公开(公告)号：US10364347B2

公开(公告)日：2019-07-30

申请号：US14006168

申请日：2012-03-22

申请人： Masao Tomioka ,  Manabu Kaneko ,  Miyuki Hagiwara

发明人： Masao Tomioka ,  Manabu Kaneko ,  Miyuki Hagiwara

IPC分类号： C08L63/04 ,  H05K5/00 ,  C08J5/24 ,  C08G59/32 ,  C08K5/21 ,  C08L63/00

摘要： To provide an epoxy-resin composition and prepreg for producing a fiber-reinforced composite material which exhibits excellent curability and has excellent flame retardance and heat resistance, as well as to provide fiber-reinforced composite materials produced using the prepreg and to provide housing for electronic/electrical devices. The epoxy resin composition contains component (A): a phosphorus compound; component (B): an epoxy resin which has at least three epoxy groups in the molecule, and which does not correspond to component (A) nor include component (A); component (C): an epoxy resin curing agent which does not have a urea structure in the molecule; and component (D): a dimethylurea compound represented by formula (a) (in formula (a), “R” is a hydrogen atom or an alkyl group having any number of 1 to 10 carbons).

公开(公告)号：US20150328828A1

公开(公告)日：2015-11-19

申请号：US14812526

申请日：2015-07-29

申请人： Manabu KANEKO ,  Tomoko ISHIMOTO ,  Kaori USAMI

发明人： Manabu KANEKO ,  Tomoko ISHIMOTO ,  Kaori USAMI

IPC分类号： B29C65/02 ,  B32B27/38 ,  B29C65/00 ,  B29C35/02 ,  B32B37/06 ,  B32B37/10

CPC分类号： B29C65/02 ,  B29C35/02 ,  B29C43/12 ,  B29C43/3607 ,  B29C43/3642 ,  B29C66/712 ,  B29C66/7311 ,  B29C70/088 ,  B29C70/342 ,  B29C70/865 ,  B29C2043/3644 ,  B29K2063/00 ,  B29K2105/0854 ,  B29K2105/12 ,  B29L2031/608 ,  B32B27/06 ,  B32B27/38 ,  B32B37/06 ,  B32B37/10 ,  B32B2250/40 ,  B32B2307/306 ,  B32B2363/00 ,  C08G59/26 ,  C08G59/3218 ,  C08J5/24 ,  C08J2363/00 ,  C08J2363/04 ,  Y10T428/31511

摘要： A prepreg comprising an epoxy resin (A), a boron chloride-amine complex (B) and a fiber base material (C) is used. Preferably, the molar ratio of boron in the boron chloride-amine complex (B) is 4-7 mol % with respect to the number of moles of epoxy groups in the epoxy resin (A), and the epoxy resin (A) includes a bifunctional epoxy resin with an oxazolidone ring structure, a bisphenol-type epoxy resin and a phenol-novolac-type epoxy resin.

摘要翻译： 使用包含环氧树脂（A），硼化胺 - 胺络合物（B）和纤维基材（C）的预浸料坯。 优选地，硼化胺 - 胺络合物（B）中的硼的摩尔比相对于环氧树脂（A）中的环氧基的摩尔数为4-7mol％，并且环氧树脂（A）包括 具有恶唑烷酮环结构的双官能环氧树脂，双酚型环氧树脂和苯酚酚醛清漆型环氧树脂。

公开(公告)号：US20100265309A1

公开(公告)日：2010-10-21

申请号：US12742104

申请日：2008-03-05

申请人： Manabu Kaneko ,  Hisato Kato

发明人： Manabu Kaneko ,  Hisato Kato

IPC分类号： B41J2/01 ,  C09D11/10

CPC分类号： C09D11/38 ,  B41M5/0023 ,  C09D11/322 ,  C09D11/36

摘要： A non-aqueous ink-jet ink which has printability on non-absorbing recording media such as polyvinyl chloride (abrasion resistance and water resistance), is excellent in ejection stability and safety, is free from problems concerning odor, does not cause operational abnormality in an ink-jet head even in long-term use, and can be stably used even after long-term storage. Also provided is a method of ink-jet recording with the ink. This non-aqueous ink-jet ink comprises a pigment, a binder resin, and an organic solvent. It is characterized in that at least 60 mass % of the organic solvent is accounted for by a water-soluble organic solvent and that the content in the ink of a metal salt which is the highest in content among the salts of metals selected among sodium, potassium, magnesium, and calcium is 3-50 ppm in terms of metal-ion concentration.

摘要翻译： 在聚氯乙烯等非吸收性记录介质（耐磨损性和耐水性）上具有可印刷性的非水性喷墨油墨，喷射稳定性和安全性优异，无异味问题，不会引起操作异常 喷墨头即使长期使用也可以稳定使用。 还提供了一种利用墨水进行喷墨记录的方法。 该非水性喷墨油墨包括颜料，粘合剂树脂和有机溶剂。 其特征在于，通过水溶性有机溶剂考虑至少60质量％的有机溶剂，并且金属盐中的含量最高的金属盐的含量选自钠， 钾，镁和钙的金属离子浓度为3-50ppm。

公开(公告)号：US20060182904A1

公开(公告)日：2006-08-17

申请号：US11352065

申请日：2006-02-10

申请人： Masayuki Ushiku ,  Manabu Kaneko ,  Shinsaku Kashiwamura

发明人： Masayuki Ushiku ,  Manabu Kaneko ,  Shinsaku Kashiwamura

IPC分类号： B41M5/00

CPC分类号： B41M5/506 ,  B41M5/5209 ,  B41M5/5218 ,  B41M2205/12

摘要： An ink-jet recording sheet containing a support having thereon at least two porous ink absorptive layers containing microparticles and a hydrophilic resin, wherein an uppermost ink absorptive layer has a smaller average void diameter than an ink absorptive layer adjacent to the uppermost ink absorptive layer, and the hydrophilic resin in the uppermost ink absorptive layer is cross-linked by irradiation with ionization radiation.

摘要翻译： 一种含有载体的喷墨记录纸，其上具有至少两个含有微粒和亲水性树脂的多孔油墨吸收层，其中最上面的吸墨层的平均空隙直径小于与最上层的吸墨层相邻的吸墨层， 并且通过用电离辐射照射将最上面的吸墨层中的亲水性树脂交联。

公开(公告)号：US20060134408A1

公开(公告)日：2006-06-22

申请号：US11015023

申请日：2004-12-20

申请人： Manabu Kaneko

发明人： Manabu Kaneko

IPC分类号： B32B15/04 ,  E04B1/16 ,  B32B7/12

CPC分类号： B32B27/36 ,  B32B3/12 ,  B32B5/022 ,  B32B5/10 ,  B32B15/06 ,  B32B15/20 ,  B32B25/045 ,  B32B25/08 ,  B32B25/20 ,  B32B27/08 ,  B32B27/12 ,  B32B37/12 ,  B32B2250/05 ,  B32B2250/40 ,  B32B2262/106 ,  B32B2266/06 ,  B32B2305/024 ,  B32B2307/54 ,  B32B2307/546 ,  B32B2307/718 ,  B32B2307/7242 ,  B32B2307/7265 ,  B32B2605/00 ,  Y10T428/28 ,  Y10T428/2826 ,  Y10T428/2852 ,  Y10T428/287 ,  Y10T428/2878 ,  Y10T428/2891 ,  Y10T428/31511 ,  Y10T428/31786 ,  Y10T442/2738 ,  Y10T442/674 ,  Y10T442/675

摘要： A process for producing a sandwich structure, includes laminating a reinforced fiber material which is substantially free from a matrix resin; a glycol modified copolymerized polyester resin film; a thermosetting resin composition film which is hardened at room temperature; a core material selected from an open cell foam and a honeycomb; a thermosetting resin composition film which is hardened at room temperature; a glycol modified copolymerized polyester resin film; and a reinforced fiber material which is substantially free from a matrix resin, in this order in a molding tool to form a sandwich, hardening the thermosetting resin composition film which is hardened at room temperature under a condition that the molding tool is closed, infusing a matrix resin into the molding tool, and adjusting a temperature in the molding tool at room temperature or a hardening temperature of the matrix resin to harden the matrix resin.

摘要翻译： 一种夹层结构体的制造方法，其特征在于，层叠基本上不含基质树脂的增强纤维材料， 二醇改性共聚聚酯树脂膜; 在室温下硬化的热固性树脂组合物膜; 选自开孔泡沫体和蜂窝体的核心材料; 在室温下硬化的热固性树脂组合物膜; 二醇改性共聚聚酯树脂膜; 以及基本上不含基质树脂的增强纤维材料，依次形成模制工具以形成夹层，硬化热固性树脂组合物膜，其在室温下在模制工具关闭的条件下硬化，注入 将基质树脂加入到成形工具中，并调节模具中的室温或基体树脂的硬化温度，使基体树脂硬化。

公开(公告)号：US09416219B2

公开(公告)日：2016-08-16

申请号：US13497884

申请日：2010-10-04

申请人： Atsushi Nohara ,  Manabu Kaneko ,  Noriya Hayashi

发明人： Atsushi Nohara ,  Manabu Kaneko ,  Noriya Hayashi

IPC分类号： C08J3/28 ,  C08L63/00 ,  C08G59/22

CPC分类号： C08G59/226 ,  C08L63/00 ,  C08L2666/22

摘要： Provided is an RTM moldable chain curing resin composition which can be molded with less energy in a short time, and which makes it possible to obtain a cured product that is superior in mechanical strength. A chain curing resin composition of the present invention includes an alicyclic epoxy compound (A) having two cyclohexene oxides in a molecule and a specific modified bisphenol A-type epoxy resin (B), and the content of the alicyclic epoxy compound (A) is 25 to 90% by mass, when the total of the component (A) and the component (B) is taken as 100% by mass.

摘要翻译： 提供一种RTM可成型链固化树脂组合物，其能够在短时间内以较少的能量模制，并且可以获得机械强度优异的固化产物。 本发明的链固化树脂组合物包括分子中具有2个环氧环己烷的脂环式环氧化合物（A）和特定的改性双酚A型环氧树脂（B），脂环族环氧化合物（A）的含量为 当成分（A）和成分（B）的合计为100质量％时，为25〜90质量％。

公开(公告)号：US08770733B2

公开(公告)日：2014-07-08

申请号：US13264952

申请日：2010-04-20

申请人： Hidenobu Ohya ,  Manabu Kaneko ,  Masami Kato

发明人： Hidenobu Ohya ,  Manabu Kaneko ,  Masami Kato

IPC分类号： B41J2/01

CPC分类号： C09D11/40 ,  C09D11/326

摘要： Disclosed is an inkjet ink which provides a high-quality image in that whitening of the recorded image film is inhibited, durability of the image is good, and there is no banding, and the like; inkjet injection stability and ink shelf life are excellent; and head maintenance returnability is excellent. Also disclosed are a method for producing an inkjet printed product using the same, and a method for producing a water-based inkjet ink. This inkjet ink comprises at least a) a pigment, b) a polymer dispersant comprising polyethylene oxide groups having an acid value of less than 50 mgKOH/g (c) acrylic copolymer resin, and (d) at least one water-soluble organic solvent selected from glycol ethers and 1,2-alkanediols having 4 or more carbons.

摘要翻译： 公开了一种喷墨油墨，其提供高质量图像，因为记录图像胶片的增白被抑制，图像的耐久性良好，并且不存在条带等; 喷墨注射稳定性和油墨保质期优良; 头部维修的回收性极佳。 还公开了使用其的喷墨印刷产品的制造方法和水性喷墨油墨的制造方法。 该喷墨油墨至少包含a）颜料，b）包含酸值小于50mgKOH / g（c）丙烯酸共聚物树脂的聚环氧乙烷基团的聚合物分散剂，和（d）至少一种水溶性有机溶剂 选自具有4个或更多个碳的二醇醚和1,2-链烷二醇。

公开(公告)号：US20130338266A1

公开(公告)日：2013-12-19

申请号：US13983088

申请日：2012-02-16

申请人： Masao Tomioka ,  Manabu Kaneko ,  Kazutami Mitani

发明人： Masao Tomioka ,  Manabu Kaneko ,  Kazutami Mitani

IPC分类号： C08L63/00 ,  C08L63/04

CPC分类号： C08L63/04 ,  C08G59/304 ,  C08G59/3272 ,  C08J5/24 ,  C08J2363/00 ,  C08J2363/04 ,  C08J2463/00 ,  C08J2463/04 ,  C08L63/00 ,  C08L2201/02 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/03

摘要： The present invention relates to an epoxy resin composition which comprises a phosphorus-containing modified epoxy resin (A) consisting of a compound (a) represented by Formula (a); a novolak epoxy resin (B); a hardener (C) for epoxy resins; and a metal hydroxide (D), wherein the content in mass % of the phosphorus-containing modified epoxy resin (A), CA, and the content in mass % of the metal hydroxide (D), CD, relative to the total amount of the epoxy resin composition, satisfy the following Formulas (1), (2), and (3): (1) 2.5CA+CD≧5; (2) 6≦CA≦40; and (3) 3≦CD≦30. This epoxy resin composition can give a composite material which has excellent flame retardancy even when neither a halogenated flame retardant, nor red phosphorus, nor a phosphoric acid ester is contained therein. According to the invention, it is also possible to provide a prepreg and a fiber-reinforced composite material obtained using the prepreg.

摘要翻译： 本发明涉及包含由式（a）表示的化合物（a）组成的含磷改性环氧树脂（A）的环氧树脂组合物。 酚醛清漆环氧树脂（B）; 环氧树脂用固化剂（C） 和金属氢氧化物（D），其中，所述含磷改性环氧树脂（A），CA的质量％含量和所述金属氢氧化物（D）的质量％的含量相对于所述金属氢氧化物的总量 环氧树脂组合物满足下列公式（1），（2）和（3）：（1）2.5CA + CD> = 5; （2）6 @ CA @ 40; 和（3）3 @ C​​D @ 30。 该环氧树脂组合物即使不含有卤化阻燃剂，也不含磷酸酯，也可以得到阻燃性优异的复合材料。 根据本发明，还可以提供使用预浸料获得的预浸料和纤维增强复合材料。

公开(公告)号：US20130295811A1

公开(公告)日：2013-11-07

申请号：US13879278

申请日：2011-10-13

申请人： Yuusuke Shinmen ,  Norifumi Hirota ,  Atsushi Nakajima ,  Naoki Aoyama ,  Naomasa Matsuyama ,  Takeshi Nii ,  Akiyoshi Kogame ,  Yasuyuki Fujii ,  Yoshiko Irie ,  Harumi Matsuda ,  Takayuki Kiriyama ,  Teppei Miura ,  Takuya Teranishi ,  Shouhei Mori ,  Manabu Kaneko ,  Kiharu Numata ,  Masahiro Ichino ,  Shigekazu Takeda ,  Takayuki Kobayashi ,  Toshiyuki Itou ,  Masahiro Hata ,  Hiroyuki Nakao ,  Kenichi Watanabe

发明人： Yuusuke Shinmen ,  Norifumi Hirota ,  Atsushi Nakajima ,  Naoki Aoyama ,  Naomasa Matsuyama ,  Takeshi Nii ,  Akiyoshi Kogame ,  Yasuyuki Fujii ,  Yoshiko Irie ,  Harumi Matsuda ,  Takayuki Kiriyama ,  Teppei Miura ,  Takuya Teranishi ,  Shouhei Mori ,  Manabu Kaneko ,  Kiharu Numata ,  Masahiro Ichino ,  Shigekazu Takeda ,  Takayuki Kobayashi ,  Toshiyuki Itou ,  Masahiro Hata ,  Hiroyuki Nakao ,  Kenichi Watanabe

IPC分类号： D01F9/12 ,  B32B37/14 ,  F27D7/00

CPC分类号： D01F9/12 ,  B29C70/44 ,  B32B37/14 ,  C08J5/042 ,  C08J5/24 ,  C08J2363/00 ,  D01D5/096 ,  D01D5/253 ,  D01F6/38 ,  D01F9/225 ,  F27D7/00 ,  Y10T428/26 ,  Y10T428/298 ,  Y10T442/3089

摘要： Provided are: a carbon fiber bundle which has a large value of single-fiber fineness and excellent productivity and which, despite this, contains few interlaced single fibers therein and has excellent spreadability; and precursor fibers which are suitable for use in producing the carbon fiber bundle. The precursor fibers are a carbon-fiber-precursor acrylic fiber bundle which comprises a polyacrylonitrile copolymer comprising 95-99 mol % acrylonitrile units and 1-5 mol % hydroxyalkyl (meth)acrylate units and which has a single-fiber fineness of 1.5-5.0 dtex. In the acrylic fiber bundle, the cross-section of each single fiber which is perpendicular to the fiber axis has a shape that has a roundness of 0.9 or less. The roundness is a value determined using equation (1) where S and L are the cross-sectional area and the circumferential length, respectively, of a single fiber which are obtained by examining, with an SEM, the cross-section of the single fiber which is perpendicular to the fiber axis and analyzing the obtained image. Roundness=4pS/L2  (1)

摘要翻译： 提供：具有大的单纤维细度值和优异的生产率的碳纤维束，尽管如此，它在其中包含很少的交错单纤维并且具有优异的铺展性; 和适用于生产碳纤维束的前体纤维。 前体纤维是碳纤维前体丙烯酸纤维束，其包含包含95-99mol％丙烯腈单元和1-5mol％（甲基）丙烯酸羟烷基酯单元的聚丙烯腈共聚物，其单纤维细度为1.5-5.0 dtex 在丙烯酸​​系纤维束中，与纤维轴垂直的各单纤维的截面为圆度为0.9以下的形状。 圆度是使用公式（1）确定的值，其中S和L分别是通过用SEM检查单根纤维的横截面而获得的单根纤维的横截面面积和圆周长度 其垂直于纤维轴并分析所获得的图像。 圆度= 4pS / L2（1）

公开(公告)号：US20120231687A1

公开(公告)日：2012-09-13

申请号：US13499800

申请日：2010-10-01

申请人： Teppei Miura ,  Manabu Kaneko

发明人： Teppei Miura ,  Manabu Kaneko

IPC分类号： B05D3/02 ,  B32B27/12 ,  B05D7/00

CPC分类号： C08J5/24 ,  C08G59/3218 ,  C08G59/3227 ,  C08G59/504 ,  C08J2363/00 ,  C08L63/00 ,  Y10T442/2631 ,  C08L2666/22

摘要： A method for producing a fiber-reinforced composite material having high mechanical properties and high heat resistance, and allowing the use of a gypsum die in primary curing, wherein a fiber-reinforced prepreg, obtained by impregnating reinforcing fibers with an epoxy resin composition comprising a triphenylmethane-type epoxy resin, N,N,N′,N′-tetraglycidyldiaminodiphenylmethane (B) and diaminodiphenylsulfone (C), is subjected to primary curing at 110-130° C., and then to secondary curing at a temperature which is at least as high as the primary curing temperature.

摘要翻译： 一种生产具有高机械性能和高耐热性的纤维增强复合材料的方法，并且允许在一次固化中使用石膏模头，其中通过用包含以下组分的环氧树脂组合物浸渍增强纤维获得的纤维增强预浸料 三苯甲烷型环氧树脂，N，N，N'，N'-四缩水甘油基二氨基二苯基甲烷（B）和二氨基二苯基砜（C）在110-130℃下进行一次固化，然后在温度为 至少与主要固化温度一样高。