摘要:
A process is disclosed for producing powdery polycarbonate from a polycarbonate solution which comprises:(a) charging the solution into the feed opening of a disolvating apparatus, the apparatus being composed of a casing and having at least two screws incorporated therein, the screws meshing with each other; the apparatus comprising two parts; a evaporating zone and a powdering zone; a space being provided above the screws in the evaporating zone, the space extending in the axial direction of the screws and having at least one degassing opening, and side and bottom portions of screws generally fitting with the casing in the evaporating zone; top, side and bottom portions of screws generally fitting with the casing in the powdering zone, heating means being installed in the casing and/or screws;(b) in the evaporating zone, evaporating the solvent of the polycarbonate solution using the heating means while moving the solution by the screws;(c) powdering the dried polycarbonate in the powdering zone; and(d) discharging the powdery polycarbonate from the product exit in the powdering zone.
摘要:
A process for the production of partially or completely hydrolyzed ethylene/vinyl acetate copolymer which is suitable for the various powder coating techniques, wherein the polymer solution is extruded in a non-gelled state into water with a temperature no more than 20.degree. C below the gellation temperature and the gelling solution is converted into particles from 0.02 to 5 mm in diameter by means of high shear forces.
摘要:
Scrap photographic film comprising at least a four component system involving a polyalkyleneterephthalate film base, an adhesive or subbing layer utilizing a terpolymer consisting chiefly of polyvinylidenechloride and a gelatin layer containing metallic silver or a compound thereof and a variety of contaminants such as causal dirt, dyes and the like is broken down for recovery of the valuable constituents therein including the silver, the polyvinylidenechloride terpolymer, and the polyesters by treating the chopped photographic film at an elevated temperature with a solvent for both the polyester and polyvinylidenechloride values in which solvent both the gelatin and silver values are insoluble, under conditions chosen to insure the quantitative recovery of the silver values.
摘要:
A method of preparing a homogeneous thermosetting powder paint composition which cures to form a coating exhibiting outstanding exterior durability, adhesion, impact strength and, in particular, color match. The method comprises: introducing a liquid paint composition including at least a cross-linkable copolymer and a uniformly dispersed pigment into an evaporating zone adapted to heat said liquid paint so as to evaporate the inert solvent contained therein; passing the liquid paint into a separating zone; causing said solvent vapor to be removed; removing the non-volatile components of said paint in a molten state; cooling said non-volatile components; and pulverizing to form a powder.
摘要:
A process for the manufacture of finely divided polyester-imide powders wherein solutions of polyester-imides in organic solvents are solidified by cooling, the solvent is removed by sublimation and the solid product is pulverized. The powders may be used, as aqueous dispersions, to produce heat-resistant coatings on metallic conductors.
摘要:
A process for manufacturing polycarbonate powder wherein a solution of polycarbonate in a water-immiscible solvent is emulsified in water which contains a very small amount of a laminator. The solvent is thereafter removed from the emulsion to form a dispersion of the polycarbonate powder. The polycarbonate powder settles out of the dispersion and is removed.
摘要:
In a process for preparing discrete, finely divided, tack-free, pourable, powdery, filler-containing elastomer particles from an admixture of (a) an aqueous elastomer emulsion comprising (i) a solution of elastomer dissolved in a volatile, inert organic solvent having a boiling point below 100*C, (ii) an elastomer emulsifying amount of an alkylamine oxyalkylate surfactant, and (iii) water; and (b) an aqueous suspension or dispersion of a solid, finely divided elastomer filler, which comprises gradually introducing said admixture into an aqueous alkali silicate solution containing 2-20 moles of SiO2 per mole of said alkylamine oxyalkylate while maintaining said silicate solution at an acidic pH of 0.1-7 and simultaneously evaporating said volatile organic solvent to form said filler-containing elastomer particles, the improvement which comprises: EMPLOYING SAID ADMIXTURE OF (A) AND (B) IN THE FORM OF A STABLE, AQUEOUS EMULSION CONTAINING AN EMULSION-STABILIZING AMOUNT OF AN IONIC, WATER SOLUBLE PROTECTIVE COLLOID AND HAVING AN ALKALINE PH of 7-14.
摘要:
A process of preparing beads of urea-formaldehyde resin in which disperse particles of an aqueous urea-formaldehyde syrup are converted to hard polymer and azeotropically dehydrated. The aqueous syrup must have a solids content of at least 65% by weight and the mol ratio of formaldehyde to urea must be within the range of 1.9 - 2.3 to 1.
摘要:
This invention comprises a method of preparing films and coatings of aromatic-heterocyclic ladder polymers. These polymers are insoluble in solvents from which films might be cast by the ordinary technique of coating a surface with a solution of a polymer and allowing the solvent to evaporate therefrom. Since the only solvents known for such ladder polymers are sulfuric acid and methane sulfonic acid, it is not possible to use the ordinary technique of laying film by the solvent evaporation process because of the high boiling points and high temperatures thereby required. Furthermore, the surface to be coated may be susceptible to attack by such corrosive solvents. According to the present invention it has been found that films and coatings of the ladder polymers can be formed by using a fine dispersion of the ladder polymer in a nonsolvent, such as alcohol or an easily evaporated hydrocarbon. A relatively smooth, strong film can be prepared by collecting the particles from the dispersion either by filtration on a porous surface such as fritted glass or by drawing a metal surface through the dispersion and allowing the dispersion medium to evaporate from the wetted metal surface and thereby deposit the dispersed polymer particles thereon.