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公开(公告)号：US06402988B1
公开(公告)日：2002-06-11
申请号：US09618749
申请日：2000-07-17
申请人： Christian Friedrich Gottzmann , Ravi Prasad , Joseph Michael Schwartz , Victor Emmanuel Bergsten , James Eric White , Terry J. Mazanec , Thomas L. Cable , John C. Fagley
发明人： Christian Friedrich Gottzmann , Ravi Prasad , Joseph Michael Schwartz , Victor Emmanuel Bergsten , James Eric White , Terry J. Mazanec , Thomas L. Cable , John C. Fagley
IPC分类号： C01B326
CPC分类号： C01B13/0251 , B01J8/009 , B01J12/007 , B01J19/2425 , B01J19/2475 , B01J2208/00309 , B01J2208/00477 , B01J2208/00495 , B01J2208/0053 , B01J2208/00539 , B01J2208/00548 , B01J2208/00628 , B01J2219/00117 , B01J2219/00155 , B01J2219/00159 , B01J2219/00162 , B01J2219/00186 , B01J2219/00777 , C01B3/382 , C01B3/384 , C01B2203/0233 , C01B2203/066 , C01B2203/0811 , C01B2203/141 , C01B2203/142 , C01B2203/148 , C01B2203/82 , C01B2210/0046 , Y02P20/129
摘要： An exothermic reaction and an endothermic reaction are thermally combined in a reactor having at least one oxygen selective ion transport membrane that provides the exothermic reaction with oxygen from an oxygen-containing gas such as air. The thermal requirements of the endothermic reaction are satisfied by the exothermic reaction. Dependent on the reactor design employed, the exothermic and endothermic reactions may be gaseously combined.
摘要翻译： 将放热反应和吸热反应在具有至少一个氧选择性离子迁移膜的反应器中热合并，所述氧选择性离子迁移膜与含氧气体如空气的氧提供放热反应。 通过放热反应来满足吸热反应的热要求。 取决于采用的反应器设计，放热和吸热反应可以气化组合。
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2.发明授权Tube and shell reactor with oxygen selective ion transport ceramic reaction tubes 失效管壳反应器采用氧选择离子迁移陶瓷反应管
公开(公告)号：US6139810A
公开(公告)日：2000-10-31
申请号：US89372
申请日：1998-06-03
申请人： Christian Friedrich Gottzmann , Ravi Prasad , Joseph Michael Schwartz , Victor Emmanuel Bergsten , James Eric White , Terry J. Mazanec , Thomas L. Cable , John C. Fagley
发明人： Christian Friedrich Gottzmann , Ravi Prasad , Joseph Michael Schwartz , Victor Emmanuel Bergsten , James Eric White , Terry J. Mazanec , Thomas L. Cable , John C. Fagley
IPC分类号： C01B3/24 , B01J8/00 , B01J8/06 , B01J12/00 , B01J19/24 , C01B3/38 , C01B13/02 , C25B13/08 , B01D52/22
CPC分类号： C01B13/0251 , B01J12/007 , B01J19/2425 , B01J19/2475 , B01J8/009 , C01B3/382 , C01B3/384 , B01J2208/00309 , B01J2208/00477 , B01J2208/00495 , B01J2208/0053 , B01J2208/00539 , B01J2208/00548 , B01J2208/00628 , B01J2219/00117 , B01J2219/00155 , B01J2219/00159 , B01J2219/00162 , B01J2219/00186 , B01J2219/00777 , C01B2203/0233 , C01B2203/066 , C01B2203/0811 , C01B2203/141 , C01B2203/142 , C01B2203/148 , C01B2203/82 , C01B2210/0046 , Y02P20/129
摘要： A reactor comprising: a hollow shell defining a hermetic enclosure; a plurality of tube sheets disposed within said hermetic enclosure, a first one of said plurality of tube sheets defining a first chamber; at least one reaction tube each having a first end and an opposing second end, said first end being fixedly attached and substantially hermetically sealed to one end of said plurality of tube sheets and opening into said first chamber, the second end being axially unrestrained; each of said reaction tubes is comprised of an oxygen selective ion transport membrane with an anode side wherein said oxygen selective ion transport membrane is formed from a mixed conductor metal oxide that is effective for the transport of elemental oxygen at elevated temperatures and at least a portion of said first and second heat transfer sections are formed of metal; each of said reaction tubes includes first and second heat transfer sections and a reaction section, said reaction section disposed between said first and second heat transfer sections; a reforming catalyst disposed about said anode side of said oxygen selective ion transport membrane; a first process gas inlet; a second process gas inlet; and, a plurality of outlets.
摘要翻译： 一种反应器，包括：限定密封外壳的中空壳体; 设置在所述密封外壳内的多个管板，所述多个管板中的第一管板限定第一室; 每个具有第一端和相对的第二端的至少一个反应管，所述第一端固定地附接并且基本上气密地密封在所述多个管板的一端并进入所述第一室，所述第二端轴向无约束; 每个所述反应管由具有阳极侧的氧选择性离子迁移膜组成，其中所述氧选择性离子迁移膜由混合导电金属氧化物形成，所述混合导体金属氧化物对于在升高的温度下运输元素氧和至少一部分 所述第一和第二传热部分由金属形成; 每个所述反应管包括第一和第二传热部分和反应部分，所述反应部分设置在所述第一和第二传热部分之间; 设置在所述氧选择性离子迁移膜的所述阳极侧周围的重整催化剂; 第一工艺气体入口; 第二工艺气体入口; 和多个出口。
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公开(公告)号：US5820655A
公开(公告)日：1998-10-13
申请号：US848204
申请日：1997-04-29
申请人： Christian Friedrich Gottzmann , Ravi Prasad , Victor Emmanuel Bergsten , Nitin Ramesh Keskar , Bart Antonie van Hassel
发明人： Christian Friedrich Gottzmann , Ravi Prasad , Victor Emmanuel Bergsten , Nitin Ramesh Keskar , Bart Antonie van Hassel
CPC分类号： C01B13/0255 , B01D53/22 , B01D53/326 , B01D63/062 , B01J12/007 , B01J19/2425 , B01J19/2475 , C01B13/0251 , B01D2313/42 , B01J2219/00081 , B01J2219/00085 , B01J2219/0015 , B01J2219/00155 , C01B2210/0046 , C01B2210/0082
摘要： An ion transport reactor and process for using same having at least one ion transport membrane with a retentate side and a permeate side, for extracting oxygen from a feed gas stream as it flows along the retentate side. A reactant gas stream is flowed along the permeate side of the ion transport tubes to react with the oxygen transported therethrough. Heat is transferred to a fluid stream flowing through the ion transport reactor while the temperature of the membrane is maintained within its operating range.
摘要翻译： 离子迁移反应器及其使用方法，其具有至少一个具有滞留侧和渗透侧的离子迁移膜，用于当其沿着渗余物侧流动时从进料气流中提取氧气。 反应物气流沿离子输送管的渗透侧流动，以与从其中输送的氧气反应。 将热量转移到流过离子迁移反应器的流体流中，同时膜的温度保持在其工作范围内。
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公开(公告)号：US06695983B2
公开(公告)日：2004-02-24
申请号：US09840101
申请日：2001-04-24
IPC分类号： C01B324
CPC分类号： C01B3/52 , C01B3/382 , C01B3/386 , C01B13/0251 , C01B2203/0233 , C01B2203/0238 , C01B2203/0244 , C01B2203/0255 , C01B2203/0261 , C01B2203/0415 , C01B2203/0475 , C01B2203/0495 , C01B2203/062 , C01B2203/0811 , C01B2203/0816 , C01B2203/0827 , C01B2203/0844 , C01B2203/0866 , C01B2203/0883 , C01B2203/0894 , C01B2203/1011 , C01B2203/1035 , C01B2203/1041 , C01B2203/1052 , C01B2203/1064 , C01B2203/1241 , C01B2203/1258 , C01B2203/127 , C01B2203/143 , C01B2203/146 , C01B2203/148 , C01B2203/82 , C01B2210/0046 , Y02C10/10
摘要： A method of producing a crude syngas product stream or a syngas product stream by further processing of the crude syngas product stream. Both the crude and syngas product stream comprise carbon monoxide and hydrogen. The crude syngas product stream additionally comprises carbon dioxide and moisture. In accordance with the method, methane in a feed stream is converted into the hydrogen and carbon monoxide in at least two stages, thereby to form a crude syngas stream. An initial stage has an oxygen transport membrane reactor having a catalyst to promote carbon dioxide or steam methane reforming. Since, the conversion is shared between two stages, the oxygen transport membrane reactor can be operated at a sufficiently low temperature to avoid ceramic membrane deterioration due to creep effect. The subsequent stage can be operated at a higher temperature with more favorable equilibrium conditions to complete the conversion of the methane.
摘要翻译： 通过进一步处理粗合成气产物流来生产粗合成气产物流或合成气产物流的方法。 粗产物和合成气产物流都包含一氧化碳和氢气。 粗合成气产物流另外包含二氧化碳和水分。 根据该方法，将进料流中的甲烷转化为至少两个阶段的氢气和一氧化碳，从而形成粗合成气流。 初始阶段具有氧传输膜反应器，其具有促进二氧化碳或蒸汽甲烷重整的催化剂。 由于转化在两个阶段之间共享，所以氧传输膜反应器可以在足够低的温度下操作，以避免由于蠕变效应导致的陶瓷膜劣化。 后续阶段可以在更高的温度下运行，更有利的平衡条件来完成甲烷的转化。
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公开(公告)号：US06537514B1
公开(公告)日：2003-03-25
申请号：US09427066
申请日：1999-10-26
IPC分类号： C01B3120
摘要： In a method for the production of carbon dioxide, an oxygen-containing first process gas is flowed along a cathode side of a first oxygen selective ion transport membrane. The membrane is at operating conditions effective to transport a first permeate oxygen portion from the cathode side to an opposite anode side. A carbon-containing second process gas is flowed along the anode side at a flow rate effective to provide a stoichiometric surplus of oxygen on combination with the first permeate oxygen portion. A first mixture of a second process gas and the first permeate oxygen portion is combusted such that substantially all of the second process gas is converted into a second mixture of water and carbon dioxide. The carbon dioxide is separated from such second mixture.
摘要翻译： 在制造二氧化碳的方法中，含氧的第一工艺气体沿着第一氧选择性离子迁移膜的阴极侧流动。 膜处于有效地将第一渗透氧部分从阴极侧输送到相对的阳极侧的操作条件。 含碳的第二工艺气体沿着阳极侧以与第一渗透氧部分组合以提供化学计量的剩余氧气的流量流动。 将第二工艺气体和第一渗透氧部分的第一混合物燃烧，使得基本上所有的第二工艺气体转化为水和二氧化碳的第二混合物。 二氧化碳与第二混合物分离。
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公开(公告)号：US06537465B2
公开(公告)日：2003-03-25
申请号：US09750082
申请日：2000-12-29
IPC分类号： B01D5322
CPC分类号： B01J19/006 , B01D53/228 , B01J19/2475 , B01J2219/00094 , B01J2219/00157 , B01J2219/00159 , B01J2219/00777 , C01B3/382 , C01B13/0251 , C01B2203/0244 , C01B2203/0811 , C01B2203/82 , C01B2210/0046 , C01B2210/0062 , Y02P20/129
摘要： Methane is formed into synthesis gas through a combination of a partial oxidation reaction and a steam reforming reaction. Oxygen for the partial oxidation reaction is obtained by contacting air with an oxygen transport membrane and recovering the oxygen transported through the membrane. To increase the oxygen flux through the membrane, steam is utilized as a sweep gas on the anode side of the membrane. The steam reduces the oxygen partial pressure on the anode side increasing the flux. The efficiency and cost benefit of the process is enhanced by utilizing in-line combustors to heat gases being delivered to the oxygen transport membrane. Membrane integrity is enhanced by conducting the reactions in a reactor that is remote from the oxygen transport membrane.
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公开(公告)号：US6153163A
公开(公告)日：2000-11-28
申请号：US89368
申请日：1998-06-03
CPC分类号： C01B13/0251 , B01J19/2475 , C01B13/0255 , C01B3/36 , B01J2219/00058 , B01J2219/00103 , B01J2219/00117 , B01J2219/00123 , B01J2219/00159 , B01J2219/00186 , C01B2210/0046 , C01B2210/0051 , C01B2210/0062
摘要： A process to generate an enhanced output of a desired product from an ion transport reactor utilizes the reaction products from both the cathode side and the anode side of an oxygen selective ion transport ceramic membrane. An oxygen donating first feed stream containing the desired product in a chemically bound state is delivered to the cathode side while an oxygen accepting second feed stream is delivered to the anode side. Following chemical reactions on both the cathode side and the anode side, a desired product is recovered from a first product stream exiting from the cathode side and from a second product stream exiting from the anode side such that the sum of the desired product contained within the two product streams exceeds that attainable from either product stream alone.
摘要翻译： 从离子转移反应器产生所需产物的增强输出的方法利用来自氧选择性离子迁移陶瓷膜的阴极侧和阳极侧的反应产物。 将含有化学结合状态的期望产物的给氧第一进料流输送到阴极侧，同时将接受氧的第二进料流输送到阳极侧。 在阴极侧和阳极侧的化学反应之后，从阴极侧离开的第一产物流和从阳极侧离开的第二产物流回收所需的产物，使得包含在阴极侧的所需产物的总和 两个产品流超过单独产品流可获得的两种产品流。
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8.发明授权
公开(公告)号：US6139604A
公开(公告)日：2000-10-31
申请号：US185523
申请日：1998-11-04
IPC分类号： B01D53/04 , B01D53/047 , B01D53/22 , C01B13/02 , C01B21/04
CPC分类号： B01D53/22 , B01D53/0462 , B01D53/047 , B01D53/229 , B01D63/06 , C01B13/0251 , C01B21/0438 , B01D2256/10 , B01D2256/12 , B01D2257/504 , B01D2257/702 , B01D2257/80 , B01D2259/40001 , B01D2259/40052 , B01D2259/40079 , B01D2259/40081 , B01D2313/22 , B01D2313/40 , C01B2210/0046 , C01B2210/0062 , Y02C10/08 , Y02C10/10 , Y02P20/129 , Y02P20/131 , Y02P20/152
摘要： A low energy cost process for the co-production of oxygen and nitrogen employing a fuel tube extending into the first oxygen selective ion transport membrane whereby fuel is introduced adjacent to the closed end and flows cocurrently with oxygen containing gas in the annulus and an oxygen selective ion transport membrane having a separator section and a reactor section. An oxygen-containing feedstock, typically air, is compressed and then contacts the cathode side of the separator section where a portion of the oxygen contained within the feedstock is transported to the anode side of the separator section and recovered as an oxygen product gas. Substantially the remainder of the oxygen contained within the feedstock is transported from the cathode side of the reactor section to the anode side and exothermically reacted with a fuel. Following the exothermic reaction, hot nitrogen rich product gas is expanded in a turbine to generate the power necessary to compress the feedstock. Expanded nitrogen rich product gas may then be recovered from the turbine exhaust.
摘要翻译： 使用延伸到第一氧选择性离子迁移膜中的燃料管共同生产氧气和氮气的低能量成本过程，由此燃料在闭合端附近引入并且与环中的含氧气体并流并且具有氧选择性 离子传送膜，其具有分隔部和反应部。 含氧原料（通常为空气）被压缩，然后接触分离器部分的阴极侧，其中原料中所含的一部分氧被输送到分离器部分的阳极侧并作为氧产物气体回收。 基本上将原料中所含的剩余氧气从反应器部分的阴极侧输送到阳极侧，并与燃料放热反应。 在放热反应之后，富含热氮的产物气体在涡轮机中膨胀以产生压缩原料所需的功率。 然后可以从涡轮机废气中回收膨胀的富氮产物气体。
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公开(公告)号：US5837125A
公开(公告)日：1998-11-17
申请号：US567699
申请日：1995-12-05
CPC分类号： B01D53/226 , B01D53/326
摘要： A system and process for producing a high-purity product from a feed stream containing elemental oxygen by applying the feed stream to at least one separator including a feed zone and a permeate zone separated by a solid electrolyte membrane, and driving a portion of oxygen contained in the feed stream from the feed zone to the permeate zone via the membrane by applying to the permeate zone a reactive purge stream containing a reactive gas which combines with oxygen to establish a lower partial pressure of oxygen in that zone. Oxygen-depleted retentate is withdrawn as a high-purity product stream.
摘要翻译： 通过将进料流施加到至少一个分离器的系统和方法，所述系统和方法由含有元素氧的进料流生产高纯度产物，所述至少一个分离器包括由固体电解质膜分离的进料区和渗透区，并驱动所含的一部分氧 在通过向渗透物区域施加包含与氧结合的反应性气体的反应性气流以在该区域中建立较低的氧分压的通过膜从进料区到渗透区的进料流中。 作为高纯度产物流取出缺氧的渗余物。
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公开(公告)号：US06296686B1
公开(公告)日：2001-10-02
申请号：US09143974
申请日：1998-08-31
IPC分类号： B01D5322
CPC分类号： B01J12/007 , B01J8/009 , B01J8/025 , B01J8/0257 , B01J8/0278 , B01J8/067 , B01J19/2425 , B01J19/2475 , B01J2208/00221 , B01J2208/00309 , B01J2208/00477 , B01J2208/00495 , B01J2208/00504 , B01J2208/0053 , B01J2208/00539 , B01J2208/00548 , B01J2208/00628 , B01J2219/00117 , B01J2219/00155 , B01J2219/00159 , B01J2219/00162 , B01J2219/00186 , B01J2219/00777 , C01B3/382 , C01B3/384 , C01B13/0251 , C01B2203/0233 , C01B2203/066 , C01B2203/0811 , C01B2203/141 , C01B2203/142 , C01B2203/148 , C01B2203/82 , C01B2210/0046
摘要： Syngas, a mixture of hydrogen and carbon monoxide, is an intermediate in the conversion of methane to liquid fuels. For certain applications, it is desirable to maintain an H2/CO molar ratio of about 3. This molar ratio is achieved by steam reforming of methane in accordance with: CH4+H2O→3H2+CO. To provide the heat required to drive the endothermic steam reforming reaction, a low grade fuel is combusted in a reactor and the heat of combustion conducted to the endothermic reaction. By using an oxygen selective ion transport membrane element to transport the oxygen required for combustion, the formation of undesirable NOx compounds is minimized.
摘要翻译： 合成气，氢气和一氧化碳的混合物，是甲烷转化为液体燃料的中间体。 对于某些应用，希望保持约3的H 2 / CO摩尔比。该摩尔比通过根据以下的甲烷的蒸汽重整实现：为了提供驱动吸热蒸汽重整反应所需的热量，低等级燃料 在反应器中燃烧，并且燃烧的热量进行吸热反应。 通过使用氧选择性离子迁移膜元件来输送燃烧所需的氧气，使不期望的NOx化合物的形成最小化。
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