公开(公告)号：US07902265B2

公开(公告)日：2011-03-08

申请号：US12253311

申请日：2008-10-17

申请人： Takamasa Kitamura ,  Makio Mori ,  Naoki Kushida ,  Toshiaki Masuda ,  Kenichi Kitano ,  Yoshiaki Shirakabe

发明人： Takamasa Kitamura ,  Makio Mori ,  Naoki Kushida ,  Toshiaki Masuda ,  Kenichi Kitano ,  Yoshiaki Shirakabe

IPC分类号： C08K9/10 ,  C08J9/16 ,  B60C1/00

CPC分类号： C08K9/10 ,  C08J9/32 ,  C08J2203/22 ,  C08J2321/00 ,  C08L21/00 ,  C08L51/00 ,  C08L51/003 ,  C08L2666/24 ,  C08L2666/02 ,  C08L2666/04

摘要： A rubber composition for a tire containing (i) 100 parts by weight of a diene-based rubber and (ii) 0.5 to 25 parts by weight of a heat-expandable microcapsule including a shell, and a substance capable of vaporizing or expanding under heating to thereby generate a gas and a nonpolar oil, both encapsulated in the shell, wherein the shell is made of a thermoplastic resin obtained by polymerization of a nitrile-based monomer (I), a monomer (II) having an unsaturated double bond and a carboxyl group in the molecule thereof, an optional monomer (III) having two or more polymerizable double bonds, and an optional copolymerizable monomer (IV) for adjusting the expansion properties.

摘要翻译： 一种轮胎用橡胶组合物，其含有（i）100重量份的二烯系橡胶和（ii）0.5〜25重量份的包含壳的热膨胀性微囊和能够在加热下蒸发或膨胀的物质 从而产生包封在壳中的气体和非极性油，其中壳由通过腈基单体（I），具有不饱和双键的单体（II）和具有不饱和双键的单体（II））聚合而获得的热塑性树脂 分子中的羧基，具有两个或更多个可聚合双键的任选单体（III）和用于调节膨胀性质的任选的可共聚单体（IV）。

公开(公告)号：US20100204349A1

公开(公告)日：2010-08-12

申请号：US12679661

申请日：2008-10-09

申请人： Takeshi Inohara ,  Yoshiaki Shirakabe ,  Ikuo Yosejima ,  Kenichi Kitano ,  Toshiaki Masuda

发明人： Takeshi Inohara ,  Yoshiaki Shirakabe ,  Ikuo Yosejima ,  Kenichi Kitano ,  Toshiaki Masuda

IPC分类号： C08J9/16 ,  B32B19/00

CPC分类号： B01J13/14 ,  B01J13/18 ,  B01J13/20 ,  C08J9/32 ,  C08J2203/22 ,  Y10T428/2982 ,  Y10T428/2998

摘要： Heat-expandable microspheres include a shell of thermoplastic resin and core material encapsulated in the shell. The core material include a blowing agent having a boiling point not higher than the softening point of the thermoplastic resin and a gas migration inhibitor having a boiling point higher than the softening point of the thermoplastic resin. The ratio of the gas migration inhibitor to the core material is at least 1 weight percent and below 30 weight percent. The average particle size of the heat-expandable microspheres ranges from 1 to 100 micrometers.

摘要翻译： 热膨胀性微球包括热塑性树脂的外壳和包封在壳中的芯材料。 核心材料包括沸点不高于热塑性树脂的软化点的发泡剂和沸点高于热塑性树脂的软化点的气体迁移抑制剂。 气体迁移抑制剂与核心材料的比例至少为1重量％且低于30重量％。 热膨胀性微球的平均粒径为1〜100微米。

公开(公告)号：US20090280328A1

公开(公告)日：2009-11-12

申请号：US12066057

申请日：2006-09-14

申请人： Toshiaki Masuda ,  Ichiro Takahara ,  Kenichi Kitano ,  Katsushi Miki ,  Takeshi Inohara ,  Takayuki Aoki

发明人： Toshiaki Masuda ,  Ichiro Takahara ,  Kenichi Kitano ,  Katsushi Miki ,  Takeshi Inohara ,  Takayuki Aoki

IPC分类号： B32B1/00 ,  C08J9/16

CPC分类号： B01J13/20 ,  B29C44/3461 ,  C08J9/143 ,  C08J9/32 ,  C08J2333/18 ,  Y10T428/2982 ,  Y10T428/2984 ,  Y10T428/2985 ,  Y10T428/2991 ,  Y10T428/2998

摘要： The present invention provides heat-expanded microspheres having high packing efficiency, and a production method thereof. The heat-expanded microspheres are produced by expanding heat-expandable microspheres, which comprise shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin and have an average particle size from 1 to 100 micrometer, at a temperature not lower than their expansion initiating temperature, and the heat-expanded microspheres result in a void fraction not higher than 0.70.

摘要翻译： 本发明提供具有高填充效率的热膨胀微球及其制造方法。 热膨胀微球体是通过膨胀包含热塑性树脂壳和封装在其中的沸点不高于热塑性树脂的软化点的发泡剂的热膨胀性微球而制成的，平均粒径为1〜100 微米，其温度不低于其膨胀起始温度，热膨胀微球导致不高于0.70的空隙率。

公开(公告)号：US20090263576A1

公开(公告)日：2009-10-22

申请号：US12091164

申请日：2006-11-16

申请人： Yoshinobu Okabe ,  Yoshiaki Tanaka ,  Yoshio Hashimoto ,  Mikio Nakagawa

发明人： Yoshinobu Okabe ,  Yoshiaki Tanaka ,  Yoshio Hashimoto ,  Mikio Nakagawa

IPC分类号： B05D3/02 ,  C09D1/00

CPC分类号： D01F9/22 ,  D01F11/06 ,  D06M7/00 ,  D06M13/224 ,  D06M15/6436 ,  D06M2101/28 ,  D06M2200/40

摘要： A finish for acrylic fiber to be processed into carbon fiber includes an ester compound having at least three ester groups in its molecule and a silicone compound, wherein the silicone compound constitutes 10 to 50 weight percent of the whole of the nonvolatile matter of the finish. A method of manufacturing carbon fiber includes the processes of applying the finish for acrylic fiber to be processed into carbon fiber to acrylic fiber to be processed into carbon fiber; oxidative-stabilizing the finish-applied acrylic fiber in an oxidizing atmosphere at 200 to 300 deg. C. to convert the fiber into oxidized fiber; and carbonizing the oxidized fiber in an inert atmosphere at 200 to 3000 deg. C.

摘要翻译： 加工成碳纤维的丙烯腈纤维的涂饰包括其分子中具有至少三个酯基的酯化合物和硅氧烷化合物，其中硅氧烷化合物占整个非完整性物质的10至50重量％。 制造碳纤维的方法包括将待加工的丙烯酸纤维的加工成型为碳纤维的丙烯酸纤维加工成碳纤维的方法; 在200至300度的氧化气氛中对涂饰丙烯酸纤维进行氧化稳定化。 C.将纤维转化为氧化纤维; 并在200-3000℃的惰性气氛中将氧化纤维碳化。 C。

公开(公告)号：US07288209B2

公开(公告)日：2007-10-30

申请号：US10494288

申请日：2002-10-30

申请人： Masahiro Hiramatsu ,  Takashi Soga

发明人： Masahiro Hiramatsu ,  Takashi Soga

IPC分类号： D06M15/643 ,  D06M13/292 ,  D06M13/50

CPC分类号： D06M15/6436 ,  C10M1/08 ,  C10N2240/62 ,  D06M7/00 ,  D06M13/02 ,  D06M13/292 ,  D06M13/295 ,  D06M15/643 ,  D06M2101/38 ,  D06M2200/00 ,  D06M2200/40 ,  Y10T442/2377

摘要： The present invention provides finishes for elastic fiber, which produce elastic fiber yarn having superior antistatic, unwinding, package buildup performance and lubricity properties. The present finishes further minimize fly sticking on the elastic fiber during the knitting operation of elastic fiber yarn and cotton spun yarn.The finishes of the present invention contain 80 to 99.99 parts by weight of at least one base component selected from the group consisting of silicone oils, mineral oils and ester oils, 0.01 to 10 parts by weight of amino-modified silicones and 0.0001 to 10 parts by weight of phosphate esters containing an acidic hydroxyl group and at least one hydrocarbon or oxyalkylene group per molecule.The elastic fiber of the present invention is characterized with the application of the finish in an amount of 0.1 to 15 weight percent of the fiber.

摘要翻译： 本发明提供弹性纤维的表面处理剂，其制造具有优异的抗静电，展开，包装积聚性能和润滑性能的弹性纤维纱线。 本发明在弹性纤维纱和棉纺纱的编织操作期间进一步减少弹性纤维上的飞沫粘附。 本发明的表面处理剂含有80〜99.99重量份的选自硅油，矿物油和酯油中的至少一种碱成分，0.01〜10重量份氨基改性硅酮和0.0001〜10重量份 的每分子含有酸性羟基和至少一个烃或氧化烯基团的磷酸酯。 本发明的弹性纤维的特征在于涂覆量为纤维的0.1〜15重量％。

公开(公告)号：US20070197698A1

公开(公告)日：2007-08-23

申请号：US10599183

申请日：2005-04-01

申请人： Yutaka Nakamura

发明人： Yutaka Nakamura

IPC分类号： C08K5/51

CPC分类号： D06M13/292 ,  C08K5/521 ,  C08L67/025 ,  D06M13/224 ,  D06M15/507 ,  D06M15/53 ,  D21H13/24 ,  D21H17/36 ,  D21H17/53 ,  C08L2666/18

摘要： [Problem]To obtain a fiber-treating agent and polyester staple fibers having excellent processability during the processing of polyester staple fibers with high-pressure water-jets, and excellent nonwoven fabric hydrophilicity after the high-pressure water-jet process. [Means of Solution]The present invention provides a fiber-treating agent comprising a component A, which is a polyester compound produced by carrying out a condensation polymerization of an alkylene glycol, a polyalkylene glycol, and at least one member selected from the group consisting of aromatic dicarboxylic acids, C4-22 aliphatic dicarboxylic acids, and their ester-forming derivatives; a component B, which is a polyester compound produced by carrying out a condensation polymerization of a polyoxyalkylene monol, an alkylene glycol, and at least one member selected from the group consisting of aromatic dicarboxylic acids and their ester-forming derivatives; and a component C, which is a C4-6 alkyl phosphate salt; and is characterized by components A, B, and C being blended in specific ratios. Also provided are polyester staple fibers treated with the treating agent, and a nonwoven fabric manufactured by processing the polyester staple fibers with high-pressure water jets.

摘要翻译： [问题]获得在高压水射流聚酯短纤维加工过程中具有优异加工性能的纤维处理剂和聚酯短纤维，以及高压喷水处理后的优异的无纺布亲水性。 [解决方案]本发明提供一种纤维处理剂，其包含成分A，其是通过进行亚烷基二醇，聚亚烷基二醇和选自以下的至少一种的缩合制备的聚酯化合物： 的芳族二羧酸，C 4-22脂族二羧酸及其酯形成衍生物; 组分B，其是通过进行聚氧化烯单醇，亚烷基二醇和选自由芳族二羧酸及其成酯衍生物组成的组中的至少一种的缩聚而制备的聚酯化合物; 和组分C，其为C 4-6烷基磷酸盐; 其特征在于组分A，B和C以特定比例混合。 还提供了用处理剂处理的聚酯短纤维和通过用高压水射流加工聚酯短纤维制成的无纺布。

公开(公告)号：US20070154711A1

公开(公告)日：2007-07-05

申请号：US10595910

申请日：2004-11-15

申请人： Toshiaki Masuda ,  Takashi Fujie ,  Ichiro Takahara ,  Ikuo Yosejima ,  Katsushi Miki

发明人： Toshiaki Masuda ,  Takashi Fujie ,  Ichiro Takahara ,  Ikuo Yosejima ,  Katsushi Miki

IPC分类号： B32B17/02 ,  C08K9/10

CPC分类号： C08J9/22 ,  B01J13/04 ,  B01J13/14 ,  C08J9/32 ,  C08J2203/142 ,  Y10T428/2985 ,  Y10T428/2987 ,  Y10T428/2991

摘要： A production process for heat-expanded microspheres comprising the step of providing a gaseous fluid containing heat-expandable microspheres, which comprise shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin and have an average particle size from 1 to 100 μm, feeding the gaseous fluid through a gas-introducing tube having a dispersion nozzle on its outlet and being fixed inside a hot gas flow, and emitting a jet of the gaseous fluid through the dispersion nozzle; a step wherein the gaseous fluid is collided on a collision plate fixed under the dispersion nozzle so as to disperse the heat-expandable microspheres in the hot gas flow; and a step wherein the dispersed heat-expandable microspheres are heated in the hot gas flow at a temperature not lower than their expansion initiating temperature and thus expanded. The production process results in minimum difference in the variation coefficient of particle size distribution between the microspheres before and after heat-expansion, slight ratio of raw microspheres and slightly expanded microspheres contained in resultant heat-expanded microspheres, and suppressed formation of aggregated microspheres.

摘要翻译： 一种热膨胀微球的制造方法，包括以下步骤：提供包含热膨胀性微球的气态流体，其包含热塑性树脂壳和封装在其中的发泡剂，沸点不高于热塑性树脂的软化点，并具有 平均粒度为1〜100μm，通过具有分散喷嘴的气体导入管在其出口处供给气体流体并固定在热气流内，并通过分散喷嘴喷射气态流体; 其中气态流体碰撞在固定在分散喷嘴下方的碰撞板上，以将热膨胀性微球分散在热气流中; 以及在热气流中以不低于其膨胀开始温度的温度加热分散的热膨胀性微球从而膨胀的步骤。 生产过程导致热膨胀前后的微球之间的粒度分布的变异系数的差异最小，所得热膨胀微球中所含的微生物微球和微球的微小比例，抑制聚集的微球的形成。

公开(公告)号：US06903143B2

公开(公告)日：2005-06-07

申请号：US10111937

申请日：2001-03-22

申请人： Toshiaki Masuda ,  Sachiko Tokumura

发明人： Toshiaki Masuda ,  Sachiko Tokumura

IPC分类号： B01J13/16 ,  B01J13/18 ,  C08F2/18 ,  C08F2/20 ,  C08J9/00 ,  C08J9/20 ,  C09D7/12 ,  C09D11/00 ,  C08L9/00

CPC分类号： C08J9/20 ,  B01J13/16 ,  C08F2/20 ,  C08J9/0014 ,  C08J2203/14 ,  C08J2203/16 ,  C08J2203/22 ,  C08J2333/02 ,  C08K9/10 ,  C08L89/00 ,  C09D7/70 ,  C09D11/03

摘要： A process for producing thermo-expansive microcapsules wherein a polymerizing mixture containing ethylenic unsaturated monomer and a blowing agent is suspend-polymerized to microencapsulate the blowing agent with the resultant polymer. The above-mentioned suspension-polymerization is performed with the presence of at least one compound selected from the group consisting of polypeptides and derivatives thereof as a suspension stabilizer. The process can control the particle size of microcapsules easily, attain stable reaction system and produce thermo-expansive microcapsules that disperse well in medium such as paint or inks.

摘要翻译： 一种制备热膨胀性微胶囊的方法，其中含有烯属不饱和单体和发泡剂的聚合混合物被悬浮聚合以将发泡剂与所得聚合物微胶囊化。 上述悬浮聚合是在存在至少一种选自多肽及其衍生物的化合物作为悬浮稳定剂的情况下进行的。 该方法可以容易地控制微胶囊的粒度，获得稳定的反应体系，并产生在介质如油漆或油墨中良好分散的热膨胀性微胶囊。

公开(公告)号：US5898077A

公开(公告)日：1999-04-27

申请号：US944549

申请日：1997-10-07

申请人： Ichiro Takahara ,  Masumi Kadobayashi ,  Noriaki Kaminaka

发明人： Ichiro Takahara ,  Masumi Kadobayashi ,  Noriaki Kaminaka

IPC分类号： C07C67/08 ,  C07C67/58 ,  C07C51/00

CPC分类号： C07C67/08 ,  C07C67/58

摘要： The present invention provides a process for preparing an ester comprising the step of reacting a carboxylic acid and an alcohol in the presence of an esterifying catalyst comprising at least one compound having the formula:O.dbd.M(RCOO).sub.2 wherein M represents Sn or Zn and R represents a saturated or unsaturated hydrocarbon group having 1-21 carbon atoms with or without side chains. According to the present process, substantially equal equivalents of the alcohol and the acid can be reacted completely. In addition, the present invention further provides a purification process to eliminate the catalyst from a homogeneous reaction system completely.

摘要翻译： 本发明提供一种制备酯的方法，包括使羧酸和醇在含有至少一种具有下式的化合物的酯化催化剂存在下反应的步骤：其中M代表Sn或Zn R表示具有或不具有侧链的具有1-21个碳原子的饱和或不饱和烃基。 根据本方法，可以完全反应基本上相等当量的醇和酸。 此外，本发明还提供了从均匀的反应体系中完全除去催化剂的纯化方法。

公开(公告)号：US4676837A

公开(公告)日：1987-06-30

申请号：US811365

申请日：1985-12-20

申请人： Yasuhiko Hiromoto ,  Yoji Mizuhiro

发明人： Yasuhiko Hiromoto ,  Yoji Mizuhiro

IPC分类号： C08L91/06 ,  D06M13/02 ,  D06M13/144 ,  D06M13/224 ,  D06M13/244 ,  D06M13/322 ,  D06M13/44

CPC分类号： D06M13/02 ,  D06M7/00 ,  D06M2200/40

摘要： The present invention relates to finishes for filling yarns suitable for weaving by AJL. It has been found that a combination of paraffins having a specific carbon distribution and viscosity with specific esters and an amine salt of alkyl phosphate gave an excellent flyability without slack and filling entangling even in AJL process.

摘要翻译： 本发明涉及用于填充适用于AJL编织的纱线的表面处理剂。 已经发现，即使在AJL方法中，具有特定碳分布和粘度与特定酯的链烷烃和磷酸烷基酯的胺盐的组合也具有优异的悬浮性，而没有松弛和填充缠结。