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8 条记录 (耗时 0.013 秒)

    Catalyst exhibiting hydrogen spillover effect
    2.
    发明授权
    Catalyst exhibiting hydrogen spillover effect 失效
    催化剂表现出氢气溢出效应

    公开(公告)号：US08785340B2

    公开(公告)日：2014-07-22

    申请号：US13278130

    申请日：2011-10-20

    申请人： Takuma Kimura ,  Mohammad Abdullah Al-Saleh ,  Halim Hamid Redhwi ,  Mohammad Ashraf Ali ,  Shakeel Ahmed ,  Masayuki Inui

    发明人： Tomoyuki Inui ,  Takuma Kimura ,  Mohammad Abdullah Al-Saleh ,  Halim Hamid Redhwi ,  Mohammad Ashraf Ali ,  Shakeel Ahmed

    IPC分类号： B01J31/00 ,  C07C27/00

    CPC分类号： B01J37/0201 ,  B01J21/16 ,  B01J23/652 ,  B01J23/89 ,  B01J23/8913 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0205 ,  B01J37/18 ,  C10G29/205 ,  C10G45/10 ,  C10G47/14

    摘要： The catalyst exhibiting hydrogen spillover effect relates to the composition of a catalyst exhibiting hydrogen spillover effect and to a process for preparing the catalyst. The catalyst has a reduced transition base metal of Group VIB or Group VIIIB, such as cobalt, nickel, molybdenum or tungsten, supported on a high porous carrier, such as saponite, the base metal being ion-exchanged with at least one precious metal of Group VIIIB. The process includes the steps of loading the base metal onto the support, reducing the base metal, preferably with H2 at 600° C., and thereafter ion-exchanging the precious metal with the base metal. Preferred examples of the catalyst include a saponite support loaded with about 10-20 wt % cobalt and about 0.1-1 wt % precious metal. The catalyst is optimized for reactions that occur in commercial processes at about 360-400° C., such as in hydrocracking.

    摘要翻译： 表现出氢气溢出效应的催化剂涉及显示氢气溢出效应的催化剂的组成和制备催化剂的方法。 该催化剂具有负载在诸如皂石的高多孔载体上的VIB族或VIIIB族的钌基过渡金属，例如钴，镍，钼或钨，贱金属与至少一种贵金属离子交换 第VIIIB组。 该方法包括以下步骤：将贱金属加载到载体上，优选在600℃下用H 2还原贱金属，然后将贵金属与贱金属进行离子交换。 催化剂的优选实例包括负载有约10-20重量％钴和约0.1-1重量％贵金属的皂石载体。 该催化剂针对在约360-400℃的商业过程中发生的反应进行优化，例如在加氢裂化中。

    System and method for conversion of molecular weights of fluids
    4.
    发明申请
    System and method for conversion of molecular weights of fluids 审中-公开
    用于转化流体分子量的系统和方法

    公开(公告)号：US20110011728A1

    公开(公告)日：2011-01-20

    申请号：US12458551

    申请日：2009-07-15

    申请人： William M. Sackinger ,  Halim Hamid Redhwi ,  Abdullah M. Aitani ,  Mohammad Ashraf Ali

    发明人： William M. Sackinger ,  Halim Hamid Redhwi ,  Abdullah M. Aitani ,  Mohammad Ashraf Ali

    IPC分类号： C10G15/08 ,  B01J19/12 ,  B01J19/08 ,  G05D23/00

    CPC分类号： C10G15/08 ,  B01J19/082 ,  B01J19/088 ,  B01J2219/0869 ,  B01J2219/0871 ,  B01J2219/0877 ,  B01J2219/0894 ,  G05D23/22

    摘要： The system and method for conversion of molecular weights of fluids includes an elongate metallic pipe. A fluid is caused to flow through the pipe. A center electrode is mounted within the pipe coaxially with the pipe axis and the flow direction, the electrode being insulated from the pipe wall. The center electrode and the pipe wall are connected to the terminals of a voltage source to create an electric field extending radially between the center electrode and the pipe wall. A source of gamma radiation positioned either within the center electrode or external to the pipe directs gamma rays transverse to the direction of fluid flow. The combined radiation and electric field disrupts chemical bonds, creating ionization zones and resulting in the formation of lower-molecular-weight compounds. Optionally, a magnetic field may be superimposed in the direction of fluid flow.

    摘要翻译： 用于转化流体分子量的系统和方法包括细长金属管。 使流体流过管道。 中心电极与管轴线和流动方向同轴地安装在管内，电极与管壁绝缘。 中心电极和管壁连接到电压源的端子，以产生在中心电极和管壁之间径向延伸的电场。 定位在中心电极内部或外部的伽马辐射源引导横向于流体流动方向的γ射线。 组合的辐射和电场破坏化学键，产生电离带并导致形成较低分子量的化合物。 可选地，可以在流体流动的方向上叠加磁场。

    Synthesis of methyl tertiary butyl ether from methanol and isobutene using aluminum-fluoride-modified zeolite catalysts
    6.
    发明授权
    Synthesis of methyl tertiary butyl ether from methanol and isobutene using aluminum-fluoride-modified zeolite catalysts 失效
    使用氟化铝改性沸石催化剂从甲醇和异丁烯合成甲基叔丁基醚

    公开(公告)号：US06500992B1

    公开(公告)日：2002-12-31

    申请号：US09708545

    申请日：2000-11-09

    申请人： Mohammad Ashraf Ali

    发明人： Mohammad Ashraf Ali

    IPC分类号： C07C4106

    CPC分类号： C07C41/06 ,  C07C43/046

    摘要： This invention concerns an improved and novel catalyst for preparing methyl tertiary butyl ether (MTBE). This invention is advantageous in that the reaction of methanol and isobutene takes place such that the catalysts exhibit levels of isobutene conversion as high as 98%, and the MTBE selectivity reaches as high as 98%. The improved catalysts comprises of a crystalline aluminosilicate zeolites, particularly MFI-type zeolites which has been treated with aluminum fluoride in the ratio 1 gram to 10 grams of zeolite with 0.5 gram to 5 grams of aluminum fluoride. A specific application of this improved and novel catalyst is reacting methanol and isobutene in a molar amount of about 0.1 mole to 10 moles of methanol per mole of isobutene, in the presence of said catalyst in a batch reactor, at about 70° C. to about 100° C., and a pressure of about 1 bar to 33 bar, to obtain MTBE product.

    摘要翻译： 本发明涉及用于制备甲基叔丁基醚（MTBE）的改进和新型催化剂。 本发明的优点在于，甲醇和异丁烯的反应发生，使得催化剂的异丁烯转化率高达98％，MTBE选择性高达98％。 改进的催化剂包括结晶硅铝酸盐沸石，特别是已用氟化铝以1克至10克沸石与0.5克至5克氟化铝进行处理的MFI型沸石。 这种改进和新型催化剂的具体应用是在约70℃至约70℃的间歇反应器存在下，使摩尔量为约0.1摩尔至10摩尔甲醇/摩尔异丁烯的甲醇和异丁烯反应至 约100℃，压力约1巴至33巴，得到MTBE产物。