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公开(公告)号：US06365641B1
公开(公告)日：2002-04-02
申请号：US09869833
申请日：2001-07-06
申请人： Toshiaki Masuda , Sachiko Tokumura
发明人： Toshiaki Masuda , Sachiko Tokumura
IPC分类号： B01J1302
摘要： The present invention provides a process for producing thermo-expansive microcapsules that disperse better than conventional products. In this process, thermo-expansive microcapsules are produced through suspension-polymerization in which a polymer is produced from polymerizing unsaturated ethylene monomers under the existence of one or more of metal compounds selected among zirconium compounds and titanium compounds and the resultant polymer microencapsulates a volatile blowing agent gasifying below the softening point of the polymer.
摘要翻译： 本发明提供了一种生产热膨胀性微胶囊的方法，其比常规产品更好地分散。 在该方法中，通过悬浮聚合制备热膨胀性微胶囊，其中通过在选自锆化合物和钛化合物中的一种或多种金属化合物的存在下聚合不饱和乙烯单体制备聚合物，并且所得聚合物微胶囊化挥发性吹塑 试剂气化低于聚合物的软化点。
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2.发明授权Thermo-expansive microcapsule, production process of expanded product and expanded product thereof 有权热膨胀微胶囊，膨胀产品的生产工艺及其膨胀产品公开(公告)号：US07566498B2
公开(公告)日：2009-07-28
申请号：US10539064
申请日：2003-12-24
IPC分类号： B32B5/16
CPC分类号： B01J13/14 , Y10T428/2984 , Y10T428/2987
摘要： Thermo-expansive microcapsule comprising: a polymeric shell produced by polymerizing 15 to 75 weight % of a nitrile monomer, 10 to 65 weight % of a monomer having a carboxyl group, 0.1 to 20 weight % of a monomer having an amide group and 0.1 to 20 weight % of a monomer having a cyclic structure in its side chain; and a blowing agent encapsulated in the polymeric shell.
摘要翻译： 热膨胀性微胶囊包含：通过使15〜75重量％的腈单体聚合而得到的聚合物壳，10〜65重量％的具有羧基的单体，0.1〜20重量％的具有酰胺基的单体和0.1〜 20重量％的侧链中具有环状结构的单体; 和封装在聚合物壳中的发泡剂。
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3.发明申请Thermally expandable microcapsule,process for producing molded foam, and molded foam 有权热膨胀性微囊，生产模制泡沫的方法和模塑泡沫公开(公告)号：US20060063000A1
公开(公告)日：2006-03-23
申请号：US10539064
申请日：2003-12-24
IPC分类号： B32B9/02
CPC分类号： B01J13/14 , Y10T428/2984 , Y10T428/2987
摘要： Thermo-expansive microcapsule comprising: a polymeric shell produced by polymerizing 15 to 75 weight % of a nitrile monomer, 10 to 65 weight % of a monomer having a carboxyl group, 0.1 to 20 weight % of a monomer having an amide group and 0.1 to 20 weight % of a monomer having a cyclic structure in its side chain; and a blowing agent encapsulated in the polymeric shell.
摘要翻译： 热膨胀性微胶囊包含：通过使15〜75重量％的腈单体聚合而得到的聚合物壳，10〜65重量％的具有羧基的单体，0.1〜20重量％的具有酰胺基的单体和0.1〜 20重量％的侧链中具有环状结构的单体; 和封装在聚合物壳中的发泡剂。
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公开(公告)号：US06903143B2
公开(公告)日：2005-06-07
申请号：US10111937
申请日：2001-03-22
申请人： Toshiaki Masuda , Sachiko Tokumura
发明人： Toshiaki Masuda , Sachiko Tokumura
IPC分类号： B01J13/16 , B01J13/18 , C08F2/18 , C08F2/20 , C08J9/00 , C08J9/20 , C09D7/12 , C09D11/00 , C08L9/00
CPC分类号： C08J9/20 , B01J13/16 , C08F2/20 , C08J9/0014 , C08J2203/14 , C08J2203/16 , C08J2203/22 , C08J2333/02 , C08K9/10 , C08L89/00 , C09D7/70 , C09D11/03
摘要： A process for producing thermo-expansive microcapsules wherein a polymerizing mixture containing ethylenic unsaturated monomer and a blowing agent is suspend-polymerized to microencapsulate the blowing agent with the resultant polymer. The above-mentioned suspension-polymerization is performed with the presence of at least one compound selected from the group consisting of polypeptides and derivatives thereof as a suspension stabilizer. The process can control the particle size of microcapsules easily, attain stable reaction system and produce thermo-expansive microcapsules that disperse well in medium such as paint or inks.
摘要翻译： 一种制备热膨胀性微胶囊的方法，其中含有烯属不饱和单体和发泡剂的聚合混合物被悬浮聚合以将发泡剂与所得聚合物微胶囊化。 上述悬浮聚合是在存在至少一种选自多肽及其衍生物的化合物作为悬浮稳定剂的情况下进行的。 该方法可以容易地控制微胶囊的粒度，获得稳定的反应体系，并产生在介质如油漆或油墨中良好分散的热膨胀性微胶囊。
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5.发明授权公开(公告)号：US09196821B2
公开(公告)日：2015-11-24
申请号：US14322032
申请日：2014-07-02
申请人： Tsutoh Aoyama , Masaru Shinkai , Masahiro Ishimori , Keiji Ueda , Kanshi Abe , Manabu Nishimura , Toshiaki Masuda
发明人： Tsutoh Aoyama , Masaru Shinkai , Masahiro Ishimori , Keiji Ueda , Kanshi Abe , Manabu Nishimura , Toshiaki Masuda
IPC分类号： B41J2/045 , H01L41/31 , B41J2/14 , H01L41/09 , H01L41/316 , H01L41/318
CPC分类号： H01L41/31 , B41J2/14201 , B41J2/14233 , B41J2202/03 , H01L41/0973 , H01L41/316 , H01L41/318 , Y10T29/42
摘要： An electromechanical transducer includes a first electrode mounted on one of a substrate and a base film, an electromechanical transducer film mounted on the first electrode and made of a piezoelectric substance having a perovskite crystal structure, and a second electrode mounted on the electromechanical transducer film. The electromechanical transducer film includes a {100} plane preferentially oriented to be orthogonal to a thickness direction of the electromechanical transducer film and has a full width at half maximum corresponding to a {200} plane in an X-ray diffraction measurement curve in 2θ-ω scan that is measured by emitting an X-ray beam onto a surface of the electromechanical transducer film at an incident angle θ. The full width at half maximum is not greater than 10 degrees.
摘要翻译： 机电换能器包括安装在基板和基膜之一上的第一电极，安装在第一电极上并由具有钙钛矿晶体结构的压电材料制成的机电换能器薄膜和安装在机电换能器薄膜上的第二电极。 机电换能器膜包括优先定向为与机电换能器膜的厚度方向正交的{100}面，并且在2θ的X射线衍射测量曲线中具有对应于{200}面的半值全宽度; -ω扫描，其通过以入射角度θ将X射线束发射到机电换能器膜的表面上来测量。 半最大宽度不大于10度。
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公开(公告)号：US09050410B2
公开(公告)日：2015-06-09
申请号：US11577209
申请日：2005-10-13
申请人： Kimihiro Mabuchi , Noriko Monden , Noriaki Kato , Yuuki Hatakeyama , Takashi Sunohara , Toshiaki Masuda
发明人： Kimihiro Mabuchi , Noriko Monden , Noriaki Kato , Yuuki Hatakeyama , Takashi Sunohara , Toshiaki Masuda
CPC分类号： A61M1/168 , A61L2/087 , A61L2202/22 , A61M1/16 , A61M1/1682 , A61M1/169 , A61M2209/06 , B01D65/022 , B01D67/0011 , B01D67/0097 , B01D69/08 , B01D71/68 , B01D2321/34 , B01D2323/34 , B01D2325/36 , B01D2325/38
摘要： The present invention provides a blood purifier which shows a decreased amount of hydrogen peroxide extracted from its selectively permeable separation membranes, and thus is highly reliable in its safety in use for hemecatharysis.The present invention relates to a blood purifier which comprises selectively permeable separation membranes as a main component and which is characterized in that the amount of hydrogen peroxide which is extracted from the selectively permeable separation membrane removed from the blood purifier after 3 months or longer has passed since the sterilization of the blood purifier by exposure to a radioactive ray and/or an electron ray is not larger than 10 ppm.
摘要翻译： 本发明提供了一种血液净化器，其显示从其选择性渗透性分离膜中提取的过氧化氢的量减少，因此在其半胱氨酸用途的安全性方面是高度可靠的。 本发明涉及一种血液净化器，其包括选择性渗透性分离膜作为主要成分，其特征在于，经过3个月以上从血液净化器除去的选择性渗透性分离膜中提取的过氧化氢的量已经过去 由于通过暴露于放射线和/或电子射线对血液净化器的灭菌不大于10ppm。
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公开(公告)号：US08329298B2
公开(公告)日：2012-12-11
申请号：US12067771
申请日：2006-10-04
CPC分类号： B01J13/14 , Y10T428/2982 , Y10T428/2984 , Y10T428/2985 , Y10T428/2987 , Y10T428/2998
摘要： A method that heat-expandable microspheres includes the use of a shell of thermoplastic resin and a non-fluorine blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin. The method includes, a step of dispersing an oily mixture containing a polymerizable component, the blowing agent, and a polymerization initiator containing a peroxydicarbonate in an aqueous dispersing medium to polymerize the polymerizable component contained in the oily mixture. The resultant heat-expandable microsphres have a shell which is less apt to become thinner than its theoretical value, contain minimum amount of resin particle inside their shell, and have excellent heat-expanding performance.
摘要翻译： 热膨胀性微球的方法包括使用热塑性树脂的壳和封入其中的沸点不高于热塑性树脂的软化点的非氟发泡剂。 该方法包括：将含有可聚合组分的油性混合物，发泡剂和含有过氧化二碳酸酯的聚合引发剂在含水分散介质中分散以使包含在油性混合物中的可聚合组分聚合的步骤。 所得到的热膨胀微孔具有较不易于其理论值变薄的外壳，其外壳中含有最少量的树脂颗粒，并且具有优异的热膨胀性能。
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8.发明申请公开(公告)号：US20090149559A1
公开(公告)日：2009-06-11
申请号：US12089600
申请日：2006-11-16
申请人： Toshiaki Masuda , Ichiro Takahara , Kenichi Kitano , Katsushi Miki , Takeshi Inohara , Takeyoshi Fukuda , Takayuki Aoki , Satoshi Kawanami
发明人： Toshiaki Masuda , Ichiro Takahara , Kenichi Kitano , Katsushi Miki , Takeshi Inohara , Takeyoshi Fukuda , Takayuki Aoki , Satoshi Kawanami
CPC分类号： B01J13/14 , C08F220/14 , C08F220/44 , C08F220/48 , C08F222/1006 , Y10T428/2984
摘要： Heat-expandable microspheres include a shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin, have a maximum expanding ratio not lower than 50 times, and are thermally expanded into hollow particulates having a repeated-compression durability not lower than 75 percent. The method of producing the heat-expandable microspheres includes the steps of dispersing an oily mixture containing a polymerizable component and the blowing agent in an aqueous dispersing medium containing a specific water-soluble compound and polymerizing the polymerizable component contained in the oily mixture.
摘要翻译： 热膨胀性微球包括热塑性树脂的壳和其中包含沸点不高于热塑性树脂的软化点的发泡剂，其最大膨胀比不低于50倍，并且被热膨胀成具有 重复压缩耐久性不低于75％。 制造热膨胀性微球的方法包括以下步骤：将含有可聚合组分和发泡剂的油性混合物分散在含有特定水溶性化合物的水性分散介质中，并使包含在油性混合物中的可聚合组分聚合。
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9.发明申请公开(公告)号：US20080293838A1
公开(公告)日：2008-11-27
申请号：US12068430
申请日：2008-02-06
CPC分类号： C08J9/32 , B01J13/14 , C08J2203/14 , C08J2203/22
摘要： The present invention provides a process for producing thermo-expansive microspheres comprising a thermoplastic resinous shell and a blowing agent being encapsulated in the shell, the blowing agent which is a fluorine-containing C2-10 compound having ether linkage, being free of chlorine and bromine atoms and gasifying at a temperature not higher than the softening point of the thermoplastic resin. The thermo-expansive microspheres have preferably an average particle size ranging from 1 to 100 μm and a CV, or coefficient of variation, of particle size distribution being 30% or less, and a retaining ratio of blowing agent encapsulated being 90% or more.
摘要翻译： 本发明提供一种包含热塑性树脂壳和包封在壳中的发泡剂的热膨胀性微球的方法，发泡剂是具有醚键的含氟C2-10化合物，不含氯和溴 原子并在不高于热塑性树脂的软化点的温度下气化。 热膨胀性微球体的平均粒径优选为1〜100μm，粒径分布的CV或变异系数为30％以下，发泡剂的保持率为90％以上。
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公开(公告)号：US20050234392A1
公开(公告)日：2005-10-20
申请号：US10521439
申请日：2003-07-15
CPC分类号： A61M1/28 , A61M1/1696 , A61M1/284
摘要： A peritoneal dialyzer including: a catheter capable of injecting and discharging peritoneal dialysate in an abdominal cavity of a patient; a peritoneal dialysate circuit connected to the catheter; and a dialyzer provided in the peritoneal dialysate circuit, the dialyzer including a hemodialysate circuit connected so that peritoneal dialysate passing through the inside can come into contact with a hemodialysate via a hollow fiber membrane, characterized in that means capable of measuring an osmotic agent concentration in the peritoneal dialysate is provided on the peritoneal dialysate circuit on the side of the end at which the catheter is connected with respect to the dialyzer, and a mechanism for dehydrating the peritoneal dialysate according to the osmotic agent concentration measured by the aforementioned means is provided on the hemodialysate circuit, and a method of peritoneal dialysis using the peritoneal dialyzer.
摘要翻译： 一种腹膜透析器包括：能够在患者的腹腔中注射和排出腹膜透析液的导管; 连接到导管的腹膜透析液回路; 以及设置在腹膜透析液回路中的透析器，所述透析器包括血液透析液回路，所述血液透析液回路连接，使得通过内部的腹膜透析液可通过中空纤维膜与血液透析液接触，其特征在于，能够测量渗透剂浓度 腹膜透析液设置在导管相对于透析器连接的端部侧的腹膜透析液回路上，并且根据通过上述方法测定的渗透剂浓度使腹膜透析液脱水的机构设置在 血液透析液回路和使用腹膜透析器进行腹膜透析的方法。
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