Fischer-Tropsch Process, Supported Fischer-Tropsch Synthesis Catalyst and Uses Thereof

    公开(公告)号:US20220186123A1

    公开(公告)日:2022-06-16

    申请号:US17554218

    申请日:2021-12-17

    申请人: BP P.L.C.

    摘要: A process for converting a mixture of hydrogen and carbon monoxide gases to a composition comprising alcohols and liquid hydrocarbons by means of a Fischer-Tropsch synthesis reaction, said process comprising contacting a mixture of hydrogen and carbon monoxide gases, preferably in the form of synthesis gas mixture, with a supported Co—Mn Fischer-Tropsch synthesis catalyst, wherein: the support material of the supported Co—Mn Fischer-Tropsch synthesis catalyst comprises a material selected from titania, zinc oxide, zirconia, and ceria; the supported synthesis catalyst comprises at least 2.5 wt % of manganese, on an elemental basis, based on the total weight of the supported synthesis catalyst; the weight ratio of manganese to cobalt, on an elemental basis, is 0.2 or greater; the molar ratio of hydrogen to carbon monoxide is at least 1; and, the Fischer-Tropsch synthesis reaction is conducted at a pressure in the range of from 1.0 to 10.0 MPa absolute.

    PROCESS
    2.
    发明申请
    PROCESS 有权

    公开(公告)号:US20220098136A1

    公开(公告)日:2022-03-31

    申请号:US17433118

    申请日:2019-02-22

    摘要: A process for dehydrating methanol to dimethyl ether product in the presence of a catalyst and a promoter, wherein the catalyst is at least one aluminosilicate zeolite, and the promoter is selected from one or more compounds of Formula I: (I) wherein each of X and any or all of the Y's may independently be selected from hydrogen, halide, a substituted or unsubstituted hydrocarbyl substituent, or a compound of the formula —CHO, —CO2R, —COR, or —OR, where R is hydrogen or a substituted or unsubstituted hydrocarbyl substituent, and wherein the molar ratio of promoter to methanol is maintained at less than 1.

    PROCESS
    5.
    发明申请
    PROCESS 审中-公开

    公开(公告)号:US20200262774A1

    公开(公告)日:2020-08-20

    申请号:US16645610

    申请日:2018-08-23

    IPC分类号: C07C41/09

    摘要: A process for dehydrating methanol to dimethyl ether product in the presence of an aluminosilicate zeolite catalyst and a promoter selected from (i) aldehyde of formula R1CHO (Formula I) in which R1 is hydrogen, a C1-C11 alkyl group or a C3-C11 alkyl group in which 3 or more carbon atoms are joined to form a ring; or (ii) acetal derivative of an aldehyde of Formula I; and the molar ratio of promoter to methanol is maintained at 0.1 or less.