公开(公告)号：US20110315921A1

公开(公告)日：2011-12-29

申请号：US13172370

申请日：2011-06-29

Applicant: Sunder Ramachandran ,  Vladimir Jovancicevic ,  Ying H. Tsang ,  Michael P. Squicciarini ,  Philippe Prince ,  Jianzhong Yang ,  Kyle C. Cattanach

Inventor： Sunder Ramachandran ,  Vladimir Jovancicevic ,  Ying H. Tsang ,  Michael P. Squicciarini ,  Philippe Prince ,  Jianzhong Yang ,  Kyle C. Cattanach

IPC: C02F1/68 ,  C09K3/00 ,  B01D53/14

CPC classification number: C10G29/26 ,  B01D53/1468 ,  B01D53/1487 ,  B01D53/1493 ,  B01D53/48 ,  B01D53/52 ,  B01D2251/304 ,  B01D2251/306 ,  B01D2252/103 ,  B01D2252/20 ,  B01D2252/60 ,  B01D2257/304 ,  B01D2257/306 ,  C02F1/683 ,  C02F2101/101 ,  C02F2101/40 ,  C02F2103/365 ,  C10G19/02 ,  C10G19/04 ,  C10G29/205 ,  C10G29/22 ,  C10G2300/202 ,  C10G2300/207 ,  C10G2300/44

Abstract: Hydrogen sulfide (H2S) and/or mercaptan scavengers are chemicals that remove H2S and/or mercaptans from gas, oil and water. Water-based formulations may be made and used employing scavenging compounds having the formulae: wherein each R1, R2, R3, and R4 are the same or different and are selected from the group consisting of hydrogen, an alkyl, an alkenyl, an aryl, an acyl, a halogen, a hydroxyl, a nitro, an alkyl ester, an aryl ester, an alkyl ether, an aryl ether, a hydroxymethyl, an anhydride group, an amino, and a sulfide. In one non-limiting embodiment the compounds (A) and (B) do not contain nitrogen atoms. Water-based formulations, such as those using a protic solvent with the above compounds, work well as H2S scavengers.

Abstract translation: 硫化氢（H2S）和/或硫醇清除剂是从气体，油和水中除去H 2 S和/或硫醇的化学物质。 可以使用具有下式的清除化合物制备和使用水性制剂：其中每个R 1，R 2，R 3和R 4相同或不同，并且选自氢，烷基，烯基，芳基， 酰基，卤素，羟基，硝基，烷基酯，芳基酯，烷基醚，芳基醚，羟甲基，酸酐基，氨基和硫醚。 在一个非限制性实施方案中，化合物（A）和（B）不含有氮原子。 水性制剂，例如使用具有上述化合物的质子溶剂的那些制剂，作为H 2 S清除剂能很好地起作用。

公开(公告)号：US07985331B2

公开(公告)日：2011-07-26

申请号：US11483742

申请日：2006-07-11

Applicant: Arnaud Baudot ,  Renaud Cadours ,  Raphaël Huyghe ,  Elsa Jolimaitre ,  Pascal Mougin ,  Eszter Toth

Inventor： Arnaud Baudot ,  Renaud Cadours ,  Raphaël Huyghe ,  Elsa Jolimaitre ,  Pascal Mougin ,  Eszter Toth

IPC: C10G45/00 ,  B01J19/00 ,  B01D69/00

CPC classification number: C10L3/10 ,  B01D61/246 ,  C10G19/02 ,  C10G29/20 ,  C10G31/11 ,  C10G53/12 ,  C10L3/102

Abstract: The liquid hydrocarbon stream including COS is introduced via line 1 into membrane contactor CM to be placed in contact, through membrane M, with the aqueous alkanolamine solution arriving via line 3. The COS contained in the hydrocarbon stream is absorbed by the aqueous alkanolamine solution. The liquid hydrocarbons from which the COS has been removed are evacuated from CM via line 2. The aqueous solution containing COS is sent via line 4 to zone R to be regenerated. The compounds released during regeneration, particularly COS and COS-derived products, are evacuated from zone R via line 5. The regenerated aqueous alkanolamine solution is recycled via line 3 into membrane contactor CM.

Abstract translation: 包括COS的液态烃流通过管线1引入膜接触器CM中，通过膜M与烷基胺胺水溶液通过管线3到达。包含在烃流中的COS被链烷醇胺水溶液吸收。 已经从中除去COS的液体烃通过管线2从CM排出。含有COS的水溶液通过管线4送到区R以再生。 在再生期间释放的化合物，特别是COS和COS衍生产物通过管线5从区域R排出。再生的链烷醇胺水溶液通过管线3再循环到膜接触器CM中。

公开(公告)号：US20100292349A1

公开(公告)日：2010-11-18

申请号：US12743358

申请日：2008-11-17

Applicant: Jens Emil Vindstad ,  Heidi Mediaas ,  Knut Vebjørn Grande

Inventor： Jens Emil Vindstad ,  Heidi Mediaas ,  Knut Vebjørn Grande

IPC: B01J13/00 ,  C07C61/12

CPC classification number: C10G31/08 ,  A23L33/10 ,  A23V2002/00 ,  B01F3/0807 ,  B01F17/0021 ,  C07C51/347 ,  C07C51/412 ,  C07C51/46 ,  C10G19/02 ,  C10G29/06 ,  C10M129/56 ,  C10M129/58 ,  C10M129/93

Abstract: A process for the preparation of at least one ARN acid or salt thereof comprising: (I) allowing at least one ARN acid salt to form during the production of crude oil in the presence of water; (II) removing at least 5 wt % of the formed at least one ARN acid salt, e.g. from the oil water interface; and optionally (III) converting said salt into an acid.

Abstract translation: 一种制备至少一种ARN酸或其盐的方法，包括：（I）在水存在下在原油生产期间允许形成至少一种ARN酸盐; （II）除去至少5重量％的形成的至少一种ARN酸盐，例如， 从油水界面; 和任选地（III）将所述盐转化成酸。

公开(公告)号：US20100187124A1

公开(公告)日：2010-07-29

申请号：US12460832

申请日：2009-07-24

Applicant: Russell J. Koveal

Inventor： Russell J. Koveal

IPC: C25B1/00 ,  C25B1/02

CPC classification number: C10G32/02 ,  C10G19/02 ,  C10G29/06 ,  C10G53/12 ,  C25B1/00 ,  C25B1/02 ,  C25B15/02

Abstract: This invention relates to the desulfurization of a hydrocarbon feedstock by contacting said feedstock with an aqueous metal hydroxide solution, thus resulting in a desulfurized feedstock and an aqueous metal sulfide stream. In the present invention, the aqueous metal sulfide stream is split into at least three fractions and each fraction is passed to a different electrochemical cell, connected in series to regenerate the metal hydroxide required in the desulfurization process and recover sulfur, metal hydroxide, and hydrogen. In a preferred embodiment, at least a portion of the metal hydroxide that is produced in the electrochemical metal hydroxide regeneration process of the present invention is recycled for use in the process for desulfurizing the sulfur-containing hydrocarbon feedstock.

Abstract translation: 本发明涉及通过使所述原料与金属氢氧化物水溶液接触使烃原料脱硫，从而得到脱硫原料和金属硫化物水流。 在本发明中，将金属硫化物流分成至少三个部分，并将每个部分通入不同的电化学电池，串联连接以再生脱硫过程中所需的金属氢氧化物并回收硫，金属氢氧化物和氢 。 在优选的实施方案中，在本发明的电化学金属氢氧化物再生方法中生产的至少一部分金属氢氧化物被再循环用于硫含烃原料的脱硫方法。

公开(公告)号：US07575669B2

公开(公告)日：2009-08-18

申请号：US11021389

申请日：2004-12-23

Applicant: Mahesh Subramaniyam

Inventor： Mahesh Subramaniyam

IPC: C10G11/00 ,  C10G9/00 ,  C10G9/16 ,  C10G9/12 ,  C10G75/04

CPC classification number: C10G75/04 ,  C10G19/02 ,  C10G70/06 ,  C10G2300/4075 ,  C10G2400/20 ,  Y02P30/464

Abstract: A method for mitigating fouling in a wash unit used in a hydrocarbon cracking process wherein the fouling is due to the presence of polymers and deposits thereof formed by condensation of carbonyl compounds contained within a feed stream of the wash unit. In one embodiment, the invention provides a method of mitigating fouling in a wash unit by introducing into the feed stream an effective amount of an additive including: an inorganic salt of dithionite; and an epsilon caprolactam or a 6-amino caproic acid derivable therefrom. The additive scavenges the carbonyl compounds contained within the feed stream and dissolves deposits of the polymers to thereby mitigate fouling in the wash unit.

Abstract translation: 用于缓解在烃裂解过程中使用的洗涤单元中的结垢的方法，其中结垢是由于聚合物的存在以及由洗涤单元的进料流中包含的羰基化合物的缩合形成的沉积物。 在一个实施方案中，本发明提供了一种通过向进料流中引入有效量的添加剂来减轻洗涤单元中的结垢的方法，所述添加剂包括：连二亚硫酸盐的无机盐; 以及可从其衍生的ε-己内酰胺或6-氨基己酸。 添加剂清除进料流中包含的羰基化合物，并溶解聚合物的沉积物，从而减轻洗涤单元中的结垢。

公开(公告)号：US20080230445A1

公开(公告)日：2008-09-25

申请号：US12042536

申请日：2008-03-05

Applicant: Timothy J. O'Brien ,  Jerry J. Weers

Inventor： Timothy J. O'Brien ,  Jerry J. Weers

IPC: C10G29/20

CPC classification number: C10G19/02 ,  C10G27/10 ,  C10G29/06 ,  C10G2300/1033 ,  C10G2300/1037 ,  C10G2300/202 ,  C10G2300/207 ,  C10G2300/80

Abstract: Hydrogen sulfide and mercaptans in hydrocarbons, gas mixtures of hydrocarbons and the like may be scavenged therefrom by being brought into intimate contact with a mercaptan scavenger formulation of quaternary ammonium alkoxide or hydroxide in the presence of a high oxidative state metal such as cobalt, iron, chromium and/or nickel. The high oxidative state metal, being an oxidizer, acts as a catalyst when combined with the quaternary ethoxide or hydroxide for improved mercaptan scavenging performance.

Abstract translation: 烃类中的硫化氢和硫醇，碳氢化合物的气体混合物等可以通过在高氧化态金属如钴，铁等的存在下与硫醇季铵盐或氢氧化物的硫醇清除剂配方紧密接触而被清除， 铬和/或镍。 作为氧化剂的高氧化态金属与季戊四醇或氢氧化物结合时用作催化剂，以改善硫醇清除性能。

公开(公告)号：US07326333B2

公开(公告)日：2008-02-05

申请号：US10027153

申请日：2001-12-20

Applicant: Luigi Laricchia ,  Jonathan A. Tertel ,  Allen W. Thomas

Inventor： Luigi Laricchia ,  Jonathan A. Tertel ,  Allen W. Thomas

IPC: C10G19/00 ,  B01J8/04

CPC classification number: B01D53/48 ,  B01D11/043 ,  B01D11/0492 ,  B01D17/0214 ,  B01D17/045 ,  B01D53/1468 ,  B01D53/8603 ,  B01D2255/20761 ,  B01D2257/304 ,  B01D2257/306 ,  B01D2257/308 ,  C10G19/02 ,  C10G21/00 ,  C10G21/08

Abstract: Described is an apparatus and process for extracting sulfur compounds from a hydrocarbon stream. A prewash section for converting hydrogen sulfide to sodium sulfide by reaction with an alkali such as caustic communicates with an extractor section disposed directly above the prewash section for converting mercaptans to mercaptides by reaction with alkali. Hydrocarbon product exits the extractor section through a coalescer that prevents alkali from exiting with the hydrocarbon product stream.

Abstract translation: 描述了从烃流中提取硫化合物的装置和方法。 通过与碱例如苛性碱反应将硫化氢转化为硫化钠的预洗部分与通过与碱反应将硫醇转化成硫醇的直接在预洗部分上方的提取部分连通。 烃产品通过聚结器离开萃取器部分，该聚结器防止碱与烃产物流一起排出。

公开(公告)号：US20060011517A1

公开(公告)日：2006-01-19

申请号：US11123516

申请日：2005-05-06

Applicant: Joseph Feimer

Inventor： Joseph Feimer

IPC: C10G19/04 ,  C10G21/00

CPC classification number: C10G29/10 ,  C10G19/02 ,  C10G19/04 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/805 ,  C10G2400/02

Abstract: A method for reducing the level of elemental sulfur from sulfur-containing hydrocarbon streams as well as reducing the level of total sulfur in such streams. Preferred hydrocarbon streams include fuel streams such as naphtha streams that are transported through a pipeline. The sulfur-containing hydrocarbon stream is contacted with a mixture of water, a caustic, a surfactant, at least one metal sulfide, and optionally an aromatic mercaptan. This results in an aqueous phase and a hydrocarbon phase containing reduced levels of both elemental sulfur and total sulfur.

Abstract translation: 一种降低含硫烃流中元素硫含量的方法以及降低这些物流中总硫的含量。 优选的烃流包括燃料流，例如通过管道输送的石脑油流。 含硫烃物流与水，苛性碱，表面活性剂，至少一种金属硫化物和任选的芳族硫醇的混合物接触。 这导致水相和烃相含有元素硫和总硫的水平降低。

公开(公告)号：US20050224394A1

公开(公告)日：2005-10-13

申请号：US11021389

申请日：2004-12-23

Applicant: Mahesh Subramaniyam

Inventor： Mahesh Subramaniyam

IPC: C07C7/00 ,  C07C11/04 ,  C07C11/167 ,  C10G19/02 ,  C10G55/04 ,  C10G70/06 ,  C10G75/04 ,  C10G9/16

CPC classification number: C10G75/04 ,  C10G19/02 ,  C10G70/06 ,  C10G2300/4075 ,  C10G2400/20 ,  Y02P30/464

Abstract: A method for mitigating fouling in a wash unit used in a hydrocarbon cracking process wherein the fouling is due to the presence of polymers and deposits thereof formed by condensation of carbonyl compounds contained within a feed stream of the wash unit. In one embodiment, the invention provides a method of mitigating fouling in a wash unit by introducing into the feed stream an effective amount of an additive including: an inorganic salt of dithionite; and an epsilon caprolactam or a 6-amino caproic acid derivable therefrom. The additive scavenges the carbonyl compounds contained within the feed stream and dissolves deposits of the polymers to thereby mitigate fouling in the wash unit.

Abstract translation: 用于缓解在烃裂解过程中使用的洗涤单元中的结垢的方法，其中结垢是由于聚合物的存在以及由洗涤单元的进料流中包含的羰基化合物的缩合形成的沉积物。 在一个实施方案中，本发明提供了一种通过向进料流中引入有效量的添加剂来减轻洗涤单元中的结垢的方法，所述添加剂包括：连二亚硫酸盐的无机盐; 以及可从其衍生的ε-己内酰胺或6-氨基己酸。 添加剂清除进料流中包含的羰基化合物，并溶解聚合物的沉积物，从而减轻洗涤单元中的结垢。

公开(公告)号：US06824750B2

公开(公告)日：2004-11-30

申请号：US09758899

申请日：2001-01-11

Applicant: Jose Luis Bravo

Inventor： Jose Luis Bravo

IPC: B01D1104

CPC classification number: B01D11/043 ,  B01D3/20 ,  C10G19/02 ,  C10G21/00

Abstract: A vertical extending liquid/liquid contacting column is disclosed, which column will, when in use, contain a dispersed and a continuous liquid phase, the column having a first liquid feed inlet in the top, a first liquid outlet in the top, a second liquid feed inlet in the bottom, a second liquid outlet in the bottom and a plurality of internal trays axially spaced from each other in the column, each tray provided with a plurality of perforations for the passage of the dispersed phase and more than one downcomer or upcomer for the transport of the continuous phase, wherein the downcomer or upcomer extends respectively below or above the tray and wherein the walls of the downcomer or upcomer are inclined towards each other in the flow direction of the continuous phase. A method of use within the column is also disclosed.

Abstract translation: 公开了一种垂直延伸的液/液接触塔，该柱在使用时将含有分散和连续的液相，该塔在顶部具有第一液体进料入口，顶部具有第一液体出口，第二液体出口在第二 底部的进料入口，底部的第二液体出口和在塔中彼此轴向间隔开的多个内部托盘，每个托盘设置有用于分散相通过的多个穿孔和多于一个降液管或 用于输送连续相的升降器，其中降液管或升液管分别延伸到托盘的下方或上方，并且其中降液管或升降管的壁在连续相的流动方向上彼此倾斜。 还公开了该柱内的使用方法。