摘要:
The invention relates to a process for the preparation of a two-coat finish on a substrate surface, in which process a basecoat is employed which contains as binder a polymer which can be obtained by subjecting an ethylenically unsaturated monomer or a mixture of ethylenically unsaturated monomers to free-radical polymerization in an aqueous dispersion of a polyurethane resin which has a number-average molecular weight of from 1000 to 30,000 and contains on average from 0.05 to 1.1 polymerizable double bonds per molecule, and in the presence of a water-insoluble initiator or of a mixture of water-insoluble initiators, the weight ratio of the polyurethane resin to the ethylenically unsaturated monomer or to the mixture of ethylenically unsaturated monomers being between 1:10 and 10:1.
摘要:
Bismuth vanadate pigments haveBi.sub.x E.sub.v Si.sub.y V.sub.(1-z) P.sub.z O.sub.wwhere x is from 0.8 to 1.2, y is from 0 to 4, z is from 0 to 0.2, v is from >0 to 0.5, and w is the number of oxygen atoms for satisfying the valence requirements of the cations, with the following provisos:a) when y=0, then z is from >0 to
摘要:
Flexible printing plates are produced from printing plates consisting essentially of a dimensionally stable substrate (1) and a recording layer (2) by a process in which the printing plate is produced alternatively either by photochemical or by mechanical structuring, and in the case of photochemical structuring the photosensitive recording layer (2) is exposed imagewise and the unexposed parts of the recording layer (2) are washed out with a developer and in the case of mechanical structuring the originally photosensitive, uniformly exposed recording layer (2) is cut imagewise and the nonprinting parts of the recording layer (2) are peeled off from the substrate (1).The printing plates produced by this process are suitable for the production of products printed by the flexographic method and for lacquering products printed by the offset method.
摘要:
The invention relates to a process for coating electrically conductive substrates, in which aqueous electrodeposition paints containing 1 to 15 percent by weight of electrically conductive carbon black and/or graphite having a primary particle diameter of less than 10 .mu.m in combination with up to 12 percent by weight of zinc powder or zinc flakes, with the percentages by weight relating to the total amount of binder and--if present--crosslinking agent contained in the electrodeposition paint, are employed.
摘要:
Epoxy resins obtainable by reactingA) a polyfunctional epoxide, which carries on average 1.5 to 2.5 epoxy groups per molecule and has an epoxide equivalent weight of from 100 to 2000, with based on 1 mol of epoxy groupsB) from 0.1 to 0.5 mol of an alkylphenol, the alkyl groups of which carry from 6 to 20 carbon atoms, andC) from 1 to 100 mmol of a polyoxyalkylenediol obtained from 1,2-propylene oxide, or of a copolymer obtained from 1,2-propylene oxide and other alkylene oxides, which has an average molecular weight of from 200 to 5000 and, on average, from 1 to 4 sulfonic acid groups bonded to methyl groups per molecule, and alsoD) from 0.2 to 0.3 mol of a diol, which isd1) a phenolic diol and/ord2) a polyoxyalkylenediol which has an average molecular weight of from 200 to 5000,with the proviso that the reaction product has an epoxide equivalent weight of from 1000 to 5000, can be converted to pigment resins suitable for electrodeposition coating and pigment pastes can then be prepared from said resins.
摘要:
The present invention relates to a process in which1. a water-dilutable basecoat composition is applied which contains at least one water-dilutable binder, metallic pigments, if desired color pigments, if desired conventional auxiliaries and additives and up to 20% by weight of organic solvents,2. a polymer film is formed from this basecoat composition,3. a transparent topcoat containing a polymer containing silyl groups and obtainable by copolymerization of p1 p.sub.1) 0.1 to 40% by weight of ethylenically unsaturated silane monomers of the general formula ##STR1## where R.sup.1 is alkyl, aryl, acyl, aralkyl having 1 to 10 carbon atomsR.sup.2 is an organic radical having a polymerizable double bondX is a hydrolyzable groupn is 1, 2 or 3p.sub.2) 5 to 30 % by weight, preferably 8 to 25% by weight, of monomers having at least 2 polymerizable ethylenically unsaturated double bonds andp.sub.3) 30 to 90% by weight of ethylenically unsaturated monomers without groups having active hydrogen,is applied to this base layer4. and the top layer is cured together with the base layer.
摘要:
Solutions of polyimide-forming starting materials are provided containing diamines and tetracarboxylic diesters; the tetracarboxylic diesters comprise a mixture of from 0.05 to 0.95 mol % of oxydiphthalic diesters and from 0.05 to 0.95 mol % of benzophenonetetracarboxylic diesters, biphenyltetracarboxylic diesters or mixtures thereof.
摘要:
The invention relates to a cathodic electro-dipcoating process, wherein the electro-dipcoating composition used contains a cationic, amine-modified epoxy resin, which is obtainable by reacting(A) a polyepoxide,(B) an amine and(C) an adduct, which is obtainable by . . . (sic)(c1) a polyether- or polyester-polyol,(c2) a polyisocyanate and(c3) a compound which contains at least one hydrogen atom which is reactive towards isocyanate groups and at least one ketimine group in the molecule, and/or(D) a hydrolysis product of (C)with one another in a relative proportion such that 20 to 90% of the epoxy groups of component (A) are reacted with component (B) and the remaining epoxy groups are reacted with component (C) and/or (D), and--if still necessary--at least partially protonating the reaction product thus obtained.
摘要:
Polymeric reaction products useful as additions to electrocoating baths are obtainable fromA. a polyoxyalkylene which has an average molecular weight M.sub.n of from 140 to 10,000 and contains on average from 1.5 to 3.0 primary and/or secondary amino groups andB. a polymer which is based on a conjugated diene, has an average molecular weight M.sub.n of from 250 to 50,000, contains on average from 1.5 to 3.0 epoxy groups per molecule and is obtainable by reacting a hydroxyl- or carboxyl-containing polymer with a glycidyl compound.
摘要:
A process for the production of a multi-layer paint coating in which base paints are employed which contain 5 to 20% by weight of crosslinked polymer microparticles, 2 to 15% by weight of a cellulose ester and 5 to 20% by weight of an epoxidized fatty acid ester, the weight percentages relating to the total content of nonvolatile constituents, excluding pigments and inorganic fillers, and the cellulose ester being so selected that a solution of 15 parts by weight of the cellulose ester in 85 parts by weight of a 9:1 mixture of acetone and ethanol at 23.degree. C. has a viscosity of 200 to 600 mPa.s.