-
81.发明授权High charge density polymeric complexes - viscosifiers for acid, base and salt (aqueous) solutions 失效高电荷密度聚合复合物 - 酸，碱和盐（水溶液）的增粘剂
公开(公告)号：US4608425A
公开(公告)日：1986-08-26
申请号：US747427
申请日：1985-06-21
IPC分类号： C08F212/14 , C08F220/60 , C08F20/60
CPC分类号： C08F212/14 , C08F220/60
摘要： The present invention relates to improved viscosification agents for a variety of aqueous solutions which comprise a family of intramolecular polymeric complexes (i.e., polyampholytes) which are copolymers of metal styrene sulfonate/methacrylamidoproplytrimethylammonium chloride (MAPTAC). The metal styrene sulfonate is an anionic monomer, while MAPTAC is cationically charged. These polyampholytes have approximately 1 to about 99 mole % of the anionic monomer and approximately 1 to about 99 mole % of the cationic moiety present within the macromolecular structure. These groups are not necessarily present in an equimolar charge ratio. The excess undissociated charge allows for facile dispensability or solubility of the polyampholytes into low ionic strength aqueous solutions.
摘要翻译： 本发明涉及用于各种水溶液的改性增稠剂，其包含金属苯乙烯磺酸盐/甲基丙烯酰胺丙基三甲基氯化铵（MAPTAC）的共聚物的分子内聚合物复合物（即聚阴离子）家族。 金属苯乙烯磺酸盐是阴离子单体，而MAPTAC是阳离子充电的。 这些多聚电解质具有约1至约99摩尔％的阴离子单体和约1至约99摩尔％的存在于大分子结构内的阳离子部分。 这些基团不一定以等摩尔电荷比存在。 过量的未解离的电荷使得多聚电解质易于分配或溶解于低离子强度的水溶液中。
-
82.发明授权
公开(公告)号：US4579669A
公开(公告)日：1986-04-01
申请号：US600976
申请日：1984-04-16
CPC分类号： C09K8/36 , Y10S507/91
摘要： A new class of viscosification agents based on water insoluble and oil insoluble neutralized sulfonated thermoplastic resins is described for oil-based drilling muds. The resultant muds display good viscosity characteristics and good stability when formulated from water insoluble and oil insoluble neutralized sulfonated thermoplastic polymers having an appropriate sulfonate level and cation type.
摘要翻译： 描述了一类新的基于水不溶性和油不溶性中和磺化热塑性树脂的增稠剂，用于油基钻井泥浆。 当由具有适当磺酸盐水平和阳离子类型的水不溶性和油不溶性中和的磺化热塑性聚合物配制时，所得泥浆表现出良好的粘度特性和良好的稳定性。
-
公开(公告)号：US4547542A
公开(公告)日：1985-10-15
申请号：US564719
申请日：1983-12-23
摘要： This invention relates to unique and novel compositions based on chemically combining a sulfonated polymer and an amine terminated polylactone composition. The resulting amine neutralized sulfonated polymer compositions have a variety of uses including those as diverse as adhesive agents, thermoplastic elastomers, additive uses wherein these materials can be utilized to compatibilize two different polymers which are normally incompatible. These compositions can also be blended with fillers and/or oils when the sulfonated polymer is elastomeric. The materials display thermoplastic character.
摘要翻译： 本发明涉及基于化学组合磺化聚合物和胺封端的聚内酯组合物的独特且新颖的组合物。 所得胺中和的磺化聚合物组合物具有多种用途，包括各种用途，包括粘合剂，热塑性弹性体，添加剂用途，其中这些材料可用于使通常不相容的两种不同聚合物相容。 当磺化聚合物是弹性体时，这些组合物也可与填料和/或油混合。 材料显示热塑性。
-
84.发明授权Intramolecular polymer complexes - viscosifiers for high ionic strength drilling fluids 失效分子内聚合物复合物 - 用于高离子强度钻井液的增粘剂
公开(公告)号：US4540496A
公开(公告)日：1985-09-10
申请号：US478683
申请日：1983-03-25
IPC分类号： C09K8/04 , C08F20/52 , C08F220/56 , C08F220/60 , C09K8/12 , C09K8/24 , C09K7/02
CPC分类号： C09K8/12 , C08F220/56 , C09K8/24
摘要： A new family of terpolymers based on acrylamide/sodium styrene sulfonate/methacrylamidopropyltrimethylammonium chloride has been found to be an improved viscosity control additive for water-based drilling muds. The resultant muds display good viscosity characteristics, thermal stability and gel strength when formulated from the terpolymer intramolecular complex having the appropriate polymer concentration and salt level.
摘要翻译： 已经发现，一种新的基于丙烯酰胺/苯乙烯磺酸钠/甲基丙烯酰胺基丙基三甲基氯化铵的三元共聚物是用于水基钻井泥浆的改进的粘度控制添加剂。 当由具有适当聚合物浓度和盐水平的三元共聚物分子内复合物配制时，所得泥浆显示出良好的粘度特性，热稳定性和凝胶强度。
-
85.发明授权Controlled gelation on nonaqueous solutions containing low charge density polyampholytes 失效含有低电荷密度聚阴离子的非水溶液的控制凝胶化
公开(公告)号：US4522960A
公开(公告)日：1985-06-11
申请号：US638218
申请日：1984-08-06
CPC分类号： C08J3/09
摘要： A process for gelling a fluid having a viscosity of at least about 50 cps which includes the steps of: forming a solvent system of the nonpolar organic liquid and a polar cosolvent, the polar cosolvent being less than about 15 weight percent of the solvent system and a viscosity of the solvent system being less than about 100 cps; dissolving a water insoluble, oil soluble terpolymer in the solvent system to form a solution, a concentration of the terpolymer in the solution being about 0.2 to about 10 weight percent and a viscosity of the solution being less than about 2000 cps, the terpolymer having the formula: ##STR1## wherein x is about 40 to about 98 mole %, y is about 1 to about 50 mole %, and z is about 1 to about 50 mole %, wherein y and z are less than 60 mole %, and M is an amine or a metal cation selected from the group consisting of antimony tin, lead, Groups IA, IIA, IB and IIB of the Periodic Table of Elements; and adding about 5 to about 500 volume percent water to the solution of the terpolymer, said water being immiscible with the solution of the terpolymer, the polar cosolvent transferring from the nonpolar organic liquid to the water thereby causing the viscosity of the organic liquid to increase to at least 5000 cps.
摘要翻译： 一种胶粘具有至少约50cps的粘度的流体的方法，其包括以下步骤：形成非极性有机液体和极性助溶剂的溶剂体系，极性助溶剂小于溶剂体系的约15重量％ 溶剂系统的粘度小于约100cps; 将水不溶性油溶性三元共聚物溶解在溶剂体系中以形成溶液，溶液中三元共聚物的浓度为约0.2至约10重量％，溶液的粘度小于约2000cps，三元共聚物具有 式：其中x为约40至约98摩尔％，y为约1至约50摩尔％，z为约1至约50摩尔％，其中y和z为小于60摩尔％，M为 是选自元素周期表的锑锡，铅，IA，IIA，IB和IIB族的胺或金属阳离子; 并向三元共聚物的溶液中加入约5至约500体积％的水，所述水与三元共聚物溶液不混溶，极性助溶剂从非极性有机液体转移到水中，从而导致有机液体的粘度增加 至少5000厘泊。
-
公开(公告)号：US4510998A
公开(公告)日：1985-04-16
申请号：US556398
申请日：1983-11-30
IPC分类号： C09K8/50 , E21B33/138
CPC分类号： C09K8/50
摘要： The present invention relates to a process for the plugging of a porous formation which may be encountered during the drilling of a well. The process entails plugging of the porous formation by means of a polymeric solution containing pseudo-emulsion spheres. These particles penetrate the pore structure within a formation. Eventually, sufficient numbers of the spheres will accumulate within the pores, blocking further flow through the formation by both the pseudo-emulsion particles and any aqueous solutions. The pseudo-emulsion system is formed by a process which includes the steps of forming a solvent system of an organic liquid or oil and a polar cosolvent, the polar cosolvent being less than about 15 weight percent of the solvent system being less than about 100 cps; dissolving a neutralized sulfonated polymer in the solvent system to form a solution, a concentration of the neutralized sulfonated polymer in the solution being about 0.01 to about 0.5 weight percent, a viscosity of the solution being less than about 200 cps; and admixing or contacting said solution with about 5 to about 500 volume percent water, the water being immiscible with the organic liquid and the polar cosolvent and neutralized sulfonated polymer transferring from the organic liquid to the water phase, thereby causing the water phase to gel (i.e., thicken).
摘要翻译： 本发明涉及在钻井过程中可能遇到的多孔地层堵塞的方法。 该方法需要通过含有假乳液球的聚合物溶液堵塞多孔结构。 这些颗粒穿透地层内的孔结构。 最终，足够数量的球体将积聚在孔内，阻止伪乳液颗粒和任何水溶液进一步流过地层。 该假乳液体系通过包括形成有机液体或油和极性助溶剂的溶剂体系的步骤的方法形成，极性助溶剂小于溶剂体系的约15重量％小于约100cps ; 将中和的磺化聚合物溶解在溶剂体系中以形成溶液，溶液中中和的磺化聚合物的浓度为约0.01至约0.5重量％，溶液的粘度小于约200cps; 并将所述溶液与约5至约500体积％的水混合或接触，所述水与有机液体和极性助溶剂不混溶，并且中和的磺化聚合物从有机液体转移到水相，从而使水相凝胶化（ 即增厚）。
-
公开(公告)号：US4497923A
公开(公告)日：1985-02-05
申请号：US547904
申请日：1983-11-02
IPC分类号： B01J13/00 , B05D5/08 , C08J3/00 , C08J3/09 , C09K3/00 , C10L7/02 , C08J3/08 , C08J3/10 , C08K5/01 , C08K5/04
CPC分类号： B05D5/08 , B01J13/0082 , C08J3/005 , C08J3/091 , C09K3/00 , C10L7/02 , Y10S524/924
摘要： The present invention relates to a process for the viscosification of an organic liquid which comprises the steps of forming a first solution of an anionic polymer dissolved in the organic liquid; forming a second solution of a cationic polymer dissolved in the organic liquid; and mixing the first and the second solutions together to form an interpolymer complex of the anionic and cationic polymer in the organic liquid, wherein the organic liquid containing the interpolymer complex has improved viscosification properties. This solution possesses higher viscosity than the mean of the separate viscosities of the starting solutions at relatively low solids content. Moreover, these interpolymer complexes, in hydrocarbon solutions, can be formulated to exhibit shear thickening at increased shear rates. This property is useful in such technological applications as antimisting of the solvent.
摘要翻译： 本发明涉及有机液体的增粘方法，其包括以下步骤：形成溶解在有机液体中的阴离子聚合物的第一溶液; 形成溶解在有机液体中的阳离子聚合物的第二溶液; 并将第一和第二溶液混合在一起形成有机液体中阴离子和阳离子聚合物的互聚物络合物，其中含有互聚物络合物的有机液体具有改进的增粘性能。 该溶液具有比起始溶液在相对较低固体含量下分开的粘度的平均值更高的粘度。 此外，在烃溶液中的这些互聚物配合物可以配制成在增加的剪切速率下显示剪切增稠。 该特性在溶剂的抗溶剂等技术应用中是有用的。
-
公开(公告)号：US4425462A
公开(公告)日：1984-01-10
申请号：US416937
申请日：1982-09-13
IPC分类号： C08F236/10 , C09K8/36 , C08K3/24 , C08L25/08 , C09K7/02
CPC分类号： C08F236/10 , C09K8/36 , Y10S507/91
摘要： The present invention relates to sulfonated elastomeric polymers which are copolymers of isoprene and sodium styrene sulfonate or teropolymers of isoprene, styrene and sodium styrene sulfonate wherein these sulfonated polymers function as viscosification agents when added to oil-based drilling muds which are the fluids used to maintain pressure, cool drill bits and lift cuttings from the holes in the drilling operation for oil and gas wells. The sulfonated and elastomeric polymers have about 5 to about 100 meq. of sulfonate groups per 100 grams of the sulfonated elastomeric polymer, wherein the sulfonated groups are neutralized with a metallic cation or an amine or ammonium counterion. A polar cosolvent can optionally be added to the mixture of oil drilling mud and sulfonated elastomeric polymer, wherein the polar cosolvent increases the solubility of the sulfonated elastomeric polymer in the oil drilling mud by decreasing the strong ionic interactions between the sulfonate groups of the sulfonated polymer.
摘要翻译： 本发明涉及作为异戊二烯和苯乙烯磺酸钠的共聚物或异戊二烯，苯乙烯和苯乙烯磺酸钠的三元共聚物的磺化弹性体聚合物，其中这些磺化聚合物当加入到用作维持的流体的油基钻井泥浆中时用作粘稠剂 石油和天然气井的钻井操作中的孔中的压力，冷钻头和提升切屑。 磺化和弹性聚合物具有约5至约100meq。 每100克磺化弹性体聚合物的磺酸盐基团，其中磺化基团被金属阳离子或胺或铵抗衡离子中和。 可以任选地将极性助溶剂加入到油钻泥浆和磺化弹性体聚合物的混合物中，其中极性助溶剂通过降低磺化聚合物的磺酸盐基团之间的强离子相互作用而增加磺化弹性体聚合物在石油钻井泥浆中的溶解度 。
-
公开(公告)号：US4288352A
公开(公告)日：1981-09-08
申请号：US23632
申请日：1979-03-26
IPC分类号： C08L23/00 , C08K3/00 , C08K3/02 , C08K3/04 , C08K5/00 , C08K5/09 , C08K7/00 , C08K7/06 , C08L7/00 , C08L21/00 , C08L23/26 , C08L25/00 , C08L33/00 , C08L33/02 , C08L101/00 , H01B1/24 , C08L91/00
摘要： This invention relates to the injection moldable and extrusion type electrically conductive polymeric blend compositions having a viscosity at 200.degree. C. at 0.73 sec.sup.-1 of less than about 8.times.10.sup.5 poises. The compositions used for elastomeric articles include a neutralized sulfonated polymer; graphite fiber at a concentration of about 1 to about 50 parts by weight per 100 parts by weight of neutralized sulfonated polymer; and a preferential plasticizer at about less than 60 parts by weight based on 100 parts by weight of the neutralized sulfonated polymer. The composition may also optionally include fillers, oils and other additives. These blend compositions can be readily processed due to their superior rheological properties on conventional plastic fabrication equipment, especially on low and high pressure injection molding or extrusion equipment into electrically conductive articles having excellent physical and electrical properties.
摘要翻译： 本发明涉及注塑和挤出型导电聚合物共混组合物，其在200℃下的粘度为0.73秒-1小于约8×10 5泊。 用于弹性制品的组合物包括中和的磺化聚合物; 石墨纤维，其浓度为每100重量份中和的磺化聚合物约1至约50重量份; 和基于100重量份中和的磺化聚合物约60重量份的优选增塑剂。 组合物还可以任选地包括填料，油和其它添加剂。 这些共混组合物由于其在常规塑料制造设备上的优异流变性能而可以容易地加工，特别是在低压和高压注塑或挤出设备上具有优异的物理和电学性能的导电制品中。
-
公开(公告)号：US4285851A
公开(公告)日：1981-08-25
申请号：US136834
申请日：1980-04-03
IPC分类号： C09D7/00 , C09D123/32 , C09J123/32 , C09K8/035 , C09K8/24 , C09K8/588 , C08L23/32
CPC分类号： C09K8/588 , C09D123/32 , C09D7/002 , C09J123/32 , C09K8/035 , C09K8/24 , C08L23/32 , Y10S260/31 , Y10S524/916
摘要： The present invention relates to a process for forming a polymeric solution or gel having a viscosity of at least about 50,000 cps which includes the steps of dissolving an amine terminated polyalkylene oxide neutralized sulfonated polymer in a solvent to form a polymeric solution, a concentration of the amine terminated polyalkylene oxide neutralized sulfonated polymer in the solution being about 0.1 to about 20 wt. %, a viscosity of the solution being less than about 20,000 cps; and adding about 1 to about 500 vol. % water to the polymeric solution having a viscosity less than about 20,000 cps, the water being immiscible with the solvent and the polymeric solution, the viscosity of said polymeric solution increasing rapidly upon the addition of said water from less than 20,000 cps to greater than 50,000 cps.
摘要翻译： 本发明涉及形成具有至少约50,000cps的粘度的聚合物溶液或凝胶的方法，其包括将胺封端的聚亚烷基氧化物中和的磺化聚合物溶解在溶剂中以形成聚合物溶液的步骤，浓度为 胺封端的聚环氧烷中和的磺化聚合物在溶液中为约0.1至约20wt。 ％，溶液的粘度小于约20,000cps; 并加入约1至约500体积％ ％的水溶于具有小于约20,000cps的粘度的聚合物溶液中，水与溶剂和聚合物溶液不混溶，所述聚合物溶液的粘度在将所述水从小于20,000cps加到大于50,000时迅速增加 cps。
-
-
-
-
-
-
-
-
-
搜索结果
253 条记录 (耗时 0.024 秒)
