PROCESS FOR INDUSTRIAL ISOLATION OF PROPENE
    81.
    发明申请
    PROCESS FOR INDUSTRIAL ISOLATION OF PROPENE 失效
    工业分离丙烯的方法

    公开(公告)号:US20110118526A1

    公开(公告)日:2011-05-19

    申请号:US13003839

    申请日:2009-07-17

    IPC分类号: C07C7/12

    CPC分类号: C07C7/12 C07C11/06

    摘要: A process for the industrial isolation of propene from a gas stream comprising at least propene and propane, which involves contacting of the gas stream with an adsorbent having a porous metal organic framework having at least one at least bidentate organic compound coordinated to at least one metal ion, with the adsorbent becoming laden with propane and the gas stream therefore having an increased proportion of propene, wherein the W least bidentate organic compound is an imidazolate which is unsubstituted or has one or more substituents selected independently from of halogen, C1-6-alkyl, phenyl, NH2, NH(C1-6-alkyl), N(C1-6-alkyl)2, OH, O-phenyl and O—C1-6-alkyl.

    摘要翻译: 一种用于从包含至少丙烯和丙烷的气流中工业分离丙烯的方法,其包括使气流与具有多孔金属有机骨架的吸附剂接触,所述多孔金属有机骨架具有与至少一种金属配位的至少二齿有机化合物 离子,吸附剂变得装满丙烷,因此气流具有增加的丙烯比例,其中W最小二齿有机化合物是未被取代的或具有一个或多个独立地选自卤素,C 1-6 - 烷基,苯基,NH 2,NH(C 1-6 - 烷基),N(C 1-6 - 烷基)2,OH,O-苯基和O-C 1-6 - 烷基。

    Mesoporous metal-organic framework
    85.
    发明授权
    Mesoporous metal-organic framework 有权
    介孔金属 - 有机骨架

    公开(公告)号:US07842827B2

    公开(公告)日:2010-11-30

    申请号:US11996976

    申请日:2006-08-16

    IPC分类号: C07F5/06 B01J33/00

    摘要: The present invention relates to a porous metal-organic framework comprising AlIII and at least one at least bidentate compound, wherein the at least one at least bidentate organic compound is a six-membered aromatic hydrocarbon ring A in which one or more ring carbons may be replaced by nitrogen and which has three substituents X and optionally one or more substituents selected from the group consisting of R, NRR′, OR, SR, F, Cl and Br, where R, R′ are each, independently of one another, hydrogen, methyl which may optionally be substituted by one or more fluorine atoms or ethyl which may optionally be substituted by one or more fluorine atoms and each X is, independently of the others, C(═O)O−, C(═S)O−, C(═O)S−, C(═S)S− or a protonated form thereof. The invention further provides a process for preparing it and provides for the use of the new porous metal-organic framework.

    摘要翻译: 本发明涉及包含AlIII和至少一种至少二齿化合物的多孔金属 - 有机骨架,其中所述至少一种至少二齿的有机化合物是其中一个或多个环碳可以是六元芳烃环A 被氮取代,并且具有三个取代基X和任选的一个或多个选自R,NRR',OR,SR,F,Cl和Br的取代基,其中R,R'彼此独立地为氢 可以任选被一个或多个氟原子取代的甲基或可任意被一个或多个氟原子取代的乙基,并且每个X独立地为C(= O)O-,C(= S)O - ,C(= O)S-,C(= S)S-或其质子化形式。 本发明还提供了一种制备该方法并提供了新的多孔金属 - 有机骨架的用途。

    CHEMICAL-MECHANICAL POLISHING COMPOSITION COMPRISING METAL-ORGANIC FRAMEWORK MATERIALS
    87.
    发明申请
    CHEMICAL-MECHANICAL POLISHING COMPOSITION COMPRISING METAL-ORGANIC FRAMEWORK MATERIALS 有权
    包含金属有机骨架材料的化学机械抛光组合物

    公开(公告)号:US20100178767A1

    公开(公告)日:2010-07-15

    申请号:US12600539

    申请日:2008-05-21

    IPC分类号: H01L21/461 C09K13/00 B23H5/06

    摘要: The present invention relates to compositions for chemical-mechanical polishing comprising A 0.01% to 40% by weight based on the total amount of the composition of abrasive particles of at least one porous metal-organic framework material, wherein the framework material comprises at least one at least bidentate organic compound which is coordinately bound to at least one metal ion; B 40% to 99.8% by weight based on the total amount of the composition of a liquid carrier; and C 0.01% to 20% by weight based on the total amount of the composition of a polishing additive component. The invention further relates to the use of said composition as well as methods for chemical-mechanical polishing of a surface with the aid of said compositions.

    摘要翻译: 本发明涉及用于化学机械抛光的组合物,其包含基于组合物的至少一种多孔金属 - 有机骨架材料的磨料颗粒的总量的0.01重量%至40重量%,其中所述骨架材料包含至少一种 与至少一种金属离子配位结合的至少二齿有机化合物; B为基于液体载体的组合物总量的40重量%至99.8重量% 和基于抛光添加剂组分的总量的0.01重量%至20重量%。 本发明还涉及所述组合物的使用以及借助所述组合物进行化学机械抛光表面的方法。

    GAS PRESSURE VESSEL COMPRISING A MIXTURE COMPRISING A METAL ORGANIC FRAMEWORK AND ALSO A LATENT HEAT STORE
    89.
    发明申请
    GAS PRESSURE VESSEL COMPRISING A MIXTURE COMPRISING A METAL ORGANIC FRAMEWORK AND ALSO A LATENT HEAT STORE 审中-公开
    包含金属有机框架的混合气体的气体压力容器,还有一个专门的热存储

    公开(公告)号:US20100133280A1

    公开(公告)日:2010-06-03

    申请号:US12594604

    申请日:2008-04-01

    IPC分类号: F17C1/00 F17C5/06

    摘要: The present invention relates to a gas pressure vessel having a prescribed maximum filling pressure for the uptake, storage and release of a gas, which comprises the gas and a mixture comprising, in each case based on the total weight of the mixture, a) from 2 to 60% by weight of a latent heat storage component A and b) from 40 to 98% by weight of a framework component B, wherein the component A comprises at least one microencapsulated latent heat storage material and the component B comprises at least one porous metal organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion and the at least one porous metal framework can adsorptively store at least part of the gas. The invention furthermore relates to a process for filling a gas pressure vessel with the abovementioned mixture for the uptake, storage and release of a gas.

    摘要翻译: 本发明涉及一种具有用于吸收,储存和释放气体的规定的最大填充压力的气体压力容器,其包括气体和混合物,每种情况基于混合物的总重量,a) 2至60重量%的潜热储存组分A和b)40至98重量%的骨架组分B,其中组分A包含至少一种微胶囊化潜热蓄热材料,组分B包含至少一种 多孔金属有机骨架包括与至少一种金属离子配位的至少一种至少二齿的有机化合物和至少一种多孔金属骨架,可吸附地存储至少部分气体。 本发明还涉及一种用上述混合物填充气体压力容器用于吸收,储存和释放气体的方法。

    Method for the production of C5 aldehydes and propene from a C4 stream containing 1-butene and 2-butene
    90.
    发明授权
    Method for the production of C5 aldehydes and propene from a C4 stream containing 1-butene and 2-butene 有权
    从含有1-丁烯和2-丁烯的C4流中生产C5醛和丙烯的方法

    公开(公告)号:US07714179B2

    公开(公告)日:2010-05-11

    申请号:US11661543

    申请日:2005-08-06

    IPC分类号: C07C6/00 C07C45/49

    摘要: Processes for preparing a C5 aldehyde and propene are disclosed, the processes comprising: (a) providing a feedstream, the feedstream comprising butane, 1-butene, 2-butene and 1,3-butadiene, the 1,3-butadiene present in the feedstream in an amount up to 1000 ppm; (b) contacting the feedstream with hydrogen and carbon monoxide in the presence of a hydroformylation catalyst to form a 2-butene-rich butane stream and a C5 aldehyde; (c) separating the 2-butene-rich butane stream and the C5 aldehyde; and (d) contacting the 2-butene-rich butane stream with ethene in the presence of a metathesis catalyst to form a propene-containing hydrocarbon stream.

    摘要翻译: 公开了制备C5醛和丙烯的方法,所述方法包括:(a)提供进料流,所述进料流包含丁烷,1-丁烯,2-丁烯和1,3-丁二烯,所述1,3-丁二烯存在于 进料流量高达1000 ppm; (b)在加氢甲酰化催化剂存在下使进料流与氢气和一氧化碳接触以形成富含2-丁烯的丁烷流和C5醛; (c)分离富含2-丁烯的丁烷流和C5醛; 和(d)在复分解催化剂存在下使富含2-丁烯的丁烷流与乙烯接触以形成含丙烯烃流。