Microfibrillated cellulose having cellulose type-II crystalline structure, and molded article containing the microfibrillated cellulose
    71.
    发明授权
    Microfibrillated cellulose having cellulose type-II crystalline structure, and molded article containing the microfibrillated cellulose 有权
    具有II型纤维结构结构的微纤维素纤维素和含有微纤化纤维素的成型制品

    公开(公告)号:US08728272B2

    公开(公告)日:2014-05-20

    申请号:US12309416

    申请日:2007-07-13

    IPC分类号: D21H17/52 D21H17/33

    摘要: Although a microfibrillated cellulose has been conventionally added to a resin molded article for the purpose of improving the properties of resin such as strength, it is only possible to achieve the same level of strength as that of the resin itself. The object is to provide a resin molded article of greater strength. A molded article can be produced by blending resin with a microfibrillated cellulose having a type-II crystalline structure produced by treating a microfibrillated cellulose with an alkali solution. The molded article can be largely increased in tensile strength or flexural strength, tensile strain at break or flexural strain at break, and fracture toughness (work-of-fracture) compared to a molded article produced with resin containing a conventional microfibrillated cellulose.

    摘要翻译: 为了提高树脂的强度等性能,为了提高树脂的成型性,通常将微纤化纤维素添加到树脂成型体中,只能达到与树脂本身相同的强度。 本发明的目的是提供一种强度更高的树脂模塑制品。 可以通过将树脂与通过用碱溶液处理微纤化纤维素而制造的具有II型晶体结构的微纤化纤维素共混来制备成型制品。 与使用含有常规微纤化纤维素的树脂制成的模制品相比,模制品的拉伸强度或弯曲强度,断裂拉伸应变或断裂韧性​​应变以及断裂韧性(断裂作用)可大大提高。

    Fiber-reinforced composite material and process for producing the same
    76.
    发明授权
    Fiber-reinforced composite material and process for producing the same 有权
    纤维增强复合材料及其制造方法

    公开(公告)号:US08030375B2

    公开(公告)日:2011-10-04

    申请号:US11815263

    申请日:2006-01-31

    IPC分类号: B32B27/38 B32B27/12

    摘要: Disclosed is a highly transparent fiber-reinforced composite material including an assembly of cellulose fibers of 4 to 200 nm average fiber diameter impregnated with a matrix material so as to not only remedy the moisture absorbency attributed to cellulose fibers but also further improve transparency. There is provided a fiber-reinforced composite material including an assembly of cellulose fibers impregnated with a matrix material. In the fiber-reinforced composite material, hydroxyl groups of cellulose fibers are chemically modified through a reaction with one or more chemical modifiers selected from the group consisting of an acid, an alcohol, a halogenating reagent, an acid anhydride, and an isocyanate so that the ratio of a functional group introduced by the chemical modification is 5 to 40 percent by mole based on the hydroxyl groups of cellulose fibers before the chemical modification. The chemical modification of hydroxyl groups of cellulose fibers can reduce the hydrophilicity of cellulose fibers to thereby reduce the moisture absorbency of fiber-reinforced composite material. Further, the affinity between cellulose fibers and matrix material can be enhanced to thereby further improve transparency.

    摘要翻译: 公开了一种高透明度的纤维增强复合材料,其包括浸渍有基质材料的4〜200nm平均纤维直径的纤维素纤维的组合,不仅能够补偿归因于纤维素纤维的吸湿性,而且进一步提高透明性。 提供了一种纤维增强复合材料,其包括浸渍有基质材料的纤维素纤维的组合。 在纤维增强复合材料中,纤维素纤维的羟基通过与选自酸,醇,卤化试剂,酸酐和异氰酸酯的一种或多种化学改性剂的反应进行化学改性,使得 通过化学改性引入的官能团的比例相对于化学改性前的纤维素纤维的羟基为5〜40摩尔%。 纤维素纤维的羟基的化学改性可以降低纤维素纤维的亲水性,从而降低纤维增强复合材料的吸湿性。 此外,可以提高纤维素纤维与基质材料之间的亲和力,从而进一步提高透明度。

    Post-CMP treating liquid and manufacturing method of semiconductor device using the same
    77.
    发明授权
    Post-CMP treating liquid and manufacturing method of semiconductor device using the same 失效
    后CMP处理液和使用其的半导体器件的制造方法

    公开(公告)号:US07951717B2

    公开(公告)日:2011-05-31

    申请号:US11967584

    申请日:2007-12-31

    CPC分类号: H01L21/02074

    摘要: Post-CMP treating liquids are provided, one of which includes water, an amphoteric surfactant, an anionic surfactant, a complexing agent, resin particles having carboxylic group and sulfonyl group on their surfaces, a primary particle diameter thereof ranging from 10 to 60 nm, and tetramethyl ammonium hydroxide. Another includes water, polyphenol, an anionic surfactant, ethylene diamine tetraacetic acid, resin particles having carboxylic group and sulfonyl group on their surfaces, a primary particle diameter thereof ranging from 10 to 60 nm, and tetramethyl ammonium hydroxide. Both of the treating liquids have a pH ranging from 4 to 9, and exhibit a polishing rate both of an insulating film and a conductive film at a rate of 10 nm/min or less.

    摘要翻译: 提供后CMP处理液,其中之一包括水,两性表面活性剂,阴离子表面活性剂,络合剂,其表面具有羧基和磺酰基的树脂颗粒,其一次粒径为10至60nm, 和四甲基氢氧化铵。 另外还包括水,多酚,阴离子表面活性剂,乙二胺四乙酸,其表面具有羧基和磺酰基的树脂颗粒,其一次粒径为10至60nm,四甲基氢氧化铵。 两种处理液的pH范围为4至9,并且以10nm / min或更低的速率显示绝缘膜和导电膜的抛光速率。

    NANOFIBER SHEET AND METHOD FOR MANUFACTURING THE SAME
    78.
    发明申请
    NANOFIBER SHEET AND METHOD FOR MANUFACTURING THE SAME 有权
    纳米纤维片及其制造方法

    公开(公告)号:US20110117319A1

    公开(公告)日:2011-05-19

    申请号:US13001879

    申请日:2009-06-26

    IPC分类号: D04H1/00 D21C9/00 B82Y30/00

    摘要: A nanofiber sheet that has a high degree of transparency, a high modulus of elasticity, a low coefficient of linear thermal expansion as well as high degrees of flatness and smoothness, in particular, a nanofiber sheet produced as a uniform and flat sheet having a high optical transmittance with cellulose as the only component. This sheet has the following characteristics: Calculated for a thickness of 60 μm, the transmittance for parallel rays of light having a wavelength of 600 nm is equal to or higher than 70%; The Young's modulus measured in accordance with the JIS K7161 method is equal to or greater than 10 GPa; The coefficient of linear thermal expansion measured in accordance with the ASTM D606 method is equal to or smaller than 10 ppm/K.

    摘要翻译: 具有高透明度,高弹性模量,低热膨胀系数以及高度的平坦度和平滑度的纳米纤维片材,特别是具有高均匀平坦度的纳米纤维片材 光纤透过率仅为纤维素成分。 该片具有以下特征:对于60μm的厚度计算,对于平均的波长为600nm的光的透射率等于或高于70%; 根据JIS K7161方法测量的杨氏模量等于或大于10GPa; 根据ASTM D606方法测量的线性热膨胀系数等于或小于10ppm / K。