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    FLUORINATED COMPOSITIONS AND SURFACE TREATMENTS MADE THEREFROM
    81.
    发明申请
    FLUORINATED COMPOSITIONS AND SURFACE TREATMENTS MADE THEREFROM 有权
    氟化组合物和表面处理

    公开(公告)号：US20100183889A1

    公开(公告)日：2010-07-22

    申请号：US12663027

    申请日：2008-06-05

    申请人： Rudolf J. Dams ,  Steven J. Martin ,  Mark J. Pellerite ,  Chetan P. Jariwala ,  Gregory D. Clark ,  Jason T. Petrin

    发明人： Rudolf J. Dams ,  Steven J. Martin ,  Mark J. Pellerite ,  Chetan P. Jariwala ,  Gregory D. Clark ,  Jason T. Petrin

    IPC分类号： B32B15/04 ,  C09D7/12

    CPC分类号： C08F14/185 ,  C08F8/40 ,  C08F220/10 ,  C08F220/18 ,  C08F220/22 ,  C08F220/36 ,  C08J3/09 ,  C08J2333/16 ,  C09D127/12 ,  C09D133/06 ,  C09D133/14 ,  C09D133/16 ,  C09D143/02 ,  Y10T428/3154 ,  Y10T428/31678 ,  C08F20/22 ,  C08F230/02

    摘要： A composition comprising at least one first divalent unit represented by formula (A) or formula (B); and at least one of a second divalent unit comprising a pendant Z group or a monovalent unit comprising a thioether linkage and a terminal Z group, wherein each Z group is independently selected from the group consisting of —P(O)(OY)2 and —O—P(O)(OY)2. Rf is a perfluoropolyether group. Q is selected from the group consisting of a bond, —C(O)—N(R1)—, and —C(O)—O—. R″, R′″, R and R1 are each independently selected from the group consisting of hydrogen and alkyl having from 1 to 4 carbon atoms. X is selected from the group consisting of alkylene, arylalkylene, and alkylarylene, wherein alkylene, arylalkylene, and alkylarylene are each optionally interrupted by at least one ether linkage. Y is selected from the group consisting of hydrogen, alkyl, trialkylsilyl, and a counter cation. Methods of treating a surface using these compositions and articles with a surface in contact with these compositions are provided. Methods of making these compositions are also provided.

    摘要翻译： 包含由式（A）或式（B）表示的至少一种第一二价单元的组合物; 和包含Z侧基团或包含硫醚键和末端Z基团的一价单元的第二二价单元中的至少一个，其中每个Z基团独立地选自-P（O）（OY）2和 -O-P（O）（OY）2。 Rf是全氟聚醚基团。 Q选自-C（O）-N（R 1） - 和-C（O）-O-。 R“，R”“，R”和“R”各自独立地选自氢和具有1至4个碳原子的烷基。 X选自亚烷基，芳基亚烷基和烷基亚芳基，其中亚烷基，芳基亚烷基和烷基亚芳基各自任选地被至少一个醚键中断。 Y选自氢，烷基，三烷基甲硅烷基和抗衡阳离子。 提供了使用这些组合物和具有与这些组合物接触的表面的制品处理表面的方法。 还提供制备这些组合物的方法。

    Fluorochemical composition and method of treatment of a substrate therewith to render substrate oil- and/or water repellent
    86.
    发明授权
    Fluorochemical composition and method of treatment of a substrate therewith to render substrate oil- and/or water repellent 失效
    含氟化合物组合物及其基质的处理方法以使底物具有油和/或拒水性

    公开(公告)号：US07470741B2

    公开(公告)日：2008-12-30

    申请号：US10444879

    申请日：2003-05-23

    申请人： Rudolf J. Dams

    发明人： Rudolf J. Dams

    IPC分类号： C08K3/00

    CPC分类号： D06M15/277 ,  C03C17/28 ,  C03C17/30 ,  C08F8/42 ,  C08K5/54 ,  C09D133/16 ,  C09D143/04 ,  D06M2200/11 ,  C08F14/18 ,  C08L33/16 ,  C08L2666/44

    摘要： The present invention provides a fluorochemical composition comprising: (a) one or more fluorochemical oligomers derivable from a free radical polymerization of one or more fluorinated monomers and optionally one or more non-fluorinated monomers in the presence of a chain transfer agent, said fluorochemical oligomer being free of acid groups and comprising one or more groups of the formula: -M1(R)q(Y)p−q−1  (I) wherein M1 is selected from the group consisting of Si, Ti, Zr, B, Al, Ge, V, Pb, Sn and Zn, R represents a non-hydrolysable group, Y represents a hydrolysable group, q is 0, 1 or 2, p equals the valence of M1 and is 3 or 4 and p−q−1 is at least 1; (b) one or more non-fluorinated compounds of an element M2 selected from the group consisting of Si, Ti, Zr, B, Al, Ge, V, Pb, Sn and Zn and having at least two hydrolysable groups per molecule in an amount sufficient to form a polycondensation product upon reaction with said fluorochemical oligomer (a); (c) water; and (d) an organic solvent in an amount sufficient to dissolve and/or disperse components (a), (b) and (c). The invention also provides compositions comprising condensates of components (a) and (b) of the above composition and a method of treatment of substrates therewith.

    摘要翻译： 本发明提供一种含氟化合物组合物，其包含：（a）一种或多种衍生自一种或多种氟化单体和任选的一种或多种非氟化单体在链转移剂存在下的自由基聚合的含氟低聚物，所述含氟低聚物 没有酸基并且包含一个或多个下式的基团：<？in-line-formula description =“In-line Formulas”end =“lead”→M1（R）q（Y）pq-1（ 其中M1选自Si，Ti，Zr，B，Al，Ge，V，Pb，Sn中的一种。 和Zn，R表示不可水解基团，Y表示可水解基团，q表示0,1或2，p表示M1的化合价，为3或4，pq-1为至少1; （b）一种或多种选自Si，Ti，Zr，B，Al，Ge，V，Pb，Sn和Zn的元素M2的非氟化化合物，并且在每个分子中具有至少两个可水解基团 足以在与所述含氟低聚物（a）反应时形成缩聚产物; （c）水; 和（d）足以溶解和/或分散组分（a），（b）和（c）的量的有机溶剂。 本发明还提供了包含上述组合物的组分（a）和（b）的缩合物的组合物和其处理底物的方法。

    FLUOROCHEMICAL COMPOSITION COMPRISING FLUORINATED OLIGOMERIC SILANE
    88.
    发明申请
    FLUOROCHEMICAL COMPOSITION COMPRISING FLUORINATED OLIGOMERIC SILANE 有权
    包含氟化低聚硅烷的氟化学组合物

    公开(公告)号：US20080027203A1

    公开(公告)日：2008-01-31

    申请号：US11460303

    申请日：2006-07-27

    申请人： Rudolf J. Dams

    发明人： Rudolf J. Dams

    IPC分类号： C08G77/24

    CPC分类号： C08G18/2885

    摘要： Fluorochemical oligomeric silanes, compositions comprising such silanes and/or the condensation products of such silanes, and coatings produced with such compositions.

    摘要翻译： 氟化物低聚硅烷，包含这种硅烷的组合物和/或这种硅烷的缩合产物，以及用这种组合物制备的涂料。