Abstract:
Flow type electrochemical cells are disclosed. The electrochemical cell has an anode half-cell, a cathode half-cell, and permeable separating layer. The half-cells are bounded by side elements. Respective porous electrodes are housed in the half-cells. The permeable separating layer is disposed between the anode half-cell and the cathode half-cell. An electrolyte region connected to an electrolyte feed and an electrolyte outflow region connected to an electrolyte drain are further provided. An electrolyte inflow region and an electrolyte outflow region are disposed on opposite sides of the porous electrodes such that inflowing electrolyte flows through the porous electrode perpendicularly to the permeable separating layer.
Abstract:
An energy storage system employing a reversible salination-desalination process includes an electrochemical desalination battery (EDB) unit including an anode and a cathode. The EDB unit runs a salination process while storing energy from a direct current power supply unit, and runs a desalination process while releasing energy to an electrical load. The energy storage system can store power from a variable output electrical power supply unit such as solar cells and wind turbines while running a salination process, and release energy, e.g., during peak energy demand hours while running a desalination process. Combined with a capacitive deionization (CD) unit, the energy storage system can generate fresh water by running desalination processes in the EDB unit and the CD unit while releasing stored energy from the EDB unit. The energy storage unit can function as a dual purpose device for energy storage and fresh water generation.
Abstract:
The invention relates to an arrangement and a method for the controlled discharge of an energy store using redox shuttle additives and to the use of redox shuttle additives for the controlled discharge of an energy store. The energy store arrangement comprises a storage container with a redox shuttle additive which is dispensed into the electrolytes of the energy store upon triggering a dispensing device such that the energy store is partly or completely discharged, wherein the redox shuttle additive is oxidized on the cathode and reduced on the anode. The redox shuttle additive has a redox potential which is less than or equal to the potential of the partially or completely discharged cathode and greater than or equal to the potential of the partially or completely discharged anode.
Abstract:
A redox flow battery is provided. The redox flow battery involves multiple-membrane (at least one cation exchange membrane and at least one anion exchange membrane), multiple-electrolyte (one electrolyte in contact with the negative electrode, one electrolyte in contact with the positive electrode, and at least one electrolyte disposed between the two membranes) as the basic characteristic, such as a double-membrane, triple electrolyte (DMTE) configuration or a triple-membrane, quadruple electrolyte (TMQE) configuration. The cation exchange membrane is used to separate the negative or positive electrolyte and the middle electrolyte, and the anion exchange membrane is used to separate the middle electrolyte and the positive or negative electrolyte.
Abstract:
A cell frame in which the structure of a positive electrode electrolyte flow path and the structure of a negative electrode electrolyte flow path are different from each other, a cell stack in which the structure of at least one of the positive electrode electrolyte flow path and the negative electrode electrolyte flow path differs between the cell frame positioned at the center and the cell frame positioned at an end, the cell stack being configured such that electrical resistance in at least one of the positive electrode electrolyte flow path and the negative electrode electrolyte flow path increases from the cell frame positioned at the center toward the cell frame positioned at the end, and a redox flow battery utilizing them.
Abstract:
A fluid chamber device for a reaction unit of a redox device, includes at least one first wall element and at least one second wall element which at least partially delimit a fluid chamber, and a sealing region which closes off the fluid chamber against a fluid exchange, in particular a gas exchange, in relation to a surrounding space. At least one of the wall elements, in an installed state, has at least one sealing contour in the sealing region, which is intended for providing a sealing effect and by means of which a spacing of the at least two wall elements in the sealing region is reduced in relation to a surrounding area of the sealing region.
Abstract:
A flow battery cell is presented. The flow battery cell includes a first electrode configured for charging a discharged catholyte, a second electrode configured for charging and discharging an anolyte, and a third electrode configured for discharging a charged catholyte. The second electrode is disposed between the first electrode and the third electrode. Each of the first electrode and the third electrode is separated from the second electrode by a bipolar membrane. A first bipolar membrane and a second bipolar membrane are disposed, respectively, between the first electrode and the second electrode, and the second electrode and the third electrode. A flow battery stack and a method for operating the flow battery stack are also presented.
Abstract:
A flow battery includes a positive electrode, a positive electrode electrolyte, a negative electrode, a negative electrode electrolyte, and a polymer electrolyte membrane interposed between the positive electrode and the negative electrode. The positive electrode electrolyte includes water and a first redox couple. The first redox couple includes a first organic compound which includes a first moiety in conjugation with a second moiety. The first organic compound is reduced during discharge while during charging the reduction product of the first organic compound is oxidized to the first organic compound. The negative electrode electrolyte includes water and a second redox couple. The second couple includes a second organic compound including a first moiety in conjugation with a second moiety. The reduction product of the second organic compound is oxidized to the second organic compound during discharge.
Abstract:
Redox flow devices are described including a positive electrode current collector, a negative electrode current collector, and an ion-permeable membrane separating said positive and negative current collectors, positioned and arranged to define a positive electroactive zone and a negative electroactive zone; wherein at least one of said positive and negative electroactive zone comprises a flowable semi-solid composition comprising ion storage compound particles capable of taking up or releasing said ions during operation of the cell, and wherein the ion storage compound particles have a polydisperse size distribution in which the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.
Abstract:
A non-aqueous redox flow battery includes a catholyte including a compound of formula (I) or a compound of formula (II): Where X1 is a moiety of formula I-A or I-B: