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公开(公告)号：US09187601B2
公开(公告)日：2015-11-17
申请号：US13253186
申请日：2011-10-05
申请人： Jinyu Huang , Frank Chang , Robert Scott , Arturo Norberto Medina , Manivakkam J. Shankernarayanan , Selma Kuyu , Dawn Alison Smith , Daqing Wu
发明人： Jinyu Huang , Frank Chang , Robert Scott , Arturo Norberto Medina , Manivakkam J. Shankernarayanan , Selma Kuyu , Dawn Alison Smith , Daqing Wu
IPC分类号： C08F230/08 , C08G77/42 , C08G77/442 , C08L83/10 , G02B1/04 , C08G77/20
CPC分类号： G02B1/043 , C08G77/20 , C08G77/42 , C08G77/442 , C08J3/075 , C08J2343/04 , C08J2383/08 , C08L83/10 , C08L101/14 , C08L83/04
摘要： The invention provide a class of water-processable polymerizable prepolymers which comprises (1) siloxane-containing monomeric units derived at least one siloxane containing monomer having one hydrophilic group or chain and/or polysiloxane-containing crosslinking units derived from at least one hydrophilized polysiloxane or chain-extended polysiloxane crosslinker; (2) hydrophilic monomeric units derived from one or more hydrophilic vinylic monomers; and (3) from about 0.05% to about 5% by weight of polymerizable units each having a pendant or terminal, ethylenically-unsaturated group and free of any polysiloxane segment. The prepolymer comprises from about 20% to about 50% by weight of silicone relative to the total weight of the prepolymer and has a high water solubility or dispersibility of at least about 5% by weight in water and suitable for making silicone hydrogel contact lenses.
摘要翻译： 本发明提供了一类可水加工的可聚合预聚物，其包含（1）衍生自至少一种含有一个含硅氧烷的单体的含硅氧烷的单体单元，所述单体具有一个亲水基团或至少一种亲水化聚硅氧烷的链和/或含聚硅氧烷的交联单元，或 链延长聚硅氧烷交联剂; （2）衍生自一种或多种亲水乙烯基单体的亲水单体单元; 和（3）约0.05％至约5％重量的各自具有侧基或末端的可聚合单元，烯属不饱和基团并且不含任何聚硅氧烷链段。 预聚物相对于预聚物的总重量包含约20重量％至约50重量％的硅氧烷，并且在水中具有至少约5重量％的高水溶性或分散性，并且适于制备硅酮水凝胶隐形眼镜。
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公开(公告)号：US06583209B2
公开(公告)日：2003-06-24
申请号：US09947836
申请日：2001-09-06
IPC分类号： C08L334
CPC分类号： C08L23/10 , C08K9/04 , C08L23/12 , C08L23/16 , C08L51/06 , C08L2205/08 , C08L2666/04
摘要： Propylene polymer composites containing modified clays and compatibilizing agents, more specifically hydrogenated tallow modified montmorillonite and maleic anhydride grafted propylene polymers, are provided. Concentrates or masterbatches used to prepare the composites are also described. The improved composites of the invention exhibit increased melt strength compared to the base resin and to composites similarly formulated using other types of modified clays. Moreover, the improved results are achievable at lower compatibilizer levels and lower ratios of compatibilizer to clay than has heretofore been considered practical.
摘要翻译： 提供了含有改性粘土和增容剂的丙烯聚合物复合材料，更具体地说是氢化牛脂改性蒙脱石和马来酸酐接枝丙烯聚合物。 还描述了用于制备复合材料的浓缩物或母料。 与基础树脂相比，本发明的改进的复合材料显示增加的熔体强度，并且与使用其它类型的改性粘土类似地配制的复合材料显示出增加的熔体强度。 此外，改善的结果可以在相对于较低的增容剂水平和相对于粘土的比例比以前被认为是实用的情况下是可实现的。
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公开(公告)号：US5171815A
公开(公告)日：1992-12-15
申请号：US705330
申请日：1991-05-24
CPC分类号： B29C67/0003 , B29C55/18 , B29C55/28 , B29C67/0029
摘要： A process is disclosed for the solid phase preparation of doubly oriented synthetic polymeric material from an orientable amorphous but crystallizable or a semicrystalline thermoplastic polymeric workpiece comprising: (a) presenting the conditioned workpiece, at the entry mode of an opposing pair of solid rollers that are spaced apart a distance substantially less than the thickness of the workpiece; and (b) deforming the workpiece by compressive passage through the paired rollers at a nominal deformation ratios of at least 2 to 1. The deformation drawing is carried out between the glass transition temperature and the melting point of the polymeric material, by applying a draw tension insufficient to cause tensile failure of the workpiece.
摘要翻译： 公开了一种从可取向的非晶态但可结晶的或半结晶的热塑性聚合物工件制备双取向合成聚合物材料的方法，包括：（a）在相对的一对实心辊的进入模式下呈现经调节的工件， 间隔开远小于工件厚度的距离; 和（b）以至少为2:1的标称变形率的压缩通过成对的辊子使工件变形。变形拉伸在玻璃化转变温度和聚合物材料的熔点之间通过施加拉伸 张力不足造成工件拉伸破坏。
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公开(公告)号：US06949605B2
公开(公告)日：2005-09-27
申请号：US10457753
申请日：2003-06-09
CPC分类号： C08L23/10 , C08L23/16 , C08L2666/06
摘要： The present invention provides a soft touch soft touch thermoplastic olefin composition. The soft touch thermoplastic olefin composition comprises a polypropylene-ethylene copolymer and a cross-linked or uncross-linked ethylene-propylene thermoplastic elastomer. The thermoplastic elastomer is present in a sufficient amount that the soft touch thermoplastic olefin composition has a 1% flexural secant modulus from about from about 10,000 psi to about 80,000 psi.
摘要翻译： 本发明提供一种软触摸软触摸热塑性烯烃组合物。 软触摸热塑性烯烃组合物包含聚丙烯 - 乙烯共聚物和交联或未交联的乙烯 - 丙烯热塑性弹性体。 热塑性弹性体以足够的量存在，使得软接触热塑性烯烃组合物具有约10,000psi至约80,000psi的1％弯曲割线模量。
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公开(公告)号：US5639818A
公开(公告)日：1997-06-17
申请号：US212630
申请日：1994-03-11
CPC分类号： C08L23/10 , C08L23/12 , C08L2023/42 , C08L23/06 , C08L23/0853 , C08L23/0869 , C08L23/0892
摘要： The instant invention is directed to a process for preparing peroxide modified polypropylene/polyethylene blends that have superior extrusion coating properties. More specifically, the peroxide modified PP/PE blends produced by the instant invention exhibit a pronounced viscosity upturn at low frequencies (about
摘要翻译： 本发明涉及一种制备具有优异的挤出涂布性能的过氧化物改性聚丙烯/聚乙烯共混物的方法。 更具体地说，本发明生产的过氧化物改性的PP / PE共混物在动态流变学数据中在低频（约<1.0rad / sec）下表现出显着的粘度上升。 具体地说，共混物在低于约1.0rad / sec的频率下显示其动态复数粘度ηa和动态储能模量G'值的增加。 本发明还涉及由本发明的方法生产的过氧化物改性的PP / PE共混物。 与现有技术的混合物相比，由本发明方法制备的这种聚合物共混物表现出优异的动态神学性质，特别是熔体强度。 此外，本发明的过氧化物改性的PP / PE共混物显示出显着降低的拉伸共振行为。 因此，具有上述特征的本发明的PP / PE共混物将适用于各种各样的应用，例如热成型，吹塑和优选的挤出涂层。
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公开(公告)号：US20120088861A1
公开(公告)日：2012-04-12
申请号：US13253186
申请日：2011-10-05
申请人： Jinyu Huang , Frank Chang , Robert Scott , Arturo Norberto Medina , Manivakkam J. Shankernarayanan , Selma Kuyu , Dawn Alison Smith , Daqing Wu
发明人： Jinyu Huang , Frank Chang , Robert Scott , Arturo Norberto Medina , Manivakkam J. Shankernarayanan , Selma Kuyu , Dawn Alison Smith , Daqing Wu
IPC分类号： G02C7/04 , C08F230/08 , B29D11/00 , C08F290/06
CPC分类号： G02B1/043 , C08G77/20 , C08G77/42 , C08G77/442 , C08J3/075 , C08J2343/04 , C08J2383/08 , C08L83/10 , C08L101/14 , C08L83/04
摘要： The invention provide a class of water-processable polymerizable prepolymers which comprises (1) siloxane-containing monomeric units derived at least one siloxane containing monomer having one hydrophilic group or chain and/or polysiloxane-containing crosslinking units derived from at least one hydrophilized polysiloxane or chain-extended polysiloxane crosslinker; (2) hydrophilic monomeric units derived from one or more hydrophilic vinylic monomers; and (3) from about 0.05% to about 5% by weight of polymerizable units each having a pendant or terminal, ethylenically-unsaturated group and free of any polysiloxane segment. The prepolymer comprises from about 20% to about 50% by weight of silicone relative to the total weight of the prepolymer and has a high water solubility or dispersibility of at least about 5% by weight in water and suitable for making silicone hydrogel contact lenses.
摘要翻译： 本发明提供了一类可水加工的可聚合预聚物，其包含（1）衍生自至少一种含有一个含硅氧烷的单体的含硅氧烷的单体单元，所述单体具有一个亲水基团或至少一种亲水化聚硅氧烷的链和/或含聚硅氧烷的交联单元，或 链延长聚硅氧烷交联剂; （2）衍生自一种或多种亲水乙烯基单体的亲水单体单元; 和（3）约0.05％至约5％重量的各自具有侧基或末端的可聚合单元，烯属不饱和基团并且不含任何聚硅氧烷链段。 预聚物相对于预聚物的总重量包含约20重量％至约50重量％的硅氧烷，并且在水中具有至少约5重量％的高水溶性或分散性，并且适于制备硅酮水凝胶隐形眼镜。
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公开(公告)号：US07439290B2
公开(公告)日：2008-10-21
申请号：US11033793
申请日：2005-01-12
IPC分类号： C07C67/08
CPC分类号： C08L23/0815 , C08L51/06 , C08L67/00 , C08L2666/02
摘要： Linear low density polyethylene compositions suitable for the production of films having improved breathability are provided. The compositions which are comprised of a linear low density polyethylene base resin, a functionalized polyolefin and a polyester polyol are melt blended under conditions of mixing and shear to increase their melt elasticity.
摘要翻译： 提供适用于生产具有改善的透气性的膜的线性低密度聚乙烯组合物。 由线性低密度聚乙烯基础树脂，官能化聚烯烃和聚酯多元醇组成的组合物在混合和剪切条件下熔融共混以增加其熔体弹性。
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公开(公告)号：US20080132640A1
公开(公告)日：2008-06-05
申请号：US11606752
申请日：2006-11-30
IPC分类号： C08F297/08
CPC分类号： C08F10/02 , C08F210/16 , Y10S526/905 , Y10S526/943 , C08F2/001 , C08F2/14 , C08F210/08 , C08F2500/05 , C08F2500/17 , C08F2500/11
摘要： A process for polymerizing ethylene is disclosed. The polymerization is performed in the presence of a Ziegler-Natta catalyst system in two slurry reaction zones. Most of the polyethylene (70-95 wt. %) is produced in one of the zones, while a smaller fraction is produced in the other zone. The ratio of the weight average molecular weight of the smaller fraction to that of the larger fraction is greater than 8:1. The resulting polyethylene blend, which should have both high melt strength and high extrudate swell, will be useful for blow-molding applications.
摘要翻译： 公开了一种聚合乙烯的方法。 聚合在齐格勒 - 纳塔催化剂体系存在下在两个浆料反应区中进行。 大部分聚乙烯（70-95重量％）是在其中一个区域中生产的，而另一个区域则产生较小的部分。 较小部分的重均分子量与较大部分的重均分子量之比大于8:1。 所得到的聚乙烯共混物，其应具有高熔体强度和高挤出物膨胀性，可用于吹塑应用。
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公开(公告)号：US5049347A
公开(公告)日：1991-09-17
申请号：US593343
申请日：1990-10-01
CPC分类号： B29C55/28 , B29C55/18 , B29C67/0003 , B29C67/0029
摘要： A process for the solid phase preparation of doubly oriented synthetic polymeric material from an orientable amorphous but crystallizable or a semicrystalline thermoplastic polymeric workpiece comprising: (a) presenting the conditioned workpiece, at the entry mode of an opposing pair of solid rollers that are spaced apart a distance substantially less than the thickness of the workpiece; and (b) deforming the workpiece by compressive passage through the paired rollers at a nominal deformation ratios of at least 2 to 1. The deformation drawing is carried out between the glass transition temperature and the melting point of the polymeric material, by applying a draw tension insufficient to cause tensile failure of the workpiece.
摘要翻译： 从可取向的非晶态但可结晶的或半结晶的热塑性聚合物工件固相制备双取向的合成聚合材料的方法，包括：（a）在相对的间隔开的一对实心辊的进入模式下呈现经调节的工件 远远大于工件的厚度; 和（b）以至少为2:1的标称变形率的压缩通过成对的辊子使工件变形。变形拉伸在玻璃化转变温度和聚合物材料的熔点之间通过施加拉伸 张力不足造成工件拉伸破坏。
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10.发明授权Chain-extended polysiloxane crosslinkers with dangling hydrophilic polymer chains 有权具有悬浮亲水性聚合物链的链延长聚硅氧烷交联剂公开(公告)号：US08835525B2
公开(公告)日：2014-09-16
申请号：US13253177
申请日：2011-10-05
申请人： Selma Kuyu , Dawn Alison Smith , Jinyu Huang , Frank Chang , Robert Scott , Arturo Norberto Medina , Manivakkam J. Shankernarayanan
发明人： Selma Kuyu , Dawn Alison Smith , Jinyu Huang , Frank Chang , Robert Scott , Arturo Norberto Medina , Manivakkam J. Shankernarayanan
IPC分类号： A01N25/10 , A61K47/34 , A61P27/02 , C08F290/06 , C08G77/442 , C08L83/10 , C08G77/42 , G02B1/04 , C08G77/46 , C08G77/20
CPC分类号： G02B1/043 , A61K47/34 , C08G77/20 , C08G77/38 , C08G77/42 , C08G77/442 , C08G77/46 , C08L83/10 , G02B2207/109 , C08L83/12 , C08L83/14
摘要： The invention provide a class of linear chain-extended polysiloxane crosslinkers which comprises two terminal ethylenically unsaturated groups, at least two polysiloxane segments, and dangling hydrophilic polymer chains each covalently attached to a divalent organic radical separating each pair of adjacent polysiloxane segments. The present invention is also related to a polymer comprising crosslinking units derived from chain-extended polysiloxane crosslinker of the invention and to ophthalmic lenses comprising such a polymer.
摘要翻译： 本发明提供一类线性延伸的聚硅氧烷交联剂，其包含两个末端烯键式不饱和基团，至少两个聚硅氧烷链段和悬浮的亲水性聚合物链，每个共价连接到分隔每对相邻聚硅氧烷链段的二价有机基团。 本发明还涉及包含衍生自本发明的链延长聚硅氧烷交联剂的交联单元和包含这种聚合物的眼用透镜的聚合物。
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