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公开(公告)号：US08957268B2
公开(公告)日：2015-02-17
申请号：US12901829
申请日：2010-10-11
IPC分类号： C11C1/00 , C07C1/00 , C07C5/03 , C07C1/24 , C11B3/00 , C10G45/00 , C10G45/58 , C10G50/00 , C10G65/04 , C10L1/02 , C10L1/08 , C11C3/00 , C10G3/00 , C07C67/03 , C07C67/54 , C07C6/04 , C07C51/09 , C07C2/86
CPC分类号： C10G3/42 , C07C2/862 , C07C6/04 , C07C51/09 , C07C67/03 , C07C67/54 , C07C2531/14 , C07C2531/24 , C10G45/00 , C10G45/58 , C10G50/00 , C10G65/043 , C10G69/02 , C10G2300/1011 , C10G2300/1014 , C10G2300/1018 , C10G2300/1092 , C10G2300/1096 , C10G2300/202 , C10G2300/30 , C10G2300/301 , C10G2300/307 , C10G2300/308 , C10G2300/44 , C10G2400/00 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/20 , C10G2400/22 , C10L1/026 , C10L1/04 , C10L1/08 , C10L2200/0469 , C11B3/00 , C11C1/08 , C11C3/003 , Y02E50/13 , Y02P30/20 , Y02T50/678 , C07C69/533 , C07C57/03 , C07C57/12 , C07C11/02
摘要： Methods are provided for refining natural oil feedstocks. The methods comprise reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters. In certain embodiments, the methods further comprise separating the olefins from the esters in the metathesized product. In certain embodiments, the methods further comprise hydrogenating the olefins under conditions sufficient to form a fuel composition. In certain embodiments, the methods further comprise transesterifying the esters in the presence of an alcohol to form a transesterified product.
摘要翻译： 提供了用于精炼天然油原料的方法。 所述方法包括在复分解催化剂存在下，在足以形成包含烯烃和酯的复分解产物的条件下使原料反应。 在某些实施方案中，所述方法还包括将烯烃与复分解产物中的酯分离。 在某些实施方案中，所述方法还包括在足以形成燃料组合物的条件下氢化所述烯烃。 在某些实施方案中，所述方法还包括在醇存在下酯交酯化以形成酯交换产物。
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2.发明授权Methods of refining and producing fuel and specialty chemicals from natural oil feedstocks 有权从天然油原料精炼和生产燃料和特种化学品的方法公开(公告)号：US08735640B2
公开(公告)日：2014-05-27
申请号：US13647825
申请日：2012-10-09
申请人： Steven A. Cohen , Melvin L. Luetkens, Jr. , Chander Balakrishnan , Robert Snyder , Yenamandra Viswanath , Efimia Metsi-Guckel , Robin Weitkamp
发明人： Steven A. Cohen , Melvin L. Luetkens, Jr. , Chander Balakrishnan , Robert Snyder , Yenamandra Viswanath , Efimia Metsi-Guckel , Robin Weitkamp
CPC分类号： C10L1/02 , C10G3/42 , C10G29/205 , C10G45/00 , C10G45/58 , C10G50/00 , C10G65/043 , C10G69/123 , C10G2300/1014 , C10G2300/1018 , C10G2300/1088 , C10G2300/30 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/20 , C10G2400/22 , C10L1/026 , C10L1/08 , C11B3/00 , C11C3/003 , Y02P20/582
摘要： Methods are provided for refining natural oil feedstocks. The methods comprise reacting the feedstock with a low-molecular-weight olefin or mid-weight olefin in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters. In certain embodiments, the methods further comprise separating the olefins from the esters in the metathesized product. In certain embodiments, the methods further comprise transesterifying the esters in the presence of an alcohol to form a transesterified product.
摘要翻译： 提供了用于精炼天然油原料的方法。 所述方法包括在复分解催化剂存在下在足以形成包含烯烃和酯的复分解产物的条件下使原料与低分子量烯烃或中等重量的烯烃反应。 在某些实施方案中，所述方法还包括将烯烃与复分解产物中的酯分离。 在某些实施方案中，所述方法还包括在醇存在下酯交酯化以形成酯交换产物。
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3.发明申请METHODS OF REFINING AND PRODUCING FUEL AND SPECIALTY CHEMICALS FROM NATURAL OIL FEEDSTOCKS 有权从天然油料中精炼和生产燃料和特种化学品的方法公开(公告)号：US20130035502A1
公开(公告)日：2013-02-07
申请号：US13647825
申请日：2012-10-09
申请人： Steven A. Cohen , Melvin L. Luetkens, Jr. , Chander Balakrishnan , Robert Snyder , Yenamandra Viswanath , Efimia Metsi-Guckel , Robin Weitkamp
发明人： Steven A. Cohen , Melvin L. Luetkens, Jr. , Chander Balakrishnan , Robert Snyder , Yenamandra Viswanath , Efimia Metsi-Guckel , Robin Weitkamp
CPC分类号： C10L1/02 , C10G3/42 , C10G29/205 , C10G45/00 , C10G45/58 , C10G50/00 , C10G65/043 , C10G69/123 , C10G2300/1014 , C10G2300/1018 , C10G2300/1088 , C10G2300/30 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/20 , C10G2400/22 , C10L1/026 , C10L1/08 , C11B3/00 , C11C3/003 , Y02P20/582
摘要： Methods are provided for refining natural oil feedstocks. The methods comprise reacting the feedstock with a low-molecular-weight olefin or mid-weight olefin in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters. In certain embodiments, the methods further comprise separating the olefins from the esters in the metathesized product. In certain embodiments, the methods further comprise transesterifying the esters in the presence of an alcohol to form a transesterified product.
摘要翻译： 提供了用于精炼天然油原料的方法。 所述方法包括在复分解催化剂存在下在足以形成包含烯烃和酯的复分解产物的条件下使原料与低分子量烯烃或中等重量的烯烃反应。 在某些实施方案中，所述方法还包括将烯烃与复分解产物中的酯分离。 在某些实施方案中，所述方法还包括在醇存在下酯交酯化以形成酯交换产物。
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4.发明授权Methods of producing jet fuel from natural oil feedstocks through metathesis reactions 有权通过复分解反应从天然油原料生产喷气燃料的方法公开(公告)号：US08933285B2
公开(公告)日：2015-01-13
申请号：US13129170
申请日：2009-11-25
CPC分类号： C10L1/08 , C10G3/50 , C10G2300/1014 , C10G2300/1088 , C10G2300/30 , C10G2400/08 , C10L1/04 , C10L2200/0484 , C10L2270/04 , Y02P30/20
摘要： Methods are provided for producing a jet fuel composition from a feedstock comprising a natural oil. The methods comprise reacting the feedstock with a low-weight olefin in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product. The methods further comprise hydrogenating the metathesized product under conditions sufficient to form a jet fuel composition.
摘要翻译： 提供了从包含天然油的原料生产喷气燃料组合物的方法。 所述方法包括在复分解催化剂存在下在足以形成复分解产物的条件下使原料与低重量烯烃反应。 所述方法还包括在足以形成喷气燃料组合物的条件下氢化复分解产物。
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5.发明授权Methods of producing jet fuel from natural oil feedstocks through oxygen-cleaved reactions 有权通过氧裂解反应从天然油原料生产喷气燃料的方法公开(公告)号：US08889932B2
公开(公告)日：2014-11-18
申请号：US13129172
申请日：2009-11-25
CPC分类号： C10G3/50 , C10G3/00 , C10G7/00 , C10G27/04 , C10G27/14 , C10G31/00 , C10G31/09 , C10G31/10 , C10G65/043 , C10G65/08 , C10G67/12 , C10G2300/1011 , C10G2300/1014 , C10G2300/1018 , C10G2300/30 , C10G2400/08 , C10L1/04 , C10L1/06 , C10L2200/0484 , C10L2270/04 , C10L2290/543 , C10L2290/547 , Y02P30/20
摘要： Methods are provided for producing a jet fuel composition from a feedstock comprising a natural oil. The methods comprise reacting the feedstock with oxygen under conditions sufficient to form an oxygen-cleaved product. The methods further comprise hydrogenating the oxygen-cleaved product under conditions sufficient to form a jet fuel composition.
摘要翻译： 提供了从包含天然油的原料生产喷气燃料组合物的方法。 所述方法包括在足以形成氧切割产物的条件下使原料与氧气反应。 所述方法还包括在足以形成喷气燃料组合物的条件下氢化氧切割产物。
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6.发明授权Methods for preparing ruthenium carbene complex precursors and ruthenium carbene complexes 有权制备钌卡宾络合物前体和钌卡宾络合物的方法公开(公告)号：US08779152B2
公开(公告)日：2014-07-15
申请号：US13272788
申请日：2011-10-13
IPC分类号： C07F15/00
CPC分类号： C07F15/0046 , B01J31/2295 , C07F15/0053
摘要： A method for preparing a ruthenium carbene complex precursor includes reacting a ruthenium refinery salt with a hydrogen halide to form a ruthenium intermediate, and reacting the ruthenium intermediate with an L-type ligand to form the ruthenium carbene complex precursor. A method for preparing a ruthenium vinylcarbene complex includes converting a ruthenium carbene complex precursor into a ruthenium hydrido halide complex, and reacting the ruthenium hydrido halide complex with a propargyl halide to form the ruthenium vinylcarbene complex. A method for preparing a ruthenium carbene complex includes converting a ruthenium carbene complex precursor into a ruthenium carbene complex having a structure (PR1R2R3)2Cl2Ru═CH—R4, wherein R1, R2, R3, and R4 are alike or different, and wherein covalent bonds may optionally exist between two or more of R1, R2, and R3.
摘要翻译： 制备钌卡宾络合物前体的方法包括使钌精炼盐与卤化氢反应形成钌中间体，并使钌中间体与L型配体反应以形成钌卡宾复合物前体。 制备钌乙烯基卡巴复合物的方法包括将钌卡宾络合物前体转化为卤化钌卤化物络合物，并使卤化钌卤化物络合物与炔丙基卤反应形成钌乙烯基卡巴复合物。 制备钌卡宾络合物的方法包括将钌卡宾络合物前体转化成具有结构（PR1R2R3）2Cl2Ru=CH-R4的钌卡宾络合物，其中R 1，R 2，R 3和R 4相同或不同，并且其中共价键 可以任选地存在于R 1，R 2和R 3中的两个或多个之间。
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7.发明授权Aromatic acid monomers, polymers, products and processes for their manufacture 有权芳香族酸单体，聚合物，产品及其制造方法公开(公告)号：US06284920B1
公开(公告)日：2001-09-04
申请号：US09412458
申请日：1999-10-04
申请人： Edward E. Paschke , Bruce I. Rosen , David A. Peterson , David E. James , Melvin L. Luetkens, Jr. , Charles W. Bauer , Gary T. Brooks
发明人： Edward E. Paschke , Bruce I. Rosen , David A. Peterson , David E. James , Melvin L. Luetkens, Jr. , Charles W. Bauer , Gary T. Brooks
IPC分类号： C07C5109
CPC分类号： C08G63/189 , C07C51/265 , C07C51/42 , C07C63/38 , Y10T428/1352 , Y10T428/29 , Y10T428/2913
摘要： Processes for producing aromatic monomers useful for forming polyesters are disclosed. Cost effective steps employed in the processes permit small amounts of process-related materials typically removed from monomer to remain in an aromatic monomer product. In many cases, the presence of the process-related materials left in the monomer product by the cost effective process steps can enhance the performance of the monomer in certain applications. Aromatic monomer products and polymers produced therefrom having these advantages also are disclosed, as well as products such as pasteurizable bottles made from these polymers.
摘要翻译： 公开了用于制备用于形成聚酯的芳族单体的方法。 在该方法中使用的成本有效的步骤允许通常从单体中除去残留在芳族单体产物中的少量与工艺相关的材料。 在许多情况下，通过成本有效的工艺步骤留在单体产品中的工艺相关材料的存在可以在某些应用中提高单体的性能。 还公开了具有这些优点的芳族单体产物和由其制备的聚合物，以及由这些聚合物制成的诸如可巴氏消毒瓶的产品。
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8.发明授权Aromatic acid monomers, polymers, products and processes for their manufacture 有权芳香族酸单体，聚合物，产品及其制造方法公开(公告)号：US06461700B2
公开(公告)日：2002-10-08
申请号：US09935458
申请日：2001-08-23
申请人： Edward E. Paschke , Bruce I. Rosen , David A. Peterson , David E. James , Melvin L. Luetkens, Jr. , Charles W Bauer , Gary T. Brooks
发明人： Edward E. Paschke , Bruce I. Rosen , David A. Peterson , David E. James , Melvin L. Luetkens, Jr. , Charles W Bauer , Gary T. Brooks
IPC分类号： B29D2200
CPC分类号： C08G63/189 , C07C51/265 , C07C51/42 , C07C63/38 , Y10T428/1352 , Y10T428/29 , Y10T428/2913
摘要： Processes for producing aromatic monomers useful for forming polyesters are disclosed. Cost effective steps employed in the processes permit small amounts of process-related materials typically removed from monomer to remain in an aromatic monomer product. In many cases, the presence of the process-related materials left in the monomer product by the cost effective process steps can enhance the performance of the monomer in certain applications. Aromatic monomer products and polymers produced therefrom having these advantages also are disclosed, as well as products such as pasteurizable bottles made from these polymers
摘要翻译： 公开了用于制备用于形成聚酯的芳族单体的方法。 在该方法中使用的成本有效的步骤允许通常从单体中除去残留在芳族单体产物中的少量与工艺相关的材料。 在许多情况下，通过成本有效的工艺步骤留在单体产品中的工艺相关材料的存在可以在某些应用中提高单体的性能。 还公开了具有这些优点的芳族单体产物和由其制备的聚合物，以及由这些聚合物制成的诸如可巴氏消毒瓶的产品
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9.发明授权Foamed core-reclaim multi layer sheet having improved resistance to barrier film delamination 失效具有提高的阻挡层分层耐性的发泡芯回收多层片
公开(公告)号：US5462794A
公开(公告)日：1995-10-31
申请号：US99911
申请日：1993-07-30
申请人： David C. Lindemann , Weilong L. Chiang , Melvin L. Luetkens, Jr. , Robert D. Pischke , John C. Schubert
发明人： David C. Lindemann , Weilong L. Chiang , Melvin L. Luetkens, Jr. , Robert D. Pischke , John C. Schubert
CPC分类号： C08J9/365 , B29C44/50 , B32B5/18 , B29K2105/26 , C08J2325/06 , Y10T428/249982 , Y10T428/249988 , Y10T428/249991 , Y10T428/249992
摘要： Disclosed is a multi-layer sheet in a which a foamed thermpolastic core layer is extrusion coated with a multi-resin reclaim-containing layer, and an EVOH or acrylonitrile barrier layer is laminated to the multi-resin layer. The multi-resin layer is formulated to contain at least about 5 weight percent, and preferably about 8 to about 16 weight percent, based on the weight of the layer, of an adhesive resin to reduce the tendency of the barrier layer to delaminate from the multi-resin layer over time. The preferred adhesive is EMA.
摘要翻译： 公开了一种多层片材，其中发泡热塑性芯层被多树脂回收层挤出涂覆，并且EVOH或丙烯腈阻挡层层压到多树脂层上。 将多层树脂配制成含有至少约5重量％，优选约8至约16重量％，基于该层的重量，粘合树脂，以减少阻挡层从 多层树脂层随着时间的推移。 优选的粘合剂是EMA。
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10.发明授权Polyamide having improved gas barrier properties from adipic acid, isophthalic acid and m-xylylene diamine 失效具有从己二酸，间苯二甲酸和间苯二甲胺改进的阻气性的聚酰胺
公开(公告)号：US5175238A
公开(公告)日：1992-12-29
申请号：US575070
申请日：1990-08-30
申请人： John D. Matlack , James G. Villanueva , Bruce A. Newman , Lawrence D. Lillwitz , Melvin L. Luetkens, Jr. , Gregory E. Schmidt
发明人： John D. Matlack , James G. Villanueva , Bruce A. Newman , Lawrence D. Lillwitz , Melvin L. Luetkens, Jr. , Gregory E. Schmidt
CPC分类号： C08G69/265 , C08L77/00
摘要： A polyamide composition comprising the following recurring units: ##STR1## in proportions such that the mole ratio of the dicarboxylic acid moieties in the A, B and C units is about 49.5-0.5/0-20/0.5-49.5 and wherein R is a divalent radical comprising ##STR2## in a mole ratio of about 0.5-50/49.5-0 and preferably having a glass transition temperature of 90.degree. C. or greater and an oxygen transmission rate of about 2.0 cc-mil/100 in.sup.2 -day-atm or less.
摘要翻译： 一种聚酰胺组合物，其包含以下重复单元：A，B和C单元中二羧酸部分的摩尔比为约49.5-0.5 / 0-20的比例 /0.5-49.5，其中R是包含摩尔比为约0.5-50 / 49.5-0，优选玻璃化转变温度为90℃或更高，氧气透过率为约2.0的二价基团 cc-mil / 100 in-day-atm以下。
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