公开(公告)号：US09608287B2

公开(公告)日：2017-03-28

申请号：US14113722

申请日：2012-04-25

申请人： Koji Abe ,  Shoji Shikita

发明人： Koji Abe ,  Shoji Shikita

IPC分类号： H01M10/056 ,  C07D327/04 ,  C07D327/06 ,  H01M10/0567 ,  H01M10/0525

CPC分类号： H01M10/056 ,  C07D327/04 ,  C07D327/06 ,  H01M10/0525 ,  H01M10/0567 ,  Y02T10/7011

摘要： An object of the present invention is to provide a nonaqueous electrolytic solution capable of improving electrochemical characteristics in a broad temperature range, an energy storage device using it.A nonaqueous electrolytic solution of an electrolyte salt dissolved in a nonaqueous solvent, which comprises at least one cyclic sulfonic acid ester compound represented by the following general formula (I), and an energy storage device. (wherein R1 and R2 may be the same or different, each representing a hydrogen atom, an alkyl group in which at least one hydrogen atom may be substituted with a halogen atom, orahalogenatom; L represents a divalent hydrocarbon group of an alkylene group in which at least one hydrogen atom is substituted with OR3, or a divalent hydrocarbon group of an alkylene group in which at least one methylene (CH2) is substituted with C(═O); R3 represents a formyl group, an alkylcarbonyl group, an alkenylcarbonyl group, an alkynylcarbonyl group, an arylcarbonyl group, an alkoxycarbonyl group, an alkenyloxycarbonyl group, an alkynyloxycarbonyl group, an aryloxycarbonyl group, a 2,2-dioxide-1,2-oxathiolan-4-yloxycarbonyl group, a 2,2-dioxide-1,2-oxathian-4-yloxycarbonyl group, an alkanesulfonyl group, an arylsulfonyl group, a dialkylphosphoryl group, an alkoxy(alkyl)phosphoryl group, a dialkoxyphosphoryl group, —S(O)—OR4, or —C(O)CH2P(O)(OR5)2; R4 represents an alkyl group, a 2,2-dioxide-1,2-oxathiolan-4-yl group, or a 2,2-dioxide-1,2-oxathian-4-yl group; R5 represents an alkyl group; further, in R3, at least one hydrogen atom may be substituted with a halogen atom, and L may be further substituted with any of an alkyl group, a haloalkyl group or a halogen atom).

公开(公告)号：US09240614B2

公开(公告)日：2016-01-19

申请号：US13701193

申请日：2011-06-03

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Shoji Shikita ,  Kei Shimamoto

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Shoji Shikita ,  Kei Shimamoto

IPC分类号： H01M10/0567 ,  H01G11/58 ,  H01M10/0569 ,  H01M10/052 ,  H01M10/0566

CPC分类号： H01M10/0567 ,  H01G11/58 ,  H01M10/052 ,  H01M10/0566 ,  H01M10/0569 ,  H01M2300/0025 ,  Y02E60/122 ,  Y02E60/13 ,  Y02T10/7011 ,  Y02T10/7022

摘要： The present invention provides a nonaqueous electrolytic solution which can improve the electrochemical characteristics in a broad temperature range, an electrochemical element produced by using the same and a sulfonic ester compound having a branched structure which is used for the same.The present invention relates to a nonaqueous electrolytic solution prepared by dissolving an electrolyte salt in a nonaqueous solvent, which comprises a sulfonic ester compound represented by the following Formula (I) in an amount of 0.001 to 5% by mass of the nonaqueous electrolytic solution: (wherein R represents an alkyl group or an aryl group; A represents a >CH group or a >SiZ group (Z represents an alkyl group or an aryl group); X represents an alkyl group, a cycloalkyl group or an aryl group; Y represents a cycloalkyl group, a -L1CHRaOSO2Rb group or a —Si(Rc)(Rd)OSO2Rb group; W represents 1 or 2; Ra represents an alkyl group; Rb, Rc and Rd represent an alkyl group or an aryl group; L1 represents an alkylene group in which at least one hydrogen atom may be substituted with —OSO2Re (Re has the same meaning as that of R), a divalent linkage group containing at least one ether bond or a single bond).

摘要翻译： 本发明提供一种可以提高宽温度范围内的电化学特性的非水电解液，使用该电解质的电化学元件和具有分支结构的磺酸酯化合物。 本发明涉及通过将电解质盐溶解在非水溶剂中而制备的非水电解液，该非水溶剂包含以下式（I）表示的磺酸酯化合物：非水电解液的0.001〜5质量％ （其中R表示烷基或芳基; A表示> CH基或> SiZ基（Z表示烷基或芳基）; X表示烷基，环烷基或芳基; Y 表示环烷基，-L1CHRaOSO2Rb基或-Si（Rc）（Rd）OSO2Rb基; W表示1或2; Ra表示烷基; Rb，Rc和Rd表示烷基或芳基; L1表示 其中至少一个氢原子可以被-OSO 2 Re取代的亚烷基（Re具有与R相同的含义），含有至少一个醚键或单键的二价连接基团）。

公开(公告)号：US20120171581A1

公开(公告)日：2012-07-05

申请号：US13395660

申请日：2010-09-14

申请人： Koji Abe ,  Shoji Shikita ,  Kazuyuki Kawabe ,  Masahide Kondo ,  Tatsuo Fujino

发明人： Koji Abe ,  Shoji Shikita ,  Kazuyuki Kawabe ,  Masahide Kondo ,  Tatsuo Fujino

IPC分类号： H01M10/0564 ,  C07C255/23 ,  H01G9/155 ,  C07C69/66 ,  C07C317/46 ,  H01G9/022 ,  C07F7/18 ,  C07C69/675

CPC分类号： H01M10/0567 ,  C07C69/67 ,  C07C69/96 ,  C07C255/16 ,  C07C255/19 ,  C07C309/66 ,  C07F7/1804 ,  C07F9/11 ,  H01M6/168 ,  H01M10/052 ,  H01M10/0566 ,  H01M10/0569 ,  H01M2300/0017 ,  Y02E60/122 ,  Y02T10/7011

摘要： Disclosed are a nonaqueous electrolytic solution of an electrolyte dissolved in a nonaqueous solvent, which contains a carboxylate represented by the following general formula (I) in an amount of from 0.01 to 10% by mass of the nonaqueous electrolytic solution; and an electrochemical element using it. (In the formula, R1 represents an alkyl group, an alkenyl group, an alkynyl group, a cycloalkyl group, or a cyanoalkyl group; R2 represents a hydrogen atom, an alkoxy group, a formyloxy group, an acyloxy group, an alkoxycarbonyloxy group, an alkanesulfonyloxy group, an arylsulfonyloxy group, an alkylsilyloxy group, a dialkylphosphoryloxy group, an alkoxy(alkyl)phosphoryloxy group, or a dialkoxyphosphoryloxy group; R3 represents a hydrogen atom, —CH2COOR6, or an alkyl group; R4 represents a hydrogen atom or an alkyl group; R5 has the same meaning as R2, or represents a hydrogen atom, an alkyl group, or —CH2COOR7; R6 and R7 each independently represent an alkyl group, an alkenyl group, an alkynyl group, or a cycloalkyl group; X represents —OR8, -A2-C≡Y2, -A2-C(═O)O-A3-C≡Y2, -A2-C(═O)O-A4 or COOR1; R5 is the same as R1; A1 to A3 each independently represent an alkylene group; A4 represents an alkyl group; Y2 represents CH or N; m indicates an integer of from 0 to 4; n indicates 0 or 1.)

摘要翻译： 公开了溶解在非水溶剂中的电解质的非水电解液，其含有由以下通式（I）表示的羧酸盐，其量为非水电解液的0.01〜10质量％ 和使用它的电化学元件。 （式中，R 1表示烷基，烯基，炔基，环烷基或氰基烷基; R 2表示氢原子，烷氧基，甲酰氧基，酰氧基，烷氧基羰基氧基， 烷基磺酰氧基，芳基磺酰氧基，烷基甲硅烷氧基，二烷基磷酰氧基，烷氧基（烷基）磷酰氧基或二烷氧基磷酰氧基; R3表示氢原子，-CH2COOR6或烷基; R4表示氢原子或 烷基; R5表示与R2相同的含义，或表示氢原子，烷基或-CH 2 COOR 7; R 6和R 7各自独立地表示烷基，烯基，炔基或环烷基; X表示 -OR8，-A2-C≡Y2，-A2-C（= O）O-A3-C≡Y2，-A2-C（= O）O-A4或COOR1; R5与R1相同; A1〜A3 各自独立地表示亚烷基; A4表示烷基; Y2表示CH或N; m表示0〜4的整数; n表示 0或1）

公开(公告)号：US09130244B2

公开(公告)日：2015-09-08

申请号：US13395660

申请日：2010-09-14

申请人： Koji Abe ,  Shoji Shikita ,  Kazuyuki Kawabe ,  Masahide Kondo ,  Tatsuo Fujino

发明人： Koji Abe ,  Shoji Shikita ,  Kazuyuki Kawabe ,  Masahide Kondo ,  Tatsuo Fujino

IPC分类号： H01M10/0567 ,  H01M6/16 ,  C07F7/18 ,  H01M10/052 ,  H01M10/0569 ,  H01M10/0566

CPC分类号： H01M10/0567 ,  C07C69/67 ,  C07C69/96 ,  C07C255/16 ,  C07C255/19 ,  C07C309/66 ,  C07F7/1804 ,  C07F9/11 ,  H01M6/168 ,  H01M10/052 ,  H01M10/0566 ,  H01M10/0569 ,  H01M2300/0017 ,  Y02E60/122 ,  Y02T10/7011

摘要： A nonaqueous electrolytic solution of an electrolyte salt dissolved in a nonaqueous solvent, which contains a carboxylate represented by the following general formula (8) in an amount of from 0.01 to 5% by mass of the nonaqueous electrolytic solution: wherein X31 represents -A2-C≡Y2, -A2-C(═O)O-A3-C≡Y2 or -A2-C(═O)O-A4; A1, A2 and A3 each independently represent an alkylene group having from 1 to 6 carbon atoms; A4 represents an alkyl group having from 1 to 6 carbon atoms; Y1 and Y2 each independently represent CH or N.

摘要翻译： 溶解在非水溶剂中的电解质盐的非水电解液，其含有下述通式（8）表示的羧酸盐，其量为非水电解液的0.01〜5质量％：其中X31表示-A2- C≡Y2，-A2-C（= O）O-A3-C≡Y2或-A2-C（= O）O-A4; A1，A2和A3各自独立地表示具有1至6个碳原子的亚烷基; A4表示具有1至6个碳原子的烷基; Y1和Y2各自独立地表示CH或N.

公开(公告)号：US20140093787A1

公开(公告)日：2014-04-03

申请号：US14113722

申请日：2012-04-25

申请人： Koji Abe ,  Shoji Shikita

发明人： Koji Abe ,  Shoji Shikita

IPC分类号： H01M10/056 ,  H01M10/0525

CPC分类号： H01M10/056 ,  C07D327/04 ,  C07D327/06 ,  H01M10/0525 ,  H01M10/0567 ,  Y02T10/7011

摘要： An object of the present invention is to provide a nonaqueous electrolytic solution capable of improving electrochemical characteristics in a broad temperature range, an energy storage device using it.A nonaqueous electrolytic solution of an electrolyte salt dissolved in a nonaqueous solvent, which comprises at least one cyclic sulfonic acid ester compound represented by the following general formula (I), and an energy storage device. (wherein R1 and R2 may be the same or different, each representing a hydrogen atom, an alkyl group in which at least one hydrogen atom may be substituted with a halogen atom, orahalogenatom; L represents a divalent hydrocarbon group of an alkylene group in which at least one hydrogen atom is substituted with OR3, or a divalent hydrocarbon group of an alkylene group in which at least one methylene (CH2) is substituted with C(═O); R3 represents a formyl group, an alkylcarbonyl group, an alkenylcarbonyl group, an alkynylcarbonyl group, an arylcarbonyl group, an alkoxycarbonyl group, an alkenyloxycarbonyl group, an alkynyloxycarbonyl group, an aryloxycarbonyl group, a 2,2-dioxide-1,2-oxathiolan-4-yloxycarbonyl group, a 2,2-dioxide-1,2-oxathian-4-yloxycarbonyl group, an alkanesulfonyl group, an arylsulfonyl group, a dialkylphosphoryl group, an alkoxy(alkyl)phosphoryl group, a dialkoxyphosphoryl group, —S(O)—OR4, or —C(O)CH2P(O)(OR5)2; R4 represents an alkyl group, a 2,2-dioxide-1,2-oxathiolan-4-yl group, or a 2,2-dioxide-1,2-oxathian-4-yl group; R5 represents an alkyl group; further, in R3, at least one hydrogen atom may be substituted with a halogen atom, and L may be further substituted with any of an alkyl group, a haloalkyl group or a halogen atom).

摘要翻译： 本发明的目的是提供一种能够在宽温度范围内改善电化学特性的非水电解溶液，即使用它的储能装置。 溶解在非水溶剂中的电解质盐的非水电解液，其包含至少一种由以下通式（I）表示的环状磺酸酯化合物和能量储存装置。 （其中R 1和R 2可以相同或不同，各自表示氢原子，其中至少一个氢原子可以被卤素原子取代的烷基或ah原子; L表示亚烷基的二价烃基，其中 至少一个氢原子被OR 3取代，或亚烷基的二价烃基，其中至少一个亚甲基（CH 2）被C（= O）取代; R 3表示甲酰基，烷基羰基，烯基羰基 ，炔基羰基，芳基羰基，烷氧基羰基，烯氧基羰基，炔氧基羰基，芳氧基羰基，2,2-二氧化物-1,2-氧硫杂环戊烷-4-基氧基羰基，2,2-二氧化物 - 1,2-氧硫杂环戊烷-4-基氧基羰基，烷基磺酰基，芳基磺酰基，二烷基磷酰基，烷氧基（烷基）磷酰基，二烷氧基磷酰基，-S（O）-OR4或-C（O）CH2P （O）（OR 5）2; R 4表示烷基，2,2-二氧代-1,2- 氧硫杂环戊烷-4-基或2,2-二氧化-1,2-氧硫杂-4-基; R5表示烷基; 此外，在R3中，至少一个氢原子可以被卤素原子取代，L可以进一步被烷基，卤代烷基或卤素原子中的任何一个取代）。

公开(公告)号：US20130071733A1

公开(公告)日：2013-03-21

申请号：US13701193

申请日：2011-06-03

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Shoji Shikita ,  Kei Shimamoto

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Shoji Shikita ,  Kei Shimamoto

IPC分类号： H01M10/0566

CPC分类号： H01M10/0567 ,  H01G11/58 ,  H01M10/052 ,  H01M10/0566 ,  H01M10/0569 ,  H01M2300/0025 ,  Y02E60/122 ,  Y02E60/13 ,  Y02T10/7011 ,  Y02T10/7022

摘要： The present invention provides a nonaqueous electrolytic solution which can improve the electrochemical characteristics in a broad temperature range, an electrochemical element produced by using the same and a sulfonic ester compound having a branched structure which is used for the same.The present invention relates to a nonaqueous electrolytic solution prepared by dissolving an electrolyte salt in a nonaqueous solvent, which comprises a sulfonic ester compound represented by the following Formula (I) in an amount of 0.001 to 5% by mass of the nonaqueous electrolytic solution: (wherein R represents an alkyl group or an aryl group; A represents a >CH group or a >SiZ group (Z represents an alkyl group or an aryl group); X represents an alkyl group, a cycloalkyl group or an aryl group; Y represents a cycloalkyl group, a -L1CHRaOSO2Rb group or a —Si(Rc)(Rd)OSO2Rb group; W represents 1 or 2; Ra represents an alkyl group; Rb, Rc and Rd represent an alkyl group or an aryl group; L1 represents an alkylene group in which at least one hydrogen atom may be substituted with —OSO2Re (Re has the same meaning as that of R), a divalent linkage group containing at least one ether bond or a single bond).

摘要翻译： 本发明提供一种可以提高宽温度范围内的电化学特性的非水电解液，使用该电解质的电化学元件和具有分支结构的磺酸酯化合物。 本发明涉及通过将电解质盐溶解在非水溶剂中而制备的非水电解液，该非水溶剂包含以下式（I）表示的磺酸酯化合物：非水电解液的0.001〜5质量％ （其中R表示烷基或芳基; A表示> CH基或> SiZ基（Z表示烷基或芳基）; X表示烷基，环烷基或芳基; Y 表示环烷基，-L1CHRaOSO2Rb基或-Si（Rc）（Rd）OSO2Rb基; W表示1或2; Ra表示烷基; Rb，Rc和Rd表示烷基或芳基; L1表示 其中至少一个氢原子可以被-OSO 2 Re取代的亚烷基（Re具有与R相同的含义），含有至少一个醚键或单键的二价连接基团）。

公开(公告)号：US09371268B2

公开(公告)日：2016-06-21

申请号：US13061329

申请日：2009-08-31

申请人： Koji Abe ,  Akikazu Ito

发明人： Koji Abe ,  Akikazu Ito

IPC分类号： C07C69/96 ,  C07C68/00

CPC分类号： C07C68/00 ,  C07C69/96

摘要： An asymmetric chain carbonate can be produced in a single-step reaction comprising a step of reacting methyl nitrite, carbon monoxide, and 0.05-1.5 moles of an aliphatic alcohol having 2-6 carbon atoms or an alicyclic alcohol having 5-6 carbon atoms per one mole of methyl nitrile in a gaseous phase in the presence of a solid catalyst comprising a platinum group metal or a compound thereof placed on a support.

摘要翻译： 可以在单步反应中制备不对称链碳酸酯，其包括使亚硝酸甲酯，一氧化碳和0.05-1.5摩尔具有2-6个碳原子的脂族醇或具有5-6个碳原子的脂环族醇反应的步骤 在含有铂族金属或其化合物的固体催化剂存在下，在气相中加入1摩尔甲基腈。

公开(公告)号：US09364400B2

公开(公告)日：2016-06-14

申请号：US14002124

申请日：2012-08-09

申请人： Yosuke Ikebe ,  Koji Abe

发明人： Yosuke Ikebe ,  Koji Abe

IPC分类号： A61Q17/04 ,  A61K8/06 ,  A61K8/895 ,  A61K8/81 ,  A61K8/894 ,  A61K8/02

CPC分类号： A61K8/064 ,  A61K8/0254 ,  A61K8/8152 ,  A61K8/894 ,  A61K8/895 ,  A61K2800/612 ,  A61Q17/04

摘要： The present invention provides a water-in-oil emulsified sunscreen cosmetic characteristically comprising the following (a) through (g): (a) Ultraviolet absorbent (b) Silicone backbone powder (c) Methyl polymethacrylate powder (d) Hydrophobicized platelike powder (e) Surfactant (f) Oil component (g) Water The object of the present invention is to provide a water-in-oil emulsified sunscreen cosmetic that manifests a superior texture during use, a high ultraviolet protection effect, and superior stability.

摘要翻译： 本发明提供一种油包水乳化防晒化妆品，其特征在于包括以下（a）至（g）：（a）紫外线吸收剂（b）硅酮骨架粉末（c）聚甲基丙烯酸甲酯粉末（d）疏水性扁平粉末 ）表面活性剂（f）油成分（g）水本发明的目的是提供一种油包水乳化防晒化妆品，其在使用中表现出优异的质地，高的紫外线防护效果和优异的稳定性。

公开(公告)号：US09362595B2

公开(公告)日：2016-06-07

申请号：US14111451

申请日：2012-03-26

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Yuichi Kotou

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Yuichi Kotou

IPC分类号： H01M10/056 ,  H01M10/0567 ,  H01M10/0569 ,  H01M10/0525 ,  H01G11/06 ,  H01G11/60 ,  H01M10/48 ,  H01G11/64

CPC分类号： H01M10/0569 ,  H01G11/06 ,  H01G11/60 ,  H01G11/64 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/48 ,  H01M2200/20 ,  H01M2220/20 ,  Y02E60/122 ,  Y02E60/13 ,  Y02T10/7011 ,  Y02T10/7022

摘要： The present invention is to provide a nonaqueous electrolytic solution prepared by dissolving an electrolyte salt in a nonaqueous solvent, wherein the nonaqueous solvent includes 0.01 to 40% by volume of an ester having two alkyl groups at the α-position carbon of the carbonyl group and being represented by the following general formula (I), and an energy storage device. (in the above formula, R1 is an alkyl group, an alkenyl group or an alkynyl group in which at least one of the hydrogen atoms may be substituted with a halogen atom, R2 and R3 are an alkyl group in which at least one of the hydrogen atoms may be substituted with a halogen atom, and R2 and R3 may be linked to each other to form a ring. However, when R2 and R3 do not form a ring, R3 is an alkyl group in which at least one of the hydrogen atoms may be substituted with a halogen atom.).

摘要翻译： 本发明提供一种通过将电解质盐溶解在非水溶剂中制备的非水电解液，其中非水溶剂包括0.01至40体积％的在羰基的α-位碳上具有两个烷基的酯， 由以下通式（I）表示，以及储能装置。 （在上式中，R 1是其中至少一个氢原子可以被卤素原子取代的烷基，烯基或炔基，R 2和R 3是烷基，其中至少一个 氢原子可以被卤素原子取代，R2和R3可以彼此连接形成环，但是当R2和R3不形成环时，R3是烷基，其中至少一个氢 原子可以被卤素原子取代）。

公开(公告)号：US09236635B2

公开(公告)日：2016-01-12

申请号：US14237492

申请日：2012-08-07

申请人： Koji Abe ,  Kei Shimamoto

发明人： Koji Abe ,  Kei Shimamoto

IPC分类号： H01M10/0567 ,  H01M10/0569 ,  H01M10/0525 ,  H01M4/131 ,  H01M4/505 ,  H01M4/52 ,  H01M4/58 ,  H01M4/583 ,  H01M4/38 ,  H01M4/485 ,  C07C309/65 ,  H01M10/052 ,  C07C69/65 ,  C07D327/00 ,  H01M10/0568

CPC分类号： H01M10/0567 ,  C07C69/65 ,  C07C309/65 ,  C07D327/00 ,  H01M4/13 ,  H01M4/131 ,  H01M4/386 ,  H01M4/387 ,  H01M4/485 ,  H01M4/505 ,  H01M4/52 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/583 ,  H01M4/587 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0568 ,  H01M10/0569 ,  Y02E60/122 ,  Y02T10/7011

摘要： The present invention provides a nonaqueous electrolytic solution capable of improving electrochemical characteristics in a broad temperature range, such as low-temperature cycle properties and low-temperature discharge properties after high-temperature storage, and provides an energy storage device using the nonaqueous electrolytic solution. The invention includes (1) a nonaqueous electrolytic solution of an electrolyte salt dissolved in a nonaqueous solvent, which comprises from 0.001 to 10% by mass of a compound represented by the following general formula (I), and (2) an energy storage device comprising a positive electrode, a negative electrode, and a nonaqueous electrolytic solution of an electrolyte salt dissolved in a nonaqueous solvent, wherein the nonaqueous electrolytic solution is the nonaqueous electrolytic solution of (1). (In the formula, Y represents a group —C(═O)— or a group —S(═O)2—; R3 and R4 each independently represent an aryl group having from 6 to 10 carbon atoms in which at least one hydrogen atom is substituted with a halogen atom, or R3 and R4 bonding to each other represent a cycloalkanediyl group or a benzenediyl group, having from 5 to 12 carbon atoms. R represents —C(R1)(R2)— or -L-; R1 and R2 each independently represent a hydrogen atom, a halogen atom, or an alkyl group having from 1 to 4 carbon atoms; and L represents a divalent linking group having from 1 to 6 carbon atoms and optionally substituted with a halogen atom).

摘要翻译： 本发明提供一种能够在高温保存后的低温循环特性和低温放电性等宽温度范围内提高电化学特性的非水电解液，提供使用该非水电解液的储能装置。 本发明包括（1）溶解在非水溶剂中的电解质盐的非水电解液，其含有0.001〜10质量％的下述通式（I）表示的化合物，和（2）能量储存装置 包括正极，负极和溶解在非水溶剂中的电解质盐的非水电解液，其中非水电解液是（1）的非水电解液。 （在该式中，Y表示基团-C（= O） - 或基团-S（= O）2 - ; R 3和R 4各自独立地表示具有6至10个碳原子的芳基，其中至少一个氢 原子被卤素原子取代，或者R 3和R 4彼此键合表示具有5至12个碳原子的环烷二基或苯二基，R表示-C（R 1）（R 2） - 或-L-; R 1 和R 2各自独立地表示氢原子，卤素原子或具有1〜4个碳原子的烷基; L表示具有1〜6个碳原子并且任选被卤素原子取代的二价连接基团）。