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    Low viscosity polyester-polyols and polyurethane foams prepared therefrom
    3.
    发明授权
    Low viscosity polyester-polyols and polyurethane foams prepared therefrom 失效
    低粘度聚酯多元醇和由其制备的聚氨酯泡沫

    公开(公告)号：US06284811B1

    公开(公告)日：2001-09-04

    申请号：US09508454

    申请日：2000-05-17

    申请人： Minoru Sawai ,  Makoto Okubo ,  Kenichi Miyamoto ,  Kazunari Takemura ,  Masahiro Mori

    发明人： Minoru Sawai ,  Makoto Okubo ,  Kenichi Miyamoto ,  Kazunari Takemura ,  Masahiro Mori

    IPC分类号： C08G1814

    CPC分类号： C08G63/16 ,  C08G18/10 ,  C08G18/4216 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0066 ,  C08G2101/0083 ,  C08G18/797 ,  C08G18/664 ,  C08G18/42

    摘要： A polyester-polyol being liquid at 40° C. and having a viscosity of not more than 10,000 mPa·s at 60° C., prepared by polycondensation of an acid component including at least one phthalic acid component selected from phthalic anhydride and o-phthalic acid, and an aliphatic polybasic acid, with a polyhydric alcohol; a process for preparing a polyurethane foam including reacting a polyisocyanate component with a polyol component including the polyester-polyol; a process for preparing an isocyanate prepolymer from a polyisocyanate component and a polyol component including the polyester-polyol; and a process for preparing a polyurethane foam including reacting an isocyanate prepolymer prepared from a polyisocyanate component and a polyol component including the polyester-polyol, with a polyol component. The resulting polyurethane foam shows remarkably improved physical properties such as tensile strength and tear strength, while having low density, acceptable appearance and texture.

    摘要翻译： 聚酯多元醇在40℃下为液体，并且在60℃下具有不大于10,000mPa.s的粘度，通过包含至少一种选自邻苯二甲酸酐和邻苯二甲酸的邻苯二甲酸组分的酸组分的缩聚制备 ，和脂肪族多元酸与多元醇; 一种制备聚氨酯泡沫的方法，包括使多异氰酸酯组分与包含所述聚酯多元醇的多元醇组分反应; 由多异氰酸酯组分和包含所述聚酯多元醇的多元醇组分制备异氰酸酯预聚物的方法; 以及制备聚氨酯泡沫的方法，包括使由多异氰酸酯组分制备的异氰酸酯预聚物和包含所述聚酯多元醇的多元醇组分与多元醇组分反应。 所得到的聚氨酯泡沫体具有显着改善的物理性能，例如拉伸强度和撕裂强度，同时具有低密度，可接受的外观和质地

    Process for preparing polyurethane foam
    4.
    发明授权
    Process for preparing polyurethane foam 失效
    制备聚氨酯泡沫的方法

    公开(公告)号：US5821554A

    公开(公告)日：1998-10-13

    申请号：US815589

    申请日：1997-03-12

    申请人： Shoichiro Harada ,  Mitsuru Sakai ,  Kazunari Takemura ,  Akito Itoi ,  Makoto Okubo

    发明人： Shoichiro Harada ,  Mitsuru Sakai ,  Kazunari Takemura ,  Akito Itoi ,  Makoto Okubo

    IPC分类号： C08G18/08 ,  C08G18/42 ,  C08G63/183 ,  C08G18/14

    CPC分类号： C08G18/089 ,  C08G18/4216 ,  C08G63/183 ,  C08G2101/0066 ,  C08G2101/0083 ,  C08G2410/00

    摘要： A polyester-polyol prepared by polycondensation of an acid component comprising terephthalic acid and adipic acid, and a polyhydric alcohol component, wherein the molar ratio of the terephthalic acid/adipic acid is 0.05 to 0.3; a process for preparing a polyurethane foam comprising reacting a polyisocyanate component and a polyol component, wherein the polyol component contains the above polyester-polyol; and a process for preparing a polyurethane foam comprising reacting an isocyanate prepolymer made of a polyisocyanate component and a polyol component (I) with a polyol component (II), wherein the polyol component (I) comprises the above polyester-polyol.

    摘要翻译： 通过包含对苯二甲酸和己二酸的酸成分和多元醇组分缩聚制备的聚酯多元醇，其中对苯二甲酸/己二酸的摩尔比为0.05至0.3; 一种制备聚氨酯泡沫的方法，包括使多异氰酸酯组分和多元醇组分反应，其中多元醇组分含有上述聚酯多元醇; 以及制备聚氨酯泡沫的方法，包括使由多异氰酸酯组分制备的异氰酸酯预聚物和多元醇组分（I）与多元醇组分（II）反应，其中多元醇组分（I）包含上述聚酯多元醇。

    Polyurethane foam for shoe soles
    6.
    发明授权
    Polyurethane foam for shoe soles 失效
    聚氨酯泡沫鞋底

    公开(公告)号：US06329441B1

    公开(公告)日：2001-12-11

    申请号：US09555928

    申请日：2000-06-06

    申请人： Makoto Okubo ,  Atsushi Ishikawa ,  Hiroshi Kitagawa

    发明人： Makoto Okubo ,  Atsushi Ishikawa ,  Hiroshi Kitagawa

    IPC分类号： C08L7508

    CPC分类号： C08G18/4854 ,  C08G18/0857 ,  C08G18/0876 ,  C08G18/409 ,  C08G18/6674 ,  C08G2101/0008 ,  C08G2101/0066 ,  C08G2101/0083 ,  C08G2410/00

    摘要： Microcellular polyurethane elastomer shoe sole components having exceptional physical properties may be prepared from isocyanate-terminated prepolymers derived from polyoxypropylene diols having a molecular weight of from about 2000 Da to 8000 Da, an unsaturation less than about 0.02 meq/g, and a random oxyethylene content of from about 5 to about 15 weight percent. The shoe sole components exhibit high tensile strength, elongation, resilience, and in addition have excellent tear strength, particularly 90° angle tear.

    摘要翻译： 具有特殊物理性能的微孔聚氨酯弹性体鞋底部件可以由衍生自分子量为约2000Da至8000Da，不饱和度小于约0.02meq / g的聚氧丙烯二醇的异氰酸酯封端的预聚物和随机氧化乙烯含量 为约5至约15重量％。 鞋底部件具有高拉伸强度，伸长率，回弹性，并且还具有优异的撕裂强度，特别是90°角度撕裂。

    Urethane foam for shoe soles
    9.
    发明授权
    Urethane foam for shoe soles 有权
    用于鞋底的聚氨酯泡沫

    公开(公告)号：US6099955A

    公开(公告)日：2000-08-08

    申请号：US142231

    申请日：1998-09-03

    申请人： Mitsuru Sakai ,  Shoichiro Harada ,  Kazunari Takemura ,  Akito Itoi ,  Makoto Okubo

    发明人： Mitsuru Sakai ,  Shoichiro Harada ,  Kazunari Takemura ,  Akito Itoi ,  Makoto Okubo

    IPC分类号： C08G18/10 ,  C08G18/42 ,  B32B5/32

    CPC分类号： C08G18/425 ,  C08G18/10 ,  C08G2101/0008 ,  C08G2101/0033 ,  C08G2101/0058 ,  C08G2101/0066 ,  C08G2101/0083 ,  C08G2410/00 ,  Y10T428/2495 ,  Y10T428/24992

    摘要： A urethane foam for shoe soles prepared by reacting a compound having at least two isocyanate-reactive hydrogen atoms and a molecular weight of 400 to 10000 with a polyisocyanate in the presence of a foam stabilizer, water and a catalyst, characterized in that the ratio r.sub.1 /r.sub.2 of a mean skill cell diameter r.sub.1 to a mean core cell diameter r.sub.2 is 0.02 to 0.80, wherein the mean skin cell diameter r.sub.1 is defined as the mean diameter of the cells which form the skin portion of a urethane foam extending from the surface to a depth of 5% of the foam thickness and the mean core cell diameter r.sub.2 is defined as the mean diameter of the cells which form the core portion of a urethane foam extending from a depth of 40% to a depth of 60% of the foam thickness.

    摘要翻译： PCT No.PCT / JP97 / 00632 Sec。 371日期：1998年9月3日 102（e）1998年9月3日PCT PCT 1997年2月28日提交PCT公布。 公开号WO97 / 32923 日期1997年9月12日在泡沫稳定剂，水和催化剂存在下，通过使具有至少两个异氰酸酯反应性氢原子和分子量为400〜10000的化合物与多异氰酸酯反应制备的鞋底聚氨酯泡沫体，其特征在于 平均技术细胞直径r1与平均核心细胞直径r2的比率r1 / r2为0.02〜0.80，其中平均皮肤细胞直径r1定义为形成氨基甲酸酯的皮肤部分的细胞的平均直径 泡沫从表面延伸到泡沫厚度的5％的深度，平均核心细胞直径r2定义为形成从40％的深度延伸到深度的聚氨酯泡沫的芯部分的细胞的平均直径 为泡沫厚度的60％。