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    Compositions containing silicates and ion-conducting films containing the same
    1.
    发明授权
    Compositions containing silicates and ion-conducting films containing the same 失效
    含有硅酸盐和含有它们的离子导电膜的组合物

    公开(公告)号：US07118694B2

    公开(公告)日：2006-10-10

    申请号：US10133346

    申请日：2002-04-29

    Applicant: Bernd Bronstert ,  Helmut Möhwald

    Inventor： Bernd Bronstert ,  Helmut Möhwald

    IPC: G02F1/00 ,  C08J9/24 ,  C08K3/34 ,  H01M6/18 ,  H01M2/16

    CPC classification number: H01M10/0565 ,  C08G65/3322 ,  C08K9/06 ,  C08L71/02 ,  C08L2205/05 ,  H01G11/52 ,  H01G11/56 ,  H01M2/1653 ,  H01M2/166 ,  H01M4/13 ,  H01M4/621 ,  H01M4/622 ,  H01M6/40 ,  H01M10/052 ,  H01M10/0525 ,  H01M2300/0025 ,  Y02E60/13 ,  C08L63/00 ,  C08L71/00 ,  C08L2666/04

    Abstract: A mixture Ia which comprises a composition IIa consisting of a) 1 to 95% by weight of a solid III, preferably a basic solid III, having a primary particle size of 5 nm to 20 microns, and b) 5 to 99% by weight of a polymeric mass IV obtainable by polymerizing b1) 5 to 100% by weight, based on the mass IV of a condensation product V of α) at least one compound VI which is capable to react with a carboxylic acid or a sulfonic acid or a derivative thereof or a mixture of two or more thereof, and β) at least one mole per mole of the compound VI of a carboxylic acid or a sulfonic acid VII which exhibits at least one radically polymerizable functional group, or a derivative thereof or a mixture of two or more thereof and b2) 0 to 95% by weight, based on the mass IV, of a further compound VIII having an average molecular weight (number average) of at least 5000 and having polyether segments in the main or side chain, wherein the proportion by weight of the composition IIa in the mixture Ia is 1 to 100% by weight.

    Abstract translation: 混合物Ia，其包含由a）1至95重量％的固体III，优选碱性固体III，一次粒径为5nm至20微米，和b）5至99重量％的组合物IIa 聚合物质量IV可通过以b1）5至100重量％为基准，基于α的缩合产物V的质量IV）至少一种能够与羧酸或磺酸反应的化合物VI或 衍生物或其两种或多种的混合物，和β）至少一摩尔每摩尔显示至少一种可自由基聚合的官能团的羧酸或磺酸VII的化合物VI，或其衍生物或混合物 的两种或多种，​​b2）0至95重量％，基于质量IV，平均分子量（数均）为至少5000并且在主链或侧链具有聚醚链段的另外的化合物VIII， 其中混合物中组合物IIa的重量比例 Ia为1至100重量％。

    Composite bodies used as separators in electrochemical cells
    2.
    发明授权
    Composite bodies used as separators in electrochemical cells 失效
    复合体用作电化学电池中的分离器

    公开(公告)号：US06746803B1

    公开(公告)日：2004-06-08

    申请号：US09958288

    申请日：2001-10-09

    Applicant: Stephan Bauer ,  Bernd Bronstert ,  Helmut Möhwald

    Inventor： Stephan Bauer ,  Bernd Bronstert ,  Helmut Möhwald

    IPC: H01M216

    CPC classification number: H01M2/164 ,  H01M2/1686 ,  H01M6/181 ,  H01M10/052 ,  H01M10/0565 ,  Y10T29/49112

    Abstract: A composite comprises at least one first layer which includes a composite comprising (a) from 1 to 99% by weight of a solid (I) with a primary particle size of from 5 nm to 100 &mgr;m or a mixture made from at least two solids, (b) from 99 to 1% by weight of a polymeric binder (II) obtainable by polymerizing b1) from 5 to 100% by weight, based on the binder (II), of a condensation product III made from at least one compound IV which is capable of reacting with a carboxylic acid or with a sulfonic acid or with a derivative or with a mixture of two or more of these, and at least one mol per mole of compound IV of a carboxylic or sulfonic acid V which has at least one functional group capable of free-radical polymerization, or of a derivative of these or of a mixture of two or more of these and b2) from 0 to 95% by weight, based on the binder (II), of another compound VII with an average molecular weight (number average) of at least 5000 having polyether segments in a main or side chain, where the at least one layer has been applied to at least one second layer comprising at least one conventional separator.

    Abstract translation: 复合材料包括至少一个第一层，其包括复合材料，所述复合材料包含（a）1至99重量％的初级粒度为5nm至100μm的固体（I）或由至少两种固体制成的混合物 ，（b）99至1重量％的聚合物粘合剂（II），其通过聚合b1）基于粘合剂（II）的5至100重量％的可由至少一种化合物IV制成的缩合产物III获得，其为 能够与羧酸或与磺酸或衍生物或这些中的两种或更多种的混合物反应，并且每摩尔化合物IV至少一摩尔具有至少一个官能团的羧酸或磺酸V的化合物IV 基团，其能够自由基聚合，或这些的衍生物，或这些中的两种或多种的混合物，和b2），基于粘合剂（II），0至95重量％的另一种化合物VII的平均分子量 （数均）为至少5000，其中主链或侧链具有聚醚链段，其中a 至少一层已经施加到包括至少一个常规分离器的至少一个第二层。

    Compositions suitable for electrochemical cells
    5.
    发明授权
    Compositions suitable for electrochemical cells 失效
    适用于电化学电池的组合物

    公开(公告)号：US06991874B1

    公开(公告)日：2006-01-31

    申请号：US09674541

    申请日：1999-05-04

    Applicant: Helmut Möhwald ,  Gerhard Dötter ,  Rainer Blum ,  Peter Keller ,  Stephan Bauer ,  Bernd Bronstert

    Inventor： Helmut Möhwald ,  Gerhard Dötter ,  Rainer Blum ,  Peter Keller ,  Stephan Bauer ,  Bernd Bronstert

    IPC: H01M2/14

    CPC classification number: H01G9/025 ,  G01N27/4073 ,  H01G9/02 ,  H01M2/1653 ,  H01M4/13 ,  H01M4/621 ,  H01M4/622 ,  H01M6/168 ,  H01M10/052 ,  H01M10/0565 ,  Y10T428/31504 ,  Y10T428/31721 ,  Y10T428/31725

    Abstract: The compositions comprise: (a) from 1 to 99% by weight of a pigment (I) having a primary particle size of from 5 nm to 100 μm which is a solid Ia or a compound Ib which acts as cathode material in electrochemical cells or a compound Ic which acts as anode material in electrochemical cells or a mixture of the solid Ia with the compound Ib or the compound Ic, (b) from 1 to 99% by weight of a polymeric material (II) which comprises: (IIa) from 1 to 100% by weight of a polymer or copolymer (IIa) which has, as part of the chain, at the end(s) of the chain and/or laterally on the chain, reactive groups (RG) which are capable of crosslinking reactions under the action of heat and/or UV radiation, and (IIb) from 0 to 99% by weight of at least one polymer or copolymer (IIb) which is free of reactive groups RG.

    Abstract translation: 组合物包含：（a）1至99重量％的初级粒度为5至100微米的颜料（I），其为在电化学电池中充当阴极材料的固体Ia或化合物1b，或 在电化学电池中充当阳极材料的化合物Ic或固体Ia与化合物Ib或化合物Ic的混合物，（b）1至99重量％的聚合物材料（II），其包含：（IIa） 1至100重量％的聚合物或共聚物（IIa），其作为链的一部分在链的末端和/或在侧链上具有反应性基团（RG），其能够 在热和/或UV辐射的作用下的交联反应，和（IIb）0至99重量％的至少一种不含反应性基团RG的聚合物或共聚物（IIb）。

    Mixtures with special softening agents suited as a solid electrolyte or separator for electrochemical cells
    6.
    发明授权
    Mixtures with special softening agents suited as a solid electrolyte or separator for electrochemical cells 失效
    具有适合作为电解质电池的固体电解质或隔膜的特殊软化剂的混合物

    公开(公告)号：US06642294B1

    公开(公告)日：2003-11-04

    申请号：US09509690

    申请日：2000-07-17

    Applicant: Stephan Bauer ,  Bernd Bronstert ,  Helmut Möhwald ,  Hans-Josef Sterzel ,  Werner Hesse

    Inventor： Stephan Bauer ,  Bernd Bronstert ,  Helmut Möhwald ,  Hans-Josef Sterzel ,  Werner Hesse

    IPC: C08K318

    CPC classification number: H01G9/025 ,  A01N59/16 ,  C08J5/2256 ,  C08J2381/06 ,  C08J2385/02 ,  C08K3/01 ,  C08K5/0016 ,  H01G9/02 ,  H01M2/1653 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0565 ,  A01N2300/00

    Abstract: A mixture Ia comprises a mix IIa composed of a) from 1 to 95% by weight of a solid III, preferably a basic solid III, with a primary particle size of from 5 nm to 20 &mgr;m and b) from 5 to 99% by weight of a polymeric composition IV, obtainable by polymerizing b1) from 5 to 100% by weight, based on the composition IV, of a condensation product V of &agr;) at least one compound VI which is capable of reacting with a carboxylic acid or with a sulfonic acid or with a derivative or a iixture of two or more of these, and &bgr;) at least 1 mol per mole of the compound VI of a carboxylic acid or sulfonic acid VII which has at least one functional group capable of free-radical polymerization, or of a derivative thereof or of a mixture of two or more thereof and b2) from 0 to 95% by weight, based on the composition IV, of another compound VIII with an average molecular weight (number average) of at least 5000 having polyether segments in its main or side chain and at least one ester of the formula (E1) to (E5) where each of R1, R2, R3 and R4 is identical with or different from the others and, independently of the others, is linear or branched-chain C1-C4-alkyl (—CH2—CH2—O)n—CH3, where n is from 1 to 3, C3-C6-cycloalkyl or an aromatic hydrocarbon group which may in turn be substituted, with the proviso that at least one of the groups R1, R2, R3 or R4 is (—CH2—CH2—O)n—CH3, where n is from 1 to 3.

    Abstract translation: 混合物Ia包含由以下组成的混合物IIa：a）1至95重量％的固体III，优选碱性固体III，一次粒径为5nm至20μm，和b）5至99重量％的 聚合物组合物IV，其可通过以下方式获得：b）基于组合物IV的5至100重量％的α的缩合产物V至少一种能够与羧酸或与磺酸反应的化合物VI，或 或其中两种或更多种的衍生物或混合物，和β）至少1摩尔每摩尔具有至少一个能够自由基聚合的官能团的羧酸或磺酸VII的化合物VI，或 衍生物或其两种或多种的混合物和b2）0至95重量％，基于组合物IV，另一种平均分子量（数均）至少为5000的化合物VIII在其主体中具有聚醚链段 或侧链和至少一个式（E1）的酯， 至（E5）其中R 1，R 2，R 3和R 4各自与其它基团相同或不同，并且独立地为直链或支链C1-C4 - 烷基（-CH 2 -CH 2 -O）n -CH 3，其中n为1至3，可以被取代的C 3 -C 6环烷基或芳族烃基，条件是基团R R 1，R 3，R 3或R 4为（-CH 2 -CH 2 -O）n -CH 3，其中n为1至3。

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