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    Synthesis of aminoarylboronic esters and substituted anilines from arenes via catalytic C-H activation/borylation/amination and uses thereof
    3.
    发明授权
    Synthesis of aminoarylboronic esters and substituted anilines from arenes via catalytic C-H activation/borylation/amination and uses thereof 有权
    通过催化C-H活化/硼化/胺化合成氨基芳基硼酸酯和芳烃的取代苯胺及其用途

    公开(公告)号：US06958420B2

    公开(公告)日：2005-10-25

    申请号：US10623196

    申请日：2003-07-18

    申请人： Robert E. Maleczka, Jr. ,  Milton R. Smith, III ,  Daniel Holmes

    发明人： Robert E. Maleczka, Jr. ,  Milton R. Smith, III ,  Daniel Holmes

    IPC分类号： C07F5/02

    CPC分类号： C07F5/025

    摘要： A process is described for synthesizing aminoarylboronic esters of the general formula wherein R, R2, and R3 are each an alkyl, aryl, vinyl, alkoxy, carboxylic esters, amides, or halogen; Ar is any variety of phenyl, naphthyl, anthracyl, heteroaryl; and R1 is alkyl, hydrogen, or aryl. The aminoarylboronic esters are produced via the metal-catalyzed coupling of arylboronic esters of the general formula wherein R and R1 are any non-interfering group and X is chloro, bromo, iodo, triflates, or nonaflates to amines (primary and secondary). In particular, a process is described for the synthesis of the aminoarylboronic esters via a step-wise or tandem process in which one catalytic event is a metal-catalyzed borylation and the other catalytic event is a metal-catalyzed amination.

    摘要翻译： 描述了用于合成通式的氨基芳基硼酸酯的方法，其中R 1，R 2和R 3各自为烷基，芳基，乙烯基，烷氧基，羧酸酯，酰胺 ，或卤素; Ar是任何各种苯基，萘基，蒽基，杂芳基; 并且R 1是烷基，氢或芳基。 氨基芳基硼酸酯通过以下通式的芳基硼酸酯的金属催化偶合而制备：其中R和R 1是任何非干扰基团，X是氯，溴，碘，三氟甲磺酸酯或非卤化物， 胺（初级和次级）。 特别地，描述了通过逐步或串联方法合成氨基芳基硼酸酯的方法，其中一个催化事件是金属催化的硼化反应，另一个催化事件是金属催化的胺化。

    Process for the synthesis of phenols from arenes
    4.
    发明授权
    Process for the synthesis of phenols from arenes 有权
    从芳烃合成苯酚的方法

    公开(公告)号：US06828466B2

    公开(公告)日：2004-12-07

    申请号：US10620122

    申请日：2003-07-15

    申请人： Robert E. Maleczka, Jr. ,  Milton R. Smith, III ,  Daniel Holmes ,  Feng Shi

    发明人： Robert E. Maleczka, Jr. ,  Milton R. Smith, III ,  Daniel Holmes ,  Feng Shi

    IPC分类号： C07C3700

    CPC分类号： C07D213/68 ,  C07B41/02 ,  C07C37/50 ,  C07C41/26 ,  C07C67/31 ,  C07C213/00 ,  C07C69/88 ,  C07C69/92 ,  C07C215/76 ,  C07C39/27 ,  C07C43/23 ,  C07C39/28 ,  C07C39/245 ,  C07C39/32 ,  C07C39/07 ,  C07C39/24 ,  C07C39/30 ,  C07C69/84

    摘要： A process to synthesize substituted phenols such as those of the general formula RR′R″Ar(OH) wherein R, R′, and R″ are each independently hydrogen or any group which does not interfere in the process for synthesizing the substituted phenol including, but not limited to, halo, alkyl, alkoxy, carboxylic ester, amine, amide; and Ar is any variety of aryl or hetroaryl by means of oxidation of substituted arylboronic esters is described. In particular, a metal-catalyzed C—H activation/borylation reaction is described, which when followed by direct oxidation in a single or separate reaction vessel affords phenols without the need for any intermediate manipulations. More particularly, a process wherein Ir-catalyzed borylation of arenes using pinacolborane (HBPin) followed by oxidation of the intermediate arylboronic ester by OXONE is described.

    摘要翻译： 合成取代酚的方法，例如通式为R'R''Ar（OH）的取代酚，其中R，R'和R“各自独立地为氢或任何不干扰合成取代基的方法的基团 苯酚，包括但不限于卤素，烷基，烷氧基，羧酸酯，胺，酰胺; 并且描述了通过取代的芳基硼酸酯的氧化的任何种类的芳基或杂芳基。 特别地，描述了金属催化的C-H活化/硼烷化反应，当在单个或单独的反应容器中直接氧化时，其提供酚，而不需要任何中间操作。 更具体地说，描述了使用频哪醇硼烷（HBPin）进行Ir催化的芳烃硼烷化，然后用OXONE氧化中间体芳基硼酸酯的方法。

    Energy Accumulating Actuator
    7.
    发明申请
    Energy Accumulating Actuator 审中-公开
    能量积累致动器

    公开(公告)号：US20130067918A1

    公开(公告)日：2013-03-21

    申请号：US13236677

    申请日：2011-09-20

    申请人： Martin Daniel Holmes

    发明人： Martin Daniel Holmes

    IPC分类号： F01B29/08

    CPC分类号： F03G7/00

    摘要： A device for storing and converting chemical energy into controlled mechanical motion requires that chemical energy is released through ignition and stored in an accumulator. When a release valve is activated the stored energy is used to move a piston and push-rod arrangement, which can be used to actuate certain power tools.

    摘要翻译： 用于将化学能量存储和转化成受控机械运动的装置要求化学能通过点火释放并储存在蓄能器中。 当释放阀被启动时，存储的能量用于移动可用于致动某些电动工具的活塞和推杆装置。

    Remote forcible entry tool
    10.
    发明申请
    Remote forcible entry tool 审中-公开
    远程强制输入工具

    公开(公告)号：US20080105447A1

    公开(公告)日：2008-05-08

    申请号：US11593201

    申请日：2006-11-03

    申请人： Martin Daniel Holmes

    发明人： Martin Daniel Holmes

    IPC分类号： B25D17/28

    CPC分类号： A62B3/005

    摘要： The present invention provides a device which will provide a remotely activated forcible entry device. The device has retractable parts to reduce bulk of the device when in transit. The Device is lighter than traditional battering rams and is used to breach a conventional door without putting emergency personnel in the line of fire. The device uses traditional cartridges to apply force to the doorway without any specialist training.

    摘要翻译： 本发明提供一种将提供远程激活的强制进入装置的装置。 该设备具有可缩回的部件，可在运输过程中减少设备的体积。 该装置比传统的打击式公羊更轻，并且用于违反常规门而不将应急人员置于火中。 该设备使用传统的墨盒向门口施加强度，无需任何专业培训。