L. Cable , John C. Fagley
IPC分类号： C01B3/24 , B01J8/00 , B01J8/06 , B01J12/00 , B01J19/24 , C01B3/38 , C01B13/02 , C25B13/08 , B01D52/22
CPC分类号： C01B13/0251 , B01J12/007 , B01J19/2425 , B01J19/2475 , B01J8/009 , C01B3/382 , C01B3/384 , B01J2208/00309 , B01J2208/00477 , B01J2208/00495 , B01J2208/0053 , B01J2208/00539 , B01J2208/00548 , B01J2208/00628 , B01J2219/00117 , B01J2219/00155 , B01J2219/00159 , B01J2219/00162 , B01J2219/00186 , B01J2219/00777 , C01B2203/0233 , C01B2203/066 , C01B2203/0811 , C01B2203/141 , C01B2203/142 , C01B2203/148 , C01B2203/82 , C01B2210/0046 , Y02P20/129
摘要： A reactor comprising: a hollow shell defining a hermetic enclosure; a plurality of tube sheets disposed within said hermetic enclosure, a first one of said plurality of tube sheets defining a first chamber; at least one reaction tube each having a first end and an opposing second end, said first end being fixedly attached and substantially hermetically sealed to one end of said plurality of tube sheets and opening into said first chamber, the second end being axially unrestrained; each of said reaction tubes is comprised of an oxygen selective ion transport membrane with an anode side wherein said oxygen selective ion transport membrane is formed from a mixed conductor metal oxide that is effective for the transport of elemental oxygen at elevated temperatures and at least a portion of said first and second heat transfer sections are formed of metal; each of said reaction tubes includes first and second heat transfer sections and a reaction section, said reaction section disposed between said first and second heat transfer sections; a reforming catalyst disposed about said anode side of said oxygen selective ion transport membrane; a first process gas inlet; a second process gas inlet; and, a plurality of outlets.
摘要翻译： 一种反应器，包括：限定密封外壳的中空壳体; 设置在所述密封外壳内的多个管板，所述多个管板中的第一管板限定第一室; 每个具有第一端和相对的第二端的至少一个反应管，所述第一端固定地附接并且基本上气密地密封在所述多个管板的一端并进入所述第一室，所述第二端轴向无约束; 每个所述反应管由具有阳极侧的氧选择性离子迁移膜组成，其中所述氧选择性离子迁移膜由混合导电金属氧化物形成，所述混合导体金属氧化物对于在升高的温度下运输元素氧和至少一部分 所述第一和第二传热部分由金属形成; 每个所述反应管包括第一和第二传热部分和反应部分，所述反应部分设置在所述第一和第二传热部分之间; 设置在所述氧选择性离子迁移膜的所述阳极侧周围的重整催化剂; 第一工艺气体入口; 第二工艺气体入口; 和多个出口。
-
公开(公告)号：US6117210A
公开(公告)日：2000-09-12
申请号：US848260
申请日：1997-04-29
CPC分类号： B01D53/32 , B01D53/228 , C01B13/0251 , B01D2257/104 , C01B2210/0046
摘要： A process for separating a feed gas stream containing elemental oxygen and at least one other gas into an oxygen product gas stream having a selected concentration of oxygen, by removing the oxygen from a feed gas stream using an ion transport module containing an ion transport membrane having a retentate side and a permeate side to produce both an ultrapure oxygen gas stream emerging from the membrane into the permeate side and a retentate gas stream. The ultrapure oxygen gas stream is blended with an additive gas stream to produce an oxygen product gas stream having a selected concentration of oxygen.
摘要翻译： 一种将含有元素氧和至少一种其它气体的进料气流分离成具有选定浓度的氧气的氧气产物气流的方法，通过使用含有离子迁移膜的离子迁移组件从原料气流中除去氧气， 滞留侧和渗透侧，以产生从膜流入渗透侧的超纯氧气流和滞留气流。 将超纯氧气流与添加气流混合以产生具有选定浓度的氧气的氧产物气流。
-
74.发明授权
公开(公告)号：US6017646A
公开(公告)日：2000-01-25
申请号：US089513
申请日：1998-06-03
IPC分类号： H01M8/02 , B01D53/32 , C01B3/36 , C01B3/38 , C01B13/02 , H01M8/04 , H01M8/06 , H01M8/10 , H01M8/12 , H01M14/00
CPC分类号： C01B3/36 , B01D53/326 , C01B13/0251 , C01B3/386 , H01M8/06 , H01M8/0662 , H01M8/1231 , C01B2210/0046 , C01B2210/0051 , C01B2210/0062 , H01M2008/1293 , H01M2300/0074 , H01M8/04014 , H01M8/04022 , Y02P20/129
摘要： An integrated system utilizing a solid oxide fuel cell and at least one ion transport reactor to generate electric power and a product gas by delivering an oxygen-containing gas, typically air, to a first cathode side of the solid oxide fuel cell and delivering a gaseous fuel to a first anode side. Oxygen ions are transported through a membrane in the fuel cell to the first anode side and exothermally react with the gaseous fuel to generate electric power and heat. The heat and oxygen transport produces a higher-temperature, reduced-oxygen-content gaseous retentate stream exiting the cathode side of the solid oxide fuel cell which is delivered to a first ion transport reactor where a substantial portion of the residual oxygen is transported through an oxygen selective ion transport membrane. A product gas stream is then recovered.
摘要翻译： 一种利用固体氧化物燃料电池和至少一个离子迁移反应器通过将含氧气体（通常为空气）输送到固体氧化物燃料电池的第一阴极侧并产生气体的集成系统， 燃料到第一阳极侧。 氧离子通过燃料电池中的膜输送到第一阳极侧，并与气体燃料放热反应以产生电力和热量。 热和氧传输产生离开固体氧化物燃料电池的阴极侧的更高温度，低氧含量的气态滞留物流，其被输送到第一离子迁移反应器，其中大部分残余氧被输送通过 氧选择性离子迁移膜。 然后回收产物气流。
-
75.发明授权Solid electrolyte ionic conductor with adjustable steam-to-oxygen production 失效固体电解质离子导体，具有可调节的蒸汽 - 氧气生产
公开(公告)号：US5964922A
公开(公告)日：1999-10-12
申请号：US972412
申请日：1997-11-18
CPC分类号： B01D53/32 , B01D53/22 , C01B13/0251 , C10J3/00 , C10J3/723 , B01D2257/106 , C01B2210/0046 , C01B2210/0062 , C10J2300/093 , C10J2300/0956 , C10J2300/0959 , C10J2300/0979 , C10J2300/1671 , C10J2300/1807 , Y02E20/16 , Y02E20/18
摘要： A process for producing a gas stream containing oxygen and steam to feed a coal gasifier or other downstream process by compressing and heating a feed gas stream, and separating the heated feed gas stream into an oxygen-depleted gas stream on a retentate side of an ion transport membrane and an oxygen-containing gas stream on a permeate side. The permeate side is purged with a purge gas stream containing steam to produce a gas stream containing oxygen and steam, and at least a portion of the gas stream containing oxygen and steam is fed to the coal gasifier after blending with a pure oxygen stream recovered from the remaining portion of the purge stream or by a parallel nonpurged ion transport separator in the system to achieve the appropriate steam-to-oxygen ratio for the downstream process.
摘要翻译： 一种用于生产含有氧气和蒸汽的气流以通过压缩和加热进料气流来供给煤气化器或其它下游方法的方法，并将加热的进料气流分离成离子的渗余物侧上的贫氧气体流 输送膜和含氧气流在渗透侧。 用含有蒸汽的吹扫气流吹扫渗透侧，产生含有氧气和蒸汽的气流，并且将含有氧气和蒸汽的气流的至少一部分与从回收的纯氧气流混合后进料到煤气化器 净化流的剩余部分或通过系统中的并联非膨胀离子迁移分离器，以实现用于下游方法的适当的蒸汽 - 氧气比。
-
76.发明授权
公开(公告)号：US5954859A
公开(公告)日：1999-09-21
申请号：US972020
申请日：1997-11-18
IPC分类号： B01D53/04 , B01D53/047 , B01D53/22 , C01B13/02 , C01B21/04
CPC分类号： B01D53/22 , B01D53/0462 , B01D53/047 , B01D53/229 , B01D63/06 , C01B13/0251 , C01B21/0438 , B01D2256/10 , B01D2256/12 , B01D2257/504 , B01D2257/702 , B01D2257/80 , B01D2259/40001 , B01D2259/40052 , B01D2259/40079 , B01D2259/40081 , B01D2313/22 , B01D2313/40 , C01B2210/0046 , C01B2210/0062 , Y02C10/08 , Y02C10/10 , Y02P20/129 , Y02P20/131 , Y02P20/152
摘要： A process for producing an oxygen-depleted gas stream and a high-pressure gas stream containing oxygen and steam by compressing a feed gas stream containing elemental oxygen, heating the feed gas stream, and separating the heated feed gas stream using one or more ion transport modules into the oxygen-depleted gas stream on a retentate side and an oxygen gas stream on a permeate side of an ion transport membrane. The permeate side is purged using a high-pressure purge gas stream containing steam to produce the high-pressure gas stream containing oxygen and steam, which is directed to a turbine to recover power and produce an expanded, lower-pressure gas stream containing oxygen and steam.
摘要翻译： 一种用于通过压缩含有元素氧的进料气流，加热进料气流以及使用一种或多种离子转运分离加热的进料气流来生产贫氧气流和含有氧气和蒸汽的高压气流 模块进入离子传输膜的渗透侧上的贫氧气体流和氧气流。 使用含有蒸汽的高压吹扫气流吹扫渗透侧，以产生含有氧气和蒸汽的高压气流，其被引导至涡轮机以回收功率并产生膨胀的低压气流，所述气体流包含氧气和 蒸汽。
-
77.发明授权
公开(公告)号：US5938822A
公开(公告)日：1999-08-17
申请号：US850672
申请日：1997-05-02
CPC分类号： B01D69/145 , B01D67/0041 , B01D67/0046 , B01D69/04 , B01D69/12 , B01D71/02 , B01D71/024 , B01J35/0006 , B01J35/0033 , C01B13/0255 , B01D2323/12 , B01D2325/26 , C01B2210/0079
摘要： A solid electrolyte ion transport membrane composite for separating a gaseous species from a gaseous mixture in which the composite has a dense matrix material and a porous coating. The dense membrane is comprised of a matrix material which conducts at least one type of ion, and at least one membrane constituent. The porous coating is disposed on the membrane to enhance the rate of surface reactions involving the gaseous species.
摘要翻译： 一种用于从气体混合物中分离出气态物质的固体电解质离子迁移膜复合物，其中复合材料具有致密基质材料和多孔涂层。 致密膜由导电至少一种类型的离子的基质材料和至少一种膜成分组成。 多孔涂层设置在膜上以增强涉及气态物质的表面反应速率。
-
78.发明授权Process for enriched combustion using solid electrolyte ionic conductor systems 失效使用固体电解质离子导体系统进行富集燃烧的方法
公开(公告)号：US5888272A
公开(公告)日：1999-03-30
申请号：US868962
申请日：1997-06-05
申请人： Ravi Prasad , Christian Friedrich Gottzmann , Raymond Francis Drnevich , Nitin Ramesh Keskar , Hisashi Kobayashi
发明人： Ravi Prasad , Christian Friedrich Gottzmann , Raymond Francis Drnevich , Nitin Ramesh Keskar , Hisashi Kobayashi
IPC分类号： F02B33/00 , B01D53/22 , B01D53/32 , B01D61/00 , B01D71/02 , C01B13/02 , F23C99/00 , F23L7/00
CPC分类号： F23L7/007 , B01D53/22 , B01D53/228 , B01D53/32 , B01D53/326 , C01B13/0251 , F23M5/085 , C01B2210/0046 , F23L2900/07001 , Y02E20/322 , Y02E20/344 , Y02P20/125 , Y02P20/129
摘要： A process for separating a feed gas stream into an oxygen-enriched gas stream which is used in a combustor and an oxygen-depleted gas stream. The feed gas stream is compressed, and oxygen is separated from the compressed feed gas stream using an ion transport module including an ion transport membrane having a retentate side and a permeate side. The permeate side of the ion transport membrane is purged with at least a portion of a combustion product gas stream obtained from the combustion in the combustor of the gas stream exiting the permeate side of the ion transport module.
摘要翻译： 将进料气流分离成用于燃烧器和贫氧气流的富氧气流的方法。 进料气流被压缩，并且使用包括具有滞留侧和渗透侧的离子迁移膜的离子传递模块将氧气与压缩的进料气流分离。 离子迁移膜的渗透侧用从离开离子迁移模块的渗透侧的气流的燃烧器中的燃烧获得的燃烧产物气流的至少一部分吹扫。
-
79.发明授权Method for producing oxygen and generating power using a solid electrolyte membrane integrated with a gas turbine 失效使用与燃气轮机一体化的固体电解质膜来生产氧气和发电的方法
公开(公告)号：US5852925A
公开(公告)日：1998-12-29
申请号：US933248
申请日：1997-09-18
CPC分类号： C01B13/0251 , B01D53/22 , B01D53/326 , C01B2210/0046
摘要： A compressed, oxygen-containing gas stream is combusted and then contacted with a solid electrolyte membrane to produce an oxygen-depleted, compressed gas stream and product oxygen. Preferably, the oxygen-depleted gas stream is further combusted, used to produce steam, and/or used to preheat the oxygen-containing gas stream prior to expansion in a gas turbine.
摘要翻译： 将压缩的含氧气流燃烧，然后与固体电解质膜接触以产生贫氧的压缩气流和产物氧。 优选地，贫氧气流进一步燃烧，用于产生蒸汽，和/或用于在燃气轮机中膨胀之前预热含氧气体流。
-
80.发明授权Hybrid solid electrolyte ionic conductor systems for purifying inert gases 失效用于净化惰性气体的混合固体电解质离子导体系统
公开(公告)号：US5851266A
公开(公告)日：1998-12-22
申请号：US880879
申请日：1997-06-23
CPC分类号： B01D53/226
摘要： A process for removing oxygen from a feed gas stream to produce an oxygen-depleted retentate gas stream by supplying the feed gas stream to a bulk oxygen separation system for removing oxygen to produce an oxygen-depleted crude product gas stream and a first oxygen-containing permeate effluent stream, and supplying the oxygen-depleted crude product gas stream to a separator having a primary ion transport membrane to produce a second permeate effluent stream and the oxygen-depleted retentate gas stream. A reactive purge gas is added to react with a portion of the oxygen permeating through the primary ion transport membrane and purge the permeate side of the primary ion transport membrane, and/or a recycle gas stream comprising at least a portion of one gas stream produced during the process is added to at least one other of the gas streams.
摘要翻译： 一种从进料气流中除去氧气以通过将原料气流供应到体氧分离系统以除去氧气以产生贫氧的粗产物气流和第一含氧的气体流的方法 渗透物流出物流，并将贫氧的粗产物气流供给到具有初级离子迁移膜的分离器中以产生第二渗透物流出物流和贫氧的滞留气流。 加入反应性净化气体以与透过初级离子迁移膜的氧气的一部分反应并吹扫主离子迁移膜的渗透侧，和/或包含产生一种气流的至少一部分的再循环气流 在该过程中加入到至少另一个气流中。
-
-
-
-
-
-
-
-
-
搜索结果
87 条记录 (耗时 0.031 秒)
