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1.发明授权
公开(公告)号：US5938822A
公开(公告)日：1999-08-17
申请号：US850672
申请日：1997-05-02
CPC分类号： B01D69/145 , B01D67/0041 , B01D67/0046 , B01D69/04 , B01D69/12 , B01D71/02 , B01D71/024 , B01J35/0006 , B01J35/0033 , C01B13/0255 , B01D2323/12 , B01D2325/26 , C01B2210/0079
摘要： A solid electrolyte ion transport membrane composite for separating a gaseous species from a gaseous mixture in which the composite has a dense matrix material and a porous coating. The dense membrane is comprised of a matrix material which conducts at least one type of ion, and at least one membrane constituent. The porous coating is disposed on the membrane to enhance the rate of surface reactions involving the gaseous species.
摘要翻译： 一种用于从气体混合物中分离出气态物质的固体电解质离子迁移膜复合物，其中复合材料具有致密基质材料和多孔涂层。 致密膜由导电至少一种类型的离子的基质材料和至少一种膜成分组成。 多孔涂层设置在膜上以增强涉及气态物质的表面反应速率。
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2.发明授权
公开(公告)号：US6139604A
公开(公告)日：2000-10-31
申请号：US185523
申请日：1998-11-04
IPC分类号： B01D53/04 , B01D53/047 , B01D53/22 , C01B13/02 , C01B21/04
CPC分类号： B01D53/22 , B01D53/0462 , B01D53/047 , B01D53/229 , B01D63/06 , C01B13/0251 , C01B21/0438 , B01D2256/10 , B01D2256/12 , B01D2257/504 , B01D2257/702 , B01D2257/80 , B01D2259/40001 , B01D2259/40052 , B01D2259/40079 , B01D2259/40081 , B01D2313/22 , B01D2313/40 , C01B2210/0046 , C01B2210/0062 , Y02C10/08 , Y02C10/10 , Y02P20/129 , Y02P20/131 , Y02P20/152
摘要： A low energy cost process for the co-production of oxygen and nitrogen employing a fuel tube extending into the first oxygen selective ion transport membrane whereby fuel is introduced adjacent to the closed end and flows cocurrently with oxygen containing gas in the annulus and an oxygen selective ion transport membrane having a separator section and a reactor section. An oxygen-containing feedstock, typically air, is compressed and then contacts the cathode side of the separator section where a portion of the oxygen contained within the feedstock is transported to the anode side of the separator section and recovered as an oxygen product gas. Substantially the remainder of the oxygen contained within the feedstock is transported from the cathode side of the reactor section to the anode side and exothermically reacted with a fuel. Following the exothermic reaction, hot nitrogen rich product gas is expanded in a turbine to generate the power necessary to compress the feedstock. Expanded nitrogen rich product gas may then be recovered from the turbine exhaust.
摘要翻译： 使用延伸到第一氧选择性离子迁移膜中的燃料管共同生产氧气和氮气的低能量成本过程，由此燃料在闭合端附近引入并且与环中的含氧气体并流并且具有氧选择性 离子传送膜，其具有分隔部和反应部。 含氧原料（通常为空气）被压缩，然后接触分离器部分的阴极侧，其中原料中所含的一部分氧被输送到分离器部分的阳极侧并作为氧产物气体回收。 基本上将原料中所含的剩余氧气从反应器部分的阴极侧输送到阳极侧，并与燃料放热反应。 在放热反应之后，富含热氮的产物气体在涡轮机中膨胀以产生压缩原料所需的功率。 然后可以从涡轮机废气中回收膨胀的富氮产物气体。
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公开(公告)号：US5837125A
公开(公告)日：1998-11-17
申请号：US567699
申请日：1995-12-05
CPC分类号： B01D53/226 , B01D53/326
摘要： A system and process for producing a high-purity product from a feed stream containing elemental oxygen by applying the feed stream to at least one separator including a feed zone and a permeate zone separated by a solid electrolyte membrane, and driving a portion of oxygen contained in the feed stream from the feed zone to the permeate zone via the membrane by applying to the permeate zone a reactive purge stream containing a reactive gas which combines with oxygen to establish a lower partial pressure of oxygen in that zone. Oxygen-depleted retentate is withdrawn as a high-purity product stream.
摘要翻译： 通过将进料流施加到至少一个分离器的系统和方法，所述系统和方法由含有元素氧的进料流生产高纯度产物，所述至少一个分离器包括由固体电解质膜分离的进料区和渗透区，并驱动所含的一部分氧 在通过向渗透物区域施加包含与氧结合的反应性气体的反应性气流以在该区域中建立较低的氧分压的通过膜从进料区到渗透区的进料流中。 作为高纯度产物流取出缺氧的渗余物。
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公开(公告)号：US06695983B2
公开(公告)日：2004-02-24
申请号：US09840101
申请日：2001-04-24
IPC分类号： C01B324
CPC分类号： C01B3/52 , C01B3/382 , C01B3/386 , C01B13/0251 , C01B2203/0233 , C01B2203/0238 , C01B2203/0244 , C01B2203/0255 , C01B2203/0261 , C01B2203/0415 , C01B2203/0475 , C01B2203/0495 , C01B2203/062 , C01B2203/0811 , C01B2203/0816 , C01B2203/0827 , C01B2203/0844 , C01B2203/0866 , C01B2203/0883 , C01B2203/0894 , C01B2203/1011 , C01B2203/1035 , C01B2203/1041 , C01B2203/1052 , C01B2203/1064 , C01B2203/1241 , C01B2203/1258 , C01B2203/127 , C01B2203/143 , C01B2203/146 , C01B2203/148 , C01B2203/82 , C01B2210/0046 , Y02C10/10
摘要： A method of producing a crude syngas product stream or a syngas product stream by further processing of the crude syngas product stream. Both the crude and syngas product stream comprise carbon monoxide and hydrogen. The crude syngas product stream additionally comprises carbon dioxide and moisture. In accordance with the method, methane in a feed stream is converted into the hydrogen and carbon monoxide in at least two stages, thereby to form a crude syngas stream. An initial stage has an oxygen transport membrane reactor having a catalyst to promote carbon dioxide or steam methane reforming. Since, the conversion is shared between two stages, the oxygen transport membrane reactor can be operated at a sufficiently low temperature to avoid ceramic membrane deterioration due to creep effect. The subsequent stage can be operated at a higher temperature with more favorable equilibrium conditions to complete the conversion of the methane.
摘要翻译： 通过进一步处理粗合成气产物流来生产粗合成气产物流或合成气产物流的方法。 粗产物和合成气产物流都包含一氧化碳和氢气。 粗合成气产物流另外包含二氧化碳和水分。 根据该方法，将进料流中的甲烷转化为至少两个阶段的氢气和一氧化碳，从而形成粗合成气流。 初始阶段具有氧传输膜反应器，其具有促进二氧化碳或蒸汽甲烷重整的催化剂。 由于转化在两个阶段之间共享，所以氧传输膜反应器可以在足够低的温度下操作，以避免由于蠕变效应导致的陶瓷膜劣化。 后续阶段可以在更高的温度下运行，更有利的平衡条件来完成甲烷的转化。
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公开(公告)号：US06537514B1
公开(公告)日：2003-03-25
申请号：US09427066
申请日：1999-10-26
IPC分类号： C01B3120
摘要： In a method for the production of carbon dioxide, an oxygen-containing first process gas is flowed along a cathode side of a first oxygen selective ion transport membrane. The membrane is at operating conditions effective to transport a first permeate oxygen portion from the cathode side to an opposite anode side. A carbon-containing second process gas is flowed along the anode side at a flow rate effective to provide a stoichiometric surplus of oxygen on combination with the first permeate oxygen portion. A first mixture of a second process gas and the first permeate oxygen portion is combusted such that substantially all of the second process gas is converted into a second mixture of water and carbon dioxide. The carbon dioxide is separated from such second mixture.
摘要翻译： 在制造二氧化碳的方法中，含氧的第一工艺气体沿着第一氧选择性离子迁移膜的阴极侧流动。 膜处于有效地将第一渗透氧部分从阴极侧输送到相对的阳极侧的操作条件。 含碳的第二工艺气体沿着阳极侧以与第一渗透氧部分组合以提供化学计量的剩余氧气的流量流动。 将第二工艺气体和第一渗透氧部分的第一混合物燃烧，使得基本上所有的第二工艺气体转化为水和二氧化碳的第二混合物。 二氧化碳与第二混合物分离。
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公开(公告)号：US06402988B1
公开(公告)日：2002-06-11
申请号：US09618749
申请日：2000-07-17
申请人： Christian Friedrich Gottzmann , Ravi Prasad , Joseph Michael Schwartz , Victor Emmanuel Bergsten , James Eric White , Terry J. Mazanec , Thomas L. Cable , John C. Fagley
发明人： Christian Friedrich Gottzmann , Ravi Prasad , Joseph Michael Schwartz , Victor Emmanuel Bergsten , James Eric White , Terry J. Mazanec , Thomas L. Cable , John C. Fagley
IPC分类号： C01B326
CPC分类号： C01B13/0251 , B01J8/009 , B01J12/007 , B01J19/2425 , B01J19/2475 , B01J2208/00309 , B01J2208/00477 , B01J2208/00495 , B01J2208/0053 , B01J2208/00539 , B01J2208/00548 , B01J2208/00628 , B01J2219/00117 , B01J2219/00155 , B01J2219/00159 , B01J2219/00162 , B01J2219/00186 , B01J2219/00777 , C01B3/382 , C01B3/384 , C01B2203/0233 , C01B2203/066 , C01B2203/0811 , C01B2203/141 , C01B2203/142 , C01B2203/148 , C01B2203/82 , C01B2210/0046 , Y02P20/129
摘要： An exothermic reaction and an endothermic reaction are thermally combined in a reactor having at least one oxygen selective ion transport membrane that provides the exothermic reaction with oxygen from an oxygen-containing gas such as air. The thermal requirements of the endothermic reaction are satisfied by the exothermic reaction. Dependent on the reactor design employed, the exothermic and endothermic reactions may be gaseously combined.
摘要翻译： 将放热反应和吸热反应在具有至少一个氧选择性离子迁移膜的反应器中热合并，所述氧选择性离子迁移膜与含氧气体如空气的氧提供放热反应。 通过放热反应来满足吸热反应的热要求。 取决于采用的反应器设计，放热和吸热反应可以气化组合。
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公开(公告)号：US06296686B1
公开(公告)日：2001-10-02
申请号：US09143974
申请日：1998-08-31
IPC分类号： B01D5322
CPC分类号： B01J12/007 , B01J8/009 , B01J8/025 , B01J8/0257 , B01J8/0278 , B01J8/067 , B01J19/2425 , B01J19/2475 , B01J2208/00221 , B01J2208/00309 , B01J2208/00477 , B01J2208/00495 , B01J2208/00504 , B01J2208/0053 , B01J2208/00539 , B01J2208/00548 , B01J2208/00628 , B01J2219/00117 , B01J2219/00155 , B01J2219/00159 , B01J2219/00162 , B01J2219/00186 , B01J2219/00777 , C01B3/382 , C01B3/384 , C01B13/0251 , C01B2203/0233 , C01B2203/066 , C01B2203/0811 , C01B2203/141 , C01B2203/142 , C01B2203/148 , C01B2203/82 , C01B2210/0046
摘要： Syngas, a mixture of hydrogen and carbon monoxide, is an intermediate in the conversion of methane to liquid fuels. For certain applications, it is desirable to maintain an H2/CO molar ratio of about 3. This molar ratio is achieved by steam reforming of methane in accordance with: CH4+H2O→3H2+CO. To provide the heat required to drive the endothermic steam reforming reaction, a low grade fuel is combusted in a reactor and the heat of combustion conducted to the endothermic reaction. By using an oxygen selective ion transport membrane element to transport the oxygen required for combustion, the formation of undesirable NOx compounds is minimized.
摘要翻译： 合成气，氢气和一氧化碳的混合物，是甲烷转化为液体燃料的中间体。 对于某些应用，希望保持约3的H 2 / CO摩尔比。该摩尔比通过根据以下的甲烷的蒸汽重整实现：为了提供驱动吸热蒸汽重整反应所需的热量，低等级燃料 在反应器中燃烧，并且燃烧的热量进行吸热反应。 通过使用氧选择性离子迁移膜元件来输送燃烧所需的氧气，使不期望的NOx化合物的形成最小化。
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8.发明授权Solid electrolyte ionic conductor systems for oxygen, nitrogen, and/or carbon dioxide production with gas turbine 失效用于燃气轮机生产氧气，氮气和/或二氧化碳的固体电解质离子导体系统
公开(公告)号：US5976223A
公开(公告)日：1999-11-02
申请号：US972409
申请日：1997-11-18
CPC分类号： C01B13/0251 , B01D53/22 , B01D53/32 , F02C3/28 , B01D2257/106 , C01B2210/0046 , C01B2210/0051 , C01B2210/0062 , Y02P20/123
摘要： A process for producing at least an oxygen product gas stream, and power from a gas turbine, by compressing a feed gas stream containing elemental oxygen and heating the feed gas stream on the retentate side of an ion transport reactor membrane section to produce a heated feed gas stream. Oxygen permeating the ion transport reactor membrane section is reacted with a first fuel gas stream to produce a first combustion products gas stream. The heated feed gas stream is separated using an ion transport separator membrane section having a retentate side and a permeate side into an oxygen-depleted gas stream on the retentate side and an oxygen-containing gas stream on the permeate side. At least a portion of the first combustion products gas stream can be recovered, and energy is extracted from at least one gas stream to be expanded in a gas turbine to produce energy.
摘要翻译： 一种用于通过压缩含有元素氧的进料气流并加热离子迁移反应器膜部分的渗余物侧上的进料气流以产生至少一种氧产物气流和来自燃气轮机的动力的方法，以产生加热的进料 气流。 使离子迁移反应器膜部分的氧气与第一燃料气流反应以产生第一燃烧产物气流。 使用具有滞留侧和渗透侧的离子迁移分离器膜部分将加热的原料气流分离成渗余物侧的贫氧气流和渗透侧的含氧气体流。 可以回收至少一部分第一燃烧产物气流，并且从至少一个气流中提取能量以在燃气轮机中膨胀以产生能量。
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9.发明授权Solid electrolyte ionic conductor systems for the production of high purity nitrogen 失效固体电解质离子导体系统用于生产高纯氮
公开(公告)号：US5944874A
公开(公告)日：1999-08-31
申请号：US880877
申请日：1997-06-23
IPC分类号： B01D53/04 , B01D53/22 , B01D53/047
CPC分类号： B01D53/229 , B01D53/0407 , B01D2256/10 , B01D2257/30 , B01D2257/80 , B01D2259/4009 , B01D53/0462 , B01D53/047
摘要： A process for separating a feed gas stream containing elemental oxygen and nitrogen to produce a purified nitrogen gas stream by removing oxygen from the feed gas stream using an ion transport membrane to produce a retentate gas stream and a permeate gas stream, wherein the feed gas stream or the retentate gas stream is purified to remove impurities either before or after the separation step to produce the purified nitrogen gas stream.
摘要翻译： 一种用于分离含有元素氧和氮的进料气流以通过使用离子迁移膜从进料气流中除去氧气以产生滞留气流和渗透气流来产生纯化氮气流的方法，其中进料气流 或者在分离步骤之前或之后净化滞留气流以除去杂质以产生纯化的氮气流。
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公开(公告)号：US06537465B2
公开(公告)日：2003-03-25
申请号：US09750082
申请日：2000-12-29
IPC分类号： B01D5322
CPC分类号： B01J19/006 , B01D53/228 , B01J19/2475 , B01J2219/00094 , B01J2219/00157 , B01J2219/00159 , B01J2219/00777 , C01B3/382 , C01B13/0251 , C01B2203/0244 , C01B2203/0811 , C01B2203/82 , C01B2210/0046 , C01B2210/0062 , Y02P20/129
摘要： Methane is formed into synthesis gas through a combination of a partial oxidation reaction and a steam reforming reaction. Oxygen for the partial oxidation reaction is obtained by contacting air with an oxygen transport membrane and recovering the oxygen transported through the membrane. To increase the oxygen flux through the membrane, steam is utilized as a sweep gas on the anode side of the membrane. The steam reduces the oxygen partial pressure on the anode side increasing the flux. The efficiency and cost benefit of the process is enhanced by utilizing in-line combustors to heat gases being delivered to the oxygen transport membrane. Membrane integrity is enhanced by conducting the reactions in a reactor that is remote from the oxygen transport membrane.
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