公开(公告)号：US08462297B2

公开(公告)日：2013-06-11

申请号：US12894072

申请日：2010-09-29

Applicant: Tomoyuki Okamura ,  Tamio Kawasumi ,  Yuji Inatomi ,  Michio Eriguchi ,  Masaki Misumi ,  Masataka Iwata ,  Haruo Inoue ,  Hiroshi Mori ,  Hirofumi Zenkoh

Inventor： Tomoyuki Okamura ,  Tamio Kawasumi ,  Yuji Inatomi ,  Michio Eriguchi ,  Masaki Misumi ,  Masataka Iwata ,  Haruo Inoue ,  Hiroshi Mori ,  Hirofumi Zenkoh

IPC: G02F1/1335

CPC classification number: G02B5/3083 ,  B29C55/04 ,  B29D11/00326 ,  B29D11/00644 ,  B29D11/00788 ,  B29D11/00798 ,  B29K2067/003 ,  G02B3/0056 ,  G02B5/02 ,  G02B5/3033 ,  G02B6/0051 ,  G02B6/0056 ,  G02F1/133528 ,  G02F1/133536 ,  G02F1/13362 ,  G02F2201/50

Abstract: Disclosed is a film having polarization selectivity and diffusibility, and a means for easily producing the film. The polarizing diffuser film is composed of substantially one kind of crystalline resin having an intrinsic birefringence of not less than 0.1, has a total light transmittance to visible light of 50-90%, a transmission haze to visible light of 15-90% and a transition polarization degree to visible light of 20-90%.

Abstract translation: 公开了具有极化选择性和扩散性的薄膜，以及容易制造薄膜的方法。 极化漫射膜由本征双折射率为0.1以上的基本上一种结晶性树脂构成，对可见光的总透光率为50〜90％，可见光的透射雾度为15〜90％，透明度为 过渡极化度可见光为20-90％。

公开(公告)号：US20130143014A1

公开(公告)日：2013-06-06

申请号：US13816605

申请日：2011-08-24

Applicant: Tamio Kawasumi ,  Michio Eriguchi ,  Shigeo Nishikawa

Inventor： Tamio Kawasumi ,  Michio Eriguchi ,  Shigeo Nishikawa

IPC: B32B27/32 ,  B32B27/08 ,  D02G3/04 ,  B32B27/30

CPC classification number: B32B27/32 ,  B32B27/08 ,  B32B27/30 ,  B65D31/02 ,  D01D5/30 ,  D01D5/426 ,  D01F6/04 ,  D02G3/02 ,  D02G3/045 ,  D10B2401/046 ,  H01L23/373 ,  H01L2224/16225 ,  H01L2224/32225 ,  H01L2224/73204 ,  Y10T428/2495 ,  Y10T428/31909 ,  Y10T428/3192 ,  H01L2924/00

Abstract: The purpose of the present invention is to provide a shape retaining film excellent in shape retention, and further having high tensile elasticity and good longitudinal tear resistance. The shape retaining film is composed of at least one base material layer containing an ethylene polymer that has the density of 900 kg/m3 or more, and the weight-average molecular weight (Mw)/number-average molecular weight (Mn) of 5 to 20, and at least one soft layer containing a high polymer material. The ethylene polymer is an ethylene homopolymer or an ethylene-α-olefin copolymer in which the content of a-olefin unit having 3 to 6 carbon atoms is less than 2% by weight, The high polymer material has the melting point (Tm2) lower than the melting point (Tm1) of the ethylene polymer, the tensile elasticity of 10 to 50 GPa, and the recovery angle of 65° or less as a result of 180° bending, test.

Abstract translation: 本发明的目的是提供一种形状保持性优异的形状保持膜，并且还具有高的拉伸弹性和良好的纵向抗撕裂性。 形状保持膜由至少一层含有密度为900kg / m 3以上的乙烯聚合物的基材层构成，重均分子量（Mw）/数均分子量（Mn）为5 至少20个，以及含有高分子材料的至少一层软层。 乙烯聚合物是乙烯均聚物或乙烯-α-烯烃共聚物，其中碳原子数为3〜6的α-烯烃单元的含量小于2重量％。高分子材料的熔点（Tm2）较低 比180℃弯曲试验的结果，乙烯聚合物的熔点（Tm1），拉伸弹性为10〜50GPa，回收角为65°以下。

公开(公告)号：US5997781A

公开(公告)日：1999-12-07

申请号：US829603

申请日：1997-03-31

Applicant: Shigeo Nishikawa ,  Kaoru Yorita ,  Kouzo Ichikawa ,  Haruo Inoue ,  Michio Eriguchi ,  Takanori Sueda ,  Hideo Amemiya

Inventor： Shigeo Nishikawa ,  Kaoru Yorita ,  Kouzo Ichikawa ,  Haruo Inoue ,  Michio Eriguchi ,  Takanori Sueda ,  Hideo Amemiya

IPC: B29C44/04 ,  B29C44/34 ,  B29C44/42 ,  C08J9/12 ,  B29D67/20

CPC classification number: B29C44/348 ,  B29C44/0415 ,  B29C44/421 ,  C08J9/122 ,  Y02P20/544 ,  Y10S264/13

Abstract: Disclosed is a process for the production of an injection-expansion molded, thermoplastic resin product. The process comprises a gas dissolving step, a cooling step, a metering and injection step, and an expansion controlling step. Specifically, a thermoplastic resin is molten in a continuous plasticator (1), supercritical carbon dioxide and/or nitrogen is added as a blowing agent, and the blowing agent and the thermoplastic resin are formed into a mutually-dissolved state. The resultant molten resin composition is cooled within the plasticator while maintaining a pressure equal to or higher than a critical pressure of the blowing agent. The thus-cooled molten resin composition is metered by an injector (7) and is filled in a mold (8). An internal pressure of the mold is lowered beyond the critical pressure of the blowing agent to produce cell nuclei, whereby the cell diameter is controlled. The blowing agent is maintained in a supercritical state up to the metering and injection step.

Abstract translation: 公开了一种用于生产注射膨胀模制的热塑性树脂产品的方法。 该方法包括气体溶解步骤，冷却步骤，计量和注入步骤以及膨胀控制步骤。 具体地说，热塑性树脂在连续塑化器（1）中熔融，加入超临界二氧化碳和/或氮作为发泡剂，发泡剂和热塑性树脂形成相互溶解状态。 将所得熔融树脂组合物在塑化器内冷却，同时保持等于或高于发泡剂临界压力的压力。 如此冷却的熔融树脂组合物由注射器（7）计量并填充在模具（8）中。 模具的内部压力降低到超过发泡剂的临界压力以产生细胞核，从而控制细胞直径。 发泡剂维持在超临界状态直到计量和注射步骤。

公开(公告)号：US5830393A

公开(公告)日：1998-11-03

申请号：US887323

申请日：1997-07-02

Applicant: Shigeo Nishikawa ,  Kaoru Yorita ,  Kouzo Ichikawa ,  Haruo Inoue ,  Michio Eriguchi ,  Takanori Sueda ,  Hideo Amemiya

Inventor： Shigeo Nishikawa ,  Kaoru Yorita ,  Kouzo Ichikawa ,  Haruo Inoue ,  Michio Eriguchi ,  Takanori Sueda ,  Hideo Amemiya

IPC: B29C44/34 ,  B29C44/46 ,  B29D27/00

CPC classification number: B29C44/461 ,  B29C44/3446 ,  B29C44/348 ,  Y10S264/13

Abstract: A process for preparing an expanded product of a thermoplastic resin which includes a gas dissolving step of adding supercritical carbon dioxide and/or nitrogen as an blowing agent to a thermoplastic resin, and melting it in the thermoplastic resin, a cooling step of cooling the resulting molten resin composition under a pressure not less than a critical pressure of the blowing agent, a nuclei forming step of discharging the molten resin composition from a die to lower the pressure to a level not more than the critical pressure, and an expansion controlling step of cooling an expanded product of the thermoplastic resin to a level not more than a glass transition temperature or a crystallization temperature of the resin to control a cell diameter of the expanded product.

Abstract translation: 一种制备热塑性树脂的发泡产品的方法，包括将超临界二氧化碳和/或氮气作为发泡剂加入到热塑性树脂中并在热塑性树脂中熔化的气体溶解步骤，冷却步骤， 在不低于发泡剂的临界压力的压力下的熔融树脂组合物，将熔融树脂组合物从模具中排出以将压力降低到临界压力以下的成核步骤，以及膨胀控制步骤 将热塑性树脂的发泡产品冷却至不超过树脂的玻璃化转变温度或结晶温度的水平，以控制膨胀产品的泡孔直径。

公开(公告)号：US07150615B2

公开(公告)日：2006-12-19

申请号：US10909401

申请日：2004-08-03

Applicant: Eiichi Sugihara ,  Michio Eriguchi ,  Masaki Misumi

Inventor： Eiichi Sugihara ,  Michio Eriguchi ,  Masaki Misumi

IPC: B28B1/50

CPC classification number: B29C44/348 ,  B29C44/3446 ,  B29C44/586 ,  B29D35/142 ,  B29D35/148

Abstract: A process for injection-foaming a thermoplastic resin by using an injection molding machine with a two-stage-compression screw, injecting a physical foaming agent into the cylinder of the machine at a pressure lower than the storage pressure of the physical foaming agent, mixing it with a melted resin and expanding the volume of the cavity of the mold at the time of injection, and an injection molding machine and resin composition suitable therefore.

Abstract translation: 通过使用具有两级压缩螺杆的注射成型机将热塑性树脂注射发泡的方法，将物理发泡剂以低于物理发泡剂的储存压力的压力向机器的气缸中注入，混合 其具有熔融树脂并且在注射时膨胀模具的空腔的体积，因此适用于注塑机和树脂组合物。

公开(公告)号：US20060234033A1

公开(公告)日：2006-10-19

申请号：US11092887

申请日：2005-03-29

Applicant: Shigeo Nishikawa ,  Masashi Arimoto ,  Michio Eriguchi

Inventor： Shigeo Nishikawa ,  Masashi Arimoto ,  Michio Eriguchi

IPC: B32B3/00

CPC classification number: C08J9/122 ,  B29B7/42 ,  B29B7/48 ,  B29B7/726 ,  B29B7/823 ,  B29B7/826 ,  B29B7/94 ,  B29C48/07 ,  B29C48/08 ,  B29C48/09 ,  B29C48/832 ,  B29C48/834 ,  B29C48/90 ,  B29C48/908 ,  B29K2023/0683 ,  B29K2105/043 ,  B29K2995/0002 ,  B29K2995/0015 ,  B29K2995/0058 ,  B29K2995/0087 ,  B29K2995/0089 ,  C08J2323/06 ,  Y10T428/249976 ,  Y10T428/249977

Abstract: The expanded product of the present invention is an expanded product having a density of from 0.02 to 0.7 g/cm3, which is obtained by expanding ultra-high-molecular-weight polyethylene having a viscosity average molecular weight of from 300,000 to 10,000,000. This expanded product can be prepared by adding carbon dioxide to ultra-high-molecular-weight polyethylene in the molten state in an extruder, and expanding the resin by extrusion such that each of the surface temperature and the central part temperature of the resin immediately after discharge from the die may be a predetermined temperature, while at the same time setting the residence time and pressure of the resin at the die section to specific values. Based on these, the invention provides an expanded product with good external appearance, having a skin layer to which the functions such as light weight, insulating property, sound absorption, low dielectric constant, impact absorption, flexibility and the like can be imparted without significantly deteriorating the excellent features of abrasion resistance, self-lubrication, impact strength, cryogenic properties and chemical resistance that are inherent to ultra-high-molecular-weight polyethylene; and a process for preparation of the expanded product stably.

Abstract translation: 本发明的发泡产品是通过使具有粘均分子量的超高分子量聚乙烯发泡而获得的密度为0.02-0.7g / cm 3的发泡产品 从30万到10,000,000。 该膨胀产物可以通过在挤出机中以熔融状态向超高分子量聚乙烯中加入二氧化碳，并通过挤出使树脂膨胀，使得树脂的表面温度和中心部分温度立即在 从模具排出可以是预定温度，同时将树脂在模具部分的停留时间和压力设定为具体值。 基于这些，本发明提供了具有良好外观的膨胀产品，其具有皮肤层，能够赋予诸如重量轻，绝缘性能，吸声性，低介电常数，冲击吸收性，柔软性等功能的表皮层 劣化超高分子量聚乙烯固有的耐磨性，自润滑性，冲击强度，低温性能和耐化学性的优异特征; 以及稳定地制备膨胀产品的方法。

公开(公告)号：US06328916B1

公开(公告)日：2001-12-11

申请号：US09351336

申请日：1999-07-12

Applicant: Shigeo Nishikawa ,  Eiichi Sugihara ,  Masahiro Takedachi ,  Kaoru Yorita ,  Haruo Inoue ,  Yoko Shimada ,  Michio Eriguchi

Inventor： Shigeo Nishikawa ,  Eiichi Sugihara ,  Masahiro Takedachi ,  Kaoru Yorita ,  Haruo Inoue ,  Yoko Shimada ,  Michio Eriguchi

IPC: B29C4402

CPC classification number: B29C44/348 ,  B29C44/3446

Abstract: This invention provides a method for stably adding a predetermined amount of supercritical carbon dioxide at a fixed delivery rate into a forming machine and also a process for producing an expanded thermoplastic resin product by making use of the addition method. Carbon dioxide is charged from a liquefied carbon dioxide cylinder (1) into a predetermined amount deliverable pump (2) while allowing the carbon dioxide to remain in a liquefied state. When the carbon dioxide is pressurized and delivered by the predetermined amount deliverable pump (2), a delivery pressure of the carbon dioxide is controlled at an optional pressure within a range of from a critical pressure (7.4 MPa) of carbon dioxide to 40 MPa to deliver the carbon dioxide without any fluctuation of the amount of the delivery by setting up the pressure of a pressure control valve (3). The carbon dioxide is heated to a critical temperature (31° C.) of carbon dioxide or higher to convert it into supercritical carbon dioxide. This supercritical carbon dioxide is then added to a molten thermoplastic resin in the forming machine (4).

Abstract translation: 本发明提供了一种以固定的输送速率将预定量的超临界二氧化碳稳定地添加到成形机中的方法，以及通过使用添加方法制造发泡热塑性树脂产品的方法。 二氧化碳从液化二氧化碳气瓶（1）装入预定量的输送泵（2）中，同时使二氧化碳保持在液化状态。 当二氧化碳被预定量的可输送泵（2）加压和输送时，二氧化碳的输送压力被控制在从二氧化碳的临界压力（7.4MPa）到40MPa的范围内的任选压力到 通过设置压力控制阀（3）的压力来输送二氧化碳而没有输送量的任何波动。 将二氧化碳加热至二氧化碳或更高的临界温度（31℃）以将其转化为超临界二氧化碳。 然后将该超临界二氧化碳加入到成形机（4）中的熔融热塑性树脂中。

公开(公告)号：US06303666B1

公开(公告)日：2001-10-16

申请号：US09359745

申请日：1999-07-23

Applicant: Kaoru Yorita ,  Eiichi Sugihara ,  Masahiro Takedachi ,  Haruo Inoue ,  Shigeo Nishikawa ,  Yoko Shimada ,  Michio Eriguchi ,  Takanori Sueda ,  Akira Uchiyama ,  Yuichi Ito

Inventor： Kaoru Yorita ,  Eiichi Sugihara ,  Masahiro Takedachi ,  Haruo Inoue ,  Shigeo Nishikawa ,  Yoko Shimada ,  Michio Eriguchi ,  Takanori Sueda ,  Akira Uchiyama ,  Yuichi Ito

IPC: C08J900

CPC classification number: C08J9/0061 ,  C08J9/122 ,  C08J2201/03 ,  C08J2203/08 ,  C08J2323/16 ,  C08J2423/00 ,  C08L23/02 ,  C08L23/10 ,  C08L23/16 ,  C08L2203/14 ,  C08L2666/04

Abstract: A process is provided for the production of expanded olefinic thermoplastic elastomer product having good external appearance, flexibility and heat resistance. This process features using, as raw materials, a particular olefinic thermoplastic elastomer and carbon dioxide as a blowing agent.

Abstract translation: 提供了具有良好的外观，柔韧性和耐热性的膨胀的烯烃类热塑性弹性体制品的制造方法。 该方法特征在于使用特定的烯属热塑性弹性体和作为发泡剂的二氧化碳作为原料。

公开(公告)号：US20130045347A1

公开(公告)日：2013-02-21

申请号：US13695195

申请日：2011-04-27

Applicant: Tamio Kawasumi ,  Michio Eriguchi ,  Shigeo Nishikawa

Inventor： Tamio Kawasumi ,  Michio Eriguchi ,  Shigeo Nishikawa

IPC: F28F7/00 ,  B32B15/085 ,  B32B37/16 ,  D03D13/00 ,  B29C55/02 ,  B32B33/00 ,  B32B1/08

CPC classification number: C08J5/18 ,  B29C55/06 ,  B29K2023/0625 ,  B29K2023/065 ,  C08G2280/00 ,  C08J2323/04 ,  D01D5/426 ,  D01F6/04 ,  D01F6/46 ,  D03D1/00 ,  D03D15/00 ,  D10B2401/046 ,  D10B2505/06 ,  H01L23/3733 ,  H01L23/3737 ,  H01L2224/16225 ,  Y10T156/10 ,  Y10T156/1036 ,  Y10T428/1334 ,  Y10T428/24355 ,  Y10T428/31692 ,  Y10T428/31938 ,  Y10T442/3195

Abstract: Provided are a shape-retaining film which has excellent adhesion to inks and other functional layers while retaining high shape-retaining properties and a process for producing the shape-retaining film. The shape-retaining film comprises an ethylene homopolymer or an ethylene/α-olefin copolymer having a C3-6 α-olefin content less than 2 wt. %, the ethylene homopolymer or copolymer having a density of 950 kg/m3 or higher and a weight-average molecular weight (Mw)/number-average molecular weight (Mn) ratio of 5-20. The film has a tensile elasticity modulus of 6-50 GPa and has either an angle of recovery from 90 bending of 8 or less or an angle of recovery from 180 bending of 65 or less.

Abstract translation: 提供一种形状保持膜，其具有优异的油墨和其它功能层的粘附性，同时保持高的形状保持性能和形成保持膜的方法。 形状保持膜包括乙烯均聚物或C 3-6烯烃含量小于2重量％的乙烯/α-烯烃共聚物。 ％，密度为950kg / m 3以上的乙烯均聚物或共聚物，重均分子量（Mw）/数均分子量（Mn）比为5-20。 该膜具有6-50GPa的拉伸弹性模量，并且具有从90°弯曲恢复的角度为8°或更小，或者180°弯曲的恢复角为65°或更小。

公开(公告)号：US20120262646A1

公开(公告)日：2012-10-18

申请号：US13532579

申请日：2012-06-25

Applicant: Masataka Iwata ,  Tomoyuki Okamura ,  Koichi Shimada ,  Yuji Inatomi ,  Tamio Kawasumi ,  Michio Eriguchi ,  Masaki Misumi

Inventor： Masataka Iwata ,  Tomoyuki Okamura ,  Koichi Shimada ,  Yuji Inatomi ,  Tamio Kawasumi ,  Michio Eriguchi ,  Masaki Misumi

IPC: G02F1/13357 ,  B29D11/00 ,  G02B5/30

CPC classification number: G02B5/0294 ,  G02B5/0236 ,  G02F1/133536 ,  G02F1/133606

Abstract: Disclosed are a film with excellent polarization selectivity and excellent diffusion properties, and a means for easily producing the same. The polarizing diffusion film has an intrinsic birefringence of at least 0.1 and substantially comprises one type of crystalline resin; and in the polarizing diffusion film, the total light transmittance is 50 to 90% in relation to visible light, the transmission haze is 15 to 90% in relation to visible light, and the degree of transmission polarization is 20 to 90% in relation to visible light.

Abstract translation: 公开了具有优异的极化选择性和优异的扩散性的膜，以及用于容易地制造该膜的方法。 极化扩散膜的固有双折射为至少0.1，并且基本上包含一种结晶树脂; 并且在偏光扩散膜中，总透光率相对于可见光为50〜90％，透射雾度相对于可见光为15〜90％，透射极化度相对于可见光为20〜90％ 可见光。