Catalyzed olefin equlibration and separation of the equilibrated products
    2.
    发明授权
    Catalyzed olefin equlibration and separation of the equilibrated products 失效
    催化烯烃均衡和分离平衡的产物

    公开(公告)号:US4777310A

    公开(公告)日:1988-10-11

    申请号:US139329

    申请日:1987-12-30

    IPC分类号: C07C6/04 C07C6/02

    CPC分类号: C07C6/04

    摘要: A method for the selective gas-phase equilibration of at least one C.sub.3 or greater monoalkene over a HAMS-1B crystalline borosilicate-based catalyst composition employing operating conditions in which the total butylene and t-amylene C.sub.5 and lower fraction of the product are maximized and the formation of C.sub.1 to C.sub.3 hydrocarbons, total aromatics and total paraffins are minimized. In another aspect of the invention the equilibration product is usefully separated by converting the isobutylene and t-amylene fractions to their methyl ethers by reaction with methanol.

    摘要翻译: 在HAMS-1B结晶硼硅酸盐基催化剂组合物上选择性气相平衡至少一种C3或更高级单烯烃的方法,其使用其中总的丁烯和叔丁烯C5和产物的较低级分最大化的操作条件, 形成C1至C3烃,总芳族化合物和总链烷烃最小化。 在本发明的另一方面,通过与甲醇反应将异丁烯和叔 - 亚甲基馏分转化成甲基醚来平衡产物是有用的。