公开(公告)号：US20090188429A1

公开(公告)日：2009-07-30

申请号：US10585400

申请日：2004-11-22

申请人： Pierre Caron ,  Annette Cretier ,  Annick Gascons

发明人： Pierre Caron ,  Annette Cretier ,  Annick Gascons

IPC分类号： B05C13/00

CPC分类号： B05C13/00 ,  B05C3/09

摘要： The ring comprises a hoop (1, 20) for draining and encircling the edge of the optical element, forming an arc over more than 180° and provided at each of its two ends with an outwardly-directed drip tab (10, 30).

摘要翻译： 环包括用于排出和环绕光学元件的边缘的环（1,20），形成超过180°的电弧并且在其两端的每一端处设置有向外定向的滴落片（10,30）。

公开(公告)号：US09114419B2

公开(公告)日：2015-08-25

申请号：US12956257

申请日：2010-11-30

申请人： Pierre Caron ,  Annette Cretier ,  Annick Gascons

发明人： Pierre Caron ,  Annette Cretier ,  Annick Gascons

IPC分类号： B05C13/00 ,  B05C3/09

CPC分类号： B05C13/00 ,  B05C3/09

摘要： Method for dip treatment of an optical element, wherein the optical element is held, while it is being dipped, by a holding ring, the ring including a hoop for draining and encircling a peripheral edge of the optical element, thereby exerting continuous linear contact with the peripheral edge, the hoop forming an arc over more than 180° and being provided at each of its two ends with an outwardly-directed drip tab pointing away from the optical element.

摘要翻译： 光学元件的浸渍处理方法，其中光学元件被浸渍时由保持环保持，所述环包括用于排出并包围光学元件的周缘的环，由此与光学元件的连续线性接触 外围边缘，环形件形成超过180°的弧形并且在其两端中的每一端处设置有指向远离光学元件的向外指向的滴落片。

公开(公告)号：US20140234637A1

公开(公告)日：2014-08-21

申请号：US14351327

申请日：2011-10-14

申请人： Annette Cretier ,  Charlotte Saint-Lu

发明人： Annette Cretier ,  Charlotte Saint-Lu

IPC分类号： G02B1/04 ,  G02B1/11

CPC分类号： G02B1/04 ,  G02B1/111 ,  Y10T428/31663 ,  C08L71/02

摘要： An optical article includes a substrate having a main surface coated with an antireflection coating and, directly contacting the antireflection coating, a precursor coating of an antifog coating obtained through the grafting on the antireflection coating of at least one compound B bearing a polyoxyalkylene group, the coating precursor of the antifog coating being coated with a surfactant film so as to form an antifog coating. The surfactant film contains at least one surfactant A having a sorbitan ring hydroxyl groups functionalized with OH-terminated polyoxyalkylene groups and R1 groups of formula: —(RdO)z—(Y)n2—R′, in which Rd is an alkylene group, z is an integer >1, Y is a divalent group, n2 is 0 or 1 and R′ is a saturated hydrocarbon group having 12 to 1 9, preferably 1 3 to 19 carbon atoms. Surfactants A provide a visual indication whether or not the antifogging effect will still be long-lasting.

摘要翻译： 光学制品包括具有涂覆有抗反射涂层的主表面并且与减反射涂层直接接触通过接枝获得的防雾涂层的前体涂层的至少一种带有聚氧化烯基团的化合物B的抗反射涂层的基材， 涂布前体的防雾涂层用表面活性剂膜涂覆以形成防雾涂层。 表面活性剂膜含有至少一种表面活性剂A，其具有用OH-封端的聚氧化烯官能化的脱水山梨糖醇环羟基和式为 - （RdO）z-（Y）n2-R'的R1基团，其中Rd是亚烷基， z为1以上的整数，Y为二价基团，n2为0或1，R'为碳原子数为12〜119，优选为13〜19的饱和烃基。 表面活性剂A提供了防雾效果是否仍然持久的视觉指示。

公开(公告)号：US07008690B2

公开(公告)日：2006-03-07

申请号：US10466160

申请日：2002-12-26

申请人： Pierre Caron ,  Jean-Paul Cano ,  Annette Cretier

发明人： Pierre Caron ,  Jean-Paul Cano ,  Annette Cretier

IPC分类号： B32B3/00

CPC分类号： G02B1/111 ,  G02B5/287 ,  Y10S428/913 ,  Y10T428/249955 ,  Y10T428/249972 ,  Y10T428/249973 ,  Y10T428/249974 ,  Y10T428/249981 ,  Y10T428/249982 ,  Y10T428/249987 ,  Y10T428/31551 ,  Y10T428/31573 ,  Y10T428/31598 ,  Y10T428/31609

摘要： An optical item comprising an organic or mineral glass substrate (1) and a transparent polymeric material layer (3), characterized in that it comprises at least one intermediate layer (2) in direct contact with one main side of the substrate and the polymeric material layer, the intermediate layer(s) being made of particles of at least one colloidal mineral oxide and optionally of a binder, such (an) intermediate layer(s) having an initial porosity, and the initial porosity of the intermediate layer(s) being filled either by material from the polymeric material layer or by the substrate material if the latter is made in an organic glass and, optionally partly by the binder when present, so that the intermediate layer(s), after initial porosity filling, each represent a quarter waveplate with a wavelength in the range from 400 to 700 nm, preferably from 450 to 650 nm.

摘要翻译： 一种包括有机或无机玻璃基板（1）和透明聚合材料层（3）的光学件，其特征在于，其包括至少一个与所述基板的一个主侧直接接触的中间层（2）和所述聚合材料 层，中间层由至少一种胶态矿物氧化物和任选的粘合剂的颗粒制成，例如具有初始孔隙率的中间层，以及中间层的初始孔隙率， 如果后者由有机玻璃制成，或者部分地由粘合剂（当存在时）部分地由聚合物材料层的材料或基材材料填充，使得中间层在初始孔隙率填充之后代表 波长在400至700nm，优选450至650nm的四分之一波片。

公开(公告)号：US20140177053A1

公开(公告)日：2014-06-26

申请号：US14234349

申请日：2012-06-28

申请人： Mamonjy Cadet ,  Annette Cretier ,  Charlotte Saint-Lu

发明人： Mamonjy Cadet ,  Annette Cretier ,  Charlotte Saint-Lu

IPC分类号： G02B1/10 ,  G02B27/00

CPC分类号： G02B1/18 ,  B05D1/28 ,  B05D1/36 ,  B29D11/00865 ,  C03C17/28 ,  C03C17/30 ,  C03C17/3405 ,  C03C2217/75 ,  C03C2218/10 ,  C03C2218/11 ,  C03C2218/30 ,  C03C2218/31 ,  C08G2290/00 ,  C08K5/06 ,  C08K5/41 ,  C08K5/54 ,  C08K5/5415 ,  C08K5/5419 ,  C09D171/00 ,  C09D171/02 ,  C09D183/00 ,  G02B1/10 ,  G02B1/115 ,  G02B27/0006 ,  G02C7/02 ,  Y10T428/31536 ,  Y10T442/2213

摘要： The present invention relates to an optical article comprising a substrate coated with a coating preferably comprising silanol groups on its surface and, directly contacting this coating, an antifog coating precursor coating, said precursor coating preferably having a static contact angle with water of more than 10° and of less than 50° and being obtained through the grafting of at least one organosilane compound possessing a polyoxyalkylene group and at least one silicon atom bearing at least one hydrolyzable group, and is further coated with a film obtained by applying a composition containing at least one surfactant of formula F(CF2)y—(CH2—CH2O)x+1H (VIII), wherein x is an integer ranging from 1 to 14, y is an integer lower than or equal to 10, compounds of formula (VIII) in which y=6 representing at least 90% by weight by weight, relative to the weight of compounds (VIII) present in the composition, so as to form an antifog coating, having preferably a static contact angle with water lower than or equal to 10°.

摘要翻译： 本发明涉及一种光学制品，其包括涂覆有涂层的基底，优选在其表面上包含硅烷醇基团，并且直接接触该涂层，防雾涂料前体涂层，所述前体涂层优选与水的静态接触角大于10 °并且小于50°，并且通过接枝至少一种具有聚氧化烯基团的至少一种有机硅烷化合物和至少一个具有至少一个可水解基团的硅原子获得，并进一步涂覆通过将含有 至少一种式F（CF 2）y - （CH 2 -CH 2 O）x + 1H（VIII）的表面活性剂，其中x是1至14的整数，y是低于或等于10的整数。式（VIII ），其中相对于存在于组合物中的化合物（VIII）的重量，y = 6表示至少90重量％，以形成防雾涂层，优选具有静态接触角wi 第二水低于或等于10°。

公开(公告)号：US20110228400A1

公开(公告)日：2011-09-22

申请号：US13131765

申请日：2009-11-26

申请人： Annette Cretier ,  Gerhard Keller ,  Philippe Vaneeckhoutte

发明人： Annette Cretier ,  Gerhard Keller ,  Philippe Vaneeckhoutte

IPC分类号： G02B1/11

CPC分类号： C08J7/045 ,  G02B1/113

摘要： The present invention relates to a method for making an optical article with anti-reflection properties, comprising the steps of: a) forming on at least one main surface of a support, by applying a sol comprising at least one colloidal mineral oxide with a refractive index higher than or equal to 1.80 having an initial porosity; b) optionally, forming on the first lower layer by applying a sol comprising at least one colloidal mineral oxide with a refractive index lower than 1.65 a second lower layer having an initial porosity at least equal to the initial porosity of said first layer; c) applying onto the one or more lower layer(s) an upper layer composition of an optically transparent polymer material with a refractive index lower than or equal to 1.50; d) filling the porosity of the one or more lower layer(s) through penetration into the one or more lower layer(s) of at least part of the material of the upper layer composition formed in step (c) and forming a cured upper layer which thickness is determined so that the upper layer and the one or more lower layer(s), once the initial porosity thereof has been filled, form a bilayered anti-reflection coating, within the range of from 400 to 700 nm, preferably of from 450 to 650 nm.

摘要翻译： 本发明涉及一种制备具有抗反射特性的光学制品的方法，包括以下步骤：a）在载体的至少一个主表面上形成，通过将包含至少一种具有折射率的胶态矿物氧化物的溶胶 指数高于或等于1.80具有初始孔隙率; b）任选地，通过施加包含至少一种折射率低于1.65的胶体矿物氧化物的溶胶在第一下层上形成具有至少等于所述第一层初始孔隙率的初始孔隙率的第二较低层; c）在所述一个或多个下层上施加折射率低于或等于1.50的光学透明聚合物材料的上层组合物; d）通过穿透步骤（c）中形成的上层组合物的至少部分材料的一个或多个下层来填充一个或多个下层的孔隙率，并形成固化的上部 层，其厚度确定为使得一旦其初始孔隙率被填充，上层和一个或多个下层形成双层抗反射涂层，其范围为400-700nm，优选为 从450nm到650nm。

公开(公告)号：US20110070364A1

公开(公告)日：2011-03-24

申请号：US12956257

申请日：2010-11-30

申请人： Pierre CARON ,  Annette Cretier ,  Annick Gascons

发明人： Pierre CARON ,  Annette Cretier ,  Annick Gascons

IPC分类号： B05D5/06

CPC分类号： B05C13/00 ,  B05C3/09

摘要： Method for dip treatment of an optical element, wherein the optical element is held, while it is being dipped, by a holding ring, the ring including a hoop for draining and encircling a peripheral edge of the optical element, thereby exerting continuous linear contact with the peripheral edge, the hoop forming an arc over more than 180° and being provided at each of its two ends with an outwardly-directed drip tab pointing away from the optical element.

摘要翻译： 光学元件的浸渍处理方法，其中光学元件被浸渍时由保持环保持，所述环包括用于排出并包围光学元件的周缘的环，由此与光学元件的连续线性接触 外围边缘，环形件形成超过180°的弧形并且在其两端中的每一端处设置有指向远离光学元件的向外指向的滴落片。

公开(公告)号：US09645285B2

公开(公告)日：2017-05-09

申请号：US14234349

申请日：2012-06-28

申请人： Mamonjy Cadet ,  Annette Cretier ,  Charlotte Saint-Lu

发明人： Mamonjy Cadet ,  Annette Cretier ,  Charlotte Saint-Lu

IPC分类号： C09D171/00 ,  C09D171/02 ,  C09D183/00 ,  G02B1/10 ,  G02B27/00 ,  C08K5/06 ,  C08K5/54 ,  C08K5/41 ,  C08K5/5415 ,  C08K5/5419 ,  C03C17/28 ,  C03C17/30 ,  C03C17/34 ,  B05D1/28 ,  B05D1/36 ,  G02B1/115 ,  G02C7/02 ,  B29D11/00

CPC分类号： G02B1/18 ,  B05D1/28 ,  B05D1/36 ,  B29D11/00865 ,  C03C17/28 ,  C03C17/30 ,  C03C17/3405 ,  C03C2217/75 ,  C03C2218/10 ,  C03C2218/11 ,  C03C2218/30 ,  C03C2218/31 ,  C08G2290/00 ,  C08K5/06 ,  C08K5/41 ,  C08K5/54 ,  C08K5/5415 ,  C08K5/5419 ,  C09D171/00 ,  C09D171/02 ,  C09D183/00 ,  G02B1/10 ,  G02B1/115 ,  G02B27/0006 ,  G02C7/02 ,  Y10T428/31536 ,  Y10T442/2213

摘要： The present invention relates to an optical article comprising a substrate coated with a coating preferably comprising silanol groups on its surface and, directly contacting this coating, an antifog coating precursor coating, said precursor coating preferably having a static contact angle with water of more than 10° and of less than 50° and being obtained through the grafting of at least one organosilane compound possessing a polyoxyalkylene group and at least one silicon atom bearing at least one hydrolyzable group, and is further coated with a film obtained by applying a composition containing at least one surfactant of formula F(CF2)y—(CH2—CH2O)x+1H (VIII), wherein x is an integer ranging from 1 to 14, y is an integer lower than or equal to 10, compounds of formula (VIII) in which y=6 representing at least 90% by weight by weight, relative to the weight of compounds (VIII) present in the composition, so as to form an antifog coating, having preferably a static contact angle with water lower than or equal to 10°.

公开(公告)号：US09494713B2

公开(公告)日：2016-11-15

申请号：US14351327

申请日：2011-10-14

申请人： Annette Cretier ,  Charlotte Saint-Lu

发明人： Annette Cretier ,  Charlotte Saint-Lu

IPC分类号： G02B1/04 ,  G02B1/111

CPC分类号： G02B1/04 ,  G02B1/111 ,  Y10T428/31663 ,  C08L71/02

摘要： An optical article includes a substrate having a main surface coated with an antireflection coating and, directly contacting the antireflection coating, a precursor coating of an antifog coating obtained through the grafting on the antireflection coating of at least one compound B bearing a polyoxyalkylene group, the coating precursor of the antifog coating being coated with a surfactant film so as to form an antifog coating. The surfactant film contains at least one surfactant A having a sorbitan ring hydroxyl groups functionalized with OH-terminated polyoxyalkylene groups and R1 groups of formula:—(RdO)z—(Y)n2—R′, in which Rd is an alkylene group, z is an integer >1, Y is a divalent group, n2 is 0 or 1 and R′ is a saturated hydrocarbon group having 12 to 19, preferably 13 to 19 carbon atoms. Surfactants A provide a visual indication whether or not the antifogging effect will still be long-lasting.

摘要翻译： 光学制品包括具有涂覆有抗反射涂层的主表面并且与减反射涂层直接接触通过接枝获得的防雾涂层的前体涂层的至少一种带有聚氧化烯基团的化合物B的抗反射涂层的基材， 涂布前体的防雾涂层用表面活性剂膜涂覆以形成防雾涂层。 表面活性剂膜含有至少一种表面活性剂A，其具有用OH-封端的聚氧化烯官能化的脱水山梨糖醇环羟基和式：-( RdO）z-（Y）n2-R'的R1基团，其中Rd是亚烷基， z为1以上的整数，Y为二价基团，n2为0或1，R'为碳原子数为12〜19，优选为13〜19的饱和烃基。 表面活性剂A提供了防雾效果是否仍然持久的视觉指示。

公开(公告)号：US20100171253A1

公开(公告)日：2010-07-08

申请号：US12446328

申请日：2007-10-09

申请人： Yves Aiguebonne ,  Annette Cretier ,  Daniel Darmes ,  Eric Roussel

发明人： Yves Aiguebonne ,  Annette Cretier ,  Daniel Darmes ,  Eric Roussel

IPC分类号： B23Q1/25

CPC分类号： B05C3/09 ,  B05B13/02 ,  B05C13/02 ,  B29D11/00865 ,  G02B7/02 ,  G02B27/62

摘要： Lens holder (1) for holding an optical lens (2) during dip coating, which comprises: holding means (3) for holding the optical lens, and supporting means for operating the holding means, said holding means (3) comprising a first arm (3a) and a second arm (3b) facing each other and movable toward and away from one another, each arm being connected to the supporting means and, through connecting means (6), to an accommodating means (7), the accommodating means connected to the first arm facing the accommodating means connected to the second arm, and the connecting means (6) being such that each accommodating means (7) is movable with at least one degree of freedom.

摘要翻译： 用于在浸涂期间保持光学透镜（2）的透镜架（1），其包括：用于保持光学透镜的保持装置（3）和用于操作保持装置的支撑装置，所述保持装置（3）包括第一臂 （3a）和第二臂（3b）彼此面对并且可以彼此相对移动并且彼此远离，每个臂连接到支撑装置，并且通过连接装置（6）连接到容纳装置（7），所述容纳装置 连接到面向连接到第二臂的容纳装置的第一臂，并且连接装置（6）使得每个容纳装置（7）能够以至少一个自由度移动。