公开(公告)号：US20130026996A1

公开(公告)日：2013-01-31

申请号：US13639832

申请日：2011-12-22

申请人： Takashi Kasahara ,  Kenta Tsutsui ,  Hideaki Ohyama

发明人： Takashi Kasahara ,  Kenta Tsutsui ,  Hideaki Ohyama

IPC分类号： H02J7/00

CPC分类号： H01M10/44 ,  B60L3/0046 ,  B60L11/126 ,  B60L11/1859 ,  B60L11/1862 ,  B60L2210/40 ,  B60L2240/545 ,  B60L2240/547 ,  B60L2240/549 ,  B60L2240/80 ,  H01M10/24 ,  H01M10/4242 ,  H01M10/48 ,  H02J7/0029 ,  H02J2007/0037 ,  H02J2007/004 ,  Y02E60/124 ,  Y02T10/6217 ,  Y02T10/7005 ,  Y02T10/7044 ,  Y02T10/705 ,  Y02T10/7077 ,  Y02T10/7241

摘要： A charge/discharge control method for an alkaline storage battery (11) includes: obtaining in advance a coefficient (K) representing characteristics of a memory effect of the alkaline storage battery; causing the alkaline storage battery to perform a charge/discharge between a lower-limit depth-of-charge (SOCb), of which a depth-of-charge is set within a range of 10% to 30%, and an upper-limit depth-of-charge (S), of which a depth-of-charge is set within a range of 70% to 90%; calculating an additional charge electricity quantity (C) based on the coefficient (K), the upper-limit depth-of-charge (S), and a predetermined reference time (T); measuring a charging/discharging time during which the alkaline storage battery performs the charge/discharge; and performing a charge of the alkaline storage battery with the calculated additional charge electricity quantity added to the upper-limit depth-of-charge, each time when the measured charging/discharging time reaches the reference time.

摘要翻译： 碱性蓄电池（11）的充放电控制方法包括：预先获得表示碱性蓄电池的存储效果的特性的系数（K） 使碱性蓄电池在充电深度设定在10％〜30％的范围内的下限充电深度（SOCb）和上限值之间进行充电/放电 深度电荷（S），其中充电深度设定在70％至90％的范围内; 基于系数（K），上限充电深度（S）和预定参考时间（T）计算附加充电电量（C）; 测量碱性蓄电池进行充放电的充电/放电时间; 并且每当测量的充电/放电时间达到基准时间时，利用计算出的附加充电电量加到碱性蓄电池的电荷上。

公开(公告)号：US08318349B2

公开(公告)日：2012-11-27

申请号：US12518471

申请日：2008-08-29

申请人： Hideaki Ohyama ,  Kyoko Nakatsuji ,  Yoshitaka Dansui

发明人： Hideaki Ohyama ,  Kyoko Nakatsuji ,  Yoshitaka Dansui

IPC分类号： H01M4/58 ,  H01M10/26 ,  H01M4/00

CPC分类号： H01M10/345 ,  C22C19/03 ,  H01M4/242 ,  H01M4/383 ,  Y02E60/124

摘要： A negative electrode active material for a nickel-metal hydride battery of the present invention includes a hydrogen storage alloy, the hydrogen storage alloy containing La, Mg, Ni, Co, Al, and element M. The molar ratio y of Ni to the total of La and Mg is 2≦y≦3, the molar ratio z of Co to the total of La and Mg is 0.25≦z≦0.75, the molar ratio α of Al to the total of La and Mg is 0.01≦α≦0.05, and the molar ratio x of Mg to the total of La and Mg is 0.01≦x≦0.5. Element M represents at least one selected from the group consisting of Y and Sn, and the content of element M in the hydrogen storage alloy is 0.4 wt % or less.

摘要翻译： 本发明的镍氢电池用负极活性物质包括储氢合金，含有La，Mg，Ni，Co，Al和元素M的储氢合金.Ni与总量的摩尔比y 的La和Mg的摩尔比α为2＆nlE; y＆nlE; 3，Co与La和Mg的总量的摩尔比z为0.25＆nlE; z＆nlE; 0.75，Al与La和Mg的总量的摩尔比α为0.01＆nlE;α＆nlE ; 0.05，Mg与La和Mg总量的摩尔比x为0.01＆nlE; x＆nlE; 0.5。 元素M表示选自Y和Sn中的至少一种，并且储氢合金中元素M的含量为0.4重量％以下。

公开(公告)号：US20100221608A1

公开(公告)日：2010-09-02

申请号：US12063015

申请日：2006-09-14

申请人： Hideaki Ohyama ,  Kyoko Nakatsuji ,  Yoshitaka Dansui ,  Shinichi Orimo ,  Yuko Nakamori ,  Hai-Wen Li ,  Kazutaka Ikeda

发明人： Hideaki Ohyama ,  Kyoko Nakatsuji ,  Yoshitaka Dansui ,  Shinichi Orimo ,  Yuko Nakamori ,  Hai-Wen Li ,  Kazutaka Ikeda

IPC分类号： H01M4/58 ,  B22F1/02 ,  B22F9/00

CPC分类号： H01M4/383 ,  B22F1/0018 ,  B22F9/04 ,  B22F2009/041 ,  B22F2009/043 ,  B82Y25/00 ,  B82Y30/00 ,  C01B3/0057 ,  C22C1/00 ,  C22C1/0441 ,  C22C19/03 ,  C22C19/058 ,  C22C28/00 ,  H01F1/0045 ,  H01M4/02 ,  H01M4/385 ,  H01M4/463 ,  H01M10/345 ,  H01M2004/021 ,  Y02E60/124 ,  Y02E60/327 ,  Y02P70/54 ,  Y10T428/12181

摘要： An electrode alloy powder includes a hydrogen storage alloy and magnetic material clusters. The hydrogen storage alloy contains 20 to 70 wt % of Ni. The magnetic material clusters contain metal nickel, and have an average cluster size of 8 to 10 nm. A method for producing the electrode alloy powder includes an activation step of allowing a raw material powder including a hydrogen storage alloy to be in contact with an aqueous solution containing A wt % of sodium hydroxide and held at 100° C. or greater for B minutes. A and B satisfy 2410≦A×B≦2800.

摘要翻译： 电极合金粉末包括储氢合金和磁性材料簇。 储氢合金含有20〜70重量％的Ni。 磁性材料簇含有金属镍，平均簇尺寸为8〜10nm。 电极合金粉末的制造方法包括使包含储氢合金的原料粉末与含有A重量％的氢氧化钠的水溶液接触并保持在100℃以上B分钟的活化工序 。 A和B满足2410＆nlE; A×B＆nlE; 2800。

公开(公告)号：US09024589B2

公开(公告)日：2015-05-05

申请号：US13639832

申请日：2011-12-22

申请人： Takashi Kasahara ,  Kenta Tsutsui ,  Hideaki Ohyama

发明人： Takashi Kasahara ,  Kenta Tsutsui ,  Hideaki Ohyama

IPC分类号： H02J7/00 ,  H01M10/44 ,  B60L3/00 ,  B60L11/18 ,  H01M10/48 ,  B60L11/12 ,  H01M10/24 ,  H01M10/42

CPC分类号： H01M10/44 ,  B60L3/0046 ,  B60L11/126 ,  B60L11/1859 ,  B60L11/1862 ,  B60L2210/40 ,  B60L2240/545 ,  B60L2240/547 ,  B60L2240/549 ,  B60L2240/80 ,  H01M10/24 ,  H01M10/4242 ,  H01M10/48 ,  H02J7/0029 ,  H02J2007/0037 ,  H02J2007/004 ,  Y02E60/124 ,  Y02T10/6217 ,  Y02T10/7005 ,  Y02T10/7044 ,  Y02T10/705 ,  Y02T10/7077 ,  Y02T10/7241

摘要： A charge/discharge control method for an alkaline storage battery (11) includes: obtaining in advance a coefficient (K) representing characteristics of a memory effect of the alkaline storage battery; causing the alkaline storage battery to perform a charge/discharge between a lower-limit depth-of-charge (SOCb), of which a depth-of-charge is set within a range of 10% to 30%, and an upper-limit depth-of-charge (S), of which a depth-of-charge is set within a range of 70% to 90%; calculating an additional charge electricity quantity (C) based on the coefficient (K), the upper-limit depth-of-charge (S), and a predetermined reference time (T); measuring a charging/discharging time during which the alkaline storage battery performs the charge/discharge; and performing a charge of the alkaline storage battery with the calculated additional charge electricity quantity added to the upper-limit depth-of-charge, each time when the measured charging/discharging time reaches the reference time.

摘要翻译： 碱性蓄电池（11）的充放电控制方法包括：预先获得表示碱性蓄电池的存储效果的特性的系数（K） 使碱性蓄电池在充电深度设定在10％〜30％的范围内的下限充电深度（SOCb）和上限值之间进行充电/放电 深度电荷（S），其中充电深度设定在70％至90％的范围内; 基于系数（K），上限充电深度（S）和预定参考时间（T）计算附加充电电量（C）; 测量碱性蓄电池进行充放电的充电/放电时间; 并且每当测量的充电/放电时间达到基准时间时，利用计算出的附加充电电量加到碱性蓄电池的电荷上。

公开(公告)号：US08202650B2

公开(公告)日：2012-06-19

申请号：US12518607

申请日：2008-02-20

申请人： Hideaki Ohyama ,  Kyoko Nakatsuji ,  Susumu Kikuyama ,  Yoshitaka Dansui

发明人： Hideaki Ohyama ,  Kyoko Nakatsuji ,  Susumu Kikuyama ,  Yoshitaka Dansui

IPC分类号： H01M4/58

CPC分类号： C22C19/00 ,  B22F2009/041 ,  B22F2998/10 ,  C22C9/02 ,  H01M4/383 ,  H01M10/26 ,  H01M10/345 ,  H01M2300/0014 ,  B22F9/04 ,  B22F1/0059 ,  B22F1/02

摘要： A negative electrode material for a nickel-metal hydride battery containing a hydrogen-absorbing alloy represented by a general formula: Mm1-aT1aNixAlyMnzCobT2c, in which: Mm is at least one of light rare earth elements; T1 is at least one selected from the group consisting of Mg, Ca, Sr and Ba; T2 is at least one selected from the group consisting of Sn, Cu and Fe; and 0.015≦a≦0.5, 2.5≦x≦4.5, 0.05≦y+z≦2, 0≦b≦0.6, 0≦c≦0.6 and 5.6≦x+y+z+b+c≦6 are satisfied.

摘要翻译： 一种含有由以下通式表示的吸氢合金的镍氢电池用负极材料：Mm1-aT1aNixAlyMnzCobT2c，其中：Mm为轻稀土元素中的至少一种; T1是选自Mg，Ca，Sr和Ba中的至少一种; T2是选自Sn，Cu和Fe中的至少一种; 和0.015＆nlE; x + y + z + b + c＆nlE; 6,0和nlE; x + 满意

公开(公告)号：US20100028774A1

公开(公告)日：2010-02-04

申请号：US12518607

申请日：2008-02-20

申请人： Hideaki Ohyama ,  Kyoko Nakatsuji ,  Susumu Kikuyama ,  Yoshitaka Dansui

发明人： Hideaki Ohyama ,  Kyoko Nakatsuji ,  Susumu Kikuyama ,  Yoshitaka Dansui

IPC分类号： H01M4/38 ,  H01M10/26 ,  H01M10/30 ,  H01B1/02

CPC分类号： C22C19/00 ,  B22F2009/041 ,  B22F2998/10 ,  C22C9/02 ,  H01M4/383 ,  H01M10/26 ,  H01M10/345 ,  H01M2300/0014 ,  B22F9/04 ,  B22F1/0059 ,  B22F1/02

摘要： A negative electrode material for a nickel-metal hydride battery containing a hydrogen-absorbing alloy represented by a general formula: Mm1-aT1aNixAlyMnzCobT2c, in which: Mm is at least one of light rare earth elements; T1 is at least one selected from the group consisting of Mg, Ca, Sr and Ba; T2 is at least one selected from the group consisting of Sn, Cu and Fe; and 0.015≦a≦0.5, 2.5≦x≦4.5, 0.05≦y+z≦2, 0≦b≦0.6, 0≦c≦0.6 and 5.6≦x+y+z+b+c≦6 are satisfied.

摘要翻译： 一种含有由以下通式表示的吸氢合金的镍氢电池用负极材料：Mm1-aT1aNixAlyMnzCobT2c，其中：Mm为轻稀土元素中的至少一种; T1是选自Mg，Ca，Sr和Ba中的至少一种; T2是选自Sn，Cu和Fe中的至少一种; 和0.015 <= a <= 0.5,2.5 <= x <= 4.5,0.05 <= y + z <= 2,0 <= b <= 0.6,0 <= c <= 0.6和5.6 <= x + y + z + b + c <= 6。

公开(公告)号：US20060147800A1

公开(公告)日：2006-07-06

申请号：US10545760

申请日：2004-05-21

申请人： Toshitada Sato ,  Harunari Shimamura ,  Hideaki Ohyama ,  Yasuhiko Bito

发明人： Toshitada Sato ,  Harunari Shimamura ,  Hideaki Ohyama ,  Yasuhiko Bito

IPC分类号： H01M4/58 ,  H01M4/62 ,  H01M4/66

CPC分类号： H01M10/052 ,  H01M4/134 ,  H01M4/1395 ,  H01M4/362 ,  H01M4/38 ,  H01M4/386 ,  H01M4/387 ,  H01M4/621 ,  Y10T29/49115

摘要： A nonaqueous electrolyte secondary battery with excellent charging/discharging cycle characteristics is provided, more specifically a nonaqueous electrolyte secondary battery in which deterioration of the conductivity of a negative electrode due to charging/discharging cycle is suppressed and a method for manufacturing the same are provided. The nonaqueous electrolyte secondary battery includes: a positive electrode and a negative electrode that are capable of reversibly absorbing and desorbing Li ions; and a nonaqueous electrolyte having lithium ion conductivity. The negative electrode includes a collector and active material particles that are disposed on a surface of the collector. The active material particles include Si and at least one element R selected from the group consisting of Sn, In, Ga, Pb and Bi. Metallic bond including the element R is formed between the active material particles.

公开(公告)号：US20110033748A1

公开(公告)日：2011-02-10

申请号：US12673903

申请日：2009-04-30

申请人： Kyoko Nakatsuji ,  Hideaki Ohyama

发明人： Kyoko Nakatsuji ,  Hideaki Ohyama

IPC分类号： H01M4/58 ,  B01J20/02 ,  H01F1/04

CPC分类号： H01M4/242 ,  B22F1/0088 ,  C22C1/0408 ,  C22C1/0433 ,  C22C19/03 ,  C22C23/00 ,  C22C2202/02 ,  C22C2202/04 ,  H01M4/383 ,  H01M10/345 ,  Y02E60/124

摘要： Provided is a hydrogen occluding alloy powder having an ideally activated surface state where oxide and hydroxide precipitated on the surface of said powder have been removed quickly with a simple means. The method for surface treating a hydrogen occluding alloy powder involves agitating a hydrogen occluding alloy powder containing Ni and Mg with an Ni content from 35 to 60 wt % in a lithium hydroxide aqueous solution (first process). Then the hydrogen occluding alloy powder is agitated in an alkali metal hydroxide aqueous solution containing at least either one of sodium hydroxide and potassium hydroxide (second process).

摘要翻译： 提供了具有理想的活化表面状态的氢吸留合金粉末，其中以简单的方法快速去除了在所述粉末的表面上沉淀的氧化物和氢氧化物。 含氢合金粉末的表面处理方法包括在氢氧化锂水溶液中搅拌含有Ni含量为35〜60重量％的Ni和Mg的吸氢合金粉末（第一工序）。 然后在含有氢氧化钠和氢氧化钾中的至少一种的碱金属氢氧化物水溶液中搅拌吸氢合金粉末（第二工序）。

公开(公告)号：US20100009259A1

公开(公告)日：2010-01-14

申请号：US12518471

申请日：2008-08-29

申请人： Hideaki Ohyama ,  Kyoko Nakatsuji ,  Yoshitaka Dansui

发明人： Hideaki Ohyama ,  Kyoko Nakatsuji ,  Yoshitaka Dansui

IPC分类号： H01M4/58 ,  H01M4/88

CPC分类号： H01M10/345 ,  C22C19/03 ,  H01M4/242 ,  H01M4/383 ,  Y02E60/124

摘要： A negative electrode active material for a nickel-metal hydride battery of the present invention includes a hydrogen storage alloy, the hydrogen storage alloy containing La, Mg, Ni, Co, Al, and element M. The molar ratio y of Ni to the total of La and Mg is 2≦y≦3, the molar ratio z of Co to the total of La and Mg is 0.25≦z≦0.75, the molar ratio α of Al to the total of La and Mg is 0.01≦α≦0.05, and the molar ratio x of Mg to the total of La and Mg is 0.01≦x≦0.5. Element M represents at least one selected from the group consisting of Y and Sn, and the content of element M in the hydrogen storage alloy is 0.4 wt % or less.

摘要翻译： 本发明的镍氢电池用负极活性物质包括储氢合金，含有La，Mg，Ni，Co，Al和元素M的储氢合金.Ni与总量的摩尔比y 的La和Mg为2 <= y <= 3，Co与La和Mg的总量的摩尔比z z为0.25≤z≤0.75，Al与La和Mg的总量的摩尔比α为0.01 α=α<0.05，Mg与La和Mg总量的摩尔比x为0.01≤x≤0.5。 元素M表示选自Y和Sn中的至少一种，并且储氢合金中元素M的含量为0.4重量％以下。

公开(公告)号：US08137839B2

公开(公告)日：2012-03-20

申请号：US12063015

申请日：2006-09-14

申请人： Hideaki Ohyama ,  Kyoko Nakatsuji ,  Yoshitaka Dansui ,  Shinichi Orimo ,  Yuko Nakamori ,  Hai-Wen Li ,  Kazutaka Ikeda

发明人： Hideaki Ohyama ,  Kyoko Nakatsuji ,  Yoshitaka Dansui ,  Shinichi Orimo ,  Yuko Nakamori ,  Hai-Wen Li ,  Kazutaka Ikeda

IPC分类号： H01M4/58 ,  C22C19/03 ,  B22F9/16

CPC分类号： H01M4/383 ,  B22F1/0018 ,  B22F9/04 ,  B22F2009/041 ,  B22F2009/043 ,  B82Y25/00 ,  B82Y30/00 ,  C01B3/0057 ,  C22C1/00 ,  C22C1/0441 ,  C22C19/03 ,  C22C19/058 ,  C22C28/00 ,  H01F1/0045 ,  H01M4/02 ,  H01M4/385 ,  H01M4/463 ,  H01M10/345 ,  H01M2004/021 ,  Y02E60/124 ,  Y02E60/327 ,  Y02P70/54 ,  Y10T428/12181

摘要： An electrode alloy powder includes a hydrogen storage alloy and magnetic material clusters. The hydrogen storage alloy contains 20 to 70 wt % of Ni. The magnetic material clusters contain metal nickel, and have an average cluster size of 8 to 10 nm. A method for producing the electrode alloy powder includes an activation step of allowing a raw material powder including a hydrogen storage alloy to be in contact with an aqueous solution containing A wt % of sodium hydroxide and held at 100° C. or greater for B minutes. A and B satisfy 2410≦A×B≦2800.

摘要翻译： 电极合金粉末包括储氢合金和磁性材料簇。 储氢合金含有20〜70重量％的Ni。 磁性材料簇含有金属镍，平均簇尺寸为8〜10nm。 电极合金粉末的制造方法包括使包含储氢合金的原料粉末与含有A重量％的氢氧化钠的水溶液接触并保持在100℃以上B分钟的活化工序 。 A和B满足2410＆nlE; A×B＆nlE; 2800。