摘要:
Disclosed is a pressure-sensitive adhesive sheet having a transparent film substrate and, on at least one side thereof, an acrylic pressure-sensitive adhesive layer. The transparent film substrate has a top coat layer having a specific configuration with an average thickness and a thickness variation being controlled. The acrylic pressure-sensitive adhesive layer is formed from a water-dispersible acrylic pressure-sensitive adhesive composition. The composition contains, as components, an acrylic emulsion polymer derived from constitutive monomers in a specific formulation; and a polypropylene glycol (PPG)/polyethylene glycol (PEG) block copolymer having a specific structure, or a derivative of the copolymer. The pressure-sensitive adhesive sheet is found to be highly resistant to scratches and static electrification and to have superior visual quality and satisfactory resistance to adhesive strength increase.
摘要:
Provided is a water-dispersible acrylic pressure-sensitive adhesive composition capable of forming a removable pressure-sensitive adhesive layer which has satisfactory resistance to increase in adhesive strength and a good appearance and less causes staining on an adherend. The removable water-dispersible acrylic pressure-sensitive adhesive composition includes an acrylic emulsion polymer (A) formed from constitutive monomers essentially including 70 to 99.5 percent by weight of a (meth)acrylic alkyl ester and 0.5 to 10 percent by weight of a carboxyl-containing unsaturated monomer based on the total amount of the constitutive monomers; a water-insoluble crosslinking agent (B); an acetylenic diol compound (C); and a specific polyether defoaming agent (D). The acetylenic diol compound (C) has an HLB of less than 13, and the polyether defoaming agent (D) has a PO in a content of from 70 to 100 percent by weight and a number-average molecular weight of from 1200 to 4000.
摘要:
The pressure-sensitive adhesive sheet includes a transparent film substrate; and, on at least one side thereof, an acrylic pressure-sensitive adhesive layer. The transparent film substrate includes a base layer including a resinous material and a top coat layer on a first face of the base layer. The top coat layer is formed from a polythiophene, an acrylic resin, and a melamine crosslinking agent and has an average thickness Dave of 2 to 50 nm and a thickness variation ΔD of 40% or less. The acrylic pressure-sensitive adhesive layer is formed from a water-dispersible removable acrylic pressure-sensitive adhesive composition including an acrylic emulsion polymer.
摘要:
Disclosed is a pressure-sensitive adhesive sheet that has a transparent film substrate and, on at least one side thereof, an acrylic pressure-sensitive adhesive layer. The transparent film substrate has a top coat layer having a specific configuration with an average thickness and a thickness variation being controlled. The acrylic pressure-sensitive adhesive layer is formed from a water-dispersible acrylic pressure-sensitive adhesive composition. The composition includes, as components, an acrylic emulsion polymer derived from constitutive monomers in a specific formulation; a polyether compound having a specific structure; and a specific acetylenic diol. The pressure-sensitive adhesive sheet is found to be highly resistant to scratches and static electrification, to have superior visual quality and satisfactory resistance to adhesive strength increase, and to less cause stains.
摘要:
Provided is a water-dispersible acrylic pressure-sensitive adhesive composition capable of forming a pressure-sensitive adhesive layer which is resistant to increase in adhesive strength with time, has a good appearance, and less stains an adherend. The water-dispersible acrylic pressure-sensitive adhesive composition includes an acrylic emulsion polymer; and a water-insoluble crosslinking agent having two or more carboxyl-reactive functional groups per molecule. The acrylic emulsion polymer is formed from constitutive monomers essentially including a (meth)acrylic alkyl ester (A), a carboxyl-containing unsaturated monomer (B), and at least one monomer (C) selected from methyl methacrylate, vinyl acetate, and diethylacrylamide and has a solvent-insoluble content of 70 percent by weight or more. When the acrylic pressure-sensitive adhesive composition is applied so as to have a dry thickness of 50 μm, dried at 120° C. for 2 minutes, and aged at 50° C. for 3 days to give a cross-linked acrylic pressure-sensitive adhesive film, the film has a solvent-insoluble content of 90 percent by weight or more and an elongation at break of 130% or less at 23° C.
摘要:
Provided are a water-dispersible acrylic pressure-sensitive adhesive composition capable of forming a pressure-sensitive adhesive layer which has excellent resistance to increase in adhesive strength and a good appearance and less causes staining; and a pressure-sensitive adhesive sheet having a pressure-sensitive adhesive layer formed from the pressure-sensitive adhesive composition. The water-dispersible acrylic pressure-sensitive adhesive composition includes an acrylic emulsion polymer (A) formed from constitutive monomers essentially containing 70 to 99.5 percent by weight of a (meth)acrylic alkyl ester and 0.5 to 10 percent by weight of a carboxyl-containing unsaturated monomer; and a compound (B) represented by following Formula (I): R1O-(PO)a-(EO)b-(PO)c-R2 (I) wherein R1 and R2 each represent a linear or branched chain alkyl group or hydrogen atom; PO represents oxypropylene group; EO represents oxyethylene group; and “a,” “b,” and “c” are each a positive integer, where EO and POs are added in a block manner.
摘要:
A removable water-dispersible acrylic pressure-sensitive adhesive composition according to the present invention includes an acrylic emulsion polymer (A), a water-insoluble crosslinking agent (B), and a carboxylic-acid-containing acrylic polymer (C). The polymer (A) includes a (meth) acrylic alkyl ester and a carboxyl-containing unsaturated monomer as essential constitutive monomers and has a content of the (meth) acrylic alkyl ester of 70 to 99.5 percent by weight and a content of the carboxyl-containing unsaturated monomer of 0.5 to 10 percent by weight, each based on the total amount of constitutive monomers. The polymer (C) includes (meth) acrylic acid as an essential constitutive monomer and has a total content of acrylic acid and methacrylic acid of 11 percent by weight or more based on the total amount of constitutive monomers.
摘要:
An inexpensive surface-protective film which is excellent in the ability to protect an adherend (in particular, optical sheet). With the surface-protective film (pressure-sensitive adhesive sheet) adherent to an adherend (in particular, optical sheet), an inspection of the adherend for defects can be made with satisfactory precision. Also provided is an inexpensive surface-protective film which prevents an adherend (in particular, optical member such as optical sheet) from being electrostatically charged during the processing or transportation of the adherend (in particular, optical sheet), and has the function of preventing fouling. The protective films each is a removable pressure-sensitive adhesive sheet which comprises a base layer, a pressure-sensitive adhesive layer formed on one side thereof, and an antistatic layer formed on the other side, characterized in that the antistatic layer contains a polymeric antistatic agent comprising an olefin block and a hydrophilic block.
摘要:
The present invention provides a pressure-sensitive adhesive composition which is excellent in removability, peel adhesive power temporal stability and staining properties; a pressure-sensitive adhesive layer produced with the same; and a pressure-sensitive adhesive sheet. The present invention also provides a pressure-sensitive adhesive composition which can prevent electrification of a non-antistatic protected adherend when peeled off using an ionic compound which is an antistatic agent, and is less likely to cause lifting and is also excellent in removability; a pressure-sensitive adhesive layer produced with the same; and a pressure-sensitive adhesive sheet.
摘要:
A removable water-dispersible acrylic pressure-sensitive adhesive composition according to the present invention includes an acrylic emulsion polymer (A) including, as essential constitutive monomers, a (meth)acrylic alkyl ester in a content of 70 to 99.5 percent by weight, and a carboxyl-containing unsaturated monomer in a content of 0.5 to 10 percent by weight, each based on the total amount of constitutive monomers; a water-insoluble crosslinking agent (B); an acetylenic diol compound (C); and a compound (D) represented by chemical formula [RaO—(PO)1-(EO)m—(PO)n—Rb]. The acetylenic diol compound (C) has a HLB value of less than 13.