公开(公告)号：US20100285234A1

公开(公告)日：2010-11-11

申请号：US12308355

申请日：2007-06-20

申请人： Keimpe Jan Van Den Berg ,  Josephus Christiaan Van Oorschot ,  Edith Benningshof-Hulsbos ,  Jan Cornelis Van Beelen

发明人： Keimpe Jan Van Den Berg ,  Josephus Christiaan Van Oorschot ,  Edith Benningshof-Hulsbos ,  Jan Cornelis Van Beelen

IPC分类号： B05D3/06 ,  C08G18/24

CPC分类号： C08G18/4208 ,  C08G18/242 ,  C08G18/423 ,  C08G18/792 ,  C09D175/04 ,  C09D175/06

摘要： The invention relates to an actinic radiation-curable coating composition comprising a compound having at least two isocyanate groups, a compound having at least two hydroxyl groups, and a photolatent catalyst for the isocyanate-hydroxyl addition reaction, wherein the photolatent catalyst is an organic metal compound comprising a latent catalytically active metal, and wherein the latent catalytically active metal atom in the organic metal compound has no bonds to other metal atoms. The invention further relates to a process for forming a coating on a substrate.

摘要翻译： 本发明涉及一种光化辐射固化涂料组合物，其包含具有至少两个异氰酸酯基团的化合物，具有至少两个羟基的化合物和用于异氰酸酯 - 羟基加成反应的光致变色催化剂，其中光吸收催化剂是有机金属 化合物，其包含潜催化活性金属，并且其中所述有机金属化合物中的潜催化活性金属原子与其它金属原子没有键。 本发明还涉及在基材上形成涂层的方法。

公开(公告)号：US07045579B2

公开(公告)日：2006-05-16

申请号：US10383600

申请日：2003-03-07

申请人： Keimpe Jan Van Den Berg ,  Klaus Hobel ,  Josephus Christiaan Van Oorschot ,  Marcel Johannes Antonius Mensink ,  Kenny Abdoel Nassier Raghosing ,  Edith Hulsbos

发明人： Keimpe Jan Van Den Berg ,  Klaus Hobel ,  Josephus Christiaan Van Oorschot ,  Marcel Johannes Antonius Mensink ,  Kenny Abdoel Nassier Raghosing ,  Edith Hulsbos

IPC分类号： C09D129/14 ,  C09D201/06 ,  C09D175/04 ,  C08K5/37

CPC分类号： C09D175/04 ,  C07C237/08 ,  C07C271/16 ,  C08G18/0866 ,  C08G18/12 ,  C08G18/283 ,  C08G18/3819 ,  C08G18/4036 ,  C08G18/423 ,  C08G18/8108 ,  C08G18/834 ,  C08K5/37 ,  C08K5/372 ,  C08L31/02 ,  C08L75/04 ,  C09D129/14 ,  C09D175/10 ,  Y10T428/28 ,  C08G18/3876 ,  C08G18/3271 ,  C08L57/04 ,  C08L2666/20 ,  C08L2666/04 ,  C08L75/10

摘要： The invention relates to a coating composition comprising an acetal-functional binder and a thiol-functional cross-linker, wherein the acetal-functional binder is represented by the following formula wherein P is a binder backbone, K is a divalent and/or trivalent organic moiety having 1 to 30 carbon atoms and having one or two links to the binder backbone, A is selected from oxygen, sulphur, and NRVII, wherein RVII is hydrogen or an alkyl group with 1 to 4 carbon atoms, m is an integer from 1 to 50, n is an integer from 1 to 10, and R and R′ may be the same or different and represent alkyl groups with 1 to 4 carbon atoms. In a further aspect, the invention relates to acetal-functional binders, acetal-functional monomers, a process for the preparation of said monomers, coating compositions comprising said acetal-functional binders, and to a process for the preparation of a coating composition comprising an acetal-functional polyurethane dispersion and a thiol-functional cross-linker.

摘要翻译： 本发明涉及包含缩醛官能粘合剂和硫醇官能交联剂的涂料组合物，其中缩醛官能粘合剂由下式表示：其中P是粘合剂主链，K是二价和/或三价有机物 具有1至30个碳原子并且具有一个或两个连接到粘合剂主链的部分，A选自氧，硫和NR VII，其中R VII是氢或 具有1至4个碳原子的烷基，m为1至50的整数，n为1至10的整数，R和R'可以相同或不同，表示具有1至4个碳原子的烷基。 在另一方面，本发明涉及缩醛官能的粘合剂，缩醛官能单体，制备所述单体的方法，包含所述缩醛官能粘合剂的涂料组合物，以及制备涂料组合物的方法，所述涂料组合物包含 缩醛官能聚氨酯分散体和硫醇功能交联剂。

公开(公告)号：US06297329B1

公开(公告)日：2001-10-02

申请号：US08804485

申请日：1997-02-21

申请人： Keimpe Jan van den Berg ,  Klaus Hobel ,  Huig Klinkenberg ,  Arie Noomen ,  Josephus Christiaan van Oorschot

发明人： Keimpe Jan van den Berg ,  Klaus Hobel ,  Huig Klinkenberg ,  Arie Noomen ,  Josephus Christiaan van Oorschot

IPC分类号： C08G6502

CPC分类号： C07D493/08 ,  C07D305/06 ,  C07D493/10 ,  C08G18/30 ,  C08G63/916 ,  C08G85/00 ,  C09D161/28 ,  Y10T428/31551

摘要： The invention pertains to a coating composition comprising a first compound comprising at least one bicyclo- or spiro-orthoester group and a second compound comprising at least two hydroxyl-reactive groups. The invention also comprises a process for curing the present coating composition. More particularly, the latent hydroxyl groups of the bicyclo- or spiro-orthoester groups have to be deblocked and reacted with the hydroxyl-reactive groups of the second compound if the present coating composition is to be cured. Further, a process for making bicyclo-orthoester compounds from the corresponding oxetane compound is described, as are polymers comprising at least one bicyclo- or spiro-orthoester group.

摘要翻译： 本发明涉及涂料组合物，其包含包含至少一种双环或螺 - 原酸酯基团的第一化合物和包含至少两个羟基反应性基团的第二化合物。 本发明还包括用于固化本涂料组合物的方法。 更具体地说，如果本发明的涂料组合物要固化，则双环或螺 - 原酸酯基团的潜在羟基必须被解封和与第二化合物的羟基反应性基团反应。 此外，描述了从相应的氧杂环丁烷化合物制备双环原酸酯化合物的方法，以及包含至少一种双环或螺 - 原酸酯基团的聚合物。

公开(公告)号：US06867244B2

公开(公告)日：2005-03-15

申请号：US10423542

申请日：2003-04-25

申请人： Huig Klinkenberg ,  Josephus Christiaan Van Oorschot

发明人： Huig Klinkenberg ,  Josephus Christiaan Van Oorschot

IPC分类号： C08F2/46 ,  C08G18/22 ,  C08G18/38 ,  C08G18/46 ,  C08G18/79 ,  C08K5/00 ,  C09D5/00 ,  C09D175/04 ,  C08J7/04

CPC分类号： C09D175/04 ,  C08G18/222 ,  C08G18/3876 ,  C08G18/4676 ,  C08G18/792 ,  C08K5/0008 ,  Y10T428/31551 ,  Y10T428/31605 ,  Y10T428/31678 ,  C08L75/04

摘要： Photoactivatable coating composition comprising at least one photoinitiator and a base-catalysed polymerisable or curable organic material comprising at least one polyisocyanate and at least one compound containing isocyanate reactive groups, wherein the isocyanate reactive groups comprise at least one thiol group and the photoinitiator is a photolatent base.Preference is given to a coating composition wherein the photolatent base is selected from the group of N-substituted 4-(ortho-nitrophenyl)dihydropyridine, a quaternary organo-boron photoinitiator, and an α-amino acetophenone. The composition additionally may comprise an organic acid, a metal complex and/or a metal salt as a cocatalyst and/or a sensitiser selected from the group of thioxanthones, oxazines, rhodamines, and preferably from the group of benzophenone and derivatives thereof.

摘要翻译： 包含至少一种光引发剂和碱催化的可聚合或可固化的有机材料的可光活化涂料组合物，其包含至少一种多异氰酸酯和至少一种含有异氰酸酯反应性基团的化合物，其中异氰酸酯反应性基团包含至少一个硫醇基团，光引发剂是光引发剂 优选一种涂料组合物，其中光潜碱选自N-取代的4-（邻硝基苯基）二氢吡啶，季有机硼光引发剂和α-氨基苯乙酮。 组合物另外可以包含有机酸，金属络合物和/或金属盐作为助催化剂和/或敏化剂，选自噻吨酮，恶唑，罗丹明，优选二苯甲酮及其衍生物。

公开(公告)号：US06765056B2

公开(公告)日：2004-07-20

申请号：US09928616

申请日：2001-08-13

申请人： Klaus Hobel ,  Josephus Christiaan Van Oorschot ,  Keimpe Jan Van Den Berg

发明人： Klaus Hobel ,  Josephus Christiaan Van Oorschot ,  Keimpe Jan Van Den Berg

IPC分类号： C08L7510

CPC分类号： C08G18/83 ,  C08G18/0823 ,  C08G18/2815 ,  C08G18/6625 ,  C08G18/725 ,  C08G18/84 ,  C09D175/04

摘要： The aqueous-based cross-linkable binder composition comprising (A) an aqueous dispersion of an aldehyde-functional polyurethane having a number average molecular weight of more than 1,000 and an average aldehyde functionality of ≧2, which polyurethane comprises ionic and/or non-ionic dispersing groups, and (B) a low-molecular weight aldehyde-reactive cross-linker selected from the group of low-molecular weight polyamines and low-molecular weight compounds comprising at least one group of one of the formulae E1—CHR1—E2 and H—C—(E1E2E3), wherein —E1, —E2 and —E3 are independently chosen from electron-withdrawing groups such as —P(═O)—O—, —CO—, —CN, —SO2—, —NO2 and wherein R1 has the meaning of hydrogen or a hydrocarbon radical having 1 to 10 carbon atoms. Preference is given to a coating composition wherein the ionic dispersing group is an anionic dispersing group selected from the group of carboxylate, sulphonate and/or phosph(on)ate salt groups, and/or wherein for the nonionic dispersing group use is made of a C1-C4 alkoxy poly C2-C3 alkylene-oxide group in an amount between 2.5 and 20 wt. %, based on the polyurethane.

摘要翻译： 所述水性可交联粘合剂组合物包含（A）数均分子量大于1,000且平均醛官能度> = 2的醛官能聚氨酯的水分散体，该聚氨酯包含离子和/或非 - - 离子分散基团，和（B）低分子量醛 - 反应性交联剂，其选自低分子量多胺和低分子量化合物，其包含至少一个式E 1之一 -CHR 1 -E 2和HC-（E 1 E 2 E 3），其中-E 1，-E 2和-E 3独立地选自 吸电子基团如-P（= O）-O-，-CO-，-CN，-SO 2 - ， - NO 2，其中R 1具有氢或具有1-10个碳原子的烃基 优选一种涂料组合物，其中离子分散基团是选自羧酸盐，磺酸盐和/或磷酸（酯）盐基团的阴离子分散基团，和/或其中 非离子分散组使用的量为2.5至20重量％的C 1 -C 4烷氧基聚C 2 -C 3亚烷基氧基。 ％，基于聚氨酯。

公开(公告)号：US07015298B2

公开(公告)日：2006-03-21

申请号：US10671511

申请日：2003-09-29

申请人： Keimpe Jan Van Den Berg ,  Klaus Hobel ,  Josephus Christiaan Van Oorschot ,  Jan Cornelis Van Beelen ,  Huig Klinkenberg

发明人： Keimpe Jan Van Den Berg ,  Klaus Hobel ,  Josephus Christiaan Van Oorschot ,  Jan Cornelis Van Beelen ,  Huig Klinkenberg

IPC分类号： C08G77/00

CPC分类号： C09D175/04 ,  C08G18/3893 ,  C08G18/792

摘要： The invention pertains to a coating composition comprising a compound comprising at least one spiro-ortho silicate group and a hydroxyl-reactive cross-linker, to a process for curing the composition, and to the use of the composition. The coating composition of the current invention can be formulated to a coating composition having a low content of volatile organic solvents, is curable at a temperature as low as 5° C., and the cured coating composition of the current invention is essentially free of unreacted low-molecular weight blocking agents. Further, the pot life: drying time ratio of coating compositions according to the invention is particularly favorable.

摘要翻译： 本发明涉及包含至少一种螺 - 原硅酸盐基团和羟基 - 反应性交联剂的化合物，用于固化该组合物的方法以及该组合物的用途的涂料组合物。 本发明的涂料组合物可以配制成具有低含量挥发性有机溶剂的涂料组合物，可在低至5℃的温度下固化，本发明的固化涂料组合物基本上不含未反应 低分子量封闭剂。 此外，本发明的涂料组合物的适用期：干燥时间比是特别有利的。

公开(公告)号：US06593479B2

公开(公告)日：2003-07-15

申请号：US09935308

申请日：2001-08-22

申请人： Keimpe Jan van den Berg ,  Klaus Hobel ,  Huig Klinkenberg ,  Arie Noomen ,  Josephus Christiaan van Oorschot

发明人： Keimpe Jan van den Berg ,  Klaus Hobel ,  Huig Klinkenberg ,  Arie Noomen ,  Josephus Christiaan van Oorschot

IPC分类号： C07D31914

CPC分类号： C07D493/08 ,  C07D305/06 ,  C07D493/10 ,  C08G18/30 ,  C08G63/916 ,  C08G85/00 ,  C09D161/28 ,  Y10T428/31551

摘要： The invention pertains to a coating composition comprising a first compound comprising at least one bicyclo- or spiro-orthoester group and a second compound comprising at least two hydroxyl-reactive groups. The invention also comprises a process for curing the present coating composition. More particularly, the latent hydroxyl groups of the bicyclo- or spiro-orthoester groups have to be deblocked and reacted with the hydroxyl-reactive groups of the second compound if the present coating composition is to be cured. Further, a process for making bicyclo-orthoester compounds from the corresponding oxetane compound is described, as are polymers comprising at least one bicyclo- or spiro-orthoester group.

公开(公告)号：US06579913B2

公开(公告)日：2003-06-17

申请号：US09865025

申请日：2001-05-24

申请人： Huig Klinkenberg ,  Josephus Christiaan Van Oorschot

发明人： Huig Klinkenberg ,  Josephus Christiaan Van Oorschot

IPC分类号： C08J328

CPC分类号： C09D175/04 ,  C08G18/222 ,  C08G18/3876 ,  C08G18/4676 ,  C08G18/792 ,  C08K5/0008 ,  Y10T428/31551 ,  Y10T428/31605 ,  Y10T428/31678 ,  C08L75/04

摘要： Photoactivatable coating composition comprising at least one photoinitiator and a base-catalysed polymerisable or curable organic material comprising at least one polyisocyanate and at least one compound containing isocyanate reactive groups, wherein the isocyanate reactive groups comprise at least one thiol group and the photoinitiator is a photolatent base. Preference is given to a coating composition wherein the photolatent base is selected from the group of N-substituted 4-(ortho-nitrophenyl) dihydropyridine, a quaternary organo-boron photoinitiator, and an &agr;-amino acetophenone. The composition additionally may comprise an organic acid, a metal complex and/or a metal salt as a cocatalyst and/or a sensitiser selected from the group of thioxanthones, oxazines, rhodamines, and preferably from the group of benzo-phenone and derivatives thereof.

摘要翻译： 包含至少一种光引发剂和碱催化的可聚合或可固化的有机材料的可光活化涂料组合物，其包含至少一种多异氰酸酯和至少一种含有异氰酸酯反应性基团的化合物，其中异氰酸酯反应性基团包含至少一个硫醇基团，光引发剂是光引发剂 基础。 优选涂料组合物，其中光潜碱选自N-取代的4-（邻硝基苯基）二氢吡啶，季有机 - 硼光引发剂和α-氨基苯乙酮。 组合物另外可以包含有机酸，金属络合物和/或金属盐作为助催化剂和/或敏化剂，其选自噻吨酮，恶唑，罗丹明，优选苯并菲酮及其衍生物。

公开(公告)号：US6015864A

公开(公告)日：2000-01-18

申请号：US83074

申请日：1998-05-21

申请人： Martinus Adrianus Anthonius Maria Koenraadt ,  Arie Noomen ,  Keimpe Jan Van Den Berg ,  Josephus Christiaan Van Oorschot ,  Huig Klinkenberg

发明人： Martinus Adrianus Anthonius Maria Koenraadt ,  Arie Noomen ,  Keimpe Jan Van Den Berg ,  Josephus Christiaan Van Oorschot ,  Huig Klinkenberg

IPC分类号： C09D5/03 ,  C09D167/00 ,  C08C19/30

CPC分类号： C09D5/03 ,  C09D167/00

摘要： Proposed is a thermosetting powder coating composition comprising a mixture of particles reactive towards one another, optionally in combination with a catalyst, with a portion of the reactive particles comprising a polymer reactive towards oxetane groups while another portion comprises an oxetane groups-containing cross-linking agent having an oxetane functionality of more than 1. The quantity of oxetane oxygen in the cross-linking agent preferably is at least 0.4 wt. %. The reactive polymer preferably is a polymer having groups reactive towards oxetane, such as carboxyl, epoxy, oxetane, anhydride, and hydroxyl, with preference being given to a polyester or a hydroxypolyacrylate.

摘要翻译： 提出了一种热固性粉末涂料组合物，其包含彼此反应的颗粒的混合物，任选地与催化剂组合，一部分反应性颗粒包含对氧杂环丁烷基团具有反应性的聚合物，而另一部分包含含氧杂环丁烷基团的交联 氧杂环丁烷官能度大于1.交联剂中氧杂环丁烷氧的量优选为至少0.4wt。 ％。 反应性聚合物优选是具有与氧杂环丁烷反应的基团的聚合物，例如羧基，环氧基，氧杂环丁烷，酸酐和羟基，优选给予聚酯或羟基聚丙烯酸酯。