摘要:
A process for the simultaneous preparation of sodium peroxodisulfate and sodium dithionite in an electrolysis cell divided into two by a cation exchanger membrane, wherein sodium dithionite is produced at the cathode and sodium peroxodisulfate is produced at the anode.
摘要:
A process is disclosed for producing tertiary alcohols by radical addition of secondary alcohols to alkenes. The reaction is carried out as a continuous process in the presence of an organic peroxide as a radical initiator and during a mean contact time of the reaction mixture of up to a maximum of 1 hour.
摘要:
The invention relates to a method of bleaching and/or delignifying cellulose, in which (a) a sodium hydroxide solution and a peroxydisulphate solution are first of all produced by electrolysis of a sulphate, (b) the peroxydisulphate solution is converted by hydrolysis into a Caro's acid/caroate solution, (c) said Caro's acid/caroate solution is left to cool and (d) used immediately as a bleaching solution for bleaching and/or delignifying cellulose, the Caro's acid/caroate solution becoming neutralised upon introduction into the bleaching solution.
摘要:
The present invention provides an electrolysis cell of the filter press type for the production of peroxy and perhalogenate compounds comprising alternatingly arranged cathodes and anodes provided with electrolyte feeds, wherein the cathodes (1) and anodes (2) consist of right parallelpiped-shaped hollow bodies between which are present frame-shaped seals (3) and which, via these seals (3), are connected together in a liquid-tight manner and insulated from one another to give a cell pile, the cathode hollow bodies (1) are liquid- and gas-permeable, the anode hollow bodies (2) possess, above and below a platinum layer, openings for the introduction and removal of the anolyte and the effective anode surface is formed by the platinum metal layer of a composite anode comprising a valve metal substrate and a platinum layer present thereon which is obtainable by the hot isostatic pressing of a platinum foil on to a valve metal carrier.
摘要:
A composite electrode based on a valve metal with a layer of a platinum foil securely adhering thereto is produced by hot isostatic pressing of the valve metal base and platinum foil between separating sheets; the separating sheet which comes in contact with the platinum foil during hot isostatic pressing is a metal with a melting point of at least 100.degree. C. above the hot isostatic pressing temperature.
摘要:
A single cell for a battery that includes a first housing part and a second housing part, which are electrically isolated from one another by an insulating housing frame. An electrochemically-active material is located in housing frame between housing parts. The first housing part and second housing part are in the form of plates. At least one of the housing parts exhibits a first edge area bent over towards the inside, and first housing part and second housing part are fixed by a form fit to one-piece housing frame.
摘要:
Plate-shaped current conductor (12) for a galvanic cell, with a first surface (16) and a second surface (17), which essentially face each other, and are connected with each other via a first side surface (18) and a second side surface (19), characterized in that the plate-shaped current conductor has, in the area of the first and/or second side surface (18, 19), a segment, which has a thickness (d), which is reduced in regard to its cross section vis-à-vis the thickness (D) as defined by first and second surface (16, 17) of the current conductor, which segment extends at least substantially over a sealing area (14) of the current conductor.
摘要:
A bipolar multi-purpose electrolytic cell for high current loads has a frame, two electrode edge plates with metal electrode sheet, and power supply and of bipolar plates. Each includes a plastic electrode base body with electrode rear spaces and/or with coolings spaces that are incorporated on one or both sides: incorporated supply and discharge lines for the electrolyte solutions and the cooling medium, metal electrode sheets which are applied to both sides of the base body and are solid and/or perforated in the electrochemically active area: electrolyte sealing frames, which rest on the solid metal electrode sheets and which are made of flexible plastic, and: ion exchanger membranes, which rest on the perforated metal electrode sheets and/or on the electrolyte sheets and/or on the electrolyte sealing frames and which are provided for separating the electrode spaces.
摘要:
A process to purify waste waters using chemical oxidation and Fenton's reagent by the action in the acid range of hydrogen peroxide and iron(II) compounds and subsequent precipitation in the weakly acid to alkaline range of the iron(III) compounds, said process being characterized in that the sludge containing iron(III) accumulating in addition to the purified waste water is reduced electrolytically back into iron(II) compounds and in that the sludge so reduced is fed back into the process. The process of the invention allows extensive purification of highly concentrated waste waters and furthermore problems arising with the treatment and elimination of the Fenton sludge can be circumvented.
摘要:
Stable, solid acetyl peroxyborate compounds which are active oxygen-containing compounds derived from acetic acid and boron-oxygen compounds. The compounds of the invention have a peracetic acid content which can be liberated instantly and directly in water with only minor formation of hydrogen peroxide The acetyl peroxyborates of the invention are useful in washing, bleaching and cleaning agent and disinfectant applications and as oxidizing agents in organic synthesis.