公开(公告)号：US09663678B2

公开(公告)日：2017-05-30

申请号：US14408183

申请日：2012-08-10

申请人： Alistair Mclennan ,  Linlin Miao

发明人： Alistair Mclennan ,  Linlin Miao

IPC分类号： C09D131/04 ,  C09D7/12 ,  C09D5/02

CPC分类号： C09D131/04 ,  C08L2205/025 ,  C08L2205/03 ,  C09D5/027 ,  C09D7/65 ,  C08L29/04

摘要： A coating composition comprises an emulsion copolymer of a monomer mixture comprising at least one vinyl ester, ethylene, and a stabilizing system. The stabilizing system comprises at least one polyvinyl alcohol. The monomer mixture comprises from 60 to 82 wt % of the at least one vinyl ester and from 18 to 40 wt % of the ethylene based on the total weight of monomers in the mixture. The stabilizing system comprises from 1 to 5 wt % of at least one medium molecular weight polyvinyl alcohol and at least one low molecular weight polyvinyl alcohol. The emulsion copolymer has a solids content from 50% to 60% and a viscosity ranges from 500 to 6,000 mPa·s. and a formaldehyde content of less than 10 ppm as determined by HPLC.

公开(公告)号：US09567261B2

公开(公告)日：2017-02-14

申请号：US14396506

申请日：2012-04-25

申请人： Alistair McLennan ,  Hendrikus C. M. Van Boxtel

发明人： Alistair McLennan ,  Hendrikus C. M. Van Boxtel

IPC分类号： C04B24/26 ,  C04B26/04 ,  C08F22/10 ,  C08F4/40 ,  C08F218/08 ,  C04B103/00 ,  C04B111/00 ,  C04B111/62 ,  C08F210/02

CPC分类号： C04B24/2623 ,  C04B26/04 ,  C04B2103/0057 ,  C04B2111/00637 ,  C04B2111/62 ,  C08F4/40 ,  C08F22/10 ,  C08F210/02 ,  C08F218/08 ,  Y10T428/2982 ,  C08F2/30 ,  C08F2500/17

摘要： A vinyl ester/ethylene copolymer is prepared by emulsion copolymerization of a monomer mixture comprising at least one vinyl ester, ethylene, a stabilizing system comprising polyvinyl alcohol and a free radical redox polymerization initiator system comprising i-butyl hydroperoxide as an oxidizing agent and at least one of a sulfuric acid-based compound and erythorbic acid or a salt thereof as a reducing agent. The monomer mixture comprises from 70 wt % to 95 wt % of said at least one vinyl ester and from 5 wt % to 30 wt % of ethylene based on the total weight of monomers in said mixture and the copolymer has a formaldehyde content of less than 5.0 ppmw as determined by ISO-15173.

摘要翻译： 乙烯基酯/乙烯共聚物通过包含至少一种乙烯基酯，乙烯，包含聚乙烯醇的稳定体系和包含作为氧化剂的叔丁基过氧化氢的自由基氧化还原聚合引发剂体系的单体混合物的乳液共聚制备，并且至少 作为还原剂的硫酸类化合物和异抗坏血酸或其盐之一。 所述单体混合物包含70重量％至95重量％的所述至少一种乙烯基酯和5重量％至30重量％的乙烯，基于所述混合物中单体的总重量，并且所述共聚物的甲醛含量小于 5.0 ppmw，由ISO-15173确定。

公开(公告)号：US20150184015A1

公开(公告)日：2015-07-02

申请号：US14408183

申请日：2012-08-10

申请人： Alistair Mclennan ,  Linlin Miao

发明人： Alistair Mclennan ,  Linlin Miao

IPC分类号： C09D131/04 ,  C09D7/12

CPC分类号： C09D131/04 ,  C08L2205/025 ,  C08L2205/03 ,  C09D5/027 ,  C09D7/65 ,  C08L29/04

摘要： A coating composition comprises an emulsion copolymer of a monomer mixture comprising at least one vinyl ester, ethylene, and a stabilizing system. The stabilizing system comprises at least one polyvinyl alcohol. The monomer mixture comprises from 60 to 82 wt % of the at least one vinyl ester and from 18 to 40 wt % of the ethylene based on the total weight of monomers in the mixture. The stabilizing system comprises from 1 to 5 wt % of at least one medium molecular weight polyvinyl alcohol and at least one low molecular weight polyvinyl alcohol. The emulsion copolymer has a solids content from 50% to 60% and a viscosity ranges from 500 to 6,000 mPa·s. and a formaldehyde content of less than 10 ppm as determined by HPLC.

摘要翻译： 涂料组合物包含包含至少一种乙烯基酯，乙烯和稳定体系的单体混合物的乳液共聚物。 稳定体系包含至少一种聚乙烯醇。 单体混合物包含60至82重量％的至少一种乙烯基酯和18至40重量％的乙烯，基于混合物中单体的总重量。 稳定体系包含1至5重量％的至少一种中分子量聚乙烯醇和至少一种低分子量聚乙烯醇。 乳液共聚物的固含量为50〜60％，粘度范围为500〜6000mPa·s。 和通过HPLC测定的小于10ppm的甲醛含量。

公开(公告)号：US09469792B2

公开(公告)日：2016-10-18

申请号：US14236231

申请日：2011-08-05

申请人： Alistair Mclennan

发明人： Alistair Mclennan

IPC分类号： C09J129/04 ,  C09J123/08 ,  C09J131/04 ,  C08L23/08 ,  C08F218/08 ,  C09J133/08 ,  C08F210/02

CPC分类号： C09J129/04 ,  C08F210/02 ,  C08F218/08 ,  C08L23/0846 ,  C08L29/04 ,  C09J123/0846 ,  C09J131/04 ,  C09J133/08 ,  C08F2/24 ,  C08F2500/17

摘要： Disclosed are low-formaldehyde aqueous dispersions of vinyl ester/ethylene, e.g., vinyl acetate/ethylene (VAE), copolymers suitable for use in adhesives for applications such as tobacco or food products wherein only very low levels of formaldehyde are permitted. Such dispersions are prepared by emulsion copolymerization of a monomer mixture comprising a vinyl ester, ethylene, a stabilizing system comprising polyvinyl alcohol preferably having a degree of hydrolysis of at least 97 mole %, and a selected type of free radical redox polymerization initiator system. This selected redox initiator system comprises both a water-insoluble oxidizing agent and a sulfuric acid-based reducing agent. The monomer mixture which is polymerized is substantially free of co-monomers which yield free formaldehyde upon drying or curing of the dispersion and is also substantially free of ethylene oxide-containing emulsifiers. The aqueous dispersions resulting from polymerization of this monomer mixture has a solids content in weight percent and a Brookfield viscosity in millipascal-seconds such that the ratio of solids content to the natural logarithm of viscosity ranges from about 6.34 to about 8.25 wt %/ln(mPa·s). The dispersions herein also have a formaldehyde content of less than about 5.0 ppmw as determined by ISO-15173.

摘要翻译： 公开了乙烯基酯/乙烯的低甲醛水分散体，例如乙酸乙烯酯/乙烯（VAE）），适用于诸如烟草或食品的粘合剂的共聚物，其中仅允许非常低水平的甲醛。 这样的分散体通过包含乙烯基酯，乙烯，包含优选具有至少97摩尔％的水解度的聚乙烯醇的稳定体系和选定类型的自由基氧化还原聚合引发剂体系的单体混合物的乳液共聚来制备。 该选择的氧化还原引发剂体系包含水不溶性氧化剂和硫酸系还原剂。 聚合的单体混合物基本上不含在分散体干燥或固化时产生游离甲醛的共聚单体，并且基本上不含含环氧乙烷的乳化剂。 由该单体混合物的聚合产生的水分散体具有重量百分比的固体含量和以毫帕秒为单位的布鲁克菲尔德粘度，使得固体含量与粘度的自然对数之比为约6.34至约8.25重量％/ ln（ mPa·s）。 本文的分散体还具有通过ISO-15173测定的小于约5.0ppmw的甲醛含量。

公开(公告)号：US20150141553A1

公开(公告)日：2015-05-21

申请号：US14396506

申请日：2012-04-25

申请人： Alistair Mclennan ,  Hendrikus C.M. Van Boxtel

发明人： Alistair Mclennan ,  Hendrikus C.M. Van Boxtel

IPC分类号： C04B24/26 ,  C08F22/10

CPC分类号： C04B24/2623 ,  C04B26/04 ,  C04B2103/0057 ,  C04B2111/00637 ,  C04B2111/62 ,  C08F4/40 ,  C08F22/10 ,  C08F210/02 ,  C08F218/08 ,  Y10T428/2982 ,  C08F2/30 ,  C08F2500/17

摘要： A vinyl ester/ethylene copolymer is prepared by emulsion copolymerization of a monomer mixture comprising at least one vinyl ester, ethylene, a stabilizing system comprising polyvinyl alcohol and a free radical redox polymerization initiator system comprising i-butyl hydroperoxide as an oxidizing agent and at least one of a sulfuric acid-based compound and erythorbic acid or a salt thereof as a reducing agent. The monomer mixture comprises from 70 wt % to 95 wt % of said at least one vinyl ester and from 5 wt % to 30 wt % of ethylene based on the total weight of monomers in said mixture and the copolymer has a formaldehyde content of less than 5.0 ppmw as determined by ISO-15173.

摘要翻译： 乙烯基酯/乙烯共聚物通过包含至少一种乙烯基酯，乙烯，包含聚乙烯醇的稳定体系和包含作为氧化剂的叔丁基过氧化氢的自由基氧化还原聚合引发剂体系的单体混合物的乳液共聚制备，并且至少 作为还原剂的硫酸类化合物和异抗坏血酸或其盐之一。 所述单体混合物包含70重量％至95重量％的所述至少一种乙烯基酯和5重量％至30重量％的乙烯，基于所述混合物中单体的总重量，并且所述共聚物的甲醛含量小于 5.0 ppmw，由ISO-15173确定。

公开(公告)号：US09676958B2

公开(公告)日：2017-06-13

申请号：US14364407

申请日：2011-12-16

申请人： Stefan Nogai ,  Alistair McLennan

发明人： Stefan Nogai ,  Alistair McLennan

IPC分类号： C09D133/14 ,  C09D123/08 ,  C08K5/05 ,  C08K5/101 ,  C08K5/41 ,  C08K5/42 ,  C09D133/08 ,  C09D133/10

CPC分类号： C09D133/14 ,  C08K5/05 ,  C08K5/101 ,  C08K5/41 ,  C08K5/42 ,  C08L2312/00 ,  C09D123/0869 ,  C09D133/08 ,  C09D133/10

摘要： A copolymer dispersion is described comprising a copolymer derived from a monomer mixture comprising: (a) 88.5 to 94% by weight of at least one vinyl ester of a saturated carboxylic acid; (b) 5 to 10.5% by weight of ethylene; (c) 0.5 to 5% by weight of at least one ethylenically unsaturated acid and/or an anhydride thereof and/or a salt thereof; and (d) 0.5 to 5% by weight of at least one ethylenically unsaturated monomer having at least one crosslinkable functional unit. The weight ratio of vinylester units to ethylene units in the copolymer is between 89:11 and 94:6 and the dispersion is stabilized with at least 1% by weight of an emulsifier, wherein the amounts of monomers and emulsifier refer to the total amount of monomers in the copolymer.

公开(公告)号：US20120061607A1

公开(公告)日：2012-03-15

申请号：US13233219

申请日：2011-09-15

申请人： Alistair McLennan ,  Paolo Bavaj ,  Rian van Straeten ,  Steve Laborda ,  Peter M. Zeimentz ,  Hendrikus C.M. Van Boxtel

发明人： Alistair McLennan ,  Paolo Bavaj ,  Rian van Straeten ,  Steve Laborda ,  Peter M. Zeimentz ,  Hendrikus C.M. Van Boxtel

IPC分类号： E04B1/78

CPC分类号： D04H1/64 ,  C08F210/08 ,  C08F218/08 ,  D04H3/004 ,  C08F210/02 ,  C08F220/58 ,  C08F228/02 ,  C08F218/12

摘要： Disclosed is an aqueous formulation comprising a polymer which is based on a vinyl acetate copolymer, a binder system comprising said aqueous formulation and additionally an aqueous formulation comprising polymer (B). The invention further relates to a fibrous product comprising a fibrous substrate as well as the aqueous formulation or the binder system and use of the aqueous formulation or the binder system for coating synthetic or mineral fibres, for the manufacturing of Eternal Insulation Finishing Systems (EIFS), for increasing the alkali resistance of synthetic or mineral fibres and use in a process for the manufacturing of an alkali resistant glass fibre scrim. Further, the invention relates to a method for the manufacturing of the aqueous formulation.

摘要翻译： 公开了一种包含基于乙酸乙烯酯共聚物的聚合物的水性制剂，包含所述水性制剂的粘合剂体系，以及另外包含聚合物（B）的水性制剂。 本发明还涉及包含纤维底物以及水性制剂或粘合剂体系的纤维制品以及用于涂覆合成或矿物纤维的水性制剂或粘合剂体系的用途，用于制造永久性绝缘整理系统（EIFS） ，用于提高合成或矿物纤维的耐碱性，并用于制造耐碱玻璃纤维稀松布的方法。 此外，本发明涉及一种制备含水制剂的方法。

公开(公告)号：US20140171574A1

公开(公告)日：2014-06-19

申请号：US14236231

申请日：2011-08-05

申请人： Alistair Mclennan

发明人： Alistair Mclennan

IPC分类号： C09J129/04 ,  C09J131/04 ,  C09J133/08

CPC分类号： C09J129/04 ,  C08F210/02 ,  C08F218/08 ,  C08L23/0846 ,  C08L29/04 ,  C09J123/0846 ,  C09J131/04 ,  C09J133/08 ,  C08F2/24 ,  C08F2500/17

摘要： Disclosed are low-formaldehyde aqueous dispersions of vinyl ester/ethylene, e.g., vinyl acetate/ethylene (VAE), copolymers suitable for use in adhesives for applications such as tobacco or food products wherein only very low levels of formaldehyde are permitted. Such dispersions are prepared by emulsion copolymerization of a monomer mixture comprising a vinyl ester, ethylene, a stabilizing system comprising polyvinyl alcohol preferably having a degree of hydrolysis of at least 97 mole %, and a selected type of free radical redox polymerization initiator system. This selected redox initiator system comprises both a water-insoluble oxidizing agent and a sulfuric acid-based reducing agent. The monomer mixture which is polymerized is substantially free of co-monomers which yield free formaldehyde upon drying or curing of the dispersion and is also substantially free of ethylene oxide-containing emulsifiers. The aqueous dispersions resulting from polymerization of this monomer mixture has a solids content in weight percent and a Brookfield viscosity in millipascal-seconds such that the ratio of solids content to the natural logarithm of viscosity ranges from about 6.34 to about 8.25 wt %/ln(mPa·s). The dispersions herein also have a formaldehyde content of less than about 5.0 ppmw as determined by ISO-15173.

摘要翻译： 公开了乙烯基酯/乙烯的低甲醛水分散体，例如乙酸乙烯酯/乙烯（VAE）），适用于诸如烟草或食品的粘合剂的共聚物，其中仅允许非常低水平的甲醛。 这样的分散体通过包含乙烯基酯，乙烯，包含优选具有至少97摩尔％的水解度的聚乙烯醇的稳定体系和选定类型的自由基氧化还原聚合引发剂体系的单体混合物的乳液共聚来制备。 该选择的氧化还原引发剂体系包含水不溶性氧化剂和硫酸系还原剂。 聚合的单体混合物基本上不含在分散体干燥或固化时产生游离甲醛的共聚单体，并且基本上不含含环氧乙烷的乳化剂。 由该单体混合物的聚合产生的水分散体具有重量百分比的固体含量和以毫帕秒为单位的布鲁克菲尔德粘度，使得固体含量与粘度的自然对数之比为约6.34至约8.25重量％/ ln（ mPa·s）。 本文的分散体还具有通过ISO-15173测定的小于约5.0ppmw的甲醛含量。